CN103031549B - 一种含有二乙基甲苯二胺的金属表面硅烷处理剂及其制备方法 - Google Patents
一种含有二乙基甲苯二胺的金属表面硅烷处理剂及其制备方法 Download PDFInfo
- Publication number
- CN103031549B CN103031549B CN201210551039.3A CN201210551039A CN103031549B CN 103031549 B CN103031549 B CN 103031549B CN 201210551039 A CN201210551039 A CN 201210551039A CN 103031549 B CN103031549 B CN 103031549B
- Authority
- CN
- China
- Prior art keywords
- water
- zinc oxide
- weight portion
- toluene diamine
- diethyl toluene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 29
- 239000002184 metal Substances 0.000 title claims abstract description 29
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 229910000077 silane Inorganic materials 0.000 title claims abstract description 26
- PISLZQACAJMAIO-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine Chemical compound CCC1=CC(C)=C(N)C(CC)=C1N PISLZQACAJMAIO-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 56
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000011787 zinc oxide Substances 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 23
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 14
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 claims abstract description 9
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000006185 dispersion Substances 0.000 claims abstract description 8
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims abstract description 8
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- BDLXTDLGTWNUFM-UHFFFAOYSA-N 2-[(2-methylpropan-2-yl)oxy]ethanol Chemical compound CC(C)(C)OCCO BDLXTDLGTWNUFM-UHFFFAOYSA-N 0.000 claims abstract description 7
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 7
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 7
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 7
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004327 boric acid Substances 0.000 claims abstract description 7
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 7
- 239000001488 sodium phosphate Substances 0.000 claims abstract description 7
- 229910000162 sodium phosphate Inorganic materials 0.000 claims abstract description 7
- 239000013638 trimer Substances 0.000 claims abstract description 7
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims abstract description 7
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 30
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 12
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 9
- 235000019441 ethanol Nutrition 0.000 claims description 9
- 235000011187 glycerol Nutrition 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- 229940126062 Compound A Drugs 0.000 claims description 6
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims description 6
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 6
- 239000001632 sodium acetate Substances 0.000 claims description 6
- 235000017281 sodium acetate Nutrition 0.000 claims description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 3
- 238000005119 centrifugation Methods 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000007822 coupling agent Substances 0.000 claims description 3
- 239000000706 filtrate Substances 0.000 claims description 3
- KOVKEDGZABFDPF-UHFFFAOYSA-N n-(triethoxysilylmethyl)aniline Chemical compound CCO[Si](OCC)(OCC)CNC1=CC=CC=C1 KOVKEDGZABFDPF-UHFFFAOYSA-N 0.000 claims description 3
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 230000035699 permeability Effects 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 238000005452 bending Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 238000004532 chromating Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004299 exfoliation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910001335 Galvanized steel Inorganic materials 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- -1 chromium Chemical compound 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000002224 dissection Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000008397 galvanized steel Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000002444 silanisation Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210551039.3A CN103031549B (zh) | 2012-12-18 | 2012-12-18 | 一种含有二乙基甲苯二胺的金属表面硅烷处理剂及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210551039.3A CN103031549B (zh) | 2012-12-18 | 2012-12-18 | 一种含有二乙基甲苯二胺的金属表面硅烷处理剂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103031549A CN103031549A (zh) | 2013-04-10 |
CN103031549B true CN103031549B (zh) | 2016-05-11 |
Family
ID=48018934
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210551039.3A Expired - Fee Related CN103031549B (zh) | 2012-12-18 | 2012-12-18 | 一种含有二乙基甲苯二胺的金属表面硅烷处理剂及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103031549B (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104099018A (zh) * | 2014-06-19 | 2014-10-15 | 锐展(铜陵)科技有限公司 | 一种双组份铝合金表面处理剂 |
CN105220137A (zh) * | 2015-11-06 | 2016-01-06 | 刘广利 | 一种金属表面防腐溶胶及其制备方法与用途 |
CN109485087A (zh) * | 2018-12-18 | 2019-03-19 | 兴化市万润锌业有限公司 | 一种改性纳米氧化锌的加工方法 |
CN114045478A (zh) * | 2021-10-13 | 2022-02-15 | 东莞理工学院 | 一种铝合金导电转化膜的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1405933A1 (en) * | 2001-06-15 | 2004-04-07 | Nihon Parkerizing Co., Ltd. | Treating solution for surface treatment of metal and surface treatment method |
CN101434748A (zh) * | 2008-12-04 | 2009-05-20 | 上海大学 | 纳米氧化锌改性的有机硅封装胶的制备方法 |
CN102121104A (zh) * | 2011-01-22 | 2011-07-13 | 安徽工业大学 | 镀锌板的彩涂预处理及底漆涂覆相结合的水性无铬表面处理液 |
CN102409325A (zh) * | 2011-12-06 | 2012-04-11 | 中国科学院金属研究所 | 环保型耐腐蚀无铬化学转化液及化学转化膜的制备方法 |
-
2012
- 2012-12-18 CN CN201210551039.3A patent/CN103031549B/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1405933A1 (en) * | 2001-06-15 | 2004-04-07 | Nihon Parkerizing Co., Ltd. | Treating solution for surface treatment of metal and surface treatment method |
CN101434748A (zh) * | 2008-12-04 | 2009-05-20 | 上海大学 | 纳米氧化锌改性的有机硅封装胶的制备方法 |
CN102121104A (zh) * | 2011-01-22 | 2011-07-13 | 安徽工业大学 | 镀锌板的彩涂预处理及底漆涂覆相结合的水性无铬表面处理液 |
CN102409325A (zh) * | 2011-12-06 | 2012-04-11 | 中国科学院金属研究所 | 环保型耐腐蚀无铬化学转化液及化学转化膜的制备方法 |
Non-Patent Citations (2)
Title |
---|
硅烷偶联剂对纳米氧化锌的表面改性研究;佘利娟;《化工时刊》;20100606;第24卷(第6期);全文 * |
硅烷偶联剂对纳米氧化锌表面改性的机理研究;周燕;《湘潭大学自然科学学报》;20061231;第28卷(第4期);全文 * |
Also Published As
Publication number | Publication date |
---|---|
CN103031549A (zh) | 2013-04-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103031056B (zh) | 一种含有水性纳米氧化锌料的金属表面硅烷处理剂及其制备方法 | |
CN101643898B (zh) | 无磷成膜剂及其制备方法 | |
CN106906462B (zh) | 一种金属表面前处理剂及其制备方法、应用 | |
CN103031549B (zh) | 一种含有二乙基甲苯二胺的金属表面硅烷处理剂及其制备方法 | |
CN107012456B (zh) | 一种烷氧基硅乙基多面体齐聚硅倍半氧烷改性的金属表面前处理剂及其制备方法、应用 | |
CN105779988A (zh) | 一种电镀锌用无铬钝化溶液及其钝化工艺 | |
CN103031551B (zh) | 一种含有乙二胺四亚甲基叉膦酸钠的金属表面硅烷处理剂及其制备方法 | |
CN104984889A (zh) | 一种微纳尺寸颗粒增强型锌铝涂层及其生产方法 | |
CN104630765A (zh) | 一种环保型金属涂装前预处理剂及其制备方法 | |
CN102586769A (zh) | 一种无磷金属表面处理剂及其使用方法 | |
CN101476120A (zh) | 一种环保型金属表面处理剂及其制备方法 | |
CN102732869A (zh) | 一种有机硅烷为主要成分的镀锌板无铬钝化剂及其制备方法 | |
CN103088327A (zh) | 一种含有水溶性酚醛树脂的金属表面硅烷处理剂及其制备方法 | |
CN103087627B (zh) | 一种金属铝合金表面硅烷处理剂及其制备方法 | |
CN103102724B (zh) | 一种含有丙烯酸的金属表面硅烷处理剂及其制备方法 | |
CN103060787B (zh) | 一种含有二乙醇胺的金属表面硅烷处理剂及其制备方法 | |
CN103031548B (zh) | 一种含有偏钒酸铵的金属表面硅烷处理剂及其制备方法 | |
CN102268707B (zh) | 含金属锌的复合硅烷膜的制备方法及其用途 | |
CN106894009B (zh) | 一种环氧基poss改性的金属表面前处理剂及其制备方法、应用 | |
CN102304704A (zh) | 一种提高金属表面防护性能的水性硅烷处理剂 | |
CN103045086B (zh) | 一种金属表面硅烷处理剂及其制备方法 | |
CN104451634A (zh) | 铝及铝合金钝化液、制备方法及其使用方法 | |
CN103059728B (zh) | 一种耐腐蚀的金属表面硅烷处理剂及其制备方法 | |
CN106756939A (zh) | 铝钝化液及其制备方法 | |
CN103088328A (zh) | 一种镀锌钢板表面硅烷处理剂及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20160401 Address after: The road in Baohe District of Hefei city of Anhui Province, No. 208 230001 Applicant after: HEFEI ZHONGLAN NEW MATERIAL TECHNOLOGY CO., LTD. Address before: 241000 Anhui city of Wuhu province Jiujiang Development Zone Applicant before: Anhui Liufang Zhonglian Mechanical Share Co.,Ltd. |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Zeng Jianqiang Inventor after: Liu Yanjun Inventor after: Li Qingzan Inventor after: Fu Liufeng Inventor before: Wang Lixin |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20170519 Address after: Huadu District, Guangdong city of Guangzhou province Xinya street 510800 Jinghu Road No. 8 A5-B Patentee after: Guangzhou Zede Environmental Technology Co. Ltd. Address before: The road in Baohe District of Hefei city of Anhui Province, No. 208 230001 Patentee before: HEFEI ZHONGLAN NEW MATERIAL TECHNOLOGY CO., LTD. |
|
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160511 Termination date: 20171218 |