CN114224753B - Water-in-oil type emulsified composition, foundation liquid and preparation method thereof - Google Patents
Water-in-oil type emulsified composition, foundation liquid and preparation method thereof Download PDFInfo
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- CN114224753B CN114224753B CN202111667651.2A CN202111667651A CN114224753B CN 114224753 B CN114224753 B CN 114224753B CN 202111667651 A CN202111667651 A CN 202111667651A CN 114224753 B CN114224753 B CN 114224753B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
Abstract
The invention discloses a water-in-oil type emulsion composition, foundation liquid and a preparation method thereof, wherein the weight ratio of oil to fat to emulsifier to oil phase thickener to water phase thickener is (5-13): (2.5-5): (0.4-2): (0.75-2.6); oils and fats include isononyl isononanoate, polyglycerol-2 triisostearate and cetyl ethyl hexanoate; emulsifiers include cetyl PEG/PPG-10/1 polydimethylsiloxane, PEG-10 polydimethylsiloxane and polyglycerol-3 diisostearate; the oil phase thickener comprises disteardimonium hectorite and magnesium stearate; the aqueous phase thickener comprises sodium magnesium lithium silicate and tetrasodium pyrophosphate. Experiments prove that the foundation liquid containing the water-in-oil type emulsion composition has no layering phenomenon after being placed for one year at normal temperature, and has high stability.
Description
Technical Field
The invention relates to the technical field of cosmetics, in particular to a water-in-oil type emulsified composition, foundation liquid and a preparation method thereof.
Background
With the pursuit of people for aesthetic feeling becoming higher, make-up cosmetics have become an indispensable living article for modern fashion people. Make-up cosmetics are of many varieties and mainly comprise various products such as foundation, honey powder, lipstick, eye shadow, rouge, mascara and the like. These make-up cosmetics generally contain both an aqueous phase component and an oil phase component, and an emulsifier is a raw material that must be added in order to sufficiently mix the aqueous phase component and the oil phase component. After the emulsifier is added to the oil-water system, the water and oil can be mixed with each other to form an emulsion. The powder base liquid belongs to emulsion, and comprises oil-in-water powder base liquid and water-in-oil powder base liquid. Regardless of the type of the powder base liquid, the user hopes that the product quality is stable, and the better use experience can be given to the user. However, the existing water-in-oil foundation liquid often has the phenomena of demulsification and layering, poor stability of an emulsifying system, poor skin feel and poor make-up holding effect.
Disclosure of Invention
In order to overcome the defects in the prior art, one of the purposes of the invention is to provide a water-in-oil type emulsion composition which can improve the stability of a water-in-oil system and prevent the viscosity reduction and layering phenomena of the system.
The second purpose of the invention is to provide a foundation liquid with good stability and good skin feel.
The invention further aims to provide a preparation method of the powder base solution, which is simple in process and convenient to operate.
One of the purposes of the invention is realized by adopting the following technical scheme:
a water-in-oil type emulsion composition comprises oil, an emulsifier, an oil phase thickener and an aqueous phase thickener, wherein the weight ratio of the oil to the emulsifier to the oil phase thickener to the aqueous phase thickener is (5-13): (2.5-5): (0.4-2): (0.75-2.6); the oils include isononyl isononanoate, polyglycerol-2 triisostearate and cetyl ethyl hexanoate; the emulsifier comprises cetyl PEG/PPG-10/1 polydimethylsiloxane, PEG-10 polydimethylsiloxane and polyglycerol-3 diisostearate; the oil phase thickener comprises disteardimonium hectorite and magnesium stearate; the aqueous phase thickener comprises sodium magnesium lithium silicate and tetrasodium pyrophosphate.
In a water-in-oil emulsion system, viscosity reduction and demulsification often occur, and the stability of the system can be influenced by the collocation of grease, the selection of an emulsifier, and the selection of an oil phase thickener and a water phase thickener. The invention adopts isononyl isononanoate, polyglycerol-2 triisostearate and cetyl ethyl hexanoate to form a reasonable grease system, and is matched with cetyl PEG/PPG-10/1 polydimethylsiloxane, PEG-10 polydimethylsiloxane and polyglycerol-3 diisostearate as emulsifying agents, so that the water phase can be uniformly dispersed into the oil phase to form a completely dispersed emulsion. Meanwhile, disteardimonium hectorite and magnesium stearate are selected as oil phase thickeners, sodium magnesium lithium silicate and tetrasodium pyrophosphate are selected as water phase thickeners, and the phenomena of viscosity reduction and layering of the system can be further prevented.
Further, the grease comprises 2-5 parts of isononyl isononanoate, 2-5 parts of polyglycerol-2 triisostearate and 1-3 parts of cetyl alcohol ethyl hexanoate; the emulsifier comprises 1-2 parts of cetyl PEG/PPG-10/1 polydimethylsiloxane, 1-2 parts of PEG-10 polydimethylsiloxane and 0.5-1 part of polyglycerol-3 diisostearate; the oil phase thickener comprises 0.2-1 part of disteardimonium hectorite and 0.2-1 part of magnesium stearate; the water phase thickener comprises 0.2-0.6 part of sodium magnesium lithium silicate, 0.05-0.5 part of tetrasodium pyrophosphate and 0.5-1.5 part of sodium chloride. The invention ensures that the stability of an emulsifying system reaches the optimal state by reasonably setting the dosages of each component in the grease, the emulsifying agent, the oil phase thickening agent and the water phase thickening agent, and the layering condition can not occur even if the emulsifying system is placed for one year at normal temperature.
Further, the grease comprises 3 parts of isononyl isononanoate, 3 parts of polyglycerol-2 triisostearate and 2 parts of cetyl ethyl hexanoate; the emulsifier comprises 1.5 parts of cetyl PEG/PPG-10/1 polydimethylsiloxane, 1.5 parts of PEG-10 polydimethylsiloxane and 0.8 part of polyglycerol-3 diisostearate; the oil phase thickener comprises 0.6 part of disteardimonium hectorite and 0.7 part of magnesium stearate; the aqueous phase thickener comprises 0.4 part of sodium magnesium lithium silicate, 0.25 part of tetrasodium pyrophosphate and 1 part of sodium chloride.
The second purpose of the invention is realized by adopting the following technical scheme:
the invention also provides application of the water-in-oil type emulsified composition in skin care products. The skin care products include, but are not limited to, foundation, concealer, lip gloss, make-up remover, facial cleanser, skin lotion, skin cream, essence, and the like.
The invention also provides a foundation liquid, which comprises the water-in-oil type emulsified composition as one of the purposes, wherein the weight percentage of the water-in-oil type emulsified composition in the foundation liquid is 5-35%.
Further, the foundation liquid also comprises 30-50 parts of water; 22-42 parts of an emollient; 1-3 parts of film forming agent; 0.05-0.1 part of antioxidant; 7-15 parts of a colorant; 0.4-2 parts of preservative.
Further, the emollients include cyclopentadimethicone, glycerin, dimethicone, propylene glycol, phenyl trimethicone, and tocopherols.
The foundation liquid adopts the water-soluble emollient and the oil-soluble emollient simultaneously, so that the foundation liquid can moisten skin better, avoid skin dryness and ensure fresh and non-sticky skin feel. The cyclopentadimethicone gives soft and silky feel to the skin, has good compatibility with the rest ingredients in the formula, and ensures that the foundation liquid has good spreadability. The polydimethylsiloxane can improve spreadability of the foundation liquid, endow the skin with soft and silky feeling, and simultaneously play a certain waterproof effect. Phenyl trimethyl silicone can increase the softness of the foundation liquid, and simultaneously, the product is fresh and easy to paint and is not sticky. Propylene glycol is a small molecular moisturizing component, can lock moisture to play a role in moisturizing, and can promote the skin to absorb other functional components.
Further, the film forming agent includes trimethylsiloxysilicate, which is water resistant and is fresh and non-tacky.
Further, the antioxidant comprises pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate), and the pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate) can eliminate free radicals, has an antioxidant effect, can prevent aging, and reduces the damage of color cosmetics to skin.
Further, the colorant includes toner; still further, the colorant comprises a first toner and a second toner, wherein the first toner can be CI 77891, which is titanium dioxide white powder, titanium dioxide is inert mineral, and has good safety and no anaphylactic reaction; the second toner may be selected from chromium oxide, iron oxide, etc., and the specific toner is selected according to the color system of the foundation.
Further, the preservative includes p-hydroxyacetophenone and 1, 2-hexanediol. The p-hydroxyacetophenone has the effects of corrosion prevention and synergism, can promote the efficacy of various preservatives, has excellent stability in the high-low pH and temperature ranges, and has good compatibility with the rest components in the powder base liquid. The 1, 2-hexanediol has antibacterial effect and can provide certain moisturizing effect.
Further, the foundation liquid comprises the following components in parts by weight: solvent: 30-50 parts of water;
an emollient: 8-12 parts of cyclopenta-dimethicone, 6-10 parts of glycerin, 3-8 parts of dimethicone, 3-6 parts of propylene glycol, 2-5 parts of phenyl-trimethicone and 0.05-0.5 part of tocopherol;
oil and fat: 2-5 parts of isononyl isononanoate, 2-5 parts of polyglycerol-2 triisostearate and 1-3 parts of cetyl alcohol ethyl hexanoate;
emulsifying agent: 1-2 parts of cetyl PEG/PPG-10/1 polydimethylsiloxane, 1-2 parts of PEG-10 polydimethylsiloxane and 0.5-1 part of polyglycerol-3 diisostearate;
and (3) a thickening agent: 0.2-1 part of distearyl dimethyl ammonium hectorite, 0.2-1 part of magnesium stearate, 0.2-0.6 part of sodium magnesium lithium silicate, 0.05-0.5 part of tetrasodium pyrophosphate and 0.5-1.5 part of sodium chloride;
film forming agent: 1-3 parts of trimethylsiloxysilicate;
an antioxidant; 0.05-0.1 part of pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate);
coloring agent: 7-15 parts of toner;
preservative: 0.2-1 part of p-hydroxyacetophenone and 0.2-1 part of 1, 2-hexanediol.
The third purpose of the invention is realized by adopting the following technical scheme:
a preparation method of a powder base solution comprises the following steps:
1) Mixing a formula amount of a colorant, distearyl dimethyl ammonium hectorite, cyclopenta-dimethicone, polyglycerol-3 diisostearate and dimethicone, and uniformly grinding by using three rollers to obtain a first mixture;
2) Adding isononyl isononanoate, phenyl trimethicone, polyglycerol-2 triisostearate, trimethylsiloxysilicate, cetyl ethyl hexanoate, cetyl PEG/PPG-10/1 polydimethylsiloxane, PEG-10 polydimethylsiloxane, magnesium stearate, tocopherol, pentaerythritol tetra (bis-tert-butyl hydroxy hydrocinnamate) and the first mixture into an emulsifying main pot together, heating to 80-95 ℃ and uniformly stirring;
3) Mixing water, glycerol, propylene glycol, sodium magnesium lithium silicate, tetrasodium pyrophosphate and sodium chloride according to the formula amount, uniformly stirring, and heating to 80-95 ℃ to obtain a second mixture;
4) Adding the second mixture into the emulsifying main pot, homogenizing for 3-5 minutes, cooling to below 50 ℃, and adding preservative with the formula amount to obtain the emulsion; if the formulation components contain a fragrance, the formulation amount of preservative is added along with the fragrance.
Compared with the prior art, the invention has the beneficial effects that:
(1) The water-in-oil type emulsion composition provided by the invention consists of oil and fat, an emulsifying agent, an oil phase thickening agent and an aqueous phase thickening agent in specific proportions and specific components, is suitable for a water-in-oil system, and has the advantages that the foundation liquid containing the water-in-oil type emulsion composition is free from layering phenomenon after being placed for one year at normal temperature, and has high stability.
(2) The foundation liquid provided by the invention has good stability, is moist, fresh, not greasy and good in skin feel.
(3) The preparation method of the powder base liquid provided by the invention has the advantages of simple preparation process, simplicity and convenience in operation and easiness in realization of industrial production.
Drawings
FIG. 1 is a photograph showing the powder base solution of examples 1 to 5 of the present invention after being tested at a high temperature of 50 ℃;
FIG. 2 is a photograph of the powder base solutions of comparative examples 1 to 6 of the present invention after high temperature test at 50 ℃.
Detailed Description
The present invention will be further described with reference to the accompanying drawings and detailed description, wherein it is to be understood that, on the premise of no conflict, the following embodiments or technical features may be arbitrarily combined to form new embodiments. The raw materials, equipment, etc. used in the following examples are available in a purchase manner except for special restrictions.
Examples 1 to 5
A powder base liquid is prepared from water, cyclopentadimethicone, glycerol, polydimethylsiloxane, propylene glycol, phenyl trimethicone, tocopherol, isononyl isononanoate, polyglycerol-2 triisostearate, cetyl ethyl hexanoate, cetyl PEG/PPG-10/1 polydimethylsiloxane, PEG-10 polydimethylsiloxane, polyglycerol-3 diisostearate, distearyldimonium hectorite, magnesium stearate, sodium magnesium lithium silicate, tetrasodium pyrophosphate, sodium chloride, trimethylsiloxysilicate, pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate), toner, p-hydroxyacetophenone, 1, 2-hexanediol and essence, and the weight ratio of oil, emulsifier, oil phase thickener and aqueous phase thickener is (5-13): (2.5-5): (0.4-2): (0.75-2.6). The specific formulation is shown in Table 1 below, and the amounts in the formulation represent parts by weight.
Table 1 table of formulations of examples 1-5 base fluids
The foundation solutions of examples 1-5 were prepared as follows:
1) Mixing a formula amount of a colorant, distearyl dimethyl ammonium hectorite, cyclopenta-dimethicone, polyglycerol-3 diisostearate and dimethicone, and uniformly grinding by using three rollers to obtain a first mixture;
2) Isononyl isononanoate, phenyl trimethicone, polyglycerol-2 triisostearate, trimethylsiloxysilicate, cetyl ethyl hexanoate, cetyl PEG/PPG-10/1 polydimethylsiloxane, PEG-10 polydimethylsiloxane, magnesium stearate, tocopherol, pentaerythritol tetra (bis-tert-butylhydroxyhydrocinnamate) and the first mixture are added into an emulsifying main pot together, and the temperature is raised to 90 ℃ and the mixture is stirred uniformly;
3) Mixing water, glycerol, propylene glycol, sodium magnesium lithium silicate, tetrasodium pyrophosphate and sodium chloride according to the formula amount, uniformly stirring, and heating to 90 ℃ to obtain a second mixture;
4) Adding the second mixture into the emulsifying main pot, homogenizing for 4 min, cooling to 45deg.C, and adding antiseptic and flavoring agent.
Comparative example 1
Comparative example 1 differs from example 1 in that: sodium magnesium lithium silicate and tetrasodium pyrophosphate in the aqueous phase thickener were omitted, and the remainder was the same as in example 1.
Comparative example 2
Comparative example 2 is different from example 1 in that: the oil phase thickener was replaced with distearyldimethylammonium hectorite and magnesium stearate, and replaced with sodium acrylate/sodium acryloyldimethyltaurate copolymer (and isohexadecane (and) polysorbate-80 in an amount of 1.4 parts.
Comparative example 3
Comparative example 3 is different from example 1 in that: the oils and fats in example 1 were changed, and cetyl ethyl hexanoate was replaced with coco-caprylate/caprate, and the rest was the same as in example 1.
Comparative example 4
Comparative example 4 differs from example 1 in that: the emulsifiers of example 1 were changed and cetyl PEG/PPG-10/1 polydimethylsiloxane was replaced with cetostearyl alcohol (and) coco glucoside, the remainder being identical to example 1.
Comparative example 5
Comparative example 5 is different from example 1 in that: the emollient of example 1 was changed to replace cyclopentadimethicone with C15-19 alkyl, phenyl trimethicone with trifluoropropyl dimethicone, and the remainder was the same as in example 1.
Comparative example 6
Comparative example 6 differs from example 1 in that: the weight ratio of the oil, the emulsifier, the oil phase thickener and the water phase thickener is adjusted to be 15:6:1.4:1.7, see Table 2 for details.
Effect verification
1. Stability test
Room temperature placing experiment, 100ml of the foundation solutions obtained in comparative examples 1-6 and examples 1-5 are respectively taken and respectively placed in transparent glass bottles, and each sample is placed for 3 times in parallel under the condition of keeping away from light at room temperature for one year. Samples were taken separately and observed for stability of the formulation at a high temperature of 50℃and 100ml of each sample was run in 3 replicates and left for 3 months. The results are recorded in tables 3 and 4 below.
Table 3 examples 1-5 stability test results record table
Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | |
Standing at room temperature | Non-layering | Non-layering | Non-layering | Non-layering | Non-layering |
High temperature of 50 DEG C | Non-layering | Non-layering | Non-layering | Non-layering | Non-layering |
Table 4 comparative examples 1-6 stability test results record table
Comparative example 1 | Comparative example 2 | ComparisonExample 3 | Comparative example 4 | Comparative example 5 | Comparative example 6 | |
Standing at room temperature | Layering | Layering | Layering | Layering | Non-layering | Layering |
High temperature of 50 DEG C | Layering | Layering | Layering | Layering | Non-layering | Layering |
From tables 3 to 4 above, it is apparent that the foundation solutions of examples 1 to 5 pass the stability test under both test conditions, and the compositions or proportions of the oils and fats, the emulsifier, the oil phase thickener or the aqueous phase thickener in comparative examples 1 to 4 and comparative example 6 are changed, and the foundation solutions are layered.
As shown in FIG. 1, in the examples 1 to 5, the powder base liquid was tested at a high temperature of 50℃for 3 months, and the examples 1 to 5 were free from delamination and oil production, and had high stability.
As shown in FIG. 2, in the pictures of the foundation solutions of comparative examples 1 to 6 after 3 months of high temperature test at 50 ℃, the layering and oil discharge phenomena of comparative examples 1 to 4 and comparative example 6 occur, and the foundation solution has poor documentability.
In summary, it is important to demonstrate that the invention rationally sets the proportions and specific ingredients of the oils and fats, emulsifiers, oil phase thickeners, and aqueous phase thickeners. In the embodiment of the invention, isononyl isononanoate, polyglycerol-2 triisostearate and cetyl ethyl hexanoate are adopted to form a reasonable grease system, and cetyl PEG/PPG-10/1 polydimethylsiloxane, PEG-10 polydimethylsiloxane and polyglycerol-3 diisostearate are matched as emulsifying agents, so that the water phase can be uniformly dispersed into the oil phase to form a completely dispersed emulsion. Meanwhile, disteardimonium hectorite and magnesium stearate are selected as oil phase thickeners, sodium magnesium lithium silicate and tetrasodium pyrophosphate are selected as water phase thickeners, and the phenomena of viscosity reduction and layering of the system can be further prevented. And, the weight ratio of the oils and fats, the emulsifier, the oil phase thickener and the water phase thickener of examples 1 to 5 is set at (5 to 13): (2.5-5): (0.4-2): (0.75-2.6) to ensure that the powder base liquid is stable and does not delaminate.
2. Trial test for volunteers
Selecting 110 female volunteers with mixed skin, wherein the ages are 25-30 years, and the female volunteers are equally divided into 11 groups of 10 persons, wherein each group of volunteers respectively test the foundation liquids of examples 1-5 and comparative examples 1-6, and after the skin care is carried out by adopting the same skin care product according to the same flow, the corresponding foundation liquids are tested according to the conventional cosmetic flow, and the indexes of the test comprise: the skin feel and make-up effect of the product are shown in Table 5 below (the test results are the average of 10 volunteers). The evaluation method and the index of the test index are respectively as follows:
skin feel of the product: the skin feel of volunteers when using the foundation liquid comprises the feel of sliminess, skin pasting degree, refreshing degree, sticky feel, spreading uniformity and the like, the score is between 1 and 10, and the higher the score is, the better the skin feel of the product is;
make-up effect: the makeup holding test time is 4 hours, the makeup effect is natural and durable, the closer the makeup is to the makeup just made up, the better the makeup holding effect is, the score is between 1 and 10, the higher the score is, and the better the makeup holding effect is.
TABLE 5 volunteer trial results record Table
As can be seen from the records in Table 5, the foundation liquids of examples 1 to 5 were superior to the comparative examples in both the skin feel and the makeup-holding effect, and the foundation liquids were fresh and non-greasy, good in skin feel and long in makeup holding time. Comparative example 5 replaces the type of emollient, has poor skin feel, and volunteers feedback poor spreadability, and has a sticky feel. In comparative examples 1 to 4 and comparative example 6, the components or proportions of the oil-based, the emulsifier, the oil-based and the water-based thickeners were changed, so that the skin feel and the make-up holding effect of the foundation liquid were greatly reduced, which indicates that it is important to reasonably set the proportions and specific components of the oil-based, the emulsifier, the oil-based and the water-based thickeners.
The above embodiments are only preferred embodiments of the present invention, and the scope of the present invention is not limited thereto, but any insubstantial changes and substitutions made by those skilled in the art on the basis of the present invention are intended to be within the scope of the present invention as claimed.
Claims (4)
1. The foundation liquid is characterized by comprising the following components in parts by weight: solvent: 30-50 parts of water;
an emollient: 8-12 parts of cyclopenta-dimethicone, 6-10 parts of glycerin, 3-8 parts of dimethicone, 3-6 parts of propylene glycol, 2-5 parts of phenyl-trimethicone and 0.05-0.5 part of tocopherol;
oil and fat: 2-5 parts of isononyl isononanoate, 2-5 parts of polyglycerol-2 triisostearate and 1-3 parts of cetyl alcohol ethyl hexanoate;
emulsifying agent: 1-2 parts of cetyl PEG/PPG-10/1 polydimethylsiloxane, 1-2 parts of PEG-10 polydimethylsiloxane and 0.5-1 part of polyglycerol-3 diisostearate;
and (3) a thickening agent: 0.2-1 part of distearyl dimethyl ammonium hectorite, 0.2-1 part of magnesium stearate, 0.2-0.6 part of sodium magnesium lithium silicate, 0.05-0.5 part of tetrasodium pyrophosphate and 0.5-1.5 part of sodium chloride;
film forming agent: 1-3 parts of trimethylsiloxysilicate;
an antioxidant; 0.05-0.1 part of pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate);
coloring agent: 7-15 parts of toner;
preservative: 0.2-1 part of p-hydroxyacetophenone and 0.2-1 part of 1, 2-hexanediol.
2. The powder base liquid according to claim 1, comprising the following components in parts by weight: solvent: 35-45 parts of water;
an emollient: 9-11 parts of cyclopentadimethicone, 7-9 parts of glycerol, 4-7 parts of dimethicone, 4-5 parts of propylene glycol, 3-4 parts of phenyl trimethicone and 0.1-0.4 part of tocopherol;
oil and fat: 3-4 parts of isononyl isononanoate, 3-4 parts of polyglycerol-2 triisostearate and 1.5-2.5 parts of cetyl alcohol ethyl hexanoate;
emulsifying agent: 1.5-2 parts of cetyl PEG/PPG-10/1 polydimethylsiloxane, 1.5-2 parts of PEG-10 polydimethylsiloxane and 0.6-0.8 part of polyglycerol-3 diisostearate;
and (3) a thickening agent: 0.4-0.8 part of disteardimonium hectorite, 0.4-0.8 part of magnesium stearate, 0.3-0.5 part of sodium magnesium lithium silicate, 0.1-0.4 part of tetrasodium pyrophosphate and 0.8-1.2 part of sodium chloride;
film forming agent: 1.5-2.5 parts of trimethylsiloxysilicate;
an antioxidant; 0.06-0.09 parts of pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate);
coloring agent: 1-3 parts of first color powder; 6-12 parts of second toner;
preservative: 0.4-0.8 part of p-hydroxyacetophenone, 0.4-0.8 part of 1, 2-hexanediol;
a flavoring agent: 0.05-0.2 part of essence.
3. The powder base liquid according to claim 1, comprising the following components in parts by weight: solvent: 40 parts of water;
an emollient: 10 parts of cyclopentadimethicone, 8 parts of glycerin, 5 parts of dimethicone, 4 parts of propylene glycol, 3.5 parts of phenyl trimethicone and 0.25 part of tocopherol;
oil and fat: 3.5 parts of isononyl isononanoate, 3.5 parts of polyglycerol-2 triisostearate and 2 parts of cetyl alcohol ethyl hexanoate;
emulsifying agent: 1.5 parts of cetyl PEG/PPG-10/1 polydimethylsiloxane, 1.5 parts of PEG-10 polydimethylsiloxane and 0.8 part of polyglycerol-3 diisostearate;
and (3) a thickening agent: 0.7 part of disteardimonium hectorite, 0.7 part of magnesium stearate, 0.4 part of sodium magnesium lithium silicate, 0.3 part of tetrasodium pyrophosphate and 1 part of sodium chloride;
film forming agent: 2 parts of trimethylsiloxysilicate;
an antioxidant; pentaerythritol tetrakis (bis-tert-butylhydroxyhydrocinnamate) 0.07 parts;
coloring agent: 12 parts of toner;
preservative: 0.7 part of p-hydroxyacetophenone and 0.7 part of 1, 2-hexanediol;
a flavoring agent: 0.1 part of essence.
4. A process for preparing a powder base solution according to any one of claims 1 to 3, comprising the steps of:
1) Mixing a formula amount of a colorant, distearyl dimethyl ammonium hectorite, cyclopenta-dimethicone, polyglycerol-3 diisostearate and dimethicone, and uniformly grinding by using three rollers to obtain a first mixture;
2) Adding isononyl isononanoate, phenyl trimethicone, polyglycerol-2 triisostearate, trimethylsiloxysilicate, cetyl ethyl hexanoate, cetyl PEG/PPG-10/1 polydimethylsiloxane, PEG-10 polydimethylsiloxane, magnesium stearate, tocopherol, pentaerythritol tetra (bis-tert-butyl hydroxy hydrocinnamate) and the first mixture into an emulsifying main pot together, heating to 80-95 ℃ and uniformly stirring;
3) Mixing water, glycerol, propylene glycol, sodium magnesium lithium silicate, tetrasodium pyrophosphate and sodium chloride according to the formula amount, uniformly stirring, and heating to 80-95 ℃ to obtain a second mixture;
4) Adding the second mixture into the emulsifying main pot, homogenizing for 3-5 minutes, cooling to below 50 ℃, and adding preservative with the formula amount to obtain the emulsion; if the formulation components contain a fragrance, the formulation amount of preservative is added along with the fragrance.
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CN115040437B (en) * | 2022-05-31 | 2024-03-22 | 彭氏(惠州)实业发展有限公司 | Cosmetic composition in the form of an O/W emulsion |
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