MXPA97008071A - Cosmetic composition to keep the hair shape fixed and give bright appearance to my - Google Patents

Abstract

The present invention relates to a cosmetic composition for the treatment of keratin materials, in particular of hair, comprising at least one fixed polymer, at least 5% by weight of a non-volatile arylated silicone, and at least one volatile silicone, as well as the procedure of treatment of keratimic materials with the help of this composition

Description

COSMETIC COMPOSITION FOR KEEPING HAIR THE SHAPE OF THE HAIR AND GIVE BRIGHT APPEARANCE TO THE SAME DESCRIPTION OF THE INVENTION The present invention relates to a cosmetic composition for the treatment of keratin materials, in particular hair, comprising at least one fixative polymer, at least 5% by weight of a non-volatile aryl silicone and at least one volatile silicone, as to the method of treating the keratin materials with the aid of this composition. Hair care or styling compositions containing styling polymers (fixative polymers) in their formulation generally have the drawback of making it difficult to untangle, comb or brush the hair, in particular during brushing. Styling polymers also tend to make hair dull or dull. The combination of the silicone derivatives with fixative polymers is known in cosmetic compositions for the maintenance and / or fixation of the hairstyle. It has been found that silicone derivatives improve the detangling properties, REP: 25562 softness and brilliance of the treated hair with the help of these compositions. However, on the one hand, the silicone derivatives are not favorable for the combing properties of the compositions containing the fixing polymers and, on the other hand, the gloss properties are not yet satisfactory. There are products called "brighteners" that are applied in the finishing treatment, that is, on dry hair. These products are difficult to apply because if the applied amount is very large or poorly distributed, the hair has in general a tactile sensation and a greasy visual appearance. In addition, these products do not provide any fixation. The object of the present invention is therefore to propose compositions that allow the styling to be fixed and / or put into shape, these compositions having to have good properties of firmness over time and provide excellent gloss properties. Now, the applicant has surprisingly discovered that by using compositions containing a fixative polymer in association with at least one non-volatile arylated silicone and at least one volatile silicone in a cosmetically acceptable medium, excellent gloss properties are obtained, a good time The present invention therefore has for its object a cosmetic composition comprising, in a cosmetically acceptable medium, at least one fixing polymer, at least 5% by weight of a non-volatile arylated silicone. and at least one volatile silicone Surprisingly, the decrease in fixative power of the compositions is limited despite the presence of a significant amount of silicone? The combing properties are substantially of the same degree as those of a composition that contains only the fixing polymer. In particular, the fixative power, the firmness in the time and the volume of the hair are very good. After drying, these compositions do not become dust on the hair at the time of brushing or combing (there are no white films) and they are invisible on the hair. The treated hair has a non-greasy feel and visual appearance. In addition, the brushing and / or combing of the hair after the application of the product even improves the brilliance.

In the context of the present application, cosmetic compositions for the maintenance of the hairstyle are understood to be any composition whose function is to temporarily fix the shape of the hairstyle, such as, for example, hairspray and hair spray. By the fixative power of the composition, the aptitude of the latter is designated to give the hair a cohesion in such a way that the initial shaping of the hairstyle is conserved. Fixing polymer, any polymer that has the function of temporarily fixing the shape of the hairstyle is understood. According to the invention, any known fixative polymer can be used in itself. In particular, a fixing polymer chosen from ionic, cationic, amphoteric, nonionic polymers and their mixtures can be used. The fixing polymers can be used in the solubilized form or in the form of dispersions of solid polymer particles. The cationic fixing polymers usable according to the present invention are preferably chosen from polymers which include primary, secondary, tertiary and / or quaternary amine groups, which are part of the polymer chain or directly attached to it, and which have a weight molecular weight in weight comprised between about 500 and about 5,000,000 and preferably between 1,000 and 3,000,000. Among these polymers, the following cationic polymers may be more particularly cited: (1) homopolymers or copolymers derived from esters or acrylic or methacrylic amides, and which include at least one of the portions of the following formulas: - wherein: R3 designates a hydrogen atom or a CH3 radical; A is a linear or branched alkyl group of 1 to 6 carbon atoms or a hydroxyalkyl group of 1 to 4 carbon atoms; R 4, R 5, R 2, which are identical or different, represent an alkyl group having 1 to 18 carbon atoms or a benzyl radical; Ri and R2 represent hydrogen or an alkyl group having from 1 to 6 carbon atoms; X designates a methosulfate anion or a halide such as chloride or bromide. The copolymers of the family (1) also contain one or more monomer portions which can be selected from the family of acrylamides, methacrylamides, diacetone acrylamides, acrylamides and substituted methacrylamides on nitrogen with lower alkyl of 1 to 6 carbon atoms, acrylics or methacrylics or their esters, vinyl lactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters, etc. Thus, among these copolymers of the family (1), there may be mentioned: the copolymers of acrylamide and quaternized dimethylaminesyl methacrylate or dimethyl sulfate or with a dimethyl halide such as that sold under the name of HERCOFLOC by the company HERCULES, the copolymers of acrylamide and of methacryloyloxyethyltrimethylammonium chloride described, for example, in the European Patent Application EP-A-080976 and sold under the name BINA QUAT P 100 by the company CIBA GEIGY, the acrylamide and methacryloyloxyethyltrimethylammonium metasulfate copolymer sold under the name RETEN by the company HERCULES, the quaternized or not quaternized dialkylaminoalkyl vinylpyrrolidone / methacrylate or methacrylate copolymers, such as the products sold by the name "GAFQUAT", by the ISP company such as "GAFQUAT 734" or "GAFQUAT 755" or the products called "COPOLYMER 845, 958 and 937". These polymers are described in detail in French Patents Nos. 2,077, 143 and 2,393,573. the terpolymers of dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone such as the product sold under the name GAFFIX VC 713 by the company ISP. and the quaternized dimethylaminopropyl vinylpyrrolidone / methacrylamide copolymer such as the product sold under the name "GAFQUAT HS 100" by the company ISP. (2) the quaternized polysaccharides described more particularly in U.S. Patent Nos. 3,589,578 and 4,031,307, such as the product marketed under the name JAGUAR C 13 S by the company MEYHALL; (3) the quaternary copolymers of vinylpyrrolidone and vinylimidazole; (4) chitosans and their salts; the usable salts are in particular, acetate, lactate, glutamate, gluconate or the pyrrolidone carboxylate of chitosan. Among these compounds, mention may be made of chitosan having a deacetylation ratio of 90.5% by weight, sold under the name KYTAN BRUT STANDARD by the company ABER TECHNOLOGIES, the pyrrolidone carboxylate of chitosan sold under the name KYTAMER PC by the company AMERCHOL . The anionic fixing polymers generally used are the polymers which include the carboxylic, sulfonic or phosphoric acid derivative groups and have a weight average molecular weight of between about 500 and 5,000,000. 1) carboxylic groups are provided by unsaturated mono- or dicarboxylic acid monomers such as. those that respond to the formula: in which n is an integer from 0 to 10, Ax designates a methylene group, optionally linked to the carbon atom of the unsaturated group or the neighboring methylene group when n is greater than 1, by means of a heteroatom such as oxygen or sulfur R7 denotes a hydrogen atom, a phenyl or benzyl group, R8 denotes a hydrogen atom, a lower alkyl group of 1 to 6 carbon atoms or carboxyl, R9 denotes a hydrogen atom, a lower alkyl group of 1 to 6 carbon atoms, a group -CH2-C00H, phenyl or benzyl; In the above formula a lower alkyl radical preferably designates a group having from 1 to 6 carbon atoms and in particular, methyl and ethyl. Anionic fixing polymers with preferred carboxylic groups according to the invention are: A) the homo- or copolymers of acrylic or methacrylic acid or their salts and in particular the products sold under the names VERSICOL E or K by the company ALLIED COLLOID and ULTRAHOLD by the company BASF. The acrylic acid and acrylamide copolymers sold in the form of their sodium salt under the names RETEN 421, 423 or 425 by the Company HERCULES, the sodium salts of polyhydroxycarboxylic acids. B) copolymers of acrylic or methacrylic acids with a monoethylenic monomer such as ethylene, styrene, vinyl esters, esters of acrylic or methacrylic acid, optionally grafted onto a polyalkylene glycol such as polyethylene glycol and optionally crosslinked. Such polymers are described in particular in French Patent No. 1,222,944 and German Application No. 2,330,956, copolymers of this type include in their chain an optionally N-alkylated and / or hydroxyalkylated acrylamide portion, as described mainly in the applications of Luxemburg patent 75370 and 75371 or proposals under the name QUADRAMER by the AMERICAN CYANAMID Company. Mention may also be made of copolymers of acrylic acid and alkyl methacrylate of 1 to 4 carbon atoms and terpolymers of vinylpyrrolidone, of acrylic acid and of alkyl methacrylate of 1 to 20 carbon atoms, for example of lauryl, such as sold by the company ISP under the name ACRYLIDONE LM and the terpolymers of methacrylic acid / ethyl acrylate / terbutyl acrylate such as the product sold under the name LUVIMER 100 P by the company BASF. C) copolymers derived from crotonic acid such as those which include in their chain the portions of vinyl acetate or propionate and optionally other monomers such as the allyl or metalyl esters, vinyl ether or vinyl ester of a saturated linear or branched carboxylic acid with hydrocarbon long chain, such as those including at least 5 carbon atoms, these polymers being optionally grafted and crosslinked or even a vinyl, allyl or metalyl ester of an α- or β-cyclic carboxylic acid. Such polymers are described inter alia in French patents Nos. 1,222,944, 1,580,545, 2,265,782, 2,265,781, 1,564,110 and 2,439,798. Commercial products that fall into this class are resins 28-29-30, 26-13-14 and 28-13-10 sold by the company NATIONAL STARCH.

D) copolymers derived from monounsaturated carboxylic acids or anhydrides of 4 to 8 carbon atoms chosen from: the copolymers comprising (i) one or more maleic, fumaric, itaconic acids or anhydrides and (ii) at least one monomer selected among the vinyl esters, the vinyl ethers, the vinyl halides, the phenyl vinyl derivatives, the acrylic acid and its esters, the anhydride functional groups of these copolymers which are eventually monosterified or monoamidified. Such polymers are described in particular in U.S. Patent Nos. 2,047,398, 2,723,248, 2,102,113, British Patent GB 839,805 and mainly those sold by the names GANTREZ AN or ES by the company ISP. copolymers comprising (and) one or more maleic, citraconic, itaconic anhydrides and (ii) one or more monomers chosen from the allylic or etalyl esters optionally including one or more acrylamide, methacrylamide, α-olefin groups, esters Acrylics or methacrylics, acrylic or methacrylic acids or vinylpyrrolidone in their chain, the anhydride functional groups of their copolymers are optionally monoesterified or monoamidified. These polymers are for example described in French Patent Nos. 2,350,384 and 2,357,241 of the Applicant. E) polyacrylamides which include the carboxylate groups. The polymers comprising the sulfonic groups are polymers which include vinyl sulfonic, styrene-sulfonic moieties, naphthalene sulphonic or acrylamidoalkylsulfonic. These polymers can be chosen mainly from: - the polyvinylsulfonic acid salts having a weight average molecular weight of between about 1,000 and 100,000, as well as the copolymers with an unsaturated comonomer such as acrylic or methacrylic acids and esters, as well as acrylamide or its derivatives, vinyl ethers and vinylpyrrolidone. the salts of polystyrene sulphonic acid, the sodium salts having a weight average molecular weight of about 500,000 and about 100,000 sold respectively under the names of Flexan 500 and Flexan 130 by National Starch. These compounds are described in the French patent FR 2, 198, 719. the salts of polyacrylamido-sulfonic acids such as those mentioned in the US patent No. US 4,128,631 and more particularly the polyacrylamidoethylpropane-sulfonic acid sold under the name COSMEDIA POLYMER HSP 1180 BY Henkel. According to the invention, anionic fixing polymers are preferably chosen from acrylic acid copolymers such as the terpolymer of acrylic acid / ethyl acrylate / N-terbutylacrylamide, sold under the name ULTRAHOLD STRONG by the company BASF, the copolymers crotonic acid derivatives such as the terpolymers of vinyl acetate / vinyl terbutylbenzoate / crotonic acid and the terpolymers of crotonic acid / vinyl acetate / vinyl neododecanoate, sold under the name Resin 28-29-30 by the company NATIONAL STARCH, polymers derived from maleic, fumaric, itaconic acid or anhydrides with vinyl esters, vinyl ethers, vinyl halides, phenyl vinyl derivatives, acrylic acid and their esters such as methyl vinyl ether / maleic anhydride copolymer, esterified, sold under the name GANTREZ ES 425 by the company ISP, the copolymers of ac methacrylic and methyl methacrylate sold under the name EUDRAGIT L by the company ROHM PHARMA, the copolymer of methacrylic acid and ethyl acrylate sold under the name LUVIMER MAEX or MAE by the BASF company and the vinyl acetate / acid copolymer crotónico sold under the name of LUVISET CA 66 by the company BASF and copolymer of vinyl acetate / crotonic acid grafted with polyethylene glycol under the name ARISTOFLEX A by the company BASF. The more particularly preferred anionic fixing polymers are chosen from the onesterified ethyl vinyl ether / maleic anhydride copolymer sold under the name GANTREZ ES 425 by the company ISP, the terpolymer acrylic acid / ethyl acrylate / N-terbutylacrylamide sold under the name ULTRAHOLD STRONG by company BASF, the copolymers of methacrylic acid and methyl methacrylate sold under the name EUDRAGIT L by the company ROHM PHARMA, the terpolymers of vinyl acetate / terbutilbenzoate of vinyl / crotonic acid and the terpolymers of crotonic acid / vinyl acetate / vinyl neododecanoate, sold under the name Resine 28-29-30 under the company NATIONAL STARCH, the copolymer of methacrylic acid and ethyl acrylate sold under the name LUVIMER MAEX or MAE by the company BASF, the terpolymer of vinylpyrrolidone / acid acrylic / methacrylate - lauryl sold under the name ACRYLIDONE LM by the company ISP. The amphoteric fixative polymers which can be used according to the invention can be chosen from polymers including portions B and C, statistically distributed in the polymer chain where B denotes a portion derived from a monomer that includes at least one nitrogen atom basic, and C designates a portion that is derived from an acidic monomer that includes one or more carboxylic or sulfonic groups, or B and C may designate groups that are derived from amphoteric monomers within carboxybetaines or sulfobetaines; B and C can also designate a cationic polymer chain including the primary, secondary, tertiary or quaternary amine groups, in which at least one of the amine groups includes a carboxylic or sulfonic group attached via a hydrocarbon radical, or B and C are part of a chain of a polymer with an ethylene-α, β-dicarboxylic moiety where one of the carboxylic groups has been reacted with a polyamine which includes one or more primary or secondary amine groups. Amphoteric fixative polymers meet the definition given above, more particularly preferred, are chosen from the following polymers: 1) polymers resulting from the polymerization of a monomer derived from a vinyl compound including a carboxylic group, more particularly such as acrylic acid, methacrylic acid, maleic acid, alpha-chloracrylic acid, and of a basic monomer derived from a substituted vinyl compound containing at least one basic atom more particularly such as dialkylaminoalkyl methacrylate and acrylate, dialkylaminoalkyl methacrylamide and acrylamide. Such compounds are described in U.S. Pat. 3 836 537. (2) the polymers including the derivative portions: a) of at least one monomer chosen from the acrylamides or substituted methacrylamides on the nitrogen with an alkyl radical, b) of at least one comonomer of acid contains one or more reactive carboxylic groups, and c) at least one basic comonomer such as esters with primary, secondary, tertiary and quaternary amine substituents of acrylic and methacrylic acids and the quaternization product of dimethylaminoethyl methacrylate with dimethyl sulfate or of diethyl The N-substituted acrylamides or methacrylamides more particularly preferred according to the invention are the groups in which the alkyl radicals contain from 2 to 12 carbon atoms and more particularly N-ethylacrylamide, N-tert-butyl acrylamide, N-tertiaryctylacrylamide, N-octylacrylamide, N-decylacrylamide, N-dodecyl acrylamide, as well as the corresponding methacrylamides. The acidic comonomers are chosen more particularly from acrylic, methacrylic, crotonic, itaconic, maleic, fumaric acids, as well as alkyl monoesters having from 1 to 4 carbon atoms of the maleic or fumaric acids or anhydrides. Preferred basic comonomers are aminoethyl, butylated, butyl, N, N'-dimethylaminoethyl, N-tert-butylaminoethyl methacrylates. Copolymers are particularly used where the CTFA name (4th ed.1991) is the octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer such as the products sold under the name AMPHOMER or LOVOCRYL 47 by the company NATIONAL STARCH. 3) the crosslinked and partially or fully alkylated polyammonamides which are derived from the polyaminoamides of the general formula: wherein R10 represents a divalent radical derived from a saturated dicarboxylic acid, from a mono or dicarboxylic aliphatic acid with ethylenic double bond, from an ester of a lower alkanol having from 1 to 6 carbon atoms of these acids, with a radical which is derived from the addition of any of said acids by a bis-primary or bis-secondary amine, and Z denotes a radical of a bis-primary, mono- or bis-secondary polyalkylene-polyamine and preferably represents: a) in the proportions of 60 to 100 moles%, the radical NH [IZ (CH2) X NHZI] _ (IV) where x = 2 and p = 2 or 3, or x = 3 and p = 2, deriving this radical from diethylenetriamine, triethylene tetraane or dipropylenetriamine; b) in the proportions of 0 to 40 mol% the radical (IV) above, in which x = 2 and p = 1, and which is derived from ethylenediamine, or the radical derived from piperazine: c) in the proportions of 0 to 20 mol% the radical -NH- (CH2) 6-NH- which is derived from hexamethylenediamine, these polyaminoamines being crosslinked by the addition of a bifunctional crosslinking agent selected from epihalohydrins, diepoxides, the dianhydrides, the bis-unsaturated derivatives, at least 0.025 to 0.35 moles of crosslinking agent per amine group of polyaminoamide and alkylated by the action of acrylic acid, of chloracetic acid or of an alcansulfone or one of its salts. The saturated carboxylic acids are preferably chosen from acids having from 6 to 10 carbon atoms such as adipic acid, trimethyl-2,2,4-adipic and trimethyl-2,4,4-adipic, terephthalic, acids with double ethylenic bond such as acrylic, methacrylic, and itaconic acids. The alkylamines used in the alkylation are preferably the propan-or butan-sultone, the salts of the alkylating agents are preferably the sodium or potassium salts. (4) the polymers include zirionionic moieties of the formula: (V) wherein Rn designates a polymerizable unsaturated group such as an acrylate, methacrylate, acrylamide or methacrylamide group, and yz represent an integer from 1 to 3, Ri2 and Ri3 represent a hydrogen atom, methyl, ethyl or propyl, RX and R? 5 represents a hydrogen atom or an alkyl radical such that the sum of the carbon atoms in R 4 and R 15 does not exceed 10.

The polymers comprising such units may also comprise portions derived from non-amphoteric monomers such as the dimethyl or diethylaminoethyl acrylate or methacrylate or the alkyl acrylates or methacrylates, the acrylamides or methacrylamides or the vinyl acetate. By way of example, mention may be made of the methyl methacrylate / dimethyl-carboxymethylammonium / methyl methacrylate copolymers, such as the product sold under the name DIAFORMER Z301 by the company SANDOZ. (5) the polymers derived from the cytosan that include the monomeric portions that respond to the following formulas: I NNHHC the portion D is present in the proportions comprised between 0 and 30%, the portion E in the proportions comprised between 5 and 50% and the portion F in the proportions comprised between 30 and 90%, it being understood that in this portion F, R16 represents a radical of the formula: wherein if q = 0, R ^, R13 and R19 identical or different p, each represents a hydrogen atom, a residue of methyl, hydroxyl, acetoxy or amino, a residue of monoalkylamino or a residue of dialkylamino optionally interrupted by one or several nitrogen atoms and / or optionally substituted with one or more amino, hydroxyl, carboxyl, alkylthio, sulphonic groups, an alkylthio residue wherein the alkyl group includes an amino residue, at least one of the radicals R1, Ris and R9 are in this case a hydrogen atom; or if q = 1, Ri ?, Ris and R19 each represent a hydrogen atom, as well as the salts formed by those compounds or the bases or acids. (6) polymers derived from the N-carboxyalkylation of chitosan such as N-carboxymethyl chitosan or N-carboxybutyl chitosan sold under the name "EVALSAN" by the company JAN DEKKER. (7) Polymers corresponding to the general formula (VI) are for example described in the French patent 1,400,366: wherein R2o represents a hydrogen atom, a radical CH30, CH3CH20, phenyl, R2i designates hydrogen or a lower alkyl radical such that methyl, ethyl, R22 designates hydrogen or a lower alkyl radical such as methyl, ethyl, R23 designates a lower alkyl radical such that methyl, ethyl or a radical which corresponds to the formula: -R24-N (R22) 2, R24 represents a group -CH2-CH2-, -CH2-CH2-CH2-, -CH2CH (CH3) -, R;,: has the meanings mentioned above. as well as the superior homologs of these radicals and containing up to 6 carbon atoms. (8) Amphoteric polymers of the type -D-X-D-X chosen from: a) polymers obtained by the action of chloroacetic acid or sodium chloroacetate on the compounds that include at least a portion of the formula: -D-X-D-X-D- (VII) where D designates a radical and X denotes the symbol E or E ', E or E', which are identical or different, denote a bivalent radical which is an o-branched straight-chain alkylene radical including up to 7 carbon atoms in the main chain unsubstituted or substituted by hydroxyl groups and which may further possess oxygen, nitrogen, sulfur atoms, 1 to 3 aromatic and / or heterocyclic rings; the oxygen, nitrogen and sulfur atoms are present in the form of ether, thioether, sulfoxide, sulfone, sulfonium, alkylamine, alkenylamine groups, hydroxyl groups, benzylamine, amine oxide, quaternary ammonium, amide, imide, alcohol, ester and / or urethane. b) the polymers of the formula: -D-X-D-X- (VII ') where D designates a radical and X designates the symbol E or E 'and at least once E'; having E the meaning indicated above, and E 'is a bivalent radical which is a straight chain or branched alkylene radical having up to 7 carbon atoms in the main chain, substituted or unsubstituted by one or more hydroxyl radicals including one or more several nitrogen atoms, the nitrogen atom being substituted with an alkyl chain optionally interrupted by an oxygen atom and which necessarily includes one or more carboxyl functional groups or one or more hydroxyl functional groups and betainised by reaction with the chloroacetic acid or sodium chloracetate. (9) copolymers of (alkyl of 1 to 5 carbon atoms) vinyl ether / maleic anhydride partially modified by semiamidification with a N, N-dialkylaminoalkylamine such as N, N-dimethylaminopropylamine or by semi-esterification with an N, N-dialkanolamine. These copolymers can also include other vinyl monomers such as vinylcaprolactam. Particularly preferred amphoteric fixing polymers according to the invention are those of the family (3) such as copolymers where the CTFA designation is the octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer, such as the products sold under the names AMPHOMER, AMHOMER LV 71 or LOVOCRYL 47 by the company NATIONAL STARCH and those of the family (4) such as methyl methacrylate / methyl dimethylcarboxymethylammonium methylmethacrylate copolymer sold, for example, under the name DIAFORMER Z301 by the company SANDOZ. The nonionic fixing polymers which can be used according to the present invention are selected, for example, from: polyalkyloxazolines such as polyethyloxazolines proposed by DOW CHEMICAL under the names PEOX 50 000, PEOX 200 000 and PEOX 500 000. the vinyl acetate homopolymers such as the product proposed under the name of APRETAN EM by the company HOECHST or the product proposed under the name of RHODOPAS A 012 by the company RHONE POULENC; the copolymers of vinyl acetate and acrylic ester such as the product proposed under the name RHODOPAS AD 310 of RHONE POULENC. the vinyl acetate and ethylene copolymers such as the product proposed under the name of APPRETAN TV by the company HOECHST; copolymers of vinyl acetate and maleic ester for example of ditubyl maleate such as the product proposed under the name of APPRETAN MB EXTRA by the company HOECHST; vinyl chloride homopolymers such as the products proposed under the names of GEON 460X45, GEON 460X46 and GEON 577 by the company GOODRICH; polyethylene waxes such as the products proposed under the names AQUACER 513 and AQUACER 533 by the company BYK CERA; polyethylene / polytetrafluoroethylene waxes such as the products proposed under the names DREWAX D-3750 by the company DREW AMEROID and WAX DISPERSION WD-1077 by the company R.T '. NEWEY; the polyethylene and maleic anhydride copolymers; the homopolymers of alkyl acrylates and the homopolymers of alkyl methacrylates such as the products proposed under the name MICROPEARL RQ 750 by the company MATSUMOTO or the product proposed under the name LUHYDRAN A 848 S by the company BASF; copolymers of acrylic esters such as for example the copolymers of alkyl acrylates and alkyl methacrylates such as the products proposed by the company ROHM &HAAS under the names PRIMAL AC-261 K and EUDRAGIT EN 30 D, by the company BÁSF under the names ACRONAL 601, LUHYDRAN LR 8833 or 8845, by the company HOECHST under the names APRETAN N 9213 or N9212; the copolymers of acrylonitrile and of a nonionic monomer chosen for example between butadiene and alkyl (meth) acrylates; you can quote the proposed products under the names NIPOL LX 531 B by the company NIPPON ZEON or those proposed under the denominations CJ 0601 B by the company ROHM & HASS. - styrene homopolymers such as the product RHODOPAS 50551 proposed by the company RHONE POULENC; the copolymers of styrene and of alkyl (meth) acrylate such as the products MOWILITH LDM 6911, MOWILITH DM 611 and MOWILITH LDM 6070 proposed by the company HOECHST, the products RHODOPAS SD 215 and RHODOPAS DS 910 proposed by the company RHONE POULENC; the copolymers of styrene, alkyl methacrylate and alkyl acrylate such as the product DAITISOL SPA proposed by the company WACKHERR; styrene and butadiene copolymers such as the products RHODOPAS SB 153 and RHODOPAS SB 012 proposed by the company RHONE POULENC. styrene, butadiene and vinylpyridine copolymers such as GOODRITE SB products VINYLPYRIDINE 2528X10 and GOODRITE SB VINYLPYRIDINE 2508 proposed by the company GOODRICH; - polyurethanes such as the products proposed under the names ACRYSOL RM 1020 or ACRYSOL RM 2020 by the company ROHM & HAAS, products URAFLEX XP 401 UZ, URAFLEX XP 402 UZ by the company DSM RESINS; - the alkyl acrylate and urethane copolymers such as the products 8538-33 by the company NATIONAL STARCH; the polyamides such as the product ESTAPOR LO 11 proposed by the company RHONE POULENC. The alkyl radicals of the nonionic polymers have from 1 to 6 carbon atoms unless otherwise mentioned. According to the invention, fixative polymers of the grafted silicone type comprising a portion of polysiloxane and a portion consisting of a non-silicone organic chain can also be used, one of the two portions constituting the main chain of the polymer and the other being grafted. on said main chain. These polymers are, for example, described in patent applications EP-AO 412 704, EP-AO 412 707, EP-AO 640 105 and WO 95/00578, EP-A-0582 152 and WO 93/23009 and US Pat. 4,693,935, US 4,728,571 and US 4,972,037. These polymers are preferably anionic or non-ionic. Such polymers are, for example, copolymers which can be obtained by radical polymerization from the monomer mixture consisting of: a) 50 to 90% by weight of tert-butyl acrylate; b) 0 to 40% by weight of acrylic acid; c) 5 to 40% by weight of silicone macromer of the formula: (CH2) r • CH, with v that is a number that goes from 5 to 700; the percentages by weight being calculated in relation to the total weight of the monomers. Other examples of grafted silicone polymers are, in particular, polydimethylsiloxanes (PDMS) onto which the mixed polymer portions of the poly (meth) acrylic acid type and of the poly (meth) acrylate type are grafted by means of a thiopropylene-type binding member. of alkyl and of polydimethylsiloxanes (PDMS) onto which the polymeric portions of the isobutyl poly (meth) acrylate type are grafted, by means of a thiopropylene-type binding member. According to the present invention, the fixing polymers are preferably anionic polymers. The anionic or amphoteric fixative polymers can be, if necessary partially or totally neutralized. Neutralization agents are, for example, soda, potash, 2-amino-2-methyl-1-propanol, monoethanolamine, triethanolamine or triisoporpanolamine, mineral or organic acids such as hydrochloric acid or citric acid. . By volatile silicone, it is understood according to the present invention, any silicone having a measurable vapor pressure and in particular that is measured at 25 ° C at atmospheric pressure (105 Pa) which is preferably greater than 0.01 mm Hg (2.6 Pa). Preference is given to using oils where the boiling point at atmospheric pressure is of the order of 80 to 260 ° C.

Among the volatile silicones, there may be mentioned: (i) cyclic volatile silicones having from 3 to 7 silicon atoms and preferably from 4 to 5 which can respond to the following formula (VIII): (VIII) in which r varies from 3 to 7 (limits included) It is, for example, cycotetradimethylsiloxane, cyclopentadimethylsiloxane or cyclohexadimethylsiloxane, (ii) linear volatile silicones having 2 to 9 silicon atoms. These can respond to the following formula (IX): ??: where s varies from 1 to 8 (including limits). It is, for example, hexamethyldisiloxane or octamethyltrisiloxane. The volatile silicones are preferably cyclotetradimethylsiloxane and hexamethyldisoloxane. By non-volatile silicone, it is understood according to the present invention, any silicone having a vapor pressure measured at 25 ° C at atmospheric pressure (105 Pa) preferably less than 0.01 mm Hg (2.6 Pa). Non-volatile arylated silicones including at least one radical of the optionally substituted aryl type. Aryl radicals are, for example, phenyl, naphthyl, benzyl or phenethyl. The non-volatile arylated silicones preferably have the following formula (X): wherein: R 24, identical or different, designates an alkyl radical of 1 to 10 carbon atoms. R26, identical or different, designates an aryl group, this aryl group may comprise one or more aryl sites, optionally substituted. R25, identical or different, designates R26, R24 or Si (R24) 3 t varies from 0 to 1000, u varies from 1 to 1000, the sum of t + u can vary from 1 to 2000 Substituents of the aryl groups can be alkyl, alkenyl, acyl, ketone, halogen groups (for example chlorine and bromine), amines. Examples of aryl groups are phenyl, a phenyl group substituted by alkyl radicals or alkenyl radicals of 1 to 5 carbon atoms such as allylphenyl, methylphenyl, ethylphenyl, vinylphenyl or mixtures thereof. Preferably, R 24 designates a methyl radical.

Preferably, R 26 denotes a phenyl radical. Preferably, R2s designates a methyl, phenyl or trimethylsilyl radical. More particularly, the sum t + u varies from 1 to 1000. Among the compounds of the formulas (X), for example, phenyl trimethicone, diphenyl dimethicone or phenyl dimethicone (designations) can be used.

INCI 5th edition 1993). By way of example of these compounds, mention may be made of those sold by the company BAYER under the name Oil BAYSILONE FLUID PD5, by the company Dow Corning under the name ODW CORNING 556 FLUID, by RHONE POULENC under names MIRASIL DPDM, RHODORSIL HUILE 510 V 100, RHODORSIL HUILE 550, RHODORSIL HUILE 510V500, RHODORSIL HUILE 710, under the names WACKER BELSIL PDM 20, PDM 200, PDM 1000 by the company WACKER. According to the present invention, non-volatile arylated silicones having a refractive index greater than or equal to 1.46, and in particular between 1.48 and 1.7, are preferably used. The refractive index is measured with the help of a refractometer according to well-known methods. The fixing polymer (s) are, for example, present in concentrations ranging from 0.1% to 20% by weight, and preferably in concentrations of between 1% and 10% by weight relative to the total weight of the composition. The volatile aryl silicone (s) may be present in concentrations between 5% and 40% by weight, and preferably in the concentrations they comprise between 10% and 30% by weight, and still more particularly from 15 to 25% by weight in relation to to the total weight of the composition. The non-volatile arylated silicone (s) may be present in concentrations ranging from % and 40% by weight, and preferably in concentrations comprising between 10% and 30% by weight and still more particularly from 12 to 20% by weight relative to the total weight of the composition. The sum of the concentrations of non-volatile aryl silicone and volatile silicone is generally comprised between 10% and 60% by weight, and preferably between 20% and 40% by weight, relative to the total weight of the composition.

The cosmetically acceptable medium generally comprises solvents compatible with the fixative polymer and the non-volatile arylated silicone. These solvents are preferably alcohols of 1 to 6 carbon atoms, which can be used alone or as a mixture. Among these alcohols, mention may be made of ethanol, isopropanol, polyalcohols such as diethylene glycol, glycol ethers, glycol monoalkyl ethers, diethylene glycol, propylene glycol or dipropylene glycol. Ethanol is particularly preferred. The compositions according to the invention are preferably free from water, ie they contain less than 8% by weight of water, relative to the total weight of the composition, and preferably less than 5%. The drying of the compositions is thus faster. According to the invention, volatile silicones and non-volatile arylated silicones are preferably solubilized in the compositions. The composition of the invention can also contain at least one additive chosen from thickeners, fatty acid esters, fatty acid esters and glycerol, non-volatile and non-aryl silicones, surfactants, perfumes, preservatives, sunscreens, proteins, vitamins, polymers, vegetable, animal, mineral or synthetic oils or any other additive classically used in the field of cosmetics. These additives are present in the composition according to the invention in proportions that can range from 0 to 20% by weight relative to the total weight of the composition. The precise amount of each additive is a function of its nature and is easily determined by the person skilled in the art. Of course, the person skilled in the art will be careful to choose the possible compound (s) to be added to the composition according to the invention, so that they are not, or are substantially not, altered by the considered addition, the advantageous properties intrinsically linked to the composition according to the invention. The compositions according to the invention can be presented in the form of milk, cream or more or less thick lotion. The compositions according to the invention can be used as rinsed products and preferably as unrinsed products mainly for the maintenance of styling or the shaping of keratin materials such as hair.

These are more particularly styling products such as the setting compositions (lacquers) and combing compositions. The lotions can be conditioned in various ways, mainly in vaporizers, in jars with pump in order to ensure an application of the composition under the vaporized form.

The object of the invention is also to provide a method for the cosmetic treatment of keratin materials, such as hair, consisting of applying a composition to them as defined above.

The preparation of the compositions according to the invention is carried out according to methods well known to the person skilled in the art. In particular, the ingredients are mixed and then packaged in an appropriate container according to the considered use.

The invention will now be more fully illustrated with the help of the following examples, which will not be considered as limiting the embodiments described. (In the subsequent MA means Active Matter).

EXAMPLE 1 A conditioning spray composition conditioned in a pump bottle of the following composition was prepared: Vinyl acetate / crotonic acid copolymer sold by the company BASF under the name LUVISET CA 66 3 g - 2-amino-2-methyl-l-propanol necessary for neutralization for 100% of phenyl silicone polymer sold under the name DC 556 by the company DOW CORNING 5 g Octamethyltetracyclosiloxane (MIRASIL CM4 from RHONE POULENC) 15 g Ethanol cbp lOOg This composition is vaporized on dry hair, the hairstyle is in place.

The hair is very bright and does not feel greasy to the touch.

EXAMPLE 2 A conditioned fixer spray composition was prepared in a pump-bottle of the following composition: Copolymer of methyl vinyl ether / monoesterified maleic anhydride sold by the company ISP under the name GANTREZ ES 425 8 g 2-amino-2-methyl-1-propanol necessary for neutralization for 20% of polymer - phenylated silicone sold under the name DC 556 by the company DOW CORNING 15 g Octamethyltetracyclosiloxane (MIRASIL CM4 from RHONE POULENC) 15 g - Ethanol cbp 100 g The composition has the same properties as those of Example 1.

EXAMPLE 3 A fixative spray composition conditioned in a pump-bottle of the following composition was prepared: Copolymer of methyl vinyl ether / monoesterified maleic anhydride sold by the company ISP under the name GANTREZ ES 425 5 g 2-amino-2-methyl-1-propanol necessary for neutralization for 20% of polymer Difenyldimethicone sold under the name MIRASIL DPDM for the company RHONE POULENC 5 g Octamethyltetracyclosiloxane (MIRASIL CM4 from RHONE POULENC) 25 g Ethanol cbp 100 g The composition has the same properties as those of example 1.

EXAMPLE 4 A fixative spray composition conditioned in a pump-bottle of the following composition was prepared: Vinyl acetate / vinyl p-terbutyl-benzoate / crotanic acid terpolymer sold under the name MEXOMERE PW by the company CHIMEX 10 g 2-amino-2-methyl-1-propanol necessary for neutralization for 100% of polymer - Difenyldimethicone sold under the name MIRASIL DPDM for the company RHONE POULENC 25 g Octamethyltetracyclosiloxane (MIRASIL CM4 from RHONE POULENC) 20 g - Ethanol cbp 100 g The composition has the same properties as those of example 1.

EXAMPLE 5 A fixative composition (A) according to the invention prepared in a pump bottle of the following composition was prepared: Acrylic acid / ethyl acrylate / n-tert-butylacrylamide terpolymer sold under the name ULTRAHOLD STRONG by the company BASF 5 g 2-amino-2-methyl-1-propanol necessary for neutralization for 100% polymer - Diphenyldimethicone sold under the name MIRASIL DPDM for the company RHONE POULENC 14 g Octamethyltetracyclosiloxane (MIRASIL CM4 from RHONE POULENC) 20 g - Ethanol cbp 100 g A composition (B) of conditioning spray arranged in a pump-bottle of the following composition was prepared: Acrylic acid / ethyl acrylate / n-tert-butylacrylamide terpolymer sold under the name ULTRAHOLD STRONG by the company BASF 5 g 2-amino-2-methyl-1-propanol necessary for neutralization for 100% of phenyl silicon polymer sold under the denomination DC 556 by the company DOW CORNING 14 g Octamethyltetracyclosiloxane (MIRASIL CM4 by RHONE POULENC) 20 g Ethanol cbp lOOg A composition (C) and (D) was prepared in replacement of the phenylated silicone by the same amount of a non-volatile non-aryl silicone known to provide the properties of brilliance and softness.

Composition (C): The dimeticoncopolol sold under the name POLYMER ABX by the company OSI.

Eat ición The dimeticoncopolol sold under the name MIRASIL DMCO by the company RHONE POULENC. It was applied to each of the compositions on the washed and dried hair. A panel of 5 experienced testers evaluated the properties of each composition. The results are presented in the following table: FORMULATION Fixer Brilliance Sensation to the TESTED Touch Invention! Very good very bright Touch not fat fixation B (Invention) Very good very bright Touch not greasy fixation Nothing at all touch very ; Comparative) fixation sticky and greasy brilliance D Not at all tactile (Comparative) fixation brightness acceptable Only the compositions (A) and (B) according to the invention have good properties of brilliance, fixation and feel to the touch.

Although the compositions contain 34 g of silicone, the compositions according to the invention (A) and (B) have good fixative power.

The composition (A) according to the invention was also compared to the same composition (A) which does not contain volatile silicone (octamethyltetracyclosiloxane) (Composition (E)).

The two compositions (A) and (E) were applied on the washed and dried hair. A panel of 5 experienced testers evaluates the properties of each composition.

EXAMPLE 6 A fixative spray composition conditioned in a pump-bottle of the following composition was prepared: Vinyl acetate / crotonic acid copolymer sold by the company BASF under the name of LUVISET CA 66 8 g 2-amino-2-methyl-1-propanol necessary for the neutralization for 100% of polymer Phenyl dimethicone sold under the name BELSIL PDM 200 by the company WACKER 5 g Octamethyltetracyclosiloxane (MIRASIL CM4 from RHONE POULENC) 20 g Ethanol cbp lOOg EXAMPLE 7 A fixative spray composition conditioned in a pump-bottle of the following composition was prepared: Copolymer of methyl vinyl ether / monoesterified maleic anhydride sold by the company ISP under the name GANTREZ ES 425 4 g - 2-amino-2-methyl-1-propanol necessary for the neutralization for 20% of the polymer Phenyl dimethicone sold under the name BELSIL PDM 200 by the company WACKER 20 g Hexamethyldisiloxane (BELSIL DM 0.65 WACKER) 25 g Ethanol cbp lOOg It is noted that in relation to this date, the best method known to the applicant to carry out the aforementioned invention, is that which is clear from the present description of the invention. Having described the invention as above, property is claimed as contained in the following:

Claims (24)

1. The cosmetic composition, characterized in that it comprises, in a cosmetically acceptable medium, at least one fixing polymer, at least 5% by weight of a non-volatile arylated silicone and at least one volatile silicone.

2. The composition according to the preceding claim, characterized in that the fixing polymer or polymers are present in concentrations comprised between 0.1 and 20% by weight, and preferably in concentrations between 1 and 10% by weight, based on the total weight of the composition. composition.

3. The composition according to any of claims 1 or 2, characterized in that the volatile silicone (s) are present in concentrations comprised between 5% and 40% by weight relative to the total weight of the composition.

4. The composition according to the preceding claim, characterized in that the volatile silicone (s) are present in concentrations comprised between 10% and 30% by weight relative to the total weight of the composition.

5. The composition according to the preceding claim, characterized in that the volatile silicone (s) are preceded in concentrations between 15% and 25% by weight relative to the total weight of the composition.

6. The composition according to any of the preceding claims, characterized in that the non-volatile arylated silicone (s) are present in concentrations comprised between 5% and 40% by weight relative to the total weight of the composition.

7. The composition according to the preceding claim, characterized in that the non-volatile arylated silicone (s) are present in concentrations comprised between 10% and 30% by weight relative to the total weight of the composition.

8. The composition according to the preceding claim, characterized in that the non-volatile arylated silicone (s) are present in concentrations comprised between 12% and 20% by weight relative to the total weight of the composition.

9. The composition according to any of the preceding claims, characterized in that the fixing polymer is chosen from anionic, cationic, amphoteric, nonionic polymers and mixtures thereof.

10. The compliant composition according to the preceding claim, characterized in that the anionic fixative polymer is selected from: polymers including carboxylic moieties which are derived from unsaturated mono- or dicarboxylic carboxylic monomers of the formula: wherein n is an integer from 0 to 10, A .. designates a methylene group, optionally linked to the carbon atom of the unsaturated group or the neighboring methylene group when n is greater than-1 via a heteroatom such as oxygen or sulfur, R7 designates a hydrogen atom, a phenyl or benzyl group, Rβ designates a hydrogen atom, a lower alkyl group of 1 to 6 carbon atoms or carbon or carboxyl, R9 denotes a hydrogen atom, a lower alkyl group from 1 to 6 carbon atoms, a group -CH 2 -COOH, phenyl or benzyl; the polymers comprising the portions derived from the sulfonic acid, such as the vinylsulphonic, styrenesulphonic, acrylamidoalkylsulphonic portions.

11. The compositions according to the preceding claim, characterized in that the anionic fixing polymer is chosen from: A) the homo- or copolymers of acrylic or methacrylic acid or their salts, the copolymers of acrylic acid and acrylamide and their salts, the salts of sodium of polyhydroxycarboxylic acids; B) copolymers of acrylic or methacrylic acids with a monoethylene monomer such as ethylene, styrene, vinyl esters, esters of acrylic or methacrylic acid, optionally grafted onto a polyalkylene glycol such as polyethylene glycol-1 and optionally crosslinked; copolymers of that type include in their chain a portion of optionally N-alkylated and / or hydroxyalkylated acrylamide, the copolymers of acrylic acid and of alkyl methacrylate of 1 to 4 carbon atoms; C) copolymers derived from crotonic acid such as those including in their chain portions of vinyl acetate or propionate and optionally other monomers such as allyl or metalyl esters, vinyl ether or vinyl ester of a saturated linear or branched carboxylic acid of long hydrocarbon chain such as those including at least 5 carbon atoms, these polymers possibly being grafted and crosslinked; D) copolymers derived from monounsaturated carboxylic acids or anhydrides of 4 to 8 carbon atoms chosen from: copolymers comprising (i) one or more maleic, fumaric, itaconic acids or anhydrides and (ii) at least one monomer chosen from vinyl esters, vinyl ethers, vinyl halides, phenyl vinyl derivatives, acrylic acid and their esters, the anhydride functions of these copolymers, optionally being monoesterified or monoamidified; copolymers comprising (i) one or more maleic, citraconic, itaconic anhydrides and (ii) one or more monomers selected from the allylic or etalyl esters optionally including one or more acrylamide, methacrylamide, α-olefin, acrylic or methacrylic esters , acrylic or methacrylic acids or vinylpyrrolidone in their chain, the anhydrous functional groups of these copolymers which are optionally monoesterified or monoamidified. (E) polyacrylamides including carboxylated groups.

12. The composition according to the preceding claim, characterized in that the anionic fixing polymer is chosen from: - acrylic acid copolymers such as the terpolymer of acrylic acid / ethylene acrylate / N-tert-butylacrylamide; copolymers derived from crotonic acid such as the terpolymers of vinyl acetate / tert-butyl benzoate vinyl / crotonic acid and the terpolymers of cortic acid / vinyl acetate / vinyl neododecanoate; polymers derived from acids or from maleic, fumaric, itaconic anhydrides with vinyl esters, vinyl ethers, vinyl halides, phenyl vinyl derivatives, acrylic acid and their esters such as the methylvinyl ether / maleic ester monoesterified anhydride copolymers; the copolymers of methacrylic acid and methyl methacrylate; the copolymer of methacrylic acid and ethyl acrylate; the vinyl acetate / crotonic acid copolymers; - the terpolymer of vinyl acetate / erotonic acid / polyethylene glycol.

13. The composition according to claim 9, characterized in that the amphoteric fixative polymer is selected from among the polymers including the derived portions: a) from at least one monomer selected from the acrylamides or substituted methacrylamides on the nitrogen atom with a alkyl radical, b) of at least one acid comonomer containing one or more reactive carboxylic groups, and c) at least one basic comonomer such as esters with primary, secondary, tertiary and quaternary amine substituents of acrylic and methacrylic acids and the product of quaternization of dimethylaminoethyl methacrylate with dimethyl sulfate or diethyl sulfate.

14. The composition according to the preceding claim, characterized in that the amphoteric fixative polymer is chosen from copolymers where the CTFA name is the octylacrylamide / acrylates / butylaminoethyl methacrylate polymer and the copolymers of methyl methacrylate / dimethyl-carboxymethylammonium ethyl methacrylate .

15. The composition according to claim 9, characterized in that the non-ionic fixative polymer is chosen from: - polyalkyloxazolines; the vinyl acetate homopolymers; the copolymers of vinyl acetate and of acrylic ester; the copolymers of vinyl acetate and ethylene; the copolymers of vinyl acetate and maleic ester; the vinyl chloride homopolymers; polyethylene waxes; - polyethylene / polytetrafluoroethylene waxes; the polyethylene and maleic anhydride copolymers; the homopolymers of alkyl acrylates and the homopolymers of alkyl methacrylates; copolymers of acrylic esters, such as, for example, the copolymers of alkyl acrylates and alkyl methacrylates; the copolymers of acrylonitrile and of a nonionic monomer chosen for example between butadiene and alkyl (meth) acrylates; the styrene homopolymers; the copolymers of styrene and of alkyl (meth) acrylate; copolymers of styrene, alkyl methacrylate and alkyl acrylate; the copolymers of styrene and of butadiene; styrene, butadiene and vinylpyridine copolymers; the alkyl acrylate and urethane copolymers.

16. The composition according to claim 9, characterized in that the cationic fixative polymer is chosen from: the copolymer of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulfate, the copolymers of acrylamide and of methacryloyloxyethyltrimethylammonium chloride, the copolymer of acrylamide and of methacryloyloxyethyltrimethylammonium methosulfate, the quaternized or not quaternized dialkylaminoalkyl vinylpyrrolidone / acrylate or methacrylate copolymers, the terpolymers of dimethylaminoethyl methacrylate / vinyl aprolactam / vinylpyrrolidone, - and the quaternized dimethylaminopropyl vinylpyrrolidone / methacrylamide copolymer.

17. The composition according to any of the preceding claims, characterized in that the volatile silicones are chosen from: - (i) cyclic volatile silicones having from 3 to 7 silicon atoms and preferably from 4 to 5, which can respond to the following formula (VIII): (VIII) in which r varies from 3 to 7 (limits included). - (ii) linear volatile silicones having 2 to 9 silicon atoms, which may respond to the following formula (IX): (i?: in which s varies from 1 to 8 (limits included)

18. The composition according to the preceding claim, characterized in that the volatile silicones are chosen from cyclotetradimethylsiloxane, cyclopentadimethylsiloxane, cyclohexadimethylsiloxane, hexamethyldisilyxane and octamethyltrisiloxane.

19. The composition according to any of the preceding claims, characterized in that the non-volatile arylated silicones are selected from among the silicones of the following formula (X): wherein: R2, identical or different, designates an alkyl radical of 1 to 10 carbon atoms, R2e, identical or different, designates an aryl group, this aryl group being able to comprise one or more aryl rings, optionally substituted; R25, identical or different, designates R26, R24 or t varies from 0 to 1000, - u varies from 1 to 1000, the sum of t + u can vary from 1 to 2000.

20. The composition according to the preceding claim, characterized in that the aryl group is chosen from the phenyl, a phenyl group substituted with alkyl radicals or alkenyl radicals of 1 to 5 carbon atoms and their mixtures.

21. The composition according to the preceding claim, characterized in that the non-volatile arylated silicone is chosen from phenyltrimethicone, diphenyl dimethicone and phenyl methicone.

22. The composition according to any of the preceding claims, characterized in that the cosmetically acceptable medium comprises alcohols of 1 to 6 carbon atoms.

23. The method of cosmetic treatment of keratin materials such as hair, characterized in that the method consists in applying them a composition as defined according to any of the preceding claims.

24. The use of the composition as defined according to any one of claims 1 to 22, characterized in that it is for the manufacture of a combing or hair fixing composition.