CN101643898A - 无磷成膜剂及其制备方法 - Google Patents
无磷成膜剂及其制备方法 Download PDFInfo
- Publication number
- CN101643898A CN101643898A CN200910034639A CN200910034639A CN101643898A CN 101643898 A CN101643898 A CN 101643898A CN 200910034639 A CN200910034639 A CN 200910034639A CN 200910034639 A CN200910034639 A CN 200910034639A CN 101643898 A CN101643898 A CN 101643898A
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- CN
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- Prior art keywords
- phosphorus
- film forming
- free film
- forming agent
- coupling agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000002360 preparation method Methods 0.000 title claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000007822 coupling agent Substances 0.000 claims abstract description 20
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 19
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000008367 deionised water Substances 0.000 claims abstract description 18
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 18
- 239000008399 tap water Substances 0.000 claims abstract description 14
- 235000020679 tap water Nutrition 0.000 claims abstract description 14
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 229910002651 NO3 Inorganic materials 0.000 claims abstract description 10
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002253 acid Substances 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims description 20
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 14
- 230000001476 alcoholic effect Effects 0.000 claims description 10
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 9
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 9
- 239000011737 fluorine Substances 0.000 claims description 9
- 229910052731 fluorine Inorganic materials 0.000 claims description 9
- 229910017604 nitric acid Inorganic materials 0.000 claims description 9
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 5
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 claims description 4
- MIMUSZHMZBJBPO-UHFFFAOYSA-N 6-methoxy-8-nitroquinoline Chemical compound N1=CC=CC2=CC(OC)=CC([N+]([O-])=O)=C21 MIMUSZHMZBJBPO-UHFFFAOYSA-N 0.000 claims description 4
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 claims description 4
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 claims description 4
- 235000013024 sodium fluoride Nutrition 0.000 claims description 4
- 239000011775 sodium fluoride Substances 0.000 claims description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 4
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 claims description 4
- 238000005260 corrosion Methods 0.000 abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical class [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 6
- KOEFSMLBFZGZLD-UHFFFAOYSA-L [bis(2-ethylhexoxy)-oxidophosphaniumyl] dihydrogen phosphate [bis(2-ethylhexoxy)-oxidophosphaniumyl] phosphate ethane-1,2-diolate titanium(4+) Chemical compound [Ti+4].[O-]CC[O-].CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP(O)(O)=O.CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP([O-])([O-])=O KOEFSMLBFZGZLD-UHFFFAOYSA-L 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- -1 polyoxyethylene nonylphenol Polymers 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 230000002421 anti-septic effect Effects 0.000 description 3
- 239000013522 chelant Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 238000002161 passivation Methods 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 238000002203 pretreatment Methods 0.000 description 3
- 229960004418 trolamine Drugs 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000001282 organosilanes Chemical class 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 125000005372 silanol group Chemical group 0.000 description 2
- 239000012745 toughening agent Substances 0.000 description 2
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical class O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000012412 chemical coupling Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000005543 nano-size silicon particle Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/20—Use of solutions containing silanes
Landscapes
- Chemical Treatment Of Metals (AREA)
Abstract
Description
实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 | 实施例7 | 实施例8 | |
硅烷偶联剂 | 0.5 | 1 | 2 | 2 | 3 | 3 | 4 | 4 |
钛酸酯偶联剂 | 0.5 | 08 | 1.2 | 1.5 | 1.5 | 1.8 | 2 | 2 |
氟锆酸 | 5 | 8 | 10 | |||||
硝酸氧锆 | 10 | |||||||
氯化锆 | 8 | 5 | ||||||
硝酸锆 | 1 | |||||||
氧氯化锆 | 5 | |||||||
二乙二醇 | 3 | 4 | 5 | 4 | ||||
丙二醇 | 3 | 5 | ||||||
三丙二醇 | 5 | 5 | ||||||
硝酸 | 0.5 | 2 | 1 | 2 | 1 |
硝酸盐 | 1.5 | 2 | 1 | |||||
氢氟酸 | 2 | 1.5 | 2 | 1 | ||||
氟化钠 | 0.5 | |||||||
氟化铵 | 1 | |||||||
氟化氢铵 | 1 | 2 | ||||||
过氧化氢 | 1 | 2 | 3 | 5 | 4 | 2 | 3 | 4 |
去离子水 | 87.5 | 78.8 | 82.5 | 79.5 | 79.2 | 76 | 73 | |
自来水 | 73.5 |
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2009100346390A CN101643898B (zh) | 2009-09-04 | 2009-09-04 | 无磷成膜剂及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN2009100346390A CN101643898B (zh) | 2009-09-04 | 2009-09-04 | 无磷成膜剂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101643898A true CN101643898A (zh) | 2010-02-10 |
CN101643898B CN101643898B (zh) | 2010-12-29 |
Family
ID=41655956
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN2009100346390A Active CN101643898B (zh) | 2009-09-04 | 2009-09-04 | 无磷成膜剂及其制备方法 |
Country Status (1)
Country | Link |
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CN (1) | CN101643898B (zh) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102433578A (zh) * | 2011-11-28 | 2012-05-02 | 珠海市奥美伦精细化工有限公司 | 一种用于铝合金二次阳极氧化丝印前的处理剂及铝合金二次阳极氧化工艺 |
CN103060791A (zh) * | 2012-12-18 | 2013-04-24 | 芜湖恒坤汽车部件有限公司 | 一种含有钛酸四异丙酯的金属表面硅烷处理剂及其制备方法 |
CN103295788A (zh) * | 2013-06-06 | 2013-09-11 | 海门市三鑫电子有限责任公司 | 高含水体系高频低阻抗铝电解电容器工作电解液及其制备方法 |
CN103397323A (zh) * | 2013-05-31 | 2013-11-20 | 惠州市宏亚金属处理有限公司 | 一种无磷无渣常温皮膜剂 |
CN103773234A (zh) * | 2014-01-10 | 2014-05-07 | 湖南金裕化工有限公司 | 硅烷表面处理剂及其制备方法 |
CN104294260A (zh) * | 2014-09-11 | 2015-01-21 | 泉州泉港华博化工科技有限公司 | 环保型低成本金属表面处理剂及其制备方法 |
CN105755454A (zh) * | 2016-03-03 | 2016-07-13 | 福建省闽发铝业股份有限公司 | 一种铝型材涂装前无铬钝化表面处理剂 |
CN106591818A (zh) * | 2016-12-29 | 2017-04-26 | 芜湖市瑞杰环保材料科技有限公司 | 一种使用钛酸酯偶联剂的金属表面处理剂、制备方法及其使用方法 |
CN106702363A (zh) * | 2016-12-29 | 2017-05-24 | 芜湖市瑞杰环保材料科技有限公司 | 一种电泳涂装前处理用陶化剂、制备方法及其使用方法 |
CN106752225A (zh) * | 2016-12-28 | 2017-05-31 | 河南恒润昌环保科技有限公司 | 一种酸性水洗硅烷处理剂及其制备方法 |
CN106756934A (zh) * | 2016-12-29 | 2017-05-31 | 芜湖市瑞杰环保材料科技有限公司 | 一种金属表面处理剂、制备方法及其使用方法 |
CN106756935A (zh) * | 2016-12-29 | 2017-05-31 | 芜湖市瑞杰环保材料科技有限公司 | 一种提高金属耐腐蚀性的陶化剂、制备方法及其使用方法 |
CN112226752A (zh) * | 2020-10-16 | 2021-01-15 | 台州青源精细化工有限公司 | 金属涂装前硅烷偶联预膜剂的配方及其制备方法 |
CN114197013A (zh) * | 2021-07-26 | 2022-03-18 | 重庆大学 | 一种硅烷/钛酸酯双偶联剂防腐蚀涂层的制备方法 |
CN115725964A (zh) * | 2022-09-01 | 2023-03-03 | 东莞市颖兴金属表面处理材料有限公司 | 一种低温少渣磷化液及其制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE412073T1 (de) * | 2002-12-24 | 2008-11-15 | Chemetall Gmbh | Verfahren zur vorbehandlung vor der beschichtung |
CN100469945C (zh) * | 2007-01-22 | 2009-03-18 | 杭州五源科技实业有限公司 | 金属涂装前硅烷偶联预膜剂的制备方法 |
-
2009
- 2009-09-04 CN CN2009100346390A patent/CN101643898B/zh active Active
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102433578B (zh) * | 2011-11-28 | 2014-06-11 | 珠海市奥美伦精细化工有限公司 | 一种用于铝合金二次阳极氧化丝印前的处理剂及铝合金二次阳极氧化工艺 |
CN102433578A (zh) * | 2011-11-28 | 2012-05-02 | 珠海市奥美伦精细化工有限公司 | 一种用于铝合金二次阳极氧化丝印前的处理剂及铝合金二次阳极氧化工艺 |
CN103060791A (zh) * | 2012-12-18 | 2013-04-24 | 芜湖恒坤汽车部件有限公司 | 一种含有钛酸四异丙酯的金属表面硅烷处理剂及其制备方法 |
CN103397323A (zh) * | 2013-05-31 | 2013-11-20 | 惠州市宏亚金属处理有限公司 | 一种无磷无渣常温皮膜剂 |
CN103397323B (zh) * | 2013-05-31 | 2016-07-06 | 惠州市宏亚金属处理有限公司 | 一种无磷无渣常温皮膜剂 |
CN103295788B (zh) * | 2013-06-06 | 2017-02-08 | 南通三鑫电子科技股份有限公司 | 高含水体系高频低阻抗铝电解电容器工作电解液及其制备方法 |
CN103295788A (zh) * | 2013-06-06 | 2013-09-11 | 海门市三鑫电子有限责任公司 | 高含水体系高频低阻抗铝电解电容器工作电解液及其制备方法 |
CN103773234B (zh) * | 2014-01-10 | 2016-04-06 | 湖南金裕化工有限公司 | 硅烷表面处理剂及其制备方法 |
CN103773234A (zh) * | 2014-01-10 | 2014-05-07 | 湖南金裕化工有限公司 | 硅烷表面处理剂及其制备方法 |
CN104294260A (zh) * | 2014-09-11 | 2015-01-21 | 泉州泉港华博化工科技有限公司 | 环保型低成本金属表面处理剂及其制备方法 |
CN105755454A (zh) * | 2016-03-03 | 2016-07-13 | 福建省闽发铝业股份有限公司 | 一种铝型材涂装前无铬钝化表面处理剂 |
CN106752225A (zh) * | 2016-12-28 | 2017-05-31 | 河南恒润昌环保科技有限公司 | 一种酸性水洗硅烷处理剂及其制备方法 |
CN106702363A (zh) * | 2016-12-29 | 2017-05-24 | 芜湖市瑞杰环保材料科技有限公司 | 一种电泳涂装前处理用陶化剂、制备方法及其使用方法 |
CN106591818A (zh) * | 2016-12-29 | 2017-04-26 | 芜湖市瑞杰环保材料科技有限公司 | 一种使用钛酸酯偶联剂的金属表面处理剂、制备方法及其使用方法 |
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CN106756935A (zh) * | 2016-12-29 | 2017-05-31 | 芜湖市瑞杰环保材料科技有限公司 | 一种提高金属耐腐蚀性的陶化剂、制备方法及其使用方法 |
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