CN106488765A - Skin detergent compositionss - Google Patents
Skin detergent compositionss Download PDFInfo
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- CN106488765A CN106488765A CN201580033812.9A CN201580033812A CN106488765A CN 106488765 A CN106488765 A CN 106488765A CN 201580033812 A CN201580033812 A CN 201580033812A CN 106488765 A CN106488765 A CN 106488765A
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- skin
- polyoxyethylene
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
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Abstract
The present invention provides a kind of skin detergent compositionss, and it contains：(A) polyoxyethylene alkyl ether sulfate salt 5 mass %～30 mass %, (B) alkyl dimethyl amine oxide 0.5 mass %～3 mass %, (C) oxyneurine type amphoteric surfactant 1.5 mass %～5 mass %, (D) polyoxyethylene-modified silicone or amino modified silicone 1 mass %～3 mass % and (E) are selected from least one 0.02 mass %～0.1 mass % in Glucam E-10 dioleate and Glucam E-10 trioleate；And mass ratio (C/E) is 20～200.
Description
Technical field
The present invention relates to skin detergent compositionss.
Background technology
In skin detergent compositionss, in terms of the usability from the point of view of, foaming properties are key factors.For above-mentioned bubble
Foam performance, can enumerate tendency to bubble during washing, shape retention of head retention, foam quality and foam etc..These
In, when as not enough in tendency to bubble when washing and head retention, then there is the situation of user gratification reduction.As above-mentioned
The excellent skin detergent compositionss of tendency to bubble are it is proposed that contain alkyl polyoxyethylene ether sulfate and betaine type amphoteric table
The scheme (see, for example patent documentation 1) of the personal wash compositions of face activating agent.However, there is head retention in such scheme
The problem being wanting in the ductile property on skin.In addition, as the excellent skin detergent combination of usability and foam quality
Thing is it is proposed that the skin containing alkyl polyoxyethylene ether sulfate, betaine type amphoteric surfac-tant and alkyl amine oxide is washed
Wash the scheme (see, for example patent documentation 2) of agent compositionss.However, the skin detergent compositionss of such scheme are in tendency to bubble
Can not be of great satisfaction with head retention aspect.
Further, with regard to the use feeling of skin detergent, the ductile property on skin is also critically important.So far, carry
Go out by living containing alkyl polyoxyethylene ether sulfate, betaine type amphoteric surfac-tant and specific non-ionic surface
Property and make the scheme (see, for example patent documentation 3) of the excellent skin detergent compositionss of the ductile property on skin.However, on
State scheme skin detergent compositionss exist be difficult to bubble, further wash after when being dried can to skin produce viscosity
Problem.
Accordingly, it is desirable to provide a kind of following skin detergent compositionss：Tendency to bubble and head retention are all good, and
The ductile property on skin and washing after when being dried skin inviscid aspect excellent.
Prior art literature
Patent documentation
Patent documentation 1：Japanese Patent Laid 2007-527921 publication
Patent documentation 2：Japanese Patent Laid-Open 2014-76975 publication
Patent documentation 3：Japanese Patent Laid-Open 5-117138 publication
Content of the invention
Problems to be solved by the invention
The problem of the present invention is to solve conventional above-mentioned various problems and realize following purpose.That is, the present invention
Purpose be to provide a kind of following skin detergent compositionss：Tendency to bubble and head retention are all good, and in skin
On ductile property and washing after when being dried skin inviscid aspect excellent.
The means of solve problem
For solve above-mentioned problem, the present inventor through repeatedly attentively studying, itself it is found that：Following skin detergent combination
Thing can make tendency to bubble and head retention all good and dry after the ductile property on skin and washing by cooperative effect
When dry, the inviscid aspect of skin is excellent, and described skin detergent compositionss contain：(A) polyoxyethylene alkyl ether sulfate salt 5
Quality %～30 mass %, (B) alkyl dimethyl amine oxide 0.5 mass %～3 mass %, (C) oxyneurine type two
Property surfactant 1.5 mass %～5 mass %, (D) polyoxyethylene-modified silicone or amino modified silicone 1 mass %～3 matter
Measure %, and (E) is selected from Glucam E-10 dioleate and Glucam E-10 trioleate extremely
A kind of few 0.02 mass %～0.1 mass %；And the content of described (C) oxyneurine type amphoteric surfactant
(quality %) is selected from Glucam E-10 dioleate and Glucam E-10 trioleate with described (E)
At least one content (quality %) mass ratio (C/E) be 20～200.
Invention effect
According to the present invention, it is possible to resolve conventional above-mentioned various problems simultaneously realize above-mentioned purpose, and be provided that following skin
Composition of detergent：Tendency to bubble and head retention are all good, and the ductile property on skin and washing after when being dried
The inviscid aspect of skin is excellent.
Specific embodiment
(skin detergent compositionss)
The skin detergent compositionss of the present invention contain：(A) polyoxyethylene alkyl ether sulfate salt, (B) alkyl dimethylamine oxides
Amine, (C) oxyneurine type amphoteric surfactant, (D) polyoxyethylene-modified silicone or amino modified silicone and (E)
At least one in Glucam E-10 dioleate and Glucam E-10 trioleate；Further
As needed, other compositions can also be comprised.
<(A) polyoxyethylene alkyl ether sulfate salt>
The polyoxyethylene alkyl ether sulfate salt of described (A) composition contains for following purpose：Improve tendency to bubble, bubble
After ductile property on foam persistency, skin and washing when being dried skin inviscid.
As the polyoxyethylene alkyl ether sulfate salt of described (A) composition, in terms of the tendency to bubble from the point of view of, described alkyl gathers
The carbon number of the moieties of oxygen vinyl Ether sulfuric acid is preferably 10～14, more preferably 12.Described carbon number is less than
10 or during more than 14, there is the situation that tendency to bubble becomes insufficient.
From the point of view of in terms of the head retention, as the epoxy second of the polyoxyethylene alkyl ether sulfate salt of described (A) composition
The average addition molal quantity of alkane is preferably 1～5, more preferably 2.The average addition molal quantity of described oxirane is less than 1 or super
When 5, there is the insufficient situation of head retention.
As the counter ion of the polyoxyethylene alkyl ether sulfuric acid of described (A) composition, for example, the alkali such as sodium, potassium can be enumerated
Metal ion；Ammonium ion；Complex ion of the alkanolamines such as monoethanolamine, diethanolamine, triethanolamine etc..In these, from easy to foaming
From the point of view of property aspect, preferred as alkali ion, more preferably sodium ion.
As the polyoxyethylene alkyl ether sulfate salt of described (A) composition, for example, lauryl polyoxyethylene (1) can be enumerated
Ether sodium sulfate, lauryl polyoxyethylene (2) ether sodium sulfate (another name：Lauryl ether (Laureth) sodium sulfate (2), BASF Japan is public
Department manufacture), lauryl polyoxyethylene (3) ether sodium sulfate (another name：Sodium laureth sulfate (3), Lion Corporation manufacture), the moon
Osmanthus base polyoxyethylene (4) ether sodium sulfate and lauryl polyoxyethylene (5) ether sodium sulfate etc..These can be used alone one kind or generals
Two or more it is used in combination.In these, in terms of the tendency to bubble and head retention from the point of view of, preferably lauryl polyoxyethylene (2) ether sulfur
Sour sodium and lauryl polyoxyethylene (3) ether sodium sulfate.In addition, the numeral in () represents described polyoxyethylene alkyl ether sulfate
The average addition molal quantity of the oxirane of salt.
From the ductile property tendency to bubble, skin and washing after when being dried skin inviscid in terms of from the point of view of, phase
For the total amount of skin detergent compositionss, the content as the polyoxyethylene alkyl ether sulfate salt of described (A) composition is 5 matter
Amount %～30 mass %, preferably 10 mass %～15 mass %.When described content is less than 5 mass %, tendency to bubble and skin
On ductile property become insufficient；And this content more than 30 mass % when, after washing when being dried skin inviscid aspect
Become insufficient.
<(B) alkyl dimethyl amine oxide>
The alkyl dimethyl amine oxide of described (B) composition contains for following purpose：After improving tendency to bubble and washing
When being dried skin inviscid.
As the alkyl dimethyl amine oxide of described (B) composition, the compound shown in preferably following formulas (B1).
[formula (B1)]
R-N+(CH3)2O-
In described formula (B1), R represents alkyl.From the point of view of in terms of the tendency to bubble, the carbon number of described alkyl is preferably 12～
18, more preferably 12.When described carbon number is less than 12 or more than 18, there is the situation that tendency to bubble becomes insufficient.
As the alkyl dimethyl amine oxide of described (B) composition, for example, lauryl dimethyl amine oxide, Hard Fat can be enumerated
Base dimethyl amine, oleyl dimethyl amine oxide and coconut oil alkyldimethyl base amine oxide etc..These one kind that can be used alone
Or be used in combination two or more.In these, in terms of the tendency to bubble from the point of view of, preferably lauryl dimethyl amine oxide.
From tendency to bubble and washing after when being dried skin inviscid in terms of from the point of view of, with respect to skin detergent compositionss
Total amount, as described (B) composition alkyl dimethyl amine oxide content be 0.5 mass %～3 mass %, preferably 0.8
Quality %～1.5 mass %.When described content is less than 0.5 mass %, tendency to bubble becomes insufficient；And this content is more than 3 matter
During amount %, the inviscid aspect of skin when being dried after washing becomes insufficient.
<(C) oxyneurine type amphoteric surfactant>
The oxyneurine type amphoteric surfactant of described (C) composition contains for following purpose：Improve easily
Foaming characteristic, head retention and washing after when being dried skin inviscid.
As the oxyneurine type amphoteric surfactant of described (C) composition, for example, alkyl dimethyl can be enumerated
Oxyneurine, fatty acid amide propyl dimethylaminoethyl acid glycine betaine and alkyl dihydroxyethyl glycine Radix Betae
Alkali etc..These one kind or be used in combination two or more of can be used alone.In these, come in terms of tendency to bubble and head retention
See, preferably fatty acid amides propyl-dimethyl oxyneurine.
As described alkyl dimethyl oxyneurine, for example, lauryl dimethyl glycine Radix Betae can be enumerated
Alkali and stearyl dimethyl oxyneurine etc..These one kind or be used in combination two or more of can be used alone.
As described fatty acid amide propyl dimethylaminoethyl acid glycine betaine, for example, coco-nut oil fatty acid amide third can be enumerated
Base glycine betaine etc..
As described alkyl dihydroxyethyl oxyneurine, for example, stearyl dihydroxyethyl glycine acetic acid can be enumerated
Glycine betaine etc..
In these, in terms of the head retention from the point of view of, preferably lauryl dimethyl oxyneurine and coco-nut oil fatty acid
Amido propyl betaine, more preferably coco-nut oil fatty acid amido propyl betaine.
From tendency to bubble, head retention and washing after when being dried skin inviscid in terms of from the point of view of, with respect to skin
The total amount of skin composition of detergent, the content as the oxyneurine type amphoteric surfactant of described (C) composition is
1.5 mass %～5 mass %, preferably 1.8 mass %～2.5 mass %.When described content is less than 1.5 mass %, tendency to bubble
Become insufficient with head retention；And this content more than 5 mass % when, the inviscid aspect of skin during drying property after washing
Become insufficient.
<(D) polyoxyethylene-modified silicone or amino modified silicone>
The polyoxyethylene-modified silicone of described (D) composition or amino modified silicone contain for following purpose：Improve skin
Ductile property on skin and washing after when being dried skin inviscid.
Polyoxyethylene-modified silicone as described (D) composition or amino modified silicone, the one kind that can be used alone or by two
It is used in combination more than kind.In these, from washing after when being dried skin inviscid in terms of from the point of view of, preferably polyoxyethylene-modified silicone.
- polyoxyethylene-modified silicone-
From the point of view of in terms of skin when the drying property after washing is inviscid, as the polyoxyethylene of described polyoxyethylene-modified silicone
Average degree of polymerization is preferably 9～12.When described average degree of polymerization is less than 9 or more than 12, the nothing of skin when being dried after washing is glued
Property aspect becomes insufficient.
As described polyoxyethylene-modified silicone, it is the copolymer being made up of dimethyl silscone and polyoxyalkylene, for example,
Compound shown in following formulas (D1) etc. can be enumerated.
<Formula (D1)>
【Change 1】
However, in described formula (D1), m and n is respectively independent integer, m represents that 1～20000, n represents 1～20000.A is
Independent integer, represents 9～12.R represents the alkylidene of carbon number 1～10, and R' represents the alkyl of carbon number 1～10.
From washing after when being dried skin inviscid in terms of from the point of view of, as described polyoxyethylene-modified silicone, preferably poly-
Oxygen ethylene methyl polysiloxane copolymer.
As described polyoxyethylene-modified silicone, commercially available prod can be used；As described commercially available prod, for example, can enumerate
PEG-12 polydimethylsiloxane (ProductName：SH3771M, eastern beautiful DOW CORNING (レ ダ ウ conning) Co., Ltd.
Manufacture；Or ProductName：KF-6017, Shin-Etsu Chemial Co., Ltd manufacture), KF6017 (ProductName：
ES-5612 Formulation Aid, Dong Li DOW CORNING Co., Ltd. manufactures) and PEG-9 polydimethylsiloxane (product
Name：KF-6013, Shin-Etsu Chemial Co., Ltd manufactures) etc..These one kind or be used in combination two or more of can be used alone.
- amino modified silicone-
Described amino modified silicone is the organic siloxane polymer in a molecule with least one aminoalkyl.
Formed in the organosiloxane of described amino modified silicone polymer, generally use and comprise methyl (this methyl is as amino
Functional group beyond alkyl) organosiloxane.In addition, also can comprise：The alkyl such as ethyl and propyl group；Vinyl；Pi-allyl etc.
Thiazolinyl；The aryl such as phenyl and naphthyl；The cycloalkyl such as cyclohexyl；Hydroxyl；Hydroxyalkyl etc..
As amino modified silicone, for example, the high polymerization dimethyl siloxane first shown in following formulas (D2) can be enumerated
Aminoethylamino shown in base aminopropylsiloxane copolymer (aminopropyl polydimethylsiloxane), following formula (D3)
Propylmethylsiloxane dimethylsiloxane copolymer (is recorded in CTFA dictionary with the title of ammonia end polydimethylsiloxane
In (U.S. Cosmetic Ingredient Dictionary) third edition), the aminoethylamino shown in following formula (D4)
Propyl-siloxane dimethylsiloxane copolymer (trimethyl silyl ammonia end polydimethylsiloxane) or in them plus
The amino modified silicone that is at least any of and carrying out emulsifying with surfactant and formed entering in methyl polysiloxane and water is newborn
Liquid etc..These one kind or be used in combination two or more of can be used alone.In addition, amino modified silicone for the form of oil or can use surface
The emulsion form that activating agent carries out emulsifying and formed.
<Formula (D2)>
【Change 2】
However, in described formula (D2), m and n is respectively independent integer, m represents that 1～20000, n represents 1～20000.
<Formula (D3)>
【Change 3】
However, in described formula (D3), m and n is respectively independent integer, m represents that 1～20000, n represents 1～20000.A and b
It is respectively independent integer, a represents that 1～10, b represents 1～10.
<Formula (D4)>
【Change 4】
However, in described formula (D4), m and n is respectively independent integer, m represents that 1～20000, n represents 1～20000.A and b
It is respectively independent integer, a represents that 1～10, b represents 1～10.
As the high polymerization dimethylsiloxane methyl aminopropylsiloxane copolymer (ammonia shown in described formula (D2)
Base propyl group polydimethylsiloxane), for example, KF-8020, X-52-2362 can be enumerated (by Shin-Etsu Chemial Co., Ltd's system
Make) etc..These one kind or be used in combination two or more of can be used alone.
As the aminoethylaminopropyl methylsiloxane dimethylsiloxane copolymer shown in described formula (D3)
(CTFA dictionary (U.S. Cosmetic Ingredient Dictionary) is recorded in the title of ammonia end polydimethylsiloxane
In the third edition), for example, SM-8904C (eastern beautiful DOW CORNING organosilicon Co., Ltd. (レ ダ ウ conning can be enumerated
シ リ コン Co., Ltd.) manufacture), XF42-B892, XF42-C0330, XS65-C0032, XS65-C0726, SILSOFT
200 EF are (by Momentive Performance Material's (モ メ Application テ ィ Block パ Off ォ マ Application ス マ テ リ ア Le
ズ ジ ャ パ Application contract commercial firm) manufacture) etc..These one kind or be used in combination two or more of can be used alone.
As the aminoethylaminopropyl siloxanes dimethylsiloxane copolymer (front three shown in described formula (D4)
Base silicyl ammonia end polydimethylsiloxane), for example, can enumerate FZ-4671, FZ-4672, BY22-079, SF8452C and
SS-3551 (is manufactured by eastern beautiful DOW CORNING organosilicon Co., Ltd.)；KF-8004, KF-8015 and KF-867S are (by SHIN-ETSU HANTOTAI
Learn Industrial Co., Ltd to manufacture)；ADM1650, ADM-8101E and ADM-6057E are (by Wa Ke organosilicon Co., Ltd. of Asahi Chemical Industry
(ワ ッ カ シ リ コン Co., Ltd. of Asahi Chemical Industry) manufactures)；KS65-B4280、XS65-C1539、XS65-6413、XS65-
B8124 and KF42B1989 (being manufactured by Momentive Performance Material) etc..These one kind or by two of can be used alone
It is used in combination more than kind.
In these, from washing after when being dried skin inviscid in terms of from the point of view of, be preferably equivalent to described formula (D2) institute
The height showing is polymerized KF-8020 and X-52-2362 of dimethylsiloxane methyl aminopropylsiloxane copolymer, is equivalent to institute
State the SM-8904C of aminoethylaminopropyl methylsiloxane dimethylsiloxane copolymer emulsion shown in formula (D3),
Be equivalent to the KF- of the aminoethylaminopropyl siloxanes dimethylsiloxane copolymer emulsion shown in described formula (D4)
8004.
From the ductile property skin and washing after when being dried skin inviscid in terms of from the point of view of, with respect to skin washing
The total amount of agent compositionss, the polyoxyethylene-modified silicone as described (D) composition or the content of amino modified silicone, are become with silicone
Divide meter, it is 1 mass %～3 mass %, preferably 1.5 mass %～2.5 mass %.When described content is less than 1 mass %, washing
The inviscid aspect of skin when being dried afterwards becomes insufficient；And this content more than 3 mass % when, the ductile property on skin becomes
Obtain insufficient.
<(E) it is selected from Glucam E-10 dioleate and Glucam E-10 trioleate extremely
Few one kind>
Described (E) composition in Glucam E-10 dioleate and Glucam E-10 trioleate
At least one contain for following purpose：Improve the ductile property on skin and head retention.
As described (E) composition selected from Glucam E-10 dioleate and Glucam E-10 three
At least one in oleate, the one kind that can be used alone or be used in combination two or more.In these, come in terms of head retention
See, preferably Glucam E-10 trioleate.
As described Glucam E-10 dioleate, for example, can enumerate and be formed with methyl glucoside by Oleic acid
The polyglycol ether etc. that constitutes of diester.
As described Glucam E-10 dioleate, for example, PEG-120 methyl glucose dioleate can be enumerated
Deng.In addition, described PEG-120 methyl glucose dioleate is the expression title of Japanese cosmetic industrial combination meeting defined.
As Glucam E-10 trioleate, for example, three being formed by Oleic acid and methyl glucosamine can be enumerated
Polyglycol ether that ester is constituted etc..
As Glucam E-10 trioleate, for example, PEG-120 methyl glucoside trioleate etc. can be enumerated.Separately
Outward, described PEG-120 methyl glucoside trioleate is the expression title of Japanese cosmetic industrial combination meeting defined.
From the point of view of in terms of the ductile property skin and head retention, with respect to the total amount of skin detergent compositionss,
As described (E) composition in Glucam E-10 dioleate and Glucam E-10 trioleate
At least one content be 0.02 mass %～0.1 mass %, preferably 0.05 mass %～0.08 mass %.Described content is little
When 0.02 mass %, head retention becomes insufficient；And this content more than 0.1 mass % when, the ductile property on skin
Become insufficient.
<Mass ratio (C/E)>
From the point of view of in terms of the ductile property skin and head retention, the polyoxyethylene-modified silicone of described (C) composition or ammonia
The content (quality %) of base modified silicone and described (E) composition are selected from Glucam E-10 dioleate and polyoxy second
The mass ratio (C/E) of at least one content (quality %) in alkene methyl glucosamine trioleate be 20～200, preferably 25～
40.When described mass ratio (C/E) is less than 20, the ductile property on skin becomes insufficient；And described mass ratio (C/E) exceedes
When 200, head retention becomes insufficient.
<Other compositions>
As described skin detergent compositionss, in addition to being mixed with each composition of described (A)～(E), also can not damage this
Other compositions are mixed in the range of invention effect.As described other composition, generally can be made from skin detergent compositionss
With material in suitably selected, for example, the amphoteric surface in addition to described (B) composition and described (C) composition can be enumerated
Activating agent, the nonionic surfactant in addition to described (E) composition；Lanolin derivative, protein derivatives, acrylic acid
The medicament of resin dispersion liquid, cation property copolymer, anionic polymer, nonionic polymeric, vitamin etc.；Sterilization
Agent, preservative, pH regulator, antioxidant, metal-chelator, UV absorbent, animals and plants extract and its derivant, color
The water-fast polymer powder such as element, spice, pigment, inorganic particle, clay mineral, nylon, polyethylene, water etc..
<pH>
From the point of view of in terms of the tendency to bubble, it is preferably 4～6 as the pH value at 25 DEG C of described skin detergent compositionss.Described
When pH value is less than 4 or more than 6, there is the situation that tendency to bubble becomes insufficient.PH for described skin detergent compositionss
Value, can be after mixing whole compositions while final confirmation pH value, by adding at least appointing in potassium hydroxide and citric acid etc.
One kind is being adjusted.In more detail, pH value can be measured in the following manner：Carry out mixing using Purified Water as surplus to stir
Mix, make in potassium hydroxide and citric acid etc. at least any of beyond composition amount to about 90 mass %.If necessary, also may be used
Heated.It is slowly added at least any of aqueous solution in potassium hydroxide and citric acid etc. in mix and blend, side measures
Each pH value side is added, until reaching target ph.After reaching target ph, it is eventually adding remaining Purified Water, adds water and make total amount
It is changed into 100 mass %, measure final pH value.In addition, for described pH value, for example, pH meter (trade name can be adopted：“HM-
30V ", DKK Toa Corp. manufacture) etc. be measured.
<Viscosity>
From the point of view of in terms of the ductile property skin, the viscosity at 25 DEG C of described skin detergent compositionss is preferably
500mPa s～10000mPa s, more preferably 1000mPa s～5000mPa s.Described viscosity is less than 500mPa s or super
When crossing 10000mPa s, the ductile property existing on skin becomes insufficient situation.
<Manufacture method>
As the manufacture method of described skin detergent compositionss, for example, method comprising following operations 1～3 etc. can be enumerated.
Operation 1：Described other water soluble ingredients when making described (A)～described (E) composition and needing be equivalent to skin
The mixture that the Purified Water of the amount of composition of detergent total amount about 10 mass % mixes equably dissolves, and obtains mixture 1.
Operation 2：So that described other oil-soluble ingredients (for example, isopropyl methyl phenol, spice etc.) when needing is mixed and
The mixture becoming equably dissolves, and obtains mixture 2.
Operation 3：Add described mixture 2 while stirring in described mixture 1, mixing.
As the device manufacturing described skin detergent compositionss, it is not particularly limited, can be carried out suitably according to purpose
Select, for example, the propeller that can shear and integrally mix, turbine, dispersion machine etc. can be enumerated there are multiple stirring vanes
Agitating device etc..In addition, as described (A)～described (E) composition and described other composition, manufacturing described skin detergent
During compositionss, can individually using or the state of the mixture that comprises two or more compositions use.
<Container>
As described container, it is not particularly limited, suitably can be selected according to purpose, but at the excellent aspect of usability, excellent
Select pump receptacle, bottle, the more preferably container with pump dispenser.
As the material of described container, it is not particularly limited, suitably can be selected according to purpose, for example, alkene can be enumerated
It is resins such as resin (polyethylene, polypropylene etc.), polyethylene terephthalate, nylon etc..These one kind that can be used alone
Or using the composite resin being formed by two or more combinations.
<Purposes>
Described skin detergent compositionss are suitable as the such as product such as hand soaps, bath soap, facial cleansing foam.Use according to these
When corresponding common consumption and common washing methods come using described skin detergent compositionss on the way, it is in the following areas
Favourable：Tendency to bubble and head retention are all good, and the nothing of skin when being dried after the ductile property on skin and washing is glued
Property aspect is excellent.
【Embodiment】
Hereinafter, according to embodiment and comparative example, the present invention is further illustrated, but the invention is not limited in down
State embodiment.In addition, in below example and comparative example, " % " all represents " quality % ", embodiment and comparative example are recorded
Component amount is entirely pure composition scaled value, but mulberry extract forecloses.Additionally, the content (quality %) of described (C) composition
Be recited as the 2nd after arithmetic point rounds up with the mass ratio (C/E) of the content (quality %) of described (E) composition, retain to
First and the numerical value obtained after arithmetic point.
(embodiment 1～31 and comparative example 1～23)
The skin forming and being prepared by a conventional method embodiment 1～31 and comparative example 1～23 according to table 1-1～table 1-7
Skin composition of detergent.
Specifically, using paddle stirrer, at 25 DEG C, (A) composition, (B) composition, (C) composition, (D) composition, (E) are become
Point, glycol distearate, sodium benzoate and Purified Water mix homogeneously, obtain mixture.To in gained mixture, while stirring
Mix side and add the solute being dissolved with isopropyl methyl phenol in spice.Now, the amount of adjustment Purified Water brings the mixture to skin
90 mass % of skin composition of detergent total amount.Then, with citric acid, pH value is adjusted to 5.2.When pH value is changed into 5.2, finally
Add remaining Purified Water, make total amount be changed into 100 mass %, obtain skin detergent compositionss.The measurement result of final ph
Display, the pH value in whole embodiments and comparative example is all 5.2.Additionally, described pH value is using pH meter (HM-30R, East Asia DKK
Co., Ltd. manufactures) measured.
The skin detergent compositionss of gained are filled in the container with pump dispenser (output 1mL, nozzle diameter (internal diameter)
3.5mm, Canyon (キ ャ ニ オ Application) company manufactures), for various evaluations.
For the skin detergent compositionss in the embodiment 1～31 and comparative example 1～23 of preparation, according to as follows,
To " tendency to bubble ", " foam duration ", " the ductile property on skin " and " after washing when being dried skin inviscid "
Evaluated.Result is as shown in table 1-1～table 1-7.
<Tendency to bubble>
Under the conditions of 25 DEG C, discharge the embodiment 1～31 of preparation and the skin of comparative example 1～23 from the container with pump dispenser
Composition of detergent 1g (by once), makes it bubble with handss, evaluates " tendency to bubble ".This evaluation is by 10 panel member
Carried out according to following benchmark.
[metewand]
◎：In 10 more than 8 answer easy to foaming
○：More than 6 in 10, less than 7 answer easy to foaming
△：More than 4 in 10, less than 5 answer easy to foaming
×：In 10 less than 3 answer easy to foaming
<Head retention>
Under the conditions of 25 DEG C, discharge the embodiment 1～31 of preparation and the skin of comparative example 1～23 from the container with pump dispenser
Composition of detergent 1g (by once), is put on hand, both hands twisting 10 times, after handss are stood 10 seconds, evaluates " head retention ".
This evaluation is carried out according to following benchmark by 10 panel member.
[metewand]
◎：More than 8 answer head retentions in 10 are good
○：More than 6 in 10, less than 7 answer head retentions good
△：More than 4 in 10, less than 5 answer head retentions good
×：Less than 3 answer head retentions in 10 are good
<Ductile property on skin>
Under the conditions of 25 DEG C, discharge the embodiment 1～31 of preparation and the skin of comparative example 1～23 from the container with pump dispenser
Composition of detergent 1g (by once), is put on hand, after extending to inner forearm portion, evaluates " the ductile property on skin ".
This evaluation is carried out according to following benchmark by 10 panel member.
[metewand]
◎：In 10 more than 8 answer ductile on skin
○：More than 6 in 10, less than 7 answer ductile on skin
△：More than 4 in 10, less than 5 answer ductile on skin
×：In 10 less than 3 answer ductile on skin
<After washing when being dried skin inviscid>
Under the conditions of 25 DEG C, with discharging the embodiment 1～31 of preparation and the skin of comparative example 1～23 from the container with pump dispenser
Skin composition of detergent 1g (by once) washing one's hands, after towel, evaluate " after washing when being dried skin inviscid ".
" when being dried " described herein refers to the state with remaining moisture on skin after towel.This evaluation is by 10 experts
Group membership is carried out according to following benchmark.
[metewand]
◎：Skin when being dried after more than 8 answer washings in 10 is inviscid
○：More than 6 in 10, less than 7 answer washing after skins when being dried inviscid
△：More than 4 in 10, less than 5 answer washing after skins when being dried inviscid
×：Skin when being dried after less than 3 answer washings in 10 is inviscid
【Table 1-1】
【Table 1-2】
【Table 1-3】
【Table 1-4】
【Table 1-5】
【Table 1-6】
【Table 1-7】
(embodiment 32)
According to method same as Example 1, manufacture the skin detergent compositionss of composition shown below and content.
Mass ratio (C/E)=28.6
(25 DEG C) of pH is 5.2
For the skin detergent compositionss of embodiment 32, same as Example 1ly, to " tendency to bubble ", " foam duration
Property ", " the ductile property on skin " and " after washing when being dried skin inviscid " evaluated.Result is as shown in table 2.
【Table 2】
| Embodiment 32 | |
| Tendency to bubble | ◎ |
| Head retention | ◎ |
| Ductile property on skin | ◎ |
| After washing when being dried skin inviscid | ◎ |
In addition, raw material used in the skin detergent compositionss of embodiment 1～32 and comparative example 1～23 is specifically interior
Hold as follows.
【Table 3】
*1：The average addition molal quantity of oxirane is represented in ().
As the form of the present invention, for example, following form etc. can be enumerated.
<1>A kind of skin detergent compositionss are it is characterised in that described compositionss contain：
(A) polyoxyethylene alkyl ether sulfate salt 5 mass %～30 mass %,
(B) alkyl dimethyl amine oxide 0.5 mass %～3 mass %,
(C) oxyneurine type amphoteric surfactant 1.5 mass %～5 mass %,
(D) polyoxyethylene-modified silicone or amino modified silicone 1 mass %～3 mass %, and
(E) it is selected from least one in Glucam E-10 dioleate and Glucam E-10 trioleate
0.02 mass %～0.1 mass %；
The content (quality %) of described (C) oxyneurine type amphoteric surfactant is selected from polyoxyethylene with described (E)
The matter of at least one content (quality %) in methyl glucosamine dioleate and Glucam E-10 trioleate
Amount is 20～200 than (C/E).
<2>As described<1>The skin detergent compositionss recorded, wherein, epoxy in (A) polyoxyethylene alkyl ether sulfate salt
The average addition molal quantity of ethane is 2.
Utilization probability in industry
The skin detergent compositionss of the present invention are good and ductile on skin due to tendency to bubble and head retention
Property and washing after when being dried skin inviscid aspect excellent, therefore, be suitable as hand soaps, bath soap, facial cleansing foam etc.
Product.
Claims (2)
1. a kind of skin detergent compositionss are it is characterised in that described compositionss contain：
(A) polyoxyethylene alkyl ether sulfate salt 5 mass %～30 mass %,
(B) alkyl dimethyl amine oxide 0.5 mass %～3 mass %,
(C) oxyneurine type amphoteric surfactant 1.5 mass %～5 mass %,
(D) polyoxyethylene-modified silicone or amino modified silicone 1 mass %～3 mass %, and
(E) it is selected from least one in Glucam E-10 dioleate and Glucam E-10 trioleate
0.02 mass %～0.1 mass %；
The content of described (C) oxyneurine type amphoteric surfactant is selected from polyoxyethylene methyl with described (E)
The mass ratio C/E of at least one content in glycosides dioleate and Glucam E-10 trioleate is 20～200,
Wherein, described content is in terms of quality %.
2. as the skin detergent compositionss of claim 1 record, wherein, the ring in (A) polyoxyethylene alkyl ether sulfate salt
The average addition molal quantity of oxidative ethane is 2.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014135373 | 2014-06-30 | ||
| JP2014-135373 | 2014-06-30 | ||
| PCT/JP2015/067501 WO2016002524A1 (en) | 2014-06-30 | 2015-06-17 | Skin cleanser composition |
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| Publication Number | Publication Date |
|---|---|
| CN106488765A true CN106488765A (en) | 2017-03-08 |
| CN106488765B CN106488765B (en) | 2019-06-18 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580033812.9A Active CN106488765B (en) | 2014-06-30 | 2015-06-17 | Skin detergent composition |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP6181309B2 (en) |
| KR (1) | KR102374768B1 (en) |
| CN (1) | CN106488765B (en) |
| MY (1) | MY184686A (en) |
| WO (1) | WO2016002524A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106902004A (en) * | 2015-12-22 | 2017-06-30 | 江南大学 | Preservative free preserving moisture and protecting skin emulsion formulations |
| CN115666499A (en) * | 2020-06-15 | 2023-01-31 | 狮王株式会社 | No-clean type sterilization detergent composition |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2844377T3 (en) * | 2017-02-16 | 2021-07-22 | Clariant Int Ltd | Dimethyl farnesylamine oxide and its use as a surfactant or wetting agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000129300A (en) * | 1998-10-29 | 2000-05-09 | Lion Corp | Detergent composition |
| JP2014076975A (en) * | 2012-10-12 | 2014-05-01 | Lion Corp | Skin detergent composition |
| CN103860427A (en) * | 2014-03-07 | 2014-06-18 | 澳宝化妆品（惠州）有限公司 | Moisturizing and nourishing shower gel |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2676975B2 (en) * | 1990-04-20 | 1997-11-17 | 株式会社豊田自動織機製作所 | Operation control device for unmanned vehicles |
| JPH05117138A (en) | 1991-02-08 | 1993-05-14 | Lion Corp | Liquid cleanser composition |
| JP2002284627A (en) * | 2001-03-27 | 2002-10-03 | Lion Corp | Composition for external use |
| US20050201965A1 (en) | 2004-03-11 | 2005-09-15 | The Procter & Gamble Company | Personal cleansing compositions |
-
2015
- 2015-06-17 KR KR1020167032070A patent/KR102374768B1/en active IP Right Grant
- 2015-06-17 WO PCT/JP2015/067501 patent/WO2016002524A1/en active Application Filing
- 2015-06-17 CN CN201580033812.9A patent/CN106488765B/en active Active
- 2015-06-17 JP JP2016531259A patent/JP6181309B2/en active Active
- 2015-06-17 MY MYPI2016704380A patent/MY184686A/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000129300A (en) * | 1998-10-29 | 2000-05-09 | Lion Corp | Detergent composition |
| JP2014076975A (en) * | 2012-10-12 | 2014-05-01 | Lion Corp | Skin detergent composition |
| CN103860427A (en) * | 2014-03-07 | 2014-06-18 | 澳宝化妆品（惠州）有限公司 | Moisturizing and nourishing shower gel |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106902004A (en) * | 2015-12-22 | 2017-06-30 | 江南大学 | Preservative free preserving moisture and protecting skin emulsion formulations |
| CN115666499A (en) * | 2020-06-15 | 2023-01-31 | 狮王株式会社 | No-clean type sterilization detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2016002524A1 (en) | 2017-04-27 |
| KR20170021231A (en) | 2017-02-27 |
| KR102374768B1 (en) | 2022-03-17 |
| WO2016002524A1 (en) | 2016-01-07 |
| JP6181309B2 (en) | 2017-08-16 |
| CN106488765B (en) | 2019-06-18 |
| MY184686A (en) | 2021-04-16 |
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