CN101658397A - Functional wipes containing chlorine dioxide and application thereof - Google Patents
Functional wipes containing chlorine dioxide and application thereof Download PDFInfo
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- CN101658397A CN101658397A CN200910091977A CN200910091977A CN101658397A CN 101658397 A CN101658397 A CN 101658397A CN 200910091977 A CN200910091977 A CN 200910091977A CN 200910091977 A CN200910091977 A CN 200910091977A CN 101658397 A CN101658397 A CN 101658397A
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Abstract
The invention discloses a functional wipes containing chlorine dioxide comprising a wipes carrier as well as functional composition and stabilizing agent capable of providing the chlorine dioxide. Thefunctional wipes containing the chlorine dioxide leads the functional composition of the chlorine dioxide in the wipes product to be effective and stable by adopting the components such as the stabilizing agent or stabilizing agent matching with sustained-release agent and the like, and can control the release speed of the chlorine dioxide so as to ensure the concentration of the apparent chlorine dioxide to be stable. The functional wipes containing the chlorine dioxide is high-efficiency, stable, innoxious and environment-friendly.
Description
Technical field
The present invention relates to a kind of functional wipes, especially relate to a kind of functional wipes and application thereof with cleaning, decontamination, sterilization and sterilizing use.
Background technology
Infection by diseases such as SARS and Influenza A H1N1s is popular, people's habits and customs and life idea have been subjected to very big impact, following viewpoint has obtained generally approval: 1, health concept: generally having accepted personal hygiene is to keep fit, and avoids the key of viral communication; 2, clean hand idea: generally having accepted hand hygiene is a basis that keeps personal health; 3, environmental protection ideas: generally accepted to keep environmental sanitation could effectively control the idea of transmission.In fact, increasing people has accepted and has brought into use sterile products.Yet the action time of traditional disinfectant is short, and effect is undesirable, chafe, and toxic and side effect is big, easily contaminated environment.Can't satisfy at traditional sterile products under the situation of increasingly serious safe and sanitary demand, be that the green sterile products of representative is just beginning to come into gradually people's the visual field with the chlorine dioxide, and probably derive a new industry-green sterilization industry thereupon.
Chlorine dioxide be generally acknowledge at present a kind of efficient, low toxicity, fast, wide spectrum the 4th generation the disinfecting disinfectant, classified as A1 level disinfectant with extremely strong sterilizing power, characteristic not carcinogenic, non-secondary pollution by The World Health Organization (WHO).As present optimal a kind of chemosterilant, chlorine dioxide has replaced aldehydes, phenols, quaternary ammonium disinfectant, by extensive use in the world.Through Environmental Protection Agency (EPA) and food and drug administration (FDA) approval, be used for sterilization, sterilization, deodorizing and industry, agricultural and the health care of food fresh keeping, processing, drinking water.Because of it has 100% sterilizing rate to bacterium, fungi, virus, gemma, be widely used in medical disinfecting abroad, especially in the field, oral cavity to the sterilization of sterilization, deodorizing and environment of gargling of sterilization, mildew-resistant, the oral cavity of medical material apparatus, but also do not apply in China.Under the chlorine dioxide normal temperature yellow green gas, good water solubility, but unstable volatilization easily can only be preserved very difficult long term storage 8 hours under the normal temperature.All disinfection agent of chlorine dioxide products all are chlorine dioxide precursor in fact on the domestic market, must now do existing usefulness through overactivation.
Summary of the invention
The technical problem to be solved in the present invention is to overcome problems of the prior art, provides a class to be the efficient of main functional component with chlorine dioxide, and is stable, nontoxic, the environmental protection function wet tissue.
A kind of functional wipes that contains chlorine dioxide, described wet tissue comprises wet tissue carrier, the functional component that chlorine dioxide can be provided and stabilizing agent.Described stabilizing agent is the compound that can make chlorine dioxide or chlorine dioxide matrix compound stable existence in the aqueous solution, comprises EDTA, carboxymethyl cellulose, sodium laurate, polyethylene glycol, cyclodextrin, glucan, chitin, glutinous polysaccharide, polyvinylpyrrolidone, acrylate copolymer, polyvinyl alcohol, APEO, the polyoxyethylene alcohol ester, fatty glyceride, lecithin, gelatin, agar, lanolin, melon and glue, sodium alginate, the N-alkyl pyrrolidone, sucrose ester, the glucoside ester, alanine, phosphotriester, betaine, saponin, in alkylolamides and the derivative thereof one or more.
Polyvinyl alcohol wherein, APEO, polyoxyethylene alcohol ester, fatty glyceride, lecithin, gelatin, agar, lanolin, melon and glue, sodium alginate, N-alkyl pyrrolidone, sucrose ester, glucoside ester, alanine, phosphotriester, betaine, saponin, alkylolamides and derivative thereof etc. are emulsifying agent commonly used, it promptly can be used as the stabilizing agent among the present invention, also can be used as emulsifying agent and uses.
The present invention is by adding described stabilizing agent, makes functional component chlorine dioxide in the wet tissue can be in product effectively stable and can control the rate of release of chlorine dioxide, makes apparent chlorine dioxide concentration stable.
Functional wipes of the present invention, the wherein said functional component that chlorine dioxide is provided are that aqueous solution of chlorine dioxide maybe can activate the parent compound that produces chlorine dioxide.
Functional wipes of the present invention, the wherein said parent compound that can activate the generation chlorine dioxide is stable ClO 2 solution or chlorite.
Functional wipes of the present invention, wherein said wet tissue also comprises sustained release agent.Described sustained release agent is to make the chlorine dioxide matrix compound slowly discharge the compound of chlorine dioxide, comprises in citric acid, tartaric acid, gluconic acid, sorbic acid, glycolic acid, the lactic acid one or more.The effect one that sustained release agent exists is to make the chlorine dioxide matrix compound activate, discharge chlorine dioxide lentamente under the condition that organic acid exists, the 2nd, can cooperate stabilizing agent to control the rate of release of chlorine dioxide better, make apparent chlorine dioxide concentration stable.
Functional wipes of the present invention, wherein said wet tissue also comprises pH value buffer and/or natural perfume material.
Further, wet tissue of the present invention preferably adopts by following method and makes:
Method one:
(1) prepares wet tissue carrier: 60cm
2-600cm
2
(2) preparation mixed liquor:
Aqueous solution of chlorine dioxide: 5-500ppm;
Stabilizing agent: 0.1-10 weight %;
PH value buffer: PH=4.5-7;
Natural perfume material: 0.001-1 weight %;
All the other are water.
(3) above-mentioned mixed liquor is sprayed on the wet tissue carrier every gram wet tissue carrier 2-6ml.
Method two:
(1) prepares wet tissue carrier: 60cm
2-600cm
2
(2) preparation mixed liquor:
Can activate the parent compound that produces chlorine dioxide: 0.005-1 weight %;
Stabilizing agent: 0.01-10 weight %;
Sustained release agent: 0.01-10 weight %;
PH value buffer: PH=4.5-7;
Natural perfume material: 0.001-1 weight %;
All the other are water.
(3) above-mentioned mixed liquor is sprayed on the wet tissue carrier every gram wet tissue carrier 2-6ml.
Method three:
(1) prepares wet tissue carrier: 60cm
2-600cm
2
(2) preparation mixed liquor:
Aqueous solution of chlorine dioxide: 5-500ppm;
Can activate the parent compound that produces chlorine dioxide: 0.005-1 weight %;
Stabilizing agent: 0.01-10 weight %;
Sustained release agent: 0.01-10 weight %;
PH value buffer: PH=4.5-7;
Natural perfume material: 0.001-1 weight %;
All the other are water.
Method four:
(1) prepares wet tissue carrier: 60cm
2-600cm
2
(2) preparation mixed liquor:
Stabilizing agent: 0.01-10 weight %;
Sustained release agent: 0.01-10 weight %;
PH value buffer: PH=4.5-7;
Natural perfume material: 0.001-1 weight %;
All the other are water.
(3) chlorine dioxide is passed in the mixed liquor, reaches 100-500ppm until the apparent chlorine dioxide concentration of mixed liquor.
(4) above-mentioned mixed liquor is sprayed on the wet tissue carrier every gram wet tissue carrier 2-6ml.
Above-mentioned functional wipes, wherein said pH value buffer are to make system pH maintain buffer or the combinations of buffers of 4.5-7.0.
Above-mentioned functional wipes, wherein said wet tissue carrier are spunlace non-woven cloth, weaving cloth or paper handkerchief.
Above-mentioned functional wipes, wherein said spunlace non-woven cloth is that thickness is 30g-80g/m
2, cotton content is the straight shop of 20-80% or tiltedly spreads nonwoven.
Above-mentioned functional wipes, wherein said weaving cloth are a kind of in the towelling of 20-80% of cotton or cotton content.
The purposes of above-mentioned functional wipes in the cleaning of article, decontamination, sterilization, sterilization.Described article comprise mobile phone, keyboard, mouse, refrigerator, dining table, kitchen tools, tableware, micro-wave oven, glasses, automobile, toilet, washing machine, fruit, vegetables or skin.Wherein, to the cleaning of article, decontamination, the sterilization and sterilization including, but not limited to mobile phone, keyboard, mouse, refrigerator, dining table, kitchen tools, tableware, micro-wave oven, article such as glasses; To the cleaning of fruit, sterilization, sterilization mainly is at the fruit exocuticle; Be used for skin and mainly comprise hand, face, the cleaning at positions such as foot, sterilization, sterilization; What be used for skin also comprises makeup removing, clean the moon, and it is smelly to dispel; The lavatory with and be used for virus or bacterial dermopathic sterilization, sterilization.
Except that mentioned component, wet tissue of the present invention can also comprise other functional component, and it can be regulated according to concrete function, the purposes of wet tissue, as comprises that aloe moisture-keeping becomes to grade.
Technical scheme of the present invention has following technique effect:
1, provides a kind of functional wipes that contains chlorine dioxide, it makes the chlorine dioxide functional component in the wet tissue product effectively stable by adopting compositions such as stabilizing agent or stabilizing agent cooperation sustained release agent, and can control the rate of release of chlorine dioxide, make apparent chlorine dioxide concentration stable.
2, it is unstable in product to adopt simple technological means to solve chlorine dioxide, or needs the difficult problem of complicated stable and release tech means when using in product, has enlarged the production application scope of product.
Description of drawings
Fig. 1 is the estimation of stability figure as a result of wet tissue of the present invention.
The specific embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described in further detail.Following examples are used to illustrate the present invention, but are not used for limiting the scope of the invention.
The present invention prepares wet tissue according to following steps:
1. form according to the prescription of product, each component is mixed, stir;
2. by product purpose standard cutting wet tissue carrier;
3. above-mentioned mixed liquor is sprayed on the wet tissue carrier, every gram wet tissue carrier 2-6ml, the wet tissue carrier after moistening is the functional paper handkerchief that contains chlorine dioxide.
4. the monolithic wet tissue is sealed with plastic packaging bag and be finished product.
Example one: the sterilizing handset wet tissue that contains chlorine dioxide
Wherein the mixed liquor composition is:
1), sodium chlorite: 0.28%
2), citric acid: 0.5%
3), carboxymethyl cellulose: 1.2%
4), phosphate buffer: pH=5.5,0.2mol/L
5), APG-decontamination factor: 4%
6), osmanthus flower fragrance: 0.001%-1%
7), antistatic reagent: 0.1%
All the other are water.
Example two: the glasses wet tissue that contains chlorine dioxide
Wherein the mixed liquor composition is:
1), sodium chlorite: 0.28%
2), citric acid: 0.5%
3), polyethylene glycol: 1.2%
4), phosphate buffer: pH=6.0,0.2mol/L
5), detergent: APG-decontamination factor: 4%
6), surfactant: cocoyl diglycollic amide: 5%
7), orange essence: 0.3%
8), antifoggant: turpentine oil: 0.1%
Example three: the tableware wet tissue special that contains chlorine dioxide
Wherein the mixed liquor composition is:
1), stable ClO 2 solution (available from Hualongxingyu Science and Technology Development Co., Ltd., Beijing): 0.28%,
2), sodium laurate: 1.2%,
3), citrate buffer solution: pH=6.8,0.2mol/L,
4), surfactant: cocoyl diglycollic amide: 10%
5), flavoring essence: 0.4%
Example four: the kitchen tools wet tissue special that contains chlorine dioxide
Wherein the mixed liquor composition is:
1), stable ClO 2 solution: 0.28%
2), cyclodextrin: 1.2%
3), citrate buffer solution: pH=6.8,0.2mol/L
4), surfactant: cocoyl diglycollic amide: 10%
5), flavoring essence: 0.4%
Example five: the fruit pasteurization towelette that contains chlorine dioxide
1), stable ClO 2 solution, 0.28%,
2), cyclodextrin, 1.2%,
3), citrate buffer solution, pH=6.8,0.2mol/L,
4), surfactant: cocoyl diglycollic amide: 1%
5), flavoring essence: 0.3%
Example six: the makeup-removing wet tissue that contains chlorine dioxide
1), stable ClO 2 solution: 0.10%
2), polyethylene glycol: 1.2%
3), emulsifying agent: fatty glyceride: 0.5%
4), surfactant: cocoyl diglycollic amide: 2%
5), glycerine: 4%
6), cream jasmin france: 0.3%
7), the skin care factor: leukotrienes: 0.1%
Example seven: the wet sanitary napkins (skin special use) that contains chlorine dioxide
1), aqueous solution of chlorine dioxide, 0.28%,
2), polyethylene glycol, 1.2%,
3), emulsifying agent: N-alkyl pyrrolidone: 1.2%
4), surfactant: cocoyl diglycollic amide: 2%
5), glycerine: 4%
6), NMF: sodium pyroglutamate: 3%
7), cream jasmin france: 0.3%
8), the skin care factor: leukotrienes: 0.1%
9), plant extract elite: 0.3%
Example eight: contain the smelly wet tissue of dispelling of chlorine dioxide
1), aqueous solution of chlorine dioxide, 0.28%,
2), polyethylene glycol, 1.2%,
3), emulsifying agent: alkylolamides: 1%
4), surfactant: cocoyl diglycollic amide: 2.5%
5), glycerine: 2%
6), NMF: sodium pyroglutamate 1%
7), cream jasmin france: 0.1%
8), tea tree ethereal oil: 0.08%
Example nine: the lavatory wet tissue that contains chlorine dioxide
(1) prepares wet tissue carrier: 60cm
2-600cm
2
(2) preparation mixed liquor:
1), cyclodextrin, 1.2%,
2), emulsifying agent: polyvinyl alcohol: 1%
3), glycerine: 2%
All the other are water.
(3) chlorine dioxide is passed in the mixed liquor, reaches 150ppm until the apparent chlorine dioxide concentration of mixed liquor.
(4) above-mentioned mixed liquor is sprayed on the wet tissue carrier every gram wet tissue carrier 2-6ml.
The performance evaluation of wet tissue
According to the disposable use amenities of National Standard sanitary standard " stability, validity and the security that contains the functional wipes of chlorine dioxide provided by the invention estimated.
A, estimation of stability
According to the GB requirement, the bactericidal effect of wet sanitary napkins will keep more than 1 year, can adopt 54 ℃ to quicken experiment sample is carried out estimation of stability, be about to ready-made wet tissue packing and finish and place in the baking oven that is placed on 54 ℃, sampling every day detects active ingredient chlorine dioxide wherein.The results are shown in Figure 1.
Testing result shows that the concentration of the effective chlorine dioxide of sample is moderate, remains between 55～65ppm, and the concentration stabilize of sodium chlorite descends, and product stability meets the GB requirement, and the bactericidal property of product does not have tangible change in 1 year shelf life.
B, the bactericidal effect evaluation
" disinfection technology standard " to the wet tissue series products require as follows: wet tissue must not detect pathogenic bacteria, wet sanitary napkins will be more than 90% to staphylococcus aureus and colibacillary killing rate, has the effect then should be more than 90% to the oidiomycetic killing rate of white if show to fungi.And we are in order to show the superiority of chlorine dioxide wet sanitary napkins, here 7 kinds of common pathogenic bacteria are detected, and sterilizing time only are 90 seconds (the GB examination criteria is the shortest to be 2 minutes, and only requires two kinds of bacteriums are detected).
To the summary of germ and kill the result such as following table:
| Microorganism | The disease that may cause | Killing rate (90 seconds) | Kill logarithm value |
| Escherichia coli | Enteritis, diarrhoea, urethritis, cystitis, pyelonephritis, peritonitis, appendicitis, septicemia | ??＞99.999 | ??＞6.11 |
| Staphylococcus aureus | Diarrhoea, chordapsus, vomiting, heating | ??＞99.999 | ??＞6.3 |
| Pseudomonas aeruginosa | Purulent lesion | ??＞99.999 | ??＞6.11 |
| White is read coccus | Thrush, vaginitis | ??＞99.999 | ??＞5.63 |
| Friedlander | Tracheitis, pneumonia, meningitis, Urinary system inflammation, wound pathology | ??＞99.999 | ??＞6.32 |
| Staphylococcus albus | Vomiting, diarrhoea | ??＞99.999 | ??＞6.06 |
| Aspergillus niger | Grain goes mouldy | ??96.111 | ??1.40 |
See by testing result, the bactericidal effect of product has satisfied the requirement of GB for the hand sterilization, has " sterilization " effect, and the sterilizing time of this detection will lack 25% than the minimum requirements time in the GB (2 minutes), only have 90 seconds action time, can not only read coccus to staphylococcus aureus, Escherichia coli and white and kill, can also kill pseudomonas aeruginosa, Friedlander and staphylococcus albus, aspergillus niger has also been played bactericidal effect.Be used as (GB requires 20min) when extending to 15min with the time, killing of above bacterial classification reached more than 5 number average, the killing rate to bacillus subtilis var can reach 99.98% in addition.
C, safety evaluatio
According to " disinfection technology standard " requirement, pasteurization towelette must carry out skin irritation test, and we entrust Beijing's associated mechanisms that the pasteurization towelette of example seven has been carried out the skin irritation human trial, and result of the test is as follows:
The human body patch test of pasteurization towelette (30 example)
The above only is a preferred implementation of the present invention; should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (16)
1, a kind of functional wipes that contains chlorine dioxide is characterized in that, described wet tissue comprises wet tissue carrier, the functional component that chlorine dioxide can be provided and stabilizing agent.
2, functional wipes as claimed in claim 1 is characterized in that, the described functional component that chlorine dioxide is provided is that chlorine dioxide, aqueous solution of chlorine dioxide maybe can activate the parent compound that produces chlorine dioxide.
3, functional wipes as claimed in claim 2 is characterized in that, the described parent compound that can activate the generation chlorine dioxide is stable ClO 2 solution or chlorite.
4, as each described functional wipes of claim 1-3, it is characterized in that described wet tissue also comprises sustained release agent.
5, as each described functional wipes of claim 1-4, it is characterized in that described wet tissue also comprises pH value buffer and/or natural perfume material.
6, a kind of functional wipes that contains chlorine dioxide is characterized in that, described wet tissue is made by following method:
(1) prepares wet tissue carrier: 60cm
2-600cm
2
(2) preparation mixed liquor:
Aqueous solution of chlorine dioxide: 5-500ppm;
Stabilizing agent: 0.1-10 weight %;
PH value buffer: PH=4.5-7;
Natural perfume material: 0.001-1 weight %;
All the other are water.
(3) above-mentioned mixed liquor is sprayed on the wet tissue carrier every gram wet tissue carrier 2-6ml.
7, a kind of functional wipes that contains chlorine dioxide is characterized in that, described wet tissue is made by following method:
(1) prepares wet tissue carrier: 60cm
2-600cm
2
(2) preparation mixed liquor:
Can activate the parent compound that produces chlorine dioxide: 0.005-1 weight %;
Stabilizing agent: 0.01-10 weight %;
Sustained release agent: 0.01-10 weight %;
PH value buffer: PH=4.5-7;
Natural perfume material: 0.001-1 weight %;
All the other are water.
(3) above-mentioned mixed liquor is sprayed on the wet tissue carrier every gram wet tissue carrier 2-6ml.
8, a kind of functional wipes that contains chlorine dioxide is characterized in that, described wet tissue is made by following method:
(1) prepares wet tissue carrier: 60cm
2-600cm
2
(2) preparation mixed liquor:
Aqueous solution of chlorine dioxide: 5-500ppm;
Can activate the parent compound that produces chlorine dioxide: 0.005-1 weight %;
Stabilizing agent: 0.01-10 weight %;
Sustained release agent: 0.01-10 weight %;
PH value buffer: PH=4.5-7;
Natural perfume material: 0.001-1 weight %;
All the other are water.
(3) above-mentioned mixed liquor is sprayed on the wet tissue carrier every gram wet tissue carrier 2-6ml.
9, as each described functional wipes of claim 1-8, it is characterized in that, described stabilizing agent is the compound that can make chlorine dioxide or chlorine dioxide matrix compound stable existence in the aqueous solution, comprises EDTA, carboxymethyl cellulose, sodium laurate, polyethylene glycol, cyclodextrin, glucan, chitin, glutinous polysaccharide, polyvinylpyrrolidone, acrylate copolymer, polyvinyl alcohol, APEO, the polyoxyethylene alcohol ester, fatty glyceride, lecithin, gelatin, agar, lanolin, melon and glue, sodium alginate, the N-alkyl pyrrolidone, sucrose ester, the glucoside ester, alanine, phosphotriester, betaine, saponin, in alkylolamides and the derivative thereof one or more.
10, as each described functional wipes of claim 4-8, it is characterized in that, described sustained release agent is to make the chlorine dioxide matrix compound slowly discharge the compound of chlorine dioxide, comprises in citric acid, tartaric acid, gluconic acid, sorbic acid, glycolic acid, the lactic acid one or more.
As each described functional wipes of claim 5-8, it is characterized in that 11, described pH value buffer is to make system pH maintain buffer or the combinations of buffers of 4.5-7.0.
As each described functional wipes of claim 1-11, it is characterized in that 12, described wet tissue carrier is spunlace non-woven cloth, weaving cloth or paper handkerchief.
13, functional wipes as claimed in claim 12 is characterized in that, described spunlace non-woven cloth is that thickness is 30g-80g/m
2, cotton content is the straight shop of 20-80% or tiltedly spreads nonwoven.
14, functional wipes as claimed in claim 12 is characterized in that, described weaving cloth is a kind of in the towelling of 20-80% of cotton or cotton content.
15, the purposes of each described functional wipes of claim 1-14 in the cleaning of article, decontamination, sterilization, sterilization.
16, purposes as claimed in claim 15 is characterized in that, described article comprise mobile phone, keyboard, mouse, refrigerator, dining table, kitchen tools, tableware, micro-wave oven, glasses, automobile, toilet, washing machine, fruit, vegetables or skin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910091977A CN101658397A (en) | 2009-09-08 | 2009-09-08 | Functional wipes containing chlorine dioxide and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910091977A CN101658397A (en) | 2009-09-08 | 2009-09-08 | Functional wipes containing chlorine dioxide and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101658397A true CN101658397A (en) | 2010-03-03 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910091977A Pending CN101658397A (en) | 2009-09-08 | 2009-09-08 | Functional wipes containing chlorine dioxide and application thereof |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102018632A (en) * | 2010-12-15 | 2011-04-20 | 广州潮徽化工科技有限公司 | High-efficiency moisturizing composition and preparation method and application thereof in cosmetics |
| CN102631165A (en) * | 2012-05-03 | 2012-08-15 | 张玉 | Wet tissue containing slightly acidic electrolyzed water |
| CN103074764A (en) * | 2012-12-19 | 2013-05-01 | 青岛天鹅针织有限公司 | Wet wipe |
| CN104224578A (en) * | 2013-06-15 | 2014-12-24 | 鲁慧 | Infant wet napkin capable of preventing intestinal tract infectious disease due to indirect contact transmission |
| CN106538599A (en) * | 2016-11-08 | 2017-03-29 | 东北大学秦皇岛分校 | A kind of stable chlorite compositions and preparation method thereof |
| CN109789229A (en) * | 2016-09-23 | 2019-05-21 | 国立大学法人三重大学 | Wet wipe object |
| CN110403956A (en) * | 2019-08-31 | 2019-11-05 | 韶关蓝威消毒药业有限公司 | A kind of preparation method of skin wound antibacterial agent |
| CN110477005A (en) * | 2019-08-23 | 2019-11-22 | 银河环保科技(天津)有限公司 | A kind of medicinal air freshening bactericide |
| CN112022027A (en) * | 2020-08-26 | 2020-12-04 | 山东奥古生物科技有限公司 | Disposable dish towel and preparation method thereof |
| CN112335677A (en) * | 2020-11-10 | 2021-02-09 | 深圳市加德圣环保科技有限公司 | Chlorine dioxide solution and preparation method thereof |
| CN115299457A (en) * | 2022-09-02 | 2022-11-08 | 中国农业科学院饲料研究所 | Chlorine dioxide solution disinfectant for controlling African swine fever and bringing livestock, and preparation method and application thereof |
-
2009
- 2009-09-08 CN CN200910091977A patent/CN101658397A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102018632A (en) * | 2010-12-15 | 2011-04-20 | 广州潮徽化工科技有限公司 | High-efficiency moisturizing composition and preparation method and application thereof in cosmetics |
| CN102018632B (en) * | 2010-12-15 | 2012-07-04 | 广州潮徽化工科技有限公司 | High-efficiency moisturizing composition and preparation method and application thereof in cosmetics |
| CN102631165A (en) * | 2012-05-03 | 2012-08-15 | 张玉 | Wet tissue containing slightly acidic electrolyzed water |
| CN103074764A (en) * | 2012-12-19 | 2013-05-01 | 青岛天鹅针织有限公司 | Wet wipe |
| CN104224578A (en) * | 2013-06-15 | 2014-12-24 | 鲁慧 | Infant wet napkin capable of preventing intestinal tract infectious disease due to indirect contact transmission |
| CN109789229A (en) * | 2016-09-23 | 2019-05-21 | 国立大学法人三重大学 | Wet wipe object |
| US11179486B2 (en) | 2016-09-23 | 2021-11-23 | Mie University | Wet wiper |
| CN106538599A (en) * | 2016-11-08 | 2017-03-29 | 东北大学秦皇岛分校 | A kind of stable chlorite compositions and preparation method thereof |
| CN106538599B (en) * | 2016-11-08 | 2020-05-19 | 东北大学秦皇岛分校 | Stable chlorite composition and preparation method thereof |
| CN110477005A (en) * | 2019-08-23 | 2019-11-22 | 银河环保科技(天津)有限公司 | A kind of medicinal air freshening bactericide |
| CN110403956A (en) * | 2019-08-31 | 2019-11-05 | 韶关蓝威消毒药业有限公司 | A kind of preparation method of skin wound antibacterial agent |
| CN112022027A (en) * | 2020-08-26 | 2020-12-04 | 山东奥古生物科技有限公司 | Disposable dish towel and preparation method thereof |
| CN112335677A (en) * | 2020-11-10 | 2021-02-09 | 深圳市加德圣环保科技有限公司 | Chlorine dioxide solution and preparation method thereof |
| CN115299457A (en) * | 2022-09-02 | 2022-11-08 | 中国农业科学院饲料研究所 | Chlorine dioxide solution disinfectant for controlling African swine fever and bringing livestock, and preparation method and application thereof |
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Application publication date: 20100303 |