CN101691588B - 一种制备双甘膦的清洁生产方法 - Google Patents
一种制备双甘膦的清洁生产方法 Download PDFInfo
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- CN101691588B CN101691588B CN 200910019234 CN200910019234A CN101691588B CN 101691588 B CN101691588 B CN 101691588B CN 200910019234 CN200910019234 CN 200910019234 CN 200910019234 A CN200910019234 A CN 200910019234A CN 101691588 B CN101691588 B CN 101691588B
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- pmida98
- iminodiacetic acid
- effect evaporation
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- phosphonomethyl
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- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000007788 liquid Substances 0.000 claims abstract description 31
- BSRDNMMLQYNQQD-UHFFFAOYSA-N iminodiacetonitrile Chemical compound N#CCNCC#N BSRDNMMLQYNQQD-UHFFFAOYSA-N 0.000 claims abstract description 23
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- 230000015572 biosynthetic process Effects 0.000 abstract description 2
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- 238000011084 recovery Methods 0.000 abstract 1
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- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 5
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- JQWHASGSAFIOCM-UHFFFAOYSA-M sodium periodate Chemical compound [Na+].[O-]I(=O)(=O)=O JQWHASGSAFIOCM-UHFFFAOYSA-M 0.000 description 2
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- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- ACEHCECZNDUPHO-UHFFFAOYSA-N N(CC(=O)O)CC(=O)O.N(CC#N)CC#N Chemical compound N(CC(=O)O)CC(=O)O.N(CC#N)CC#N ACEHCECZNDUPHO-UHFFFAOYSA-N 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- -1 alkali metal salts Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
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- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 244000037671 genetically modified crops Species 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- 238000010641 nitrile hydrolysis reaction Methods 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009418 renovation Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 108010046845 tryptones Proteins 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
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- Separation Using Semi-Permeable Membranes (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
Description
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CN 200910019234 CN101691588B (zh) | 2009-10-13 | 2009-10-13 | 一种制备双甘膦的清洁生产方法 |
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CN 200910019234 CN101691588B (zh) | 2009-10-13 | 2009-10-13 | 一种制备双甘膦的清洁生产方法 |
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CN101691588A CN101691588A (zh) | 2010-04-07 |
CN101691588B true CN101691588B (zh) | 2011-10-05 |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1916005A (zh) * | 2006-09-08 | 2007-02-21 | 四川贝尔实业有限责任公司 | 亚氨基二乙腈水解制备双甘膦的方法 |
CN101307073A (zh) * | 2008-05-29 | 2008-11-19 | 山东潍坊润丰化工有限公司 | 一种减少双甘膦废水并降低废水含盐量的方法 |
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2009
- 2009-10-13 CN CN 200910019234 patent/CN101691588B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1916005A (zh) * | 2006-09-08 | 2007-02-21 | 四川贝尔实业有限责任公司 | 亚氨基二乙腈水解制备双甘膦的方法 |
CN101307073A (zh) * | 2008-05-29 | 2008-11-19 | 山东潍坊润丰化工有限公司 | 一种减少双甘膦废水并降低废水含盐量的方法 |
Non-Patent Citations (2)
Title |
---|
Hui Luo et al.Gene Cloning, Overexpression, and Characterization of the Nitrilase from Rhodococcus rhodochrous tg1-A6 in E.coli.《Appl Biochem Biotechnol》.2008,第160卷393–400. * |
林志坚等.草甘膦化学合成工艺及其中间体的生物法合成技术展望.《农药》.2009,第48卷(第8期),547-551. * |
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Address after: Haiyuan Binhai Economic Development Zone, Shandong province Weifang city 262737 Street No. 600 Patentee after: Shandong Weifang Rainbow Chemical Co., Ltd. Patentee after: Shandong Herbicides Engineering Research Center Address before: 250101 Shandong city of Ji'nan province high tech Zone (Lixia District Shunhua Road No. 750) hi tech innovation service center room A-303 Patentee before: Shandong Weifang Rainbow Chemical Co., Ltd. Patentee before: Shandong Herbicides Engineering Research Center Address after: Haiyuan Binhai Economic Development Zone, Shandong province Weifang city 262737 Street No. 600 Patentee after: Shandong Weifang Rainbow Chemical Co., Ltd. Patentee after: Shandong Herbicides Engineering Research Center Address before: 250101 Shandong city of Ji'nan province high tech Zone (Lixia District Shunhua Road No. 750) hi tech innovation service center room A-303 Patentee before: Shandong Weifang Rainbow Chemical Co., Ltd. Patentee before: Shandong Herbicides Engineering Research Center |
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Address after: No. 03001, chlor alkali Road, Weifang Coastal Economic Development Zone, Shandong, Shandong Co-patentee after: SHANDONG RESEARCH CENTER OF HERBICIDES ENGINEERING TECHNOLOGY Patentee after: Shandong Weifang Rainbow Chemical Co.,Ltd. Address before: Haiyuan Binhai Economic Development Zone, Shandong province Weifang city 262737 Street No. 600 Co-patentee before: SHANDONG RESEARCH CENTER OF HERBICIDES ENGINEERING TECHNOLOGY Patentee before: Shandong Weifang Rainbow Chemical Co.,Ltd. |
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