CN101617997A - 使毛发丰盈的毛发定型剂 - Google Patents
使毛发丰盈的毛发定型剂 Download PDFInfo
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- CN101617997A CN101617997A CN200910149543A CN200910149543A CN101617997A CN 101617997 A CN101617997 A CN 101617997A CN 200910149543 A CN200910149543 A CN 200910149543A CN 200910149543 A CN200910149543 A CN 200910149543A CN 101617997 A CN101617997 A CN 101617997A
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Abstract
一种用于处理角蛋白纤维的制剂，特别是化妆用毛发定型剂，所述制剂包含：a)至少一种阳离子、两性聚合物，其由下列单体构成：乙烯基吡咯烷酮、丙烯酸叔丁酯、甲基丙烯酸、二甲基氨基丙基甲基丙烯酰胺和乙基硫酸甲基丙烯酰基乙基二甲基乙基铵，其中甲基丙烯酸的比例小于二甲基氨基丙基甲基丙烯酰胺的比例，并且所述聚合物已用适合的酸中和，b)至少一种非离子聚合物，和c)至少一种硅油。
Description
技术领域
本发明涉及一种用于处理角蛋白纤维的制剂，特别是化妆用毛发定型剂，所述制剂包含：a)至少一种阳离子、两性聚合物，其由下列单体构成：乙烯基吡咯烷酮、丙烯酸叔丁酯、甲基丙烯酸、二甲基氨基丙基甲基丙烯酰胺和乙基硫酸甲基丙烯酰氧乙基二甲基乙基铵，其中甲基丙烯酸的比例小于二甲基氨基丙基甲基丙烯酰胺的比例，并且所述聚合物已用适合的酸中和，b)至少一种非离子聚合物，和c)至少一种硅油。
背景技术
为了临时改变和稳定发型而使用已知作为定型剂的产品。其中包括喷发胶、泡沫定型剂、液体形式的定型剂、凝胶、发蜡等。
配方是多种多样的，组成成分必须是在乙醇介质、水性乙醇介质或水性介质中相容的。
这种用于定型毛发的制剂通常由成膜的天然或合成聚合物或者聚合物组合的溶液构成。在此涉及非离子、阴离子、阳离子或两性的聚合物。所述制剂施加到毛发上之后留下无色透明的薄膜。对这种薄膜有一系列的要求：所述薄膜应该是透明的、有光泽、对湿度不敏感、固定性的、保持时间长、柔韧、不粘附的，不损害毛发的自然感觉并且可以用市售的洗发剂轻易地再洗掉。毛发定型剂在造型类产品中具有特殊位置。不仅薄膜特性(保持性(Halt)、柔韧性)处于重要地位，而且对毛发的护理功效(可梳理性、经护理的感觉)也很重要。
主要使用无规共聚物作为毛发定型剂中赋予保持性(haltgebend)的聚合物。通常将具有乙烯基官能团或丙烯酸系基(Acryl-)官能团的不同的非离子、阴离子或阳离子/阳离子原(kationogen)的单体共聚合。
毛发定型剂中赋予保持性的聚合物的主要缺点是护理特性不足：毛发不易梳理且感觉无光泽、粗糙和缺少护理。干燥之后薄膜相对硬、脆和不柔韧。对使用者不利的是，薄膜的触觉特性和在梳理时残余物的形成(薄膜屑)。它们落在肩上或衣服上并且让使用者看上去不修边幅。
对于毛发定型剂配方，手感和可梳理性方面的改进典型地通过上述聚合物与阳离子聚合物、阳离子表面活性剂或聚硅氧烷(例如环状聚二甲基硅氧烷(环聚甲基硅氧烷)、聚二甲基硅氧烷类的聚硅氧烷表面活性剂(聚醚改性的硅氧烷))的组合来实现。
然而，这些阳离子聚合物或阳离子表面活性剂的使用大多数情况下导致丰盈特性(Volumeneigenschaften)明显降低。
这种缺陷又可以利用额外使用非离子聚合物来弥补。这种组合的另一优点是极好的长时间丰盈。
此外，对于泡沫定型剂，许多赋予保持性的聚合物的其它缺点也在起作用：它赋予泡沫体具有不充分的、非化妆用的泡沫特征。泡沫是粗泡状的、软的、不稳定和不太象奶油状。
为了改善泡沫特性通常加入使泡沫稳定的添加剂，例如非离子表面活性剂。
发明内容
令人惊奇地发现，通过一种用于处理角蛋白纤维的制剂，特别是化妆用毛发定型剂获得了特别良好和持久保持的使毛发丰盈的特性，所述制剂包含：
a)至少一种阳离子、两性聚合物，其由下列单体构成：乙烯基吡咯烷酮、丙烯酸叔丁酯、甲基丙烯酸、二甲基氨基丙基甲基丙烯酰胺和乙基硫酸甲基丙烯酰基乙基二甲基乙基铵，其中甲基丙烯酸的比例小于二甲基氨基丙基甲基丙烯酰胺的比例，并且所述聚合物已用适合的酸中和，
b)至少一种非离子聚合物，和
c)至少一种硅油。
在此已确定有利的是，所述一种或更多种阳离子、两性聚合物的活性含量以所述制剂的总重量计为0.01至10重量％，优选0.05至5重量％。另外有利的是，所述阳离子、两性聚合物是利用磷酸中和至pH6.0的无规、线型共聚物，其由乙烯基吡咯烷酮、丙烯酸叔丁酯、甲基丙烯酸、二甲基氨基丙基甲基丙烯酰胺和乙基硫酸甲基丙烯酰基乙基二甲基乙基铵构成。另外有利的是，所述一种或更多种非离子聚合物的活性含量以所述制剂的总重量计为0.01至10重量％，优选0.1至5重量％。另外有利的是，所述非离子聚合物是乙烯基吡咯烷酮和乙酸乙烯酯的共聚产物。另外有利的是，所述一种或更多种硅油的活性含量以所述制剂的总重量计为0.01至5重量％，优选0.05至2.5重量％。另外有利的是，所述一种或更多种硅油选自线型或环状的聚硅氧烷，PEG改性和/或PPG改性的聚硅氧烷。另外有利的是，所述制剂包含0至95重量％，优选5至60重量％的乙醇，以所述制剂的总重量计。另外有利的是，所述制剂包含0至25重量％，优选1至15重量％的推进剂，以所述制剂的总重量计。另外有利的是，所述制剂作为用于毛发的含推进剂的泡沫定型剂、泵式泡沫定型剂或者泵式喷发胶存在。另外有利的是，额外存在至少一种其它阴离子、阳离子、非离子或两性的成膜聚合物，其浓度以所述制剂的总重量计为0至10重量％，优选1至5重量％。另外有利的是，额外包含UV过滤剂、抗氧化剂、油、提取物、蛋白质和/或蛋白质水解物、颜料和/或香料。本发明还包括所述制剂用于塑造人和/或动物发型的用途。
根据本发明的定型剂可以包含具有不同功能的其它化妆用助剂，例如护理物质，防腐剂，杀菌剂，香料，乳化剂，推进剂，用于软化、润湿和/或保湿的物质，脂肪，油，蜡，脂肪醇，脂肪酸酯或其它化妆或皮肤病学配方中常见的成分，例如醇、多元醇、聚合物、电解质、有机溶剂或聚硅氧烷衍生物。
作为护理物质可以另外使用硅油和/或硅橡胶纯胶料(Silikongum)。在本发明的一个特别的实施方案中，所述制剂包含至少一种硅油和/或硅橡胶纯胶料。
根据本发明适合的硅油或者硅橡胶纯胶料特别是二烷基硅氧烷和烷基芳基硅氧烷，例如二甲基聚硅氧烷和甲基苯基聚硅氧烷，以及它们的烷氧基化、季铵化或者阴离子的衍生物。优选的是环状和线型聚二烷基硅氧烷、其烷氧基化和/或胺化的衍生物，二羟基聚二甲基硅氧烷和聚苯基烷基硅氧烷。
硅油起到不同的作用。其例如同时影响干燥时和湿发时的可梳理性、干发和湿发的手感以及光泽。专业人员将硅油的概念理解为多种结构的有机硅化合物。
举下列商业产品作为这类产品的实例：Botanisil NU-150M(Botanigenics)、Dow Corning 1-1254 Fluid、Dow Corning 2-9023Fluid、Dow Corning 2-9026 Fluid、Ultrapure Dimethiconol(UltraChemical)、Unisil SF-R(Universal Preserve)、X-21-5619(Shin-EtsuChemical Co.)、Abil OSW5(Degussa Care Specialties)、ACC DL-9430Emulsion(Taylor Chemical Company，AEC Dimethiconol&SodiumDodecylbenzenesulfonate(A&E Connock(Perfumery&Cosmetics)Ltd.)、B C Dimethiconol Emulsion 95(Basildon Chemical Company，Ltd.)、Cosmetic Fluid 1401、Cosmetic Fluid 1403、Cosmetic Fluid 1501、Cosmetic Fluid 1401DC(前述均来自Chemsil Silicones，Inc.)、DowCorning 1401 Fluid、Dow Corning 1403 Fluid、Dow Corning 1501Fluid、Dow Corning 1784 HVF Emulsion、Dow Corning 9546 SiliconeElastomer Blend(前述均来自Dow Corning Corporation)、Dub Gel SI1400(Stearinerie Dubois Fils)、HVM 4852 Emulsion(CromptonCorDoration)、Jeesilc 6056(Jeen International Corporation)、Lubrasil、Lubrasil DS(两者均来自Guardian Laboratories)、Nonychosine E、Nonychosine V(两者均来自Exsymol)、SanSurf Petrolatum-25、SatinFinish(两者均来自Collaborative Laboratories，Inc.)、Silatex-D30(Cosmetic Ingredient Resources)、Silsoft 148、Silsoft E-50、SilsoftE-623(前述均来自Crompton Corporation)、SM555、SM2725、SM2765、SM2785(前述均来自GE Silicones)、Taylor T-Sil CD-1、TaylorTME-4050E(所有来自Taylor Chemical Company)、TH V 148(Crompton Corporation)、Tixogel CYD-1429(Sud-ChemiePerformance Additives)、Wacker-Belsil CM 1000、Wacker-Belsil CM3092、Wacker-Besil CM 5040、Wacker-Belsil DM 3096、Wacker-BelsilDM 3112 VP、Wacker-Belsil DM 8005 VP、Wacker-Belsil DM 60081 VP(前述均来自Wacker-Chemie GmbH)。
其它适合的聚硅氧烷是例如：
-低聚的聚二甲基环硅氧烷(INCI名称：环聚甲基硅氧烷)，特别是四聚合和五聚合的化合物，其作为Dow Corning公司的商业产品DC 245Fluid、DC 344或DC345来销售，
-六甲基-二硅氧烷(INCI名称：六甲基二硅氧烷)，例如以Abil K 520名字销售的产品，
-聚苯基甲基硅氧烷(INCI名称：聚苯基三甲基硅氧烷)，例如来自Dow Corning的商业产品DC 556 Cosmetic Grade Fluid，
-聚硅氧烷-乙二醇共聚物的酯和偏酯，例如由Fanning公司销售的商品名Fancorsil LIM(INCI名称：聚二甲基硅氧烷共聚醇白池花籽油酸酯(Meadowfoamate))的产品，
-例如产品Dow Corning 1784的阴离子硅油，
-以及Dow Corning 5330 Fluid、Dow Corning 949、Dow Corning 1401、Dow Corning 1403和Dow Corning 1501。
所述制剂可以包含蛋白质水解物和/或其衍生物作为护理物质。
蛋白质水解物是通过酸、碱或酶促催化分解蛋白质(蛋白)得到的产物混合物。根据本发明，蛋白质水解物的概念还应理解为总水解物以及各个氨基酸和其衍生物以及由不同氨基酸构成的混合物。根据本发明，蛋白质水解物还应理解为由氨基酸和氨基酸衍生物构成的聚合物。后者包括例如聚丙氨酸、聚天冬酰胺、聚丝氨酸等。根据本发明可用的化合物的其它实例是L-丙氨酰-L-脯氨酸、聚甘氨酸、甘氨酰-L-谷氨酰胺或D/L-蛋氨酸-S-甲基氯化锍。根据本发明当然还可以使用[β]-氨基酸及其衍生物例如[β]-丙氨酸、氨基苯甲酸或马尿酸。根据本发明可用的蛋白质水解物的摩尔质量在甘氨酸的摩尔质量75和200000道尔顿之间，优选摩尔质量在75至50000道尔顿之间，更特别优选摩尔质量为75至20000道尔顿。
根据本发明，可以使用植物、动物或海洋或合成来源的蛋白质水解物。
动物蛋白质水解物例如是弹性蛋白、胶原蛋白、角蛋白、丝蛋白和乳蛋白的蛋白质水解物，它们还可以以盐的形式存在。所述产品例如以Dehylan(Cognis)、Promois(Interorgana)、Collapuron(Cognis)、Nutrilan(Cognis)、Gelita-Sol(Deutsche Gelatine Fabriken Stoess&Co)、Lexein(Inolex)、Sericin(Pentapharm)和Kerasol(Croda)的牌子销售。
特别令人感兴趣的是使用丝蛋白质水解物。丝应理解为桑蚕(Bombyx mri L.)茧的纤维。
还可使用无规共聚物作为根据本发明的毛发定型剂中赋予保持性的聚合物。通常将具有乙烯基官能团或丙烯酸系基官能团的不同的非离子、阴离子或阳离子/阳离子原单体共聚合，所述单体例如乙烯基内酰胺(乙烯基吡咯烷酮、乙烯基己内酰胺)、乙酸乙烯酯、(甲基)丙烯酸烷基酯((甲基)丙烯酸甲酯、(甲基)丙烯酸乙酯、(甲基)丙烯酸丙酯、(甲基)丙烯酸正丁酯、(甲基)丙烯酸叔丁酯、(甲基)丙烯酸环己酯等)、苯乙烯、(甲基)丙烯酰胺、烷基(甲基)丙烯酰胺、官能化的(甲基)丙烯酸烷基酯(例如(甲基)丙烯酸羟乙酯、(甲基)丙烯酸二甲氨基乙酯)、(甲基)丙烯酸二甲氨基丙酯、官能化的烷基(甲基)丙烯酰胺(二甲氨基丙基(甲基)丙烯酰胺)、(甲基)丙烯酸、马来酸、巴豆酸、丙烯酰胺基甲基丙磺酸，包含氨基基团且其氨基基团被烷基化(季铵化)的单体，例如(甲基)丙烯酰基乙基三烷基氯化铵、(甲基)丙烯酰基丙基三烷基氯化铵、(甲基)丙烯酰基氨基丙基三烷基氯化铵、甲基硫酸(甲基)丙烯酰基乙基三烷基铵、甲基硫酸(甲基)丙烯酰基丙基三烷基铵、甲基硫酸(甲基)丙烯酰基氨基丙基三烷基铵。这类用于毛发定型剂中的聚合物的实例是例如具有下列INCI名称的聚合物：丙烯酸(酯)类共聚物(BASF的
Soft，NationalStarch的Balance
Balance O/
Lubrizol的Avalure
)、丙烯酸(酯)类/羟酯类丙烯酸酯类共聚物(Rohm&Haas的
)、丙烯酸(酯)类/辛基丙烯酰胺类共聚物(National Starch的
或Resvn XP)、AMP-丙烯酸(酯)类/甲基丙烯酸烯丙基酯类共聚物(Lubrizol的
)、PVM/MA共聚物的丁酯(ISP的)、PVM/MA共聚物的乙酯(ISP的
或
)、丙烯酰胺/丙烯酰基二甲基牛黄酸钠/丙烯酸聚合物(Rohm&Haas的Acudyne
)、异丁烯/乙基马来酰亚胺/羟乙基马来酰亚胺共聚物(ISP的Aquaflex FX-
)、辛基丙烯酰胺/丙烯酸酯/甲基丙烯酸丁基氨基乙酯共聚物(National Starch的
或
)、丙烯酸(酯)类/叔丁基丙烯酰胺共聚物(BASF的
)、PEG/PPG-25/25聚二甲基硅氧烷/丙烯酸(酯)类/丙烯酸叔丁酯类共聚物(BASF的Luviflex
)、聚乙烯基己内酰胺(BASF的Luviskol
)、PVM/MA共聚物(BASF的Luviform
)、PVP(BASF的
)、PVP/VA共聚物(BASF的
)、VP/甲基丙烯酸二甲氨基乙酯共聚物(ISP的
)、聚苯乙烯磺酸钠(NationalStarch的)、VA/巴豆酸(酯)类/新癸酸乙烯基酯共聚物(BASF的Luviset
National Starch的
)、VA/巴豆酸(酯)类/丙酸乙烯基酯共聚物(BASF的Luviset
)、VA/马来酸丁酯/丙烯酸异冰片酯共聚物(ISP的Advantage
)、VA/巴豆酸(酯)类共聚物(BASF的Luviset CA
、Clariant的
)、VA/苯甲酸乙烯基丁酯/巴豆酸(酯)类共聚物(Chimex的Mexomere
)、乙烯基己内酰胺/PVP/甲基丙烯酸二甲氨基乙酯共聚物(ISP的
)、VA/马来酸丁酯/丙烯酸异冰片酯共聚物(ISP的Advantage
)、丙烯酸(酯)类/C1-2琥珀酸酯/羟基丙烯酸(酯)类共聚物(ISP的Allianz LT-
)、VP/乙烯基己内酰胺/DMAPA丙烯酸(酯)类共聚物(ISP的Aquaflex SF-
)、乙烯基己内酰胺/VP/甲基丙烯酸二甲氨基乙酯共聚物(ISP的
)、VP/DMAPA丙烯酸(酯)类共聚物(ISP的Styleze CC-10)、VP/丙烯酸(酯)类/甲基丙烯酸月桂酯共聚物(ISP的Styleze
)、VP/甲基丙烯酰胺/N-乙烯基咪唑共聚物(BASF的Luviset
)、所有的聚丙烯酸酯类型(Lubrizol的Fixate
和Fixate Superhold、BASF的Luviset
)等很多。
其它用于毛发定型剂中的聚合物类是例如聚氨酯，例如聚氨酯-1(BASF的Luviset
)、聚氨酯-2(Lubrizol的Avalure
)、聚氨酯-6(BASF的Luviset SI
)，聚酯，例如聚酯-5(Eastman的AQ-Polymere)、聚酰亚胺，例如聚酰亚胺-1(ISP的Aquaflex XL-
)等很多。
对于根据本发明的毛发定型剂配方，手感和可梳理性方面的改进通过上述聚合物与阳离子聚合物、阳离子表面活性剂或聚硅氧烷(例如环状聚二甲基硅氧烷(环聚甲基硅氧烷)、聚二甲基硅氧烷类的聚硅氧烷表面活性剂(聚醚改性的硅氧烷))的组合来实现。
适当的阳离子表面活性剂选自季铵化合物类，特别是苄基三烷基铵盐或烷基三甲基铵盐，例如鲸蜡基三甲基氯化铵或鲸蜡基三甲基溴化铵、烷基二甲基羟乙基氯化铵或烷基二甲基羟乙基溴化铵、二烷基二甲基氯化铵或二烷基二甲基溴化铵、烷基酰胺乙基三甲基铵醚硫酸盐(Alkylamidethyltrimethylammoniumethersulfate)、羟乙基鲸蜡基二甲基磷酸铵、烷基吡啶鎓盐，例如月桂基氯化吡啶鎓或鲸蜡基氯化吡啶鎓、咪唑啉衍生物和具有阳离子特征的化合物例如氧化胺，例如烷基二甲基氧化胺或烷基氨基乙基二甲基氧化胺。
适当的阳离子聚合物是被称为聚季铵盐(Polyquaternium)的聚合物例如乙烯基咪唑、乙烯基吡咯烷酮和/或乙烯基己内酰胺的季铵化共聚物(聚季铵盐-16、聚季铵盐-44或聚季铵盐-46)、季铵化的乙烯基吡咯烷酮/甲基丙烯酸二甲基氨基乙酯共聚物(聚季铵盐-11)、二甲基二烯丙基氯化铵的均聚物和共聚物(聚季铵盐-6、聚季铵盐-7或聚季铵盐-22)、季铵化的纤维素聚合物(聚季铵盐-4、聚季铵盐-10)、由阳离子纤维素和淀粉构成的共聚物(聚季铵盐-4/羟丙基淀粉共聚物)、季铵化的乙烯基吡咯烷酮/甲基丙烯酸二甲基氨基丙基酯/甲基丙烯酸月桂基二甲基氨基丙酯共聚物(聚季铵盐-55)、乙烯基吡咯烷酮/乙烯基咪唑/甲基丙烯酰胺/季铵化的乙烯基咪唑(聚季铵盐-68)、季铵化的乙烯基己内酰胺/乙烯基吡咯烷酮/二甲基氨基丙基甲基丙烯酰胺/甲基丙烯酰基氨基丙基月桂基二甲基氯化铵(聚季铵盐-69)或季铵化的瓜尔胶衍生物。
根据本发明适当的非离子聚合物例如是乙烯基吡咯烷酮的均聚物，例如BASF的Luviskol K或N-乙烯基甲酰胺的均聚物例如NationalStarch的PVF。
其它适合的聚合物是乙烯基吡咯烷酮和乙酸乙烯酯的共聚产物例如BASF的Luviskol VA类，乙烯基吡咯烷酮、乙酸乙烯酯和丙酸酯的三元共聚物例如BASF的Luviskol VAP，聚乙烯基己内酰胺，聚乙烯酰胺和它们的盐以及由乙烯基吡咯烷酮和甲基丙烯酸二甲基氨基乙酯构成的共聚物，由乙烯基己内酰胺、乙烯基吡咯烷酮和甲基丙烯酸二甲基氨基酯构成的三元共聚物；聚硅氧烷等。
根据本发明适当的非离子表面活性剂是醇；烷醇酰胺，例如椰油酰胺MEA/DEA/MIPA；氧化胺，例如氧化椰油酰氨基丙基胺；通过羧酸与环氧乙烷、甘油、脱水山梨醇或其它醇的酯化形成的酯；醚，例如乙氧基化/丙氧基化的醇、乙氧基化/丙氧基化的酯、乙氧基化/丙氧基化的甘油酯、乙氧基化/丙氧基化的胆固醇、乙氧基化/丙氧基化的甘油三酸酯、乙氧基化/丙氧基化的羊毛脂、乙氧基化/丙氧基化的聚硅氧烷、丙氧基化的POE醚和烷基聚糖苷例如月桂基葡糖苷、癸基葡糖苷和椰油基葡糖苷、蔗糖酯、蔗糖醚、聚甘油酯、双甘油酯、单甘油酯、甲基葡糖酯以及羟基酸的酯。
根据本发明适当的推进剂是烃例如丁烷、异丁烷和丙烷、二甲醚或氟碳化合物例如1，2-二氟乙烷。其它推进剂是氮气、二氧化碳、一氧化二氮或压缩空气。
具体实施方式
毛发定型剂的配方实施例：
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | |
| 聚合物1 | 3.5 | 0.8 | 2 | 0.5 | 1.5 | 0.8 | 2 |
| VP/VA共聚物 | - | 2 | 4 | 1.5 | 3.5 | - | - |
| PVP | - | - | - | - | - | 2 | 4 |
| 聚季铵盐-68(LuviquatSupreme；BASF) | - | - | - | 1 | 2 | - | - |
| 西曲氯铵 | 0.8 | 0.5 | 0.1 | 0.5 | - | 0.9 | - |
| 羟乙基鲸蜡基二甲基磷酸铵 | 1.0 | - | - | - | - | - | 0.5 |
| PEG-12聚二甲基硅氧烷 | - | 0.2 | - | 0.5 | - | 0.2 | |
| 聚二甲基硅氧烷共聚醇 | 0.3 | 0.3 | - | 0.3 | - | 0.3 | - |
| 泛醇 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
| 柠檬酸 | 0.2 | 0.2 | 0.3 | 0.2 | 0.3 | 0.3 | 0.3 |
| 苯甲酸钠 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | - | 0.2 |
| 月桂醇聚醚-3 | 1.0 | 0.3 | 1.0 | 0.3 | 1.0 | - | 1.0 |
| 十三烷醇聚醚-12 | 1.0 | 0.3 | 1.0 | 0.3 | 1.0 | 1.5 | 1.0 |
| PEG-40氢化蓖麻油 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| 香料 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 |
| 丙烷/丁烷 | 10 | 10 | - | 10 | - | 10 | 10 |
| 乙醇 | - | - | - | - | - | 15 | - |
| 水 | 加至100 | 加至100 | 加至100 | 加至100 | 加至100 | 加至100 | 加至100 |
聚合物1：利用磷酸中和至pH6.0的无规、线型共聚物，其由乙烯基吡咯烷酮、丙烯酸叔丁酯、甲基丙烯酸、二甲基氨基丙基甲基丙烯酰胺和乙基硫酸甲基丙烯酰基乙基二甲基乙基铵构成。
| 8 | 9 | 10 | 11 | 12 | 13 | 14 | |
| 聚合物1 | 3.5 | 0.8 | 2 | 0.5 | 1.5 | 0.8 | 2 |
| VP/VA共聚物 | - | 2 | 4 | 1.5 | 3.5 | - | - |
| PVP | - | - | - | - | - | 2 | 4 |
| 聚季铵盐-68(LuviquatSupreme；BASF) | - | - | - | 1 | 2 | - | - |
| 西曲氯铵 | 0.8 | 0.5 | 0.1 | 0.5 | - | 0.9 | - |
| 羟乙基鲸蜡基二甲基磷酸铵 | 1.0 | - | - | - | - | - | 0.5 |
| PEG-12聚二甲基硅氧烷 | - | 0.2 | - | 0.5 | - | 0.2 | |
| 聚二甲基硅氧烷共聚醇 | 0.3 | 0.3 | - | 0.3 | - | 0.3 | - |
| 泛醇 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
| 柠檬酸 | 0.2 | 0.2 | 0.3 | 0.2 | 0.3 | 0.3 | 0.3 |
| 苯甲酸钠 | 0.2 | - | 0.2 | 0.2 | 0.2 | - | 0.2 |
| PEG-40氢化蓖麻油 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| 香料 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 |
| 水 | 加至100 | 加至100 | 加至100 | 加至100 | 加至100 | 加至100 | 加至100 |
聚合物1：利用磷酸中和至pH6.0的无规、线型共聚物，其由乙烯基吡咯烷酮、丙烯酸叔丁酯、甲基丙烯酸、二甲基氨基丙基甲基丙烯酰胺和乙基硫酸甲基丙烯酰基乙基二甲基乙基铵构成。
| 15 | 16 | 17 | 18 | 19 | |
| 聚合物1 | 3.5 | 2.5 | 2 | 1.5 | 2 |
| VP/VA共聚物 | - | 0.5 | 4 | 3.5 | - |
| PVP | - | - | - | - | 4 |
| 聚季铵盐-68(LuviquatSupreme；BASF) | - | - | - | 2 | - |
| 西曲氯铵 | 0.8 | 0.8 | 0.1 | - | - |
| 羟乙基鲸蜡基二甲基磷酸铵 | 1.0 | 1.0 | - | - | 0.5 |
| PEG-12聚二甲基硅氧烷 | 0.2 | 0.2 | 0.5 | 0.2 | |
| 聚二甲基硅氧烷共聚醇 | 0.3 | - | - | - | - |
| 泛醇 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
| 柠檬酸 | 0.2 | 0.2 | 0.3 | 0.3 | 0.3 |
| PEG-40氢化蓖麻油 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| 香料 | 适量 | 适量 | 适量 | 适量 | 适量 |
| 乙醇 | 60 | 30 | 30 | 30 | 15 |
| 水 | 加至100 | 加至100 | 加至100 | 加至100 | 加至100 |
聚合物1：利用磷酸中和至pH6.0的无规、线型共聚物，其由乙烯基吡咯烷酮、丙烯酸叔丁酯、甲基丙烯酸、二甲基氨基丙基甲基丙烯酰胺和乙基硫酸甲基丙烯酰基乙基二甲基乙基铵构成。
Claims (13)
1.一种用于处理角蛋白纤维的制剂，特别是化妆用毛发定型剂，所述制剂包含：
a)至少一种阳离子、两性聚合物，其由下列单体构成：乙烯基吡咯烷酮、丙烯酸叔丁酯、甲基丙烯酸、二甲基氨基丙基甲基丙烯酰胺和乙基硫酸甲基丙烯酰基乙基二甲基乙基铵，其中甲基丙烯酸的比例小于二甲基氨基丙基甲基丙烯酰胺的比例，并且所述聚合物已用适合的酸中和，
b)至少一种非离子聚合物，和
c)至少一种硅油。
2.根据权利要求1的制剂，其特征在于，所述一种或更多种阳离子、两性聚合物的活性含量以所述制剂的总重量计为0.01至10重量％，优选0.05至5重量％。
3.根据前述权利要求中任一项的制剂，其特征在于，所述阳离子、两性聚合物是利用磷酸中和至pH6.0的无规、线型共聚物，其由乙烯基吡咯烷酮、丙烯酸叔丁酯、甲基丙烯酸、二甲基氨基丙基甲基丙烯酰胺和乙基硫酸甲基丙烯酰基乙基二甲基乙基铵构成。
4.根据前述权利要求中任一项的制剂，其特征在于，所述一种或更多种非离子聚合物的活性含量以所述制剂的总重量计为0.01至10重量％，优选0.1至5重量％。
5.根据前述权利要求中任一项的制剂，其特征在于，所述非离子聚合物是乙烯基吡咯烷酮和乙酸乙烯酯的共聚产物。
6.根据前述权利要求中任一项的制剂，其特征在于，所述一种或更多种硅油的活性含量以所述制剂的总重量计为0.01至5重量％，优选0.05至2.5重量％。
7.根据前述权利要求中任一项的制剂，其特征在于，所述一种或更多种硅油选自线型或环状的聚硅氧烷，PEG改性和/或PPG改性的聚硅氧烷。
8.根据前述权利要求中任一项的制剂，其特征在于，所述制剂包含0至95重量％，优选5至60重量％的乙醇，以所述制剂的总重量计。
9.根据前述权利要求中任一项的制剂，其特征在于，所述制剂包含0至25重量％，优选1至15重量％的推进剂，以所述制剂的总重量计。
10.根据前述权利要求中任一项的制剂，其作为用于毛发的含推进剂的泡沫定型剂、泵式泡沫定型剂或者泵式喷发胶的形式存在。
11.根据前述权利要求中任一项的制剂，其额外包含至少一种其它阴离子、阳离子、非离子或两性的成膜聚合物，其浓度以所述制剂的总重量计为0至10重量％，优选1至5重量％。
12.根据前述权利要求中任一项的制剂，其额外包含UV过滤剂、抗氧化剂、油、提取物、蛋白质和/或蛋白质水解物、颜料和/或香料。
13.根据前述权利要求中任一项的制剂用于塑造人和/或动物发型的用途。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102008040102.1 | 2008-07-03 | ||
| DE200810040102 DE102008040102A1 (de) | 2008-07-03 | 2008-07-03 | Volumengebender Haarfestiger |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101617997A true CN101617997A (zh) | 2010-01-06 |
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ID=41130333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910149543A Pending CN101617997A (zh) | 2008-07-03 | 2009-07-02 | 使毛发丰盈的毛发定型剂 |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP2310096A2 (zh) |
| CN (1) | CN101617997A (zh) |
| DE (1) | DE102008040102A1 (zh) |
| WO (1) | WO2010000361A2 (zh) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102488629A (zh) * | 2011-12-21 | 2012-06-13 | 广州好迪集团有限公司 | 一种发用定型剂及发用定型品 |
| CN106176288A (zh) * | 2015-05-27 | 2016-12-07 | 株式会社爱茉莉太平洋 | 增强毛发的蓬松感的毛发或头皮用组合物 |
| CN106420402A (zh) * | 2016-11-15 | 2017-02-22 | 九江天赐高新材料有限公司 | 一种头发造型组合物 |
| CN107157807A (zh) * | 2017-06-08 | 2017-09-15 | 广州天赐高新材料股份有限公司 | 一种毛发定型组合物及其制备方法 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3275422B1 (en) | 2016-07-26 | 2019-11-20 | Kao Germany GmbH | Aqueous hair styling composition comprising high amounts of waxes and fatty compounds |
| DE102018216625A1 (de) * | 2018-09-27 | 2020-04-02 | Beiersdorf Ag | Kosmetische Zubereitung für die Haare freigesetzt in Aerosolform |
| DE102018216640A1 (de) * | 2018-09-27 | 2020-04-02 | Beiersdorf Ag | Pumpbare Zubereitung für die Haare |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2335324T3 (es) * | 2006-09-15 | 2010-03-24 | Basf Se | Copolimero anfolito a base de monomeros nitrogenados cuaternizados. |
| DE102008006227A1 (de) * | 2008-01-25 | 2009-07-30 | Beiersdorf Ag | Haarspray mit besonders hohem Langzeithalt |
| DE102008012959A1 (de) * | 2008-03-06 | 2009-09-10 | Beiersdorf Ag | Haarspray mit besonders hohem Langzeithalt |
| DE202008004924U1 (de) * | 2008-03-06 | 2008-06-26 | Beiersdorf Ag | Haarspray mit besonders hohem Langzeithalt |
| DE102008013171A1 (de) * | 2008-03-07 | 2009-09-10 | Beiersdorf Ag | Volumengebender Haarfestiger mit ampholytischem Copolymer |
| DE102008001661A1 (de) * | 2008-05-08 | 2009-11-12 | Beiersdorf Ag | Haarpflegeformulierungen mit kationisch amphoteren Polymeren |
| EP2116225A1 (de) * | 2008-10-16 | 2009-11-11 | Beiersdorf AG | Ausspülhaarspülungen zur Steigerung des Frisurvolumens |
-
2008
- 2008-07-03 DE DE200810040102 patent/DE102008040102A1/de not_active Withdrawn
-
2009
- 2009-06-03 EP EP09772061A patent/EP2310096A2/de not_active Ceased
- 2009-06-03 WO PCT/EP2009/003957 patent/WO2010000361A2/de active Application Filing
- 2009-07-02 CN CN200910149543A patent/CN101617997A/zh active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102488629A (zh) * | 2011-12-21 | 2012-06-13 | 广州好迪集团有限公司 | 一种发用定型剂及发用定型品 |
| CN102488629B (zh) * | 2011-12-21 | 2012-11-14 | 广州好迪集团有限公司 | 一种发用定型剂及发用定型品 |
| CN106176288A (zh) * | 2015-05-27 | 2016-12-07 | 株式会社爱茉莉太平洋 | 增强毛发的蓬松感的毛发或头皮用组合物 |
| CN106420402A (zh) * | 2016-11-15 | 2017-02-22 | 九江天赐高新材料有限公司 | 一种头发造型组合物 |
| CN107157807A (zh) * | 2017-06-08 | 2017-09-15 | 广州天赐高新材料股份有限公司 | 一种毛发定型组合物及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2010000361A9 (de) | 2011-04-28 |
| DE102008040102A1 (de) | 2010-01-07 |
| WO2010000361A3 (de) | 2010-03-11 |
| EP2310096A2 (de) | 2011-04-20 |
| WO2010000361A2 (de) | 2010-01-07 |
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Application publication date: 20100106 |