CN106456488B - Bubbling container fills skin detergent composition - Google Patents
Bubbling container fills skin detergent composition Download PDFInfo
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- CN106456488B CN106456488B CN201580033811.4A CN201580033811A CN106456488B CN 106456488 B CN106456488 B CN 106456488B CN 201580033811 A CN201580033811 A CN 201580033811A CN 106456488 B CN106456488 B CN 106456488B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
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Abstract
The present invention provides a kind of bubbling container dress skin detergent composition, contains: (A) polyoxyethylene alkyl ether sulfate salt, (B) alkyl dimethyl amine oxide, (C) oxyneurine type amphoteric surfactant, (D) polyoxyethylene-modified silicone or amino modified silicone and (E) ethyl alcohol；(A) content of ingredient is 5 mass of mass %~13 %, (B) content of ingredient is 0.1 mass of mass %~0.5 %, (C) content of ingredient is 0.5 mass of mass %~3 %, (D) content of ingredient is 0.01 mass of mass %~5 %, (E) content of ingredient is the 1 mass % of mass %~6, and the mass ratio (A/B) of the content (quality %) of (A) ingredient and the content (quality %) of (B) ingredient is 16~90.
Description
Technical field
The present invention relates to bubbling containers to fill skin detergent composition.
Background technique
In detergent applications, it is known that amine oxide is the one kind with the surfactant of high washing force, as blistering
Stabilizer is mixed into numerous skin detergent compositions.The amine oxide can also be mixed into polyoxyethylene alkyl ether sulfate
Salt is as (see, for example Patent Documents 1 to 3) in the skin detergent composition of main activating agent.However, for mixing in high concentration
Closing has the bubbling container dress skin detergent composition of the amine oxide to have the following problems since its viscosity is got higher: low temperature ring
The pump of bubbling container under border becomes difficult to press, and muddiness is generated in skin detergent composition, and low-temperature stability is poor, and washs
Skin when drying afterwards is tacky.
On the other hand, when reducing the combined amount of the amine oxide, although the viscosity under low temperature environment can be inhibited to get higher situation,
But since foaming power reduces, there is a problem of that froth texture is roughening.In the present invention, the low temperature environment refers to south east asia
10 DEG C of the lowest temperature.
In addition, proposing a kind of scheme of liquid detergent composition below: passing through mixed alkyl polyoxyethylene ether sulphur
Sour sodium, amine oxide and ethyl alcohol can inhibit the viscosity under low temperature environment to increase, and the foam that can obtain quality exquisiteness (see, for example
Patent document 4).However, in the program, in order to inhibit the viscosity under low temperature environment to rise and mixed ethanol in high concentration, thus
It is asked in the presence of compared with the exquisiteness of the froth texture under normal temperature environment, the exquisiteness of the froth texture under low temperature environment is insufficient
Topic.
Accordingly, it is desirable to provide bubbling container below fills skin detergent composition: bubbling container under low temperature environment
The easy pressing of pump is excellent, and the froth texture to be spued is fine and smooth, and the inviscid aspect of skin is good when dry after washing, and low temperature
Excellent in stability.
Existing technical literature
Patent document
Patent document 1: Japanese Patent Laid-Open 2009-067694 bulletin
Patent document 2: Japanese patent special table 2008-515919 bulletin
Patent document 3: Japanese Patent Laid-Open 5-320692 bulletin
Patent document 4: Japanese Patent Laid-Open 2008-214403 bulletin
Summary of the invention
Problems to be solved by the invention
Problem of the present invention is that solving the problems, such as existing above-mentioned various and realizing following purpose.That is, of the invention
Be designed to provide a kind of bubbling container below dress skin detergent composition: the pump of the bubbling container under low temperature environment
Easily pressing property is excellent, and the froth texture of discharge is fine and smooth, and the inviscid aspect of skin is good when dry after washing, and low-temperature stability
It is excellent.
The means solved the problems, such as
To solve the above problems, the present inventor studies through repeatedly wholwe-hearted, as a result, it has been found that, bubbling container below fills skin
Detergent composition can make that the easy pressing of the pump of the bubbling container under low temperature environment is excellent, spits by the synergistic effect of each ingredient
Froth texture out is fine and smooth, it is dry after washing when skin inviscid aspect it is good and low-temperature stability is excellent；The blistering is held
Device contains (A) polyoxyethylene alkyl ether sulfate salt, (B) alkyl dimethylamine oxides with filling skin detergent composition specific quantity
Amine, (C) oxyneurine type amphoteric surfactant, (D) polyoxyethylene-modified silicone or amino modified silicone and (E)
Ethyl alcohol, and the content (quality %) of (A) ingredient and the mass ratio (A/B) of the content (quality %) of (B) ingredient are
16~90.
Invention effect
According to the present invention, existing above-mentioned various problems be can solve and realize above-mentioned purpose, while one kind or less can be provided
Bubbling container fill skin detergent composition: the easy pressing of the pump of the bubbling container under low temperature environment is excellent, the bubble of discharge
Foam quality is fine and smooth, and the inviscid aspect of skin is good when dry after washing, and low-temperature stability is excellent.
Specific embodiment
(bubbling container fills skin detergent composition)
Bubbling container dress skin detergent composition of the invention contains (A) polyoxyethylene alkyl ether sulfate salt, (B) alkane
Base dimethyl amine, (C) oxyneurine type amphoteric surfactant, (D) polyoxyethylene-modified silicone or amino change
Property silicone and (E) ethyl alcohol, further contain other ingredients as needed.
<(A) polyoxyethylene alkyl ether sulfate salt>
The polyoxyethylene alkyl ether sulfate salt of (A) ingredient is contained for following purpose: improving low temperature ring
The easy pressing of the pump of bubbling container under border, the exquisiteness of froth texture and bubbling container fill skin detergent composition
Low-temperature stability.
For the polyoxyethylene alkyl ether sulfate salt of (A) ingredient, hold from the exquisiteness of froth texture and blistering
From the point of view of device fills the low-temperature stability aspect of skin detergent composition, the moieties of the polyoxyethylene alkyl ether sulfate salt
Carbon atom number be preferably 10~14, more preferably 12.When the carbon atom number is less than 10, there are the changes of the exquisiteness of froth texture
Obtain insufficient situation；And the carbon atom number is when being more than 14, there are the low-temperature stabilizations of bubbling container dress skin detergent composition
The case where property becomes inadequate.
In terms of the low-temperature stability of the exquisiteness of froth texture and bubbling container dress skin detergent composition, institute
The average addition molal quantity for stating the ethylene oxide of polyoxyethylene alkyl ether sulfate salt is preferably 1~5, and more preferably 2.The ring
When the average addition molal quantity of oxidative ethane is less than 1, the case where being become inadequate there are the exquisiteness of froth texture；And the epoxy second
When the average addition molal quantity of alkane is more than 5, there are the exquisitenesses of froth texture and bubbling container to fill skin detergent composition
The case where low-temperature stability becomes inadequate.
The counter ion of polyoxyethylene alkyl ether sulfate salt as (A) ingredient, for example, the alkali such as sodium and potassium can be enumerated
Metal ion；Ammonium ion；The complex ion etc. of the alkanolamines such as monoethanolamine, diethanol amine and triethanolamine.In these, from foam matter
From the point of view of in terms of the exquisiteness on ground, preferably alkali metal ion, more preferably sodium ion.
As the polyoxyethylene alkyl ether sulfate salt of (A) ingredient, for example, lauryl polyoxyethylene (1) can be enumerated
Ether sodium sulfate, lauryl polyoxyethylene (2) ether sodium sulfate are (also known as: lauryl ether (Laureth) sodium sulphate (2), BASF Japanese strain
Formula commercial firm manufacture), lauryl polyoxyethylene (3) ether sodium sulfate (also known as: sodium laureth sulfate (3), Lion Corporation's system
Make), lauryl polyoxyethylene (4) ether sodium sulfate and lauryl polyoxyethylene (5) ether sodium sulfate etc..These can be used alone one
Kind is used in combination two or more.In these, from the low of the exquisiteness and bubbling container of froth texture dress skin detergent composition
From the point of view of in terms of temperature stability, preferably lauryl polyoxyethylene (2) ether sodium sulfate and lauryl polyoxyethylene (3) ether sodium sulfate.Separately
Outside, the average addition molal quantity of the ethylene oxide of polyoxyethylene alkyl ether sulfate salt described in the digital representation in ().
Easy pressing and bubbling container from the pump of the bubbling container under the exquisiteness of froth texture, low temperature environment fill skin
From the point of view of in terms of the low-temperature stability of skin detergent composition, relative to the total amount of bubbling container dress skin detergent composition, make
Content for the polyoxyethylene alkyl ether sulfate salt of (A) ingredient is the 5 mass % of mass %~13, preferably 7 mass %
~11 mass %.When the content is less than 5 mass %, the exquisiteness of froth texture is become inadequate；And the content is more than 13 matter
When measuring %, the low temperature of the easy pressing of the pump of the bubbling container under low temperature environment and bubbling container dress skin detergent composition is steady
It is qualitative to become inadequate.
<(B) alkyl dimethyl amine oxide>
The alkyl dimethyl amine oxide of (B) ingredient is contained for following purpose: being improved under low temperature environment
The low temperature of the easy pressing of the pump of bubbling container, the exquisiteness of froth texture and bubbling container dress skin detergent composition is steady
It is qualitative.
As the alkyl dimethyl amine oxide of (B) ingredient, preferably the following general formula (B1) compound represented.
[general formula (B1)]
R-N+(CH3)2O-
In the general formula (B1), R indicates alkyl.The carbon atom number of the alkyl is preferably 12~18, and more preferably 12.Institute
When stating carbon atom number less than 12, the case where being become inadequate there are the exquisiteness of froth texture；And the carbon atom number is when being more than 18,
The pump for depositing bubbling container at low ambient temperatures becomes difficult to the case where pressing.
As the alkyl dimethyl amine oxide of (B) ingredient, for example, lauryl dimethyl amine oxide, tristearin can be enumerated
Base dimethyl amine and oleyl dimethyl amine oxide etc..These can be used alone one kind or is used in combination two or more.These
In, in terms of the exquisiteness of froth texture, preferably lauryl dimethyl amine oxide.
The easy pressing of the pump of bubbling container under from low temperature environment, the exquisiteness of froth texture and bubbling container fill skin
From the point of view of in terms of the low-temperature stability of skin detergent composition, relative to the total amount of bubbling container dress skin detergent composition, make
Content for the alkyl dimethyl amine oxide of (B) ingredient is the 0.1 mass % of mass %~0.5, preferably 0.2 mass %~
0.4 mass %.When the content is less than 0.1 mass %, the exquisiteness of froth texture is become inadequate；And the content is more than 0.5
When quality %, the low temperature of the easy pressing of the pump of the bubbling container under low temperature environment and bubbling container dress skin detergent composition
Stability becomes inadequate.
<mass ratio (A/B)>
In terms of the exquisiteness of froth texture, the content (quality %) of (A) ingredient and containing for (B) ingredient
The mass ratio (A/B) for measuring (quality %) is 16~90, preferably 20~50.When the mass ratio (A/B) is less than 16 or more than 90,
The exquisiteness of froth texture becomes inadequate.
<(C) oxyneurine type amphoteric surfactant>
The oxyneurine type amphoteric surfactant of (C) ingredient is contained for following purpose: being mentioned
The easy pressing of the pump of bubbling container under high and low temperature environment, the exquisiteness of froth texture and bubbling container fill skin detergent
The low-temperature stability of composition.
As the oxyneurine type amphoteric surfactant of (C) ingredient, for example, alkyl dimethyl can be enumerated
Oxyneurine, fatty acid amide propyl dimethylaminoethyl acid glycine betaine and alkyl dihydroxyethyl amion acetic acid beet
Alkali etc..These can be used alone one kind or is used in combination two or more.In these, from low temperature environment under bubbling container pump it is easy
It is excellent from the point of view of in terms of the low-temperature stability of pressing property, the exquisiteness of froth texture and bubbling container dress skin detergent composition
Select fatty acid amide propyl dimethylaminoethyl acid glycine betaine.
As the alkyl dimethyl oxyneurine, for example, lauryl dimethyl amion acetic acid beet can be enumerated
Alkali and stearyl dimethyl oxyneurine etc..These can be used alone one kind or is used in combination two or more.
As the fatty acid amide propyl dimethylaminoethyl acid glycine betaine, for example, coco-nut oil fatty acid acyl can be enumerated
Amine propyl betaine etc..
As the alkyl dihydroxyethyl oxyneurine, for example, stearyl dihydroxy ethyl beet can be enumerated
Alkali etc..
In these, in terms of the exquisiteness of froth texture, preferably lauryl dimethyl oxyneurine and coconut palm
Seed oil fatty acid amide propyl glycine betaine, more preferable coco-nut oil fatty acid amido propyl betaine.
The easy pressing of the pump of bubbling container under from low temperature environment, the exquisiteness of froth texture and bubbling container fill skin
From the point of view of in terms of the low-temperature stability of skin detergent composition, relative to the total amount of bubbling container dress skin detergent composition, make
Content for the oxyneurine type amphoteric surfactant of (C) ingredient is 0.5 mass %~3 mass %, preferably 1
The mass of quality %~2.5 %.When the content is less than 0.5 mass %, the exquisiteness of froth texture is become inadequate；And the content
When more than 3 mass %, the easy pressing of the pump of the bubbling container under low temperature environment, froth texture exquisiteness and bubbling container
The low-temperature stability of dress skin detergent composition becomes inadequate.
<(D) polyoxyethylene-modified silicone or amino modified silicone>
The polyoxyethylene-modified silicone or amino modified silicone of (D) ingredient are contained for following purpose: being mentioned
The inviscid and bubbling container of skin fills skin when dry after the easy pressing of the pump of bubbling container under high and low temperature environment, washing
The low-temperature stability of skin detergent composition.
In the polyoxyethylene-modified silicone or amino modified silicone of (D) ingredient, from low temperature environment under blistering hold
The low temperature of the inviscid and bubbling container dress skin detergent composition of skin when dry after the easy pressing of the pump of device, washing
From the point of view of in terms of stability, preferably polyoxyethylene-modified silicone.
Polyoxyethylene-modified silicone-
The low-temperature stability side of the inviscid and bubbling container dress skin detergent composition of skin when dry after washing
From the point of view of face, the polyoxyethylated average degree of polymerization of the polyoxyethylene-modified silicone is preferably 9~12.The average degree of polymerization is small
When 9, the case where being become inadequate there are the low-temperature stability of bubbling container dress skin detergent composition；And the average polymerization
When degree is more than 12, the case where inviscid aspect of skin becomes inadequate when depositing dry after washing.
The polyoxyethylene-modified silicone is the copolymer being made of dimethyl silscone and polyoxyalkylene, for example, can enumerate
The following general formula (D1) compound represented etc..
<general formula (D1)>
[changing 1]
However, m and n are independent integer respectively, and m indicates that 1~20000, n indicates 1~20000 in the general formula (D1).
A is independent integer, indicates 9~12.R indicates that the alkylidene of carbon atom number 1~10, R' indicate the alkyl of carbon atom number 1~10.
When dry after the washing skin it is inviscid in terms of from the point of view of, as the polyoxyethylene-modified silicone, preferably polyoxy
Ethylene methyl polysiloxane copolymer.
As the polyoxyethylene-modified silicone, commercial product can be used；As the commercial product, for example, can enumerate
PEG-12 dimethyl silicone polymer (trade name: SH3771M, beautiful DOW CORNING (the eastern レ ダ ウ コ ー ニ Application グ) Co., Ltd. in east
Manufacture；Or trade name: KF-6017, Shin-Etsu Chemial Co., Ltd manufacture), PEG-10 Polydimethylsiloxane (trade name:
The manufacture of ES-5612Formulation Aid, Dong Li Dow Corning Corporation) and PEG-9 dimethyl silicone polymer (trade name: KF-
6013, Shin-Etsu Chemial Co., Ltd's manufacture) etc..These can be used alone one kind or is suitably combined two or more
It uses.
Amino modified silicone-
The amino modified silicone is the organic siloxane polymer in a molecule at least one aminoalkyl.
Formed in the organosiloxane of the amino modified silicone polymer, generally use comprising methyl (methyl as
Functional group other than aminoalkyl) organosiloxane.In addition, also may include: the alkyl such as ethyl and propyl；Vinyl；Allyl
The alkenyls such as base；The aryl such as phenyl and naphthalene；The naphthenic base such as cyclohexyl；Hydroxyl and hydroxyalkyl etc..
As the amino modified silicone, for example, the polymerization dimethyl silica of height shown in the following general formula (D2) can be enumerated
Amino second shown in alkane dimethylaminopropyl silicone copolymers (aminopropyl dimethyl silicone polymer), the following general formula (D3)
Base aminopropylmethylsiloxane dimethylsiloxane copolymer (is recorded in CTFA with the title of ammonia-terminated polydimethylsiloxane
In dictionary (U.S. Cosmetic Ingredient Dictionary) third edition), amino-ethyl shown in the following general formula (D4)
Aminopropylsiloxane dimethylsiloxane copolymer (trimethyl silyl ammonia-terminated polydimethylsiloxane) or at them
At least any one middle being added in methyl polysiloxane and water and emulsified with surfactant and the amino modified silicon that is formed
Ketone lotion etc..These can be used alone one kind or is used in combination two or more.In addition, amino modified silicone can be the form or use of oil
Surfactant is emulsified and the emulsion form that is formed.
<general formula (D2)>
[changing 2]
However, m and n are independent integer respectively, and m indicates that 1~20000, n indicates 1~20000 in the general formula (D2).
<general formula (D3)>
[changing 3]
However, m and n are independent integer respectively, and m indicates that 1~20000, n indicates 1~20000 in the general formula (D3).
A and b is independent integer respectively, and a indicates that 1~10, b indicates 1~10.
<general formula (D4)>
[changing 4]
However, m and n are independent integer respectively, and m indicates that 1~20000, n indicates 1~20000 in the general formula (D4).
A and b is independent integer respectively, and a indicates that 1~10, b indicates 1~10.
It polymerize dimethylsiloxane methyl aminopropylsiloxane copolymer (ammonia as height shown in the general formula (D2)
Base propyl dimethyl silicone polymer), for example, KF-8020, X-52-2362 can be enumerated (by Shin-Etsu Chemial Co., Ltd's system
Make) etc..These can be used alone one kind or is used in combination two or more.
As aminoethylaminopropyl methylsiloxane dimethylsiloxane copolymer shown in the general formula (D3)
(CTFA dictionary (U.S. Cosmetic Ingredient Dictionary) is recorded in the title of ammonia-terminated polydimethylsiloxane
In the third edition), for example, SM-8904C (beautiful DOW CORNING organosilicon (the eastern レ ダ ウ コ ー ニ Application グ シ リ コ ー in east can be enumerated
Application) Co., Ltd.'s manufacture) and XF42-B892, XF42-C0330, XS65-C0032, XS65-C0726 and SILSOFT 200
EF is (by Momentive Performance Material (モ メ Application テ ィ Block パ フ ォ ー マ Application ス マ テ リ ア Le ズ ジ
ャ パ Application contract commercial firm) manufacture) etc..These can be used alone one kind or is used in combination two or more.
As aminoethylaminopropyl siloxanes dimethylsiloxane copolymer (front three shown in the general formula (D4)
Base silicyl ammonia-terminated polydimethylsiloxane), for example, can enumerate FZ-4671, FZ-4672, BY22-079, SF8452C and
SS-3551 (by eastern beautiful DOW CORNING organosilicon Co., Ltd. manufacture), KF-8004, KF-8015 and KF-867S are (by SHIN-ETSU HANTOTAI
Learn Industrial Co., Ltd's manufacture), ADM1650, ADM-8101E and ADM-6057E are (by Wa Ke organosilicon Co., Ltd., Asahi Chemical Industry
(ワ ッ カ ー シ リ コ ー Application Co., Ltd., Asahi Chemical Industry) manufacture), KS65-B4280, XS65-C1539, XS65-6413, XS65-
B8124 and KF42B1989 (being manufactured by Momentive Performance Material) etc..These one kind or by two of can be used alone
Kind or more be used in combination.
In these, when dry after the washing skin it is inviscid in terms of from the point of view of, be preferably equivalent to shown in the general formula (D2)
High polymerization dimethylsiloxane methyl aminopropylsiloxane copolymer KF-8020 and X-52-2362, be equivalent to described
The SM-8904C of aminoethylaminopropyl methylsiloxane dimethylsiloxane copolymer lotion shown in general formula (D3) with
And it is equivalent to the KF- of aminoethylaminopropyl siloxanes dimethylsiloxane copolymer lotion shown in the general formula (D4)
8004。
The inviscid and blistering of skin when dry after the easy pressing of the pump of bubbling container under from low temperature environment, washing
From the point of view of container fills the low-temperature stability aspect of skin detergent composition, relative to bubbling container dress skin detergent composition
Total amount, the polyoxyethylene-modified silicone of (D) ingredient or the content of amino modified silicone are 0.01 in terms of silicone composition
The mass % of quality %~5, preferably 0.5 mass of mass %~2 %.When the content is less than 0.01 mass %, under low temperature environment
It is become inadequate in terms of the effect of skin-adherent when dry after the easy pressing and inhibition washing of the pump of bubbling container；And this contains
When amount is more than 5 mass %, the low-temperature stability of bubbling container dress skin detergent composition is become inadequate.
<(E) ethyl alcohol>
The ethyl alcohol of (E) ingredient is contained for following purpose: improving the pump of the bubbling container under low temperature environment
Easy pressing, froth texture exquisiteness and bubbling container dress skin detergent composition low-temperature stability.
As the ethyl alcohol of (E) ingredient, for example, dehydrated alcohol and ethyl alcohol (95 body of specification value of 95 volume % can be enumerated
The product volume % of %~95.5) etc..These can be used alone one kind or is used in combination two or more.
The easy pressing of the pump of bubbling container under from low temperature environment, the exquisiteness of froth texture and bubbling container fill skin
From the point of view of in terms of the low-temperature stability of skin detergent composition, relative to the total amount of bubbling container dress skin detergent composition, make
It is the 1 mass % of mass %~6, preferably 2 matter of mass %~4 in terms of dehydrated alcohol for the content of the ethyl alcohol of (E) ingredient
Measure %.When the content of the dehydrated alcohol is less than 1 mass %, the easy pressing and blistering of the pump of the bubbling container under low temperature environment
The low-temperature stability of container dress skin detergent composition becomes inadequate；And the content is when being more than 6 mass %, froth texture
Exquisiteness becomes inadequate.
The content of ethyl alcohol as (E) ingredient, when containing plant extracts etc. as other ingredients, which is
Total content of dehydrated alcohol comprising the ethyl alcohol brought by these ingredients.
The content (quality %) for being converted into dehydrated alcohol when using 95 volume % ethyl alcohol can pass through 1 (independent rows of following formula
Politics and law people's pharmaceuticals medical machine comprehensive organ transmits document 038-1309.pdf) and formula 2 find out.
Quality %=volume % × 0.79422 (specific gravity of 100 volume % at 15 DEG C)/d (ratio at 15 DEG C of ethyl alcohol
Weight) ... formula 1
=(95 × 0.79422)/0.81639
=92.42
The content (quality %) of dehydrated alcohol=95 volume % ethyl alcohol content (quality %) × 92.42/100... formula 2
<other ingredients>
The bubbling container fills skin detergent composition, other than being mixed with each ingredient of (A)~(E), may be used also
Other ingredients are mixed within the scope of the effect of the invention.As other ingredients, skin can be filled from bubbling container and washed
It washs in agent composition and is suitably selected in commonly used substance, for example, can enumerate in addition to (B) ingredient and described
(C) alcohols, the lanolin such as the amphoteric surfactant other than ingredient, rudimentary or higher alcohol other than (E) ingredient spread out
Biology, protein derivatives, acrylic resin dispersion liquid, cation property copolymer, anionic polymer, non-ionic polymeric
The medicament of object, vitamin etc., preservative, pH regulator, antioxidant, metal-chelator, ultraviolet absorbing agent, moves fungicide
Plant extracts and its derivative, pigment, fragrance, pigment, inorganic particle, clay mineral, nylon, polyethylene etc. it is not soluble in water
Polymer powder, water etc..
-pH-
PH in terms of the exquisiteness of froth texture, at 25 DEG C of the bubbling container dress skin detergent composition
Value preferably 4~6.When the pH value is less than 4 or more than 6, the case where being become inadequate there are the exquisiteness of froth texture.For
The pH value of the bubbling container dress skin detergent composition passes through while finally can confirming pH after mixing whole components
At least any one being added in potassium hydroxide and citric acid etc. is adjusted.In more detail, it can measure in the following manner
PH value: being mixed Purified Water as surplus, make other than at least any one in potassium hydroxide and citric acid etc. at
Subtotaling reaches about 90 mass %.If necessary, it can also be heated.Potassium hydroxide and citric acid are slowly added into mixing
The aqueous solution of at least any one in is added when measuring each pH value, until reaching target ph.After reaching target ph,
It is eventually adding remaining Purified Water, addition water makes total amount become 100 mass %, and measures final pH value.
Viscosity-
The bubbling container dress skin detergent composition can use under the conditions of 10 DEG C~50 DEG C of temperature.
At 10 DEG C of the lowest temperature of south east asia, for example, when using the bubbling container with 2 200 meshes, from low
From the point of view of in terms of the easy pressing of the pump of bubbling container under warm environment, the viscosity of the bubbling container dress skin detergent composition
Preferably 50mPas is hereinafter, more preferably 1mPas~30mPas.When the viscosity is more than 50mPas, there are pumps to become
It is difficult to press the case where easy pressing with the pump of the bubbling container under low temperature environment becomes inadequate.
The viscosity can measure by the following method:
By bubbling container dress skin detergent composition keeping under 10 DEG C of environment, and it is disposed at as BL type is viscous
On degree meter (No. 1 rotor, Tokyo Keiki Inc.'s manufacture), makes rotor with rotation speed 60rpm rotation, rotated since rotor
After 1 minute, its viscosity is measured.
Manufacturing method-
The bubbling container fills skin detergent composition, can for example, by (A)~(E) ingredient described in mixing, it is described its
Its ingredient and water (surplus is mixed into, so that the total amount of skin detergent composition becomes 100 mass %) manufacture.As manufacture
The device of the bubbling container dress skin detergent composition, is not particularly limited, can suitably be selected according to purpose, example
Such as, can enumerate has stirring for multiple stirring blades with shearing force and the propeller that can integrally mix, turbine, dispersion machine etc.
Mix device.In addition, manufacturing the bubbling container dress skin washing for (A)~(E) ingredient and other ingredients
When agent composition, can use individually or with the state of the mixture comprising two or more ingredients come using.
Bubbling container-
As the bubbling container, if its be bubbling container dress skin detergent composition can mix with air and
The container to be spued with bubblement, there is no particular limitation, can suitably be selected according to purpose.For example, can enumerate by by
Press pump portion can spue the bubbling container etc. of foam.As such bubbling container, such as Yoshino Kogyosho Co., Ltd can be used
The bubbling container etc. of manufacture.
The bubbling container usually has the Porous membrane body for being used to form foam, and bubbling container dress skin washing
Agent composition forms foam by the Porous membrane body.As the material of the Porous membrane body, for example, Buddhist nun can be enumerated
The plastic material of dragon, polyester, polyolefin etc..The easy pressing of the pump of bubbling container under from low temperature environment and froth texture it is thin
From the point of view of in terms of greasy property, the mesh of the Porous membrane body is preferably 100 mesh~400 mesh.The mesh of the Porous membrane body is less than
When 100 mesh, the case where being become inadequate there are the exquisiteness of froth texture；And the mesh of the Porous membrane body be more than 400 mesh when,
The pump for depositing bubbling container at low ambient temperatures becomes difficult to the case where pressing.
It is described more in terms of the exquisiteness of the easy pressing of the pump of the bubbling container under low temperature environment and froth texture
The piece number of hole plasmalemmasome is preferably 2~4.When the piece number of the Porous membrane body is less than 2, there are the exquisitenesses of froth texture
The case where property becomes inadequate；And the piece number, when being more than 4, the pump for depositing bubbling container at low ambient temperatures becomes difficult to press
The case where.It more specifically, is suitable for using Japanese Patent Laid-Open 7-315463 bulletin, Japanese Patent Laid-Open 8-230961
The container recorded in number bulletin and Japanese Patent Laid-Open 2005-193972 bulletin.
Purposes-
The bubbling container fills skin detergent composition, for example, being suitable for as hand soaps, bath soap and face cleaning foam etc.
Product.Skin detergent is filled using the bubbling container according to the usual dosage and common washing methods that correspond to these purposes
When composition, be advantageous in the following areas: the easy pressing of the pump of the bubbling container under low temperature environment and froth texture it is thin
Greasy property is excellent, and the low-temperature stability that bubbling container fills skin detergent composition is good, and can inhibit skin when drying after washing
Skin viscosity.
Embodiment
Hereinafter, being further illustrated according to examples and comparative examples to the present invention, but the invention is not limited under
State embodiment.
The content for each ingredient that embodiment and comparative example are recorded is entirely value obtained by being converted with sterling.In addition, (A) ingredient
Content (quality %) and the mass ratio (A/B) of content (quality %) of (B) ingredient be recorded as the 2nd four house five after decimal point
Enter, retains the numerical value found out to the 1st after decimal point.In addition, pH value is adjusted to 5.2 with citric acid.The measurement side of pH value
Method is measured at 25 DEG C according to universal method as defined in Japanese Pharmacopoeia.Viscosity is measured by the following method: will
It is filled in the skin of the capacity 50mL bottle (trade name: " SV-50A ", the manufacture of day physics and chemistry nitre subsidiary) of hard glass manufacture
The temperature of detergent composition is constant at 10 DEG C, and is disposed at (the Tokyo gauge company manufacture of BL type viscosimeter；100mPa·
When s or less, No. 1 rotor is used；When 100mPas~500mPas, No. 2 rotors are used) on, make rotor with rotation speed
60rpm rotation, after rotating 1 minute since rotor, measures its viscosity.
[Examples 1 to 31 and comparative example 1~23]
In accordance with the following methods, preparation has the skin detergent composition of composition and content shown in table 1-1~table 1-7.
Firstly, using paddle stirrer, at 25 DEG C by (A) ingredient, (B) ingredient, (C) ingredient, (D) ingredient, glycerol, sodium benzoate with
And Purified Water is uniformly mixed.In addition, isopropyl methyl phenol is dissolved in (E) ingredient, other than comparative example 20, while stirring
It is made an addition in other embodiments and comparative example.In comparative example 20, isopropyl methyl phenol is in addition dissolved in fragrance,
It is added into the mixture of comparative example 20 while stirring.At this point, adjustment purification water, makes weight become skin detergent combination
90 mass % of object total amount.Then, pH value is measured using pH meter HM-30V (DKK Toa Corp.'s manufacture), and uses citric acid
PH value is adjusted to 5.2.When pH value becomes 5.2, it is eventually adding remaining Purified Water, becomes skin detergent total composition
100 mass %.The final ph of measurement the result is that the pH value in whole embodiments and comparative example is all 5.2.
In bubbling container, (container A, 200 2, mesh, Yoshino Kogyosho Co., Ltd are manufactured (with Japanese Patent Laid-Open 2005-
Bubbling container used in the embodiment 2 of No. 193972 bulletins is identical)) in filling preparation Examples 1 to 31 and comparative example 1
~22 each skin detergent composition prepares bubbling container dress skin detergent composition.On the other hand, in band pump dispenser
Container (container B, discharge-amount 1mL, nozzle diameter (internal diameter) 3.5mm, Canyon (キ ャ ニ オ Application) company manufacture) in filling
The skin detergent composition of composition same as Example 1, the skin for preparing the container dress with pump dispenser of comparative example 23 are washed
Wash agent composition.
The skin detergent composition of Examples 1 to 31 and comparative example 1~23 for preparation is commented according to as follows
Valence " the easy pressing of the pump under low temperature environment ", " exquisiteness of froth texture ", " skin is inviscid when dry after washing " with
And " low-temperature stability ".As a result as shown in table 1-1~table 1-7.
<the easy pressing of the pump under low temperature environment>
Under the conditions of 10 DEG C, make skin detergent composition 1g (1 time of the Examples 1 to 31 prepared and comparative example 1~23
Pressing) spue in the container from bubbling container or with pump dispenser primary, it evaluates " the easy pressing of the pump under low temperature environment ".It is right
In a kind of skin detergent composition, each 10 bottles of filling saved for 1 evening under the conditions of 10 DEG C, was confirming each skin detergent combination
After the liquid temperature of object is 10 DEG C, distributes to 10 panel members and every bottle of composition is evaluated.The evaluation is according to following bases
What standard carried out.
[evaluation criteria]
8 or more the pumps answered under low temperature environment in ◎: 10 are easy to press.
6 or more, 7 or less the pumps answered under low temperature environment in zero: 10 are easy to press.
4 or more, 5 or less the pumps answered under low temperature environment in △: 10 are easy to press.
×: 3 or less the pumps answered under low temperature environment in 10 are easy to press.
<exquisiteness of froth texture>
Under the conditions of 25 DEG C, make skin detergent composition 1g (1 time of the Examples 1 to 31 prepared and comparative example 1~23
Pressing) continuously spue 5 foams from used bubbling container when the easy pressing of evaluation pump or the container with pump dispenser.
Evaluation is to be carried out by 10 panel members according to following benchmark.
[evaluation criteria]
Not coarse foam is answered for 8 or more in ◎: 10 to be mixed into, can all be discharged with the foam of quality exquisiteness.
6 or more, 7 or less in zero: 10 answer not coarse foams be mixed into, all can be with the bubble of quality exquisiteness
Foam discharge.
4 or more, 5 or less in △: 10 answer not coarse foams be mixed into, all can be with the bubble of quality exquisiteness
Foam discharge.
×: it answers not coarse foam for 3 or less in 10 and is mixed into, can be all discharged with the foam of quality exquisiteness.
<skin is inviscid when dry after washing>
Under the conditions of 25 DEG C, make skin detergent composition 1g (1 time of the Examples 1 to 31 prepared and comparative example 1~23
Pressing) it is discharged in the container from bubbling container or with pump dispenser, hand is washed, " nothing of skin is viscous when dry after washing for evaluation
Property ".Described herein refers to " when dry " with the state for having residual moisture after towel on skin.The evaluation is by 10
Panel member carries out according to following benchmark.
[evaluation criteria]
Skin is inviscid when dry after 8 or more answers washing in ◎: 10.
Skin is inviscid when dry after 6 or more, 7 or less answers washing in zero: 10.
Skin is inviscid when dry after 4 or more, 5 or less answers washing in △: 10.
×: skin is inviscid when dry after 3 or less the answers washing in 10.
<low-temperature stability>
In the capacity 50mL bottle (trade name: " SV-50A ", the manufacture of day physics and chemistry Xiao Zi Co., Ltd.) of hard glass
The Examples 1 to 31 of middle filling about 50mL preparation and the skin detergent composition of comparative example 1~23, are held in 10 DEG C in temperature
The preservation of evaluation interior one month after, by above-mentioned skin detergent composition with saved 1 month under room temperature (25 DEG C) after room
Warm preservation product are compared, and evaluate " low-temperature stability (no to precipitate and without muddiness) " of each skin detergent composition.This is commented
Valence is to be carried out by 1 panel member according to following benchmark.
[evaluation criteria]
◎: without precipitating and muddiness.
Zero: when compared with room temperature preservation product, when confirming there is slight precipitating or muddiness, but being restored to room temperature, Quick uniform
Dissolution.
△: when compared with room temperature preservation product, when confirming there is precipitating or muddiness, but being restored to room temperature, slow uniform dissolution.
×: when compared with room temperature preservation product, confirmation has precipitating or muddiness, and even if being restored to room temperature, can not be uniformly molten
Solution.
[table 1-1]
[table 1-2]
[table 1-3]
[table 1-4]
[table 1-5]
[table 1-6]
[table 1-7]
(embodiment 32)
Finger fills skin detergent composition-with bubbling container
Conventionally, the finger for preparing composition and content as shown below fills skin detergent combination with bubbling container
Object.
Mass ratio (A/B)=30
10 DEG C of viscosity is 20mPas
(embodiment 33)
Body fills skin detergent composition-with bubbling container
Conventionally, the body for preparing composition and content as shown below fills skin detergent combination with bubbling container
Object.
Mass ratio (A/B)=40
10 DEG C of viscosity is 48mPas
(embodiment 34)
The body for being mixed with anti-inflammatory agent fills skin detergent composition-with bubbling container
Conventionally, the body for being mixed with anti-inflammatory agent for preparing composition and content as shown below fills skin with bubbling container
Skin detergent composition.
Mass ratio (A/B)=40
10 DEG C of viscosity is 48mPas
Skin detergent composition is filled for the bubbling container of embodiment 32~34, such as embodiment 1, evaluates " low temperature ring
The easy pressing of pump under border ", " exquisiteness of froth texture " and bubbling container dress skin detergent composition " low temperature is steady
It is qualitative " and " skin is inviscid when dry after washing ".The results are shown in Table 2.
[table 2]
In addition, the details of various composition used in above-described embodiment and above-mentioned comparative example is as described in Table 3.
[table 3]
* 1:() in digital representation ethylene oxide average addition molal quantity.
As form of the invention, for example, pattern below etc. can be enumerated.
<1>a kind of bubbling container fills skin detergent composition, which is characterized in that the composition contains: (A) alkyl is poly-
Ethylene oxide ether sulfuric ester salt, (B) alkyl dimethyl amine oxide, (C) oxyneurine type amphoteric surfactant, (D) are poly-
Ethylene oxide modified silicone or amino modified silicone and (E) ethyl alcohol；
The content of (A) ingredient is the 5 mass % of mass %~13,
The content of (B) ingredient is the 0.1 mass % of mass %~0.5,
The content of (C) ingredient is the 0.5 mass % of mass %~3,
The content of (D) ingredient is the 0.01 mass % of mass %~5,
The content of (E) ingredient is the 1 mass % of mass %~6,
And the mass ratio (A/B) of the content (quality %) of (A) ingredient and the content (quality %) of (B) ingredient
It is 16~90.
<2>bubbling container recorded such as<1>fills skin detergent composition, wherein the alkyl dimethylamine oxides of (B) ingredient
Amine is lauryl dimethyl amine oxide.
<3>bubbling container recorded such as any one of<1>~<2>fills skin detergent composition, wherein (D) ingredient
For polyoxyethylene-modified silicone.
Utilization possibility in industry
The easy pressing of the pump of the bubbling container of bubbling container dress skin detergent composition of the invention at low ambient temperatures
Property it is excellent, the froth texture of discharge is fine and smooth, and the inviscid aspect of skin is good when dry after washing, and bubbling container dress skin is washed
The low-temperature stability for washing agent composition is excellent, can be widely used for such as bath soap, hand soaps, foam hand soaps, face cleaning foam and washes
In face milk etc..
Claims (7)
1. a kind of hand soaps, bath soap or face cleaning foam fill skin detergent composition with bubbling container, which is characterized in that described
Composition contains: (A) polyoxyethylene alkyl ether sulfate salt, (B) alkyl dimethyl amine oxide, (C) oxyneurine type
Amphoteric surfactant, (D) polyoxyethylene-modified silicone and (E) ethyl alcohol；
The content of (A) ingredient is the 5 mass % of mass %~13,
The content of (B) ingredient is the 0.1 mass % of mass %~0.5,
The content of (C) ingredient is the 0.5 mass % of mass %~3,
The content of (D) ingredient is the 0.01 mass % of mass %~5,
The content of (E) ingredient is the 1 mass % of mass %~6,
The mass ratio A/B of the content of (A) ingredient and the content of (B) ingredient is 16~90, and the content is with quality %
Meter；
Viscosity at 10 DEG C of the bubbling container dress skin detergent composition is 50mPas or less.
2. the bubbling container recorded such as claim 1 fills skin detergent composition, wherein the alkyl dimethyl oxygen of (B) ingredient
Change amine is lauryl dimethyl amine oxide.
3. the bubbling container recorded such as claims 1 or 2 fills skin detergent composition, the polyoxyethylene-modified silicon of (D) ingredient
The polyoxyethylated average degree of polymerization of ketone is 9~12.
4. the bubbling container recorded such as claims 1 or 2 fills skin detergent composition, (C) ingredient is lauryl dimethyl ammonia
Guanidine-acetic acid glycine betaine, stearyl dimethyl oxyneurine, coco-nut oil fatty acid amido propyl betaine, stearyl dihydroxy
Base ethyl glycine betaine.
5. the bubbling container recorded such as claims 1 or 2 fills skin detergent composition, the ethylene oxide of (A) ingredient is averaged
Addition molal quantity is 1~5.
6. the bubbling container recorded such as claims 1 or 2 fills skin detergent composition, the pH value at 25 DEG C is 4~6.
7. the bubbling container recorded such as claims 1 or 2 fills skin detergent composition, the bubbling container of the composition merging
In, the mesh for being used to form the Porous membrane body of foam is 100 mesh~400 mesh, and the piece number of the Porous membrane body is 2~4
Piece.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014135372 | 2014-06-30 | ||
| JP2014-135372 | 2014-06-30 | ||
| PCT/JP2015/067496 WO2016002522A1 (en) | 2014-06-30 | 2015-06-17 | Skin cleanser composition contained in foamer container |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106456488A CN106456488A (en) | 2017-02-22 |
| CN106456488B true CN106456488B (en) | 2019-08-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580033811.4A Active CN106456488B (en) | 2014-06-30 | 2015-06-17 | Bubbling container fills skin detergent composition |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP6557228B2 (en) |
| KR (1) | KR102336065B1 (en) |
| CN (1) | CN106456488B (en) |
| MY (1) | MY176755A (en) |
| WO (1) | WO2016002522A1 (en) |
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| JPWO2020158838A1 (en) * | 2019-01-31 | 2021-12-23 | 味の素株式会社 | Low viscosity liquid cleaner |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005281310A (en) * | 2004-03-26 | 2005-10-13 | Clariant Internatl Ltd | Aqueous multi-phase cleansing composition |
| JP2007145726A (en) * | 2005-11-24 | 2007-06-14 | Lion Corp | Non-aerosol type foam jetting hair detergent product and hair detergent composition |
| JP2008137943A (en) * | 2006-12-01 | 2008-06-19 | Lion Corp | Liquid body cleansing agent composition |
| JP2010163385A (en) * | 2009-01-15 | 2010-07-29 | Mandom Corp | Composition for foam detergent and foam detergent |
| JP2014076975A (en) * | 2012-10-12 | 2014-05-01 | Lion Corp | Skin detergent composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3114361B2 (en) | 1992-05-27 | 2000-12-04 | 日本油脂株式会社 | Detergent composition |
| US7531497B2 (en) | 2004-10-08 | 2009-05-12 | The Procter & Gamble Company | Personal care composition containing a cleansing phase and a benefit phase |
| JP4959379B2 (en) | 2007-02-28 | 2012-06-20 | ライオン株式会社 | Liquid detergent composition |
| JP5022154B2 (en) | 2007-09-11 | 2012-09-12 | ライオン株式会社 | Skin cleanser composition |
| JP2010070549A (en) * | 2008-08-19 | 2010-04-02 | Kao Corp | Hair dye composition |
-
2015
- 2015-06-17 KR KR1020167024134A patent/KR102336065B1/en active IP Right Grant
- 2015-06-17 WO PCT/JP2015/067496 patent/WO2016002522A1/en active Application Filing
- 2015-06-17 JP JP2016531257A patent/JP6557228B2/en active Active
- 2015-06-17 MY MYPI2016704376A patent/MY176755A/en unknown
- 2015-06-17 CN CN201580033811.4A patent/CN106456488B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005281310A (en) * | 2004-03-26 | 2005-10-13 | Clariant Internatl Ltd | Aqueous multi-phase cleansing composition |
| JP2007145726A (en) * | 2005-11-24 | 2007-06-14 | Lion Corp | Non-aerosol type foam jetting hair detergent product and hair detergent composition |
| JP2008137943A (en) * | 2006-12-01 | 2008-06-19 | Lion Corp | Liquid body cleansing agent composition |
| JP2010163385A (en) * | 2009-01-15 | 2010-07-29 | Mandom Corp | Composition for foam detergent and foam detergent |
| JP2014076975A (en) * | 2012-10-12 | 2014-05-01 | Lion Corp | Skin detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2016002522A1 (en) | 2016-01-07 |
| JP6557228B2 (en) | 2019-08-07 |
| KR102336065B1 (en) | 2021-12-07 |
| KR20170018801A (en) | 2017-02-20 |
| JPWO2016002522A1 (en) | 2017-04-27 |
| MY176755A (en) | 2020-08-21 |
| CN106456488A (en) | 2017-02-22 |
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