CN101687956B - 用于纸材的两性含氟化合物 - Google Patents

用于纸材的两性含氟化合物 Download PDF

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Publication number
CN101687956B
CN101687956B CN200880023960.2A CN200880023960A CN101687956B CN 101687956 B CN101687956 B CN 101687956B CN 200880023960 A CN200880023960 A CN 200880023960A CN 101687956 B CN101687956 B CN 101687956B
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CN
China
Prior art keywords
formula
monomer
approximately
mixture
multipolymer
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN200880023960.2A
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English (en)
Chinese (zh)
Other versions
CN101687956A (zh
Inventor
H·黄
M·J·-J·帕邦
R·塞韦拉克
L·霍伊策
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EIDP Inc
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EI Du Pont de Nemours and Co
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Publication date
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Priority to CN201310108457.XA priority Critical patent/CN103224585B/zh
Publication of CN101687956A publication Critical patent/CN101687956A/zh
Application granted granted Critical
Publication of CN101687956B publication Critical patent/CN101687956B/zh
Expired - Fee Related legal-status Critical Current
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/18Homopolymers or copolymers of nitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/22Esters containing halogen
    • C08F220/24Esters containing halogen containing perhaloalkyl radicals
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04Acids; Metal salts or ammonium salts thereof
    • C08F220/06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/34Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03Non-macromolecular organic compounds
    • D21H17/05Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/11Halides
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16Sizing or water-repelling agents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/3188Next to cellulosic
    • Y10T428/31895Paper or wood
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2279Coating or impregnation improves soil repellency, soil release, or anti- soil redeposition qualities of fabric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2279Coating or impregnation improves soil repellency, soil release, or anti- soil redeposition qualities of fabric
    • Y10T442/2287Fluorocarbon containing

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paper (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
CN200880023960.2A 2007-07-10 2008-06-23 用于纸材的两性含氟化合物 Expired - Fee Related CN101687956B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310108457.XA CN103224585B (zh) 2007-07-10 2008-06-23 向挠性纤维质非织造基底赋予表面效果的方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/827,006 2007-07-10
US11/827,006 US8071489B2 (en) 2007-07-10 2007-07-10 Amphoteric fluorochemicals for paper
PCT/US2008/067828 WO2009009280A1 (en) 2007-07-10 2008-06-23 Amphoteric fluorochemicals for paper

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201310108457.XA Division CN103224585B (zh) 2007-07-10 2008-06-23 向挠性纤维质非织造基底赋予表面效果的方法

Publications (2)

Publication Number Publication Date
CN101687956A CN101687956A (zh) 2010-03-31
CN101687956B true CN101687956B (zh) 2014-03-12

Family

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Family Applications (2)

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CN201310108457.XA Expired - Fee Related CN103224585B (zh) 2007-07-10 2008-06-23 向挠性纤维质非织造基底赋予表面效果的方法
CN200880023960.2A Expired - Fee Related CN101687956B (zh) 2007-07-10 2008-06-23 用于纸材的两性含氟化合物

Family Applications Before (1)

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Country Status (7)

Country Link
US (1) US8071489B2 (enExample)
EP (2) EP2532690A1 (enExample)
JP (2) JP5424495B2 (enExample)
CN (2) CN103224585B (enExample)
AU (1) AU2008275400B2 (enExample)
CA (1) CA2688152C (enExample)
WO (1) WO2009009280A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120016070A1 (en) * 2009-03-25 2012-01-19 Daikin Industries Ltd. Surfactant comprising fluorine-containing polymer
US9540470B2 (en) * 2009-08-18 2017-01-10 Daikin Industries, Ltd. Copolymer, treatment agent for paper, and treated paper
KR101728576B1 (ko) 2009-11-13 2017-04-19 아사히 가라스 가부시키가이샤 내수 내유제 조성물, 이것으로 처리된 물품 및 이들의 제조 방법
CA2802229C (en) * 2010-06-29 2019-01-29 Surmodics, Inc. Fluorinated polymers and lubricious coatings
US9777170B2 (en) * 2014-02-25 2017-10-03 The Chemours Company Tt, Llc Fluorinated polymer additives derived using hydrophilic chain transfer agents for architectural coatings
JP6578285B2 (ja) 2014-08-19 2019-09-18 株式会社クラレ 紙複合体、包装材料及び紙複合体の製造方法
JP6645971B2 (ja) * 2014-09-02 2020-02-14 国立大学法人九州大学 含フッ素高分岐ポリマー及び生体分子吸着抑制表面
CN111433409B (zh) * 2017-12-18 2022-03-29 Agc株式会社 纸用耐水耐油剂组合物及其制造方法、以及耐水耐油纸及其制造方法
CN111040072B (zh) * 2019-11-27 2022-07-19 广州熵能创新材料股份有限公司 乙烯基系含氟共聚物、含有该乙烯基系含氟共聚物的防水防油组合物及其应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5919527A (en) * 1996-04-12 1999-07-06 E. I. Du Pont De Nemours And Company Waterbourne fluoropolymer solutions for treating hard surfaces
CN1222166A (zh) * 1996-04-12 1999-07-07 纳幕尔杜邦公司 用氟化学品共聚物处理的耐油、耐水和耐溶剂的纸
CN1309673A (zh) * 1998-06-19 2001-08-22 纳幕尔杜邦公司 用于织物去污的聚合物组合物

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1400038A (fr) 1963-07-16 1965-05-21 Colgate Palmolive Co Produit pour le traitement des textiles et procédé pour son application
US3758543A (en) * 1967-04-25 1973-09-11 Allied Chem Novel sulfates and method for their preparation
CH927769D (enExample) * 1968-07-01 1900-01-01
BE787405A (fr) 1971-08-11 1973-02-12 Blochl Walter Esters acryliques contenant des groupes perfluoroalkyles et leurs polymerisats
JPS5218791B2 (enExample) 1972-09-07 1977-05-24
US3843579A (en) * 1973-01-31 1974-10-22 Du Pont Water in oil fluoropolymer emulsion containing hydrocarbon or halogenated hydrocarbon solvent
US4147851A (en) * 1978-06-13 1979-04-03 E. I. Du Pont De Nemours And Company Fluorine-containing oil- and water-repellant copolymers
FR2476097A1 (enExample) * 1980-02-19 1981-08-21 Ugine Kuhlmann
JPS58220894A (ja) 1982-06-15 1983-12-22 大日本インキ化学工業株式会社 紙用処理剤
US4582882A (en) * 1982-10-13 1986-04-15 Minnesota Mining And Manufacturing Company Fluorochemical copolymers and ovenable paperboard and textile fibers treated therewith
US4595518A (en) * 1985-07-10 1986-06-17 E. I. Du Pont De Nemours And Company Coating fibrous substrates with fluoropolymer amphoteric polymer and surfactants
FR2588555B1 (fr) * 1985-10-16 1987-12-11 Atochem Monomeres acryliques fluores, polymeres en derivant et leur application au traitement hydrofuge et oleofuge de substrats divers
US5010141A (en) * 1989-10-25 1991-04-23 Ciba-Geigy Corporation Reactive silicone and/or fluorine containing hydrophilic prepolymers and polymers thereof
FR2683535B1 (fr) * 1991-11-12 1994-10-28 Atochem Nouveaux copolymeres fluores et leur utilisation pour le revetement et l'impregnation de substrats divers.
EP0701020A2 (de) * 1994-07-27 1996-03-13 Bayer Ag Öl- und wasserabweisende Papiere, Verfahren zu ihrer Herstellung und neue fluorhaltige Copolymerisate hierzu
CA2191229C (en) 1995-03-31 2006-10-10 Charles D. Huber Aqueous oil and water repellent compositions
FR2756290B1 (fr) * 1996-11-27 1998-12-31 Atochem Elf Sa Copolymeres fluores pour le traitement oleophobe et hydrophobe de substrats divers
FR2801890A1 (fr) * 1999-12-06 2001-06-08 Atofina Nouveaux copolymeres fluores pour le traitement hydrophobe et oleophobe de substrats divers
US6566470B2 (en) * 2000-04-14 2003-05-20 Ciba Specialty Chemicals Corporation Fluorinated polymeric paper sizes and soil-release agents
FR2812643B1 (fr) * 2000-08-07 2002-09-13 Atofina Nouveaux copolymeres fluores, leur utilisation pour le revetement et l'impregnation de substrats, et les substrats ainsi traites
US6699933B2 (en) * 2001-08-07 2004-03-02 Ppg Industries Ohio, Inc. Method of coating coils using a high solids fluorocarbon coating composition
CN1659197A (zh) 2002-06-13 2005-08-24 大金工业株式会社 共聚物、纸用处理剂以及加工纸
JP4752760B2 (ja) 2004-03-23 2011-08-17 旭硝子株式会社 耐水耐油剤組成物

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5919527A (en) * 1996-04-12 1999-07-06 E. I. Du Pont De Nemours And Company Waterbourne fluoropolymer solutions for treating hard surfaces
CN1222166A (zh) * 1996-04-12 1999-07-07 纳幕尔杜邦公司 用氟化学品共聚物处理的耐油、耐水和耐溶剂的纸
CN1309673A (zh) * 1998-06-19 2001-08-22 纳幕尔杜邦公司 用于织物去污的聚合物组合物

Also Published As

Publication number Publication date
JP5424495B2 (ja) 2014-02-26
JP2010533230A (ja) 2010-10-21
JP2014043667A (ja) 2014-03-13
EP2167553A1 (en) 2010-03-31
JP5892994B2 (ja) 2016-03-23
US20090017321A1 (en) 2009-01-15
CN103224585B (zh) 2016-03-30
CN101687956A (zh) 2010-03-31
AU2008275400A1 (en) 2009-01-15
CN103224585A (zh) 2013-07-31
HK1187936A1 (zh) 2014-04-17
CA2688152A1 (en) 2009-01-15
EP2532690A1 (en) 2012-12-12
CA2688152C (en) 2015-04-28
US8071489B2 (en) 2011-12-06
AU2008275400B2 (en) 2013-08-22
WO2009009280A1 (en) 2009-01-15

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