CN101544738A - 一种室温自交联水性聚氨酯丙烯酸树脂及其制备方法与应用 - Google Patents
一种室温自交联水性聚氨酯丙烯酸树脂及其制备方法与应用 Download PDFInfo
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- CN101544738A CN101544738A CN 200910039124 CN200910039124A CN101544738A CN 101544738 A CN101544738 A CN 101544738A CN 200910039124 CN200910039124 CN 200910039124 CN 200910039124 A CN200910039124 A CN 200910039124A CN 101544738 A CN101544738 A CN 101544738A
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Abstract
Description
聚氨酯预聚体单体 | 用量(g) | 丙烯酸酯单体 | 用量(g) |
IPDI | 32.44 | DAAM | 3.40 |
TMXDI | 11.89 | MAA | 1.00 |
PEA | 100.00 | BA | 35.20 |
NPG | 2.61 | 2-EHA | 22.50 |
DMPA | 8.58 | MMA | 51.90 |
HEMA | 5.15 | ||
TEA | 5.83 | ||
ADH | 5.15 | ||
小计 | 171.65 | 小计 | 114.00 |
引发剂 | 用量(g) | 水 | 用量(g) |
AIBN | 5.71 | 去离子水 | 393.00 |
APS | 1.14 | ||
物料总质量(g) | 685.50 |
物质名称 | 质量(千克) |
炭黑色浆(炭黑的质量百分含量为30%的色浆) | 34.00 |
水性聚氨酯丙烯酸酯树脂(按实施例1制备) | 63.00 |
德国迪高沙公司808消泡剂 | 0.50 |
德国迪高沙公司500润湿剂 | 0.50 |
聚乙烯蜡乳液(聚乙烯蜡的质量百分含量为25%的蜡乳) | 2.00 |
合计 | 100.00 |
合成聚氨酯预聚体单体 | 用量(g) | 丙烯酸酯单体 | 用量(g) |
IPDI | 32.44 | DAAM | 5.13 |
TMXDI | 11.89 | MAA | 3.42 |
PPG | 100.00 | BA | 63.27 |
NPG | 2.61 | 2-EHA | 22.23 |
DMPA | 8.58 | MMA | 76.95 |
HEMA | 5.15 | ||
TEA | 5.83 | ||
ADH | 5.15 | ||
小计 | 171.65 | 小计 | 171.00 |
引发剂 | 用量(g) | 水 | 用量(g) |
AIBN | 3.43 | 去离子水 | 472.00 |
APS | 1.37 | ||
物料总质量(g) | 819.45 |
合成聚氨酯预聚体单体 | 用量(g) | 丙烯酸酯单体 | 用量(g) |
IPDI | 28.64 | DAAM | 2.19 |
2,4HTDI | 11.61 | MAA | 1.10 |
PTMG | 100.00 | BA | 51.51 |
DPG | 2.68 | MMA | 54.80 |
DMPA | 7.89 | ||
HEMA | 3.28 | ||
TEA | 5.36 | ||
ADH | 4.93 | ||
小计 | 164.39 | 小计 | 109.60 |
引发剂 | 用量(g) | 水 | 用量(g) |
AIBN | 3.29 | 去离子水 | 411.00 |
APS | 1.37 | ||
物料总质量(g) | 689.65 |
物质名称 | 质量(千克) |
杜邦902钛白粉色浆(钛白粉的质量百分含量为50%的色浆) | 49.00 |
水性聚氨酯丙烯酸酯树脂(按实施例3制备) | 50.00 |
德国迪高沙公司808消泡剂 | 0.50 |
德国迪高沙公司500润湿剂 | 0.50 |
合计 | 100.00 |
合成聚氨酯预聚体单体 | 用量(g) | 丙烯酸酯单体 | 用量(g) |
IPDI | 28.64 | DAAM | 4.35 |
2,4HTDI | 11.61 | MAA | 0.58 |
PTMG | 100.00 | BA | 72.33 |
DPG | 2.68 | MMA | 59.18 |
DMPA | 7.89 | 2-EHA | 27.95 |
HEMA | 3.28 | ||
TEA | 5.36 | ||
ADH | 4.93 | ||
小计 | 164.39 | 小计 | 164.39 |
引发剂 | 用量(g) | 水 | 用量(g) |
AIBN | 3.95 | 去离子水 | 351.00 |
APS | 1.64 | ||
物料总质量(g) | 685.37 |
Claims (10)
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CN 200910039124 CN101544738B (zh) | 2009-04-30 | 2009-04-30 | 一种室温自交联水性聚氨酯丙烯酸树脂及其制备方法与应用 |
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Application Number | Priority Date | Filing Date | Title |
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CN 200910039124 CN101544738B (zh) | 2009-04-30 | 2009-04-30 | 一种室温自交联水性聚氨酯丙烯酸树脂及其制备方法与应用 |
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Publication Number | Publication Date |
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CN101544738A true CN101544738A (zh) | 2009-09-30 |
CN101544738B CN101544738B (zh) | 2011-05-11 |
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Cited By (24)
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CN101864233A (zh) * | 2010-06-24 | 2010-10-20 | 江苏中金玛泰医药包装有限公司 | 新型水性铝箔保护剂和制备方法 |
CN101805439B (zh) * | 2009-10-28 | 2012-02-22 | 张伟公 | 聚氨酯纯水油墨链接料及其纯水油墨 |
CN102603990A (zh) * | 2012-02-17 | 2012-07-25 | 周杰 | 一种丙烯酸聚合物的配方及其制作方法 |
CN103031093A (zh) * | 2012-12-12 | 2013-04-10 | 常州大学 | 水性聚氨酯丙烯酸酯压敏粘合剂的制备方法 |
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CN106221546A (zh) * | 2016-08-18 | 2016-12-14 | 上海倍力新材料有限公司 | 用作涂料的多重自交联的水性聚氨酯分散液,制备方法及其用途 |
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