CN101542038A - 有益组合物及方法 - Google Patents

有益组合物及方法 Download PDF

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CN101542038A
CN101542038A CNA2007800434761A CN200780043476A CN101542038A CN 101542038 A CN101542038 A CN 101542038A CN A2007800434761 A CNA2007800434761 A CN A2007800434761A CN 200780043476 A CN200780043476 A CN 200780043476A CN 101542038 A CN101542038 A CN 101542038A
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polyurethane
agent
hair
alkyl
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CN101542038B (zh
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王际平
胡金莲
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Procter and Gamble Ltd
Procter and Gamble Co
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    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
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Abstract

公开了一种纺织物有益组合物以及制备和使用上述组合物的方法以及用这种组合物处理过的纺织物，所述组合物包含聚氨酯和/或聚氨酯共聚物；交联剂；催化剂；和载体。

Description

有益组合物及方法
发明领域
此发明涉及有益组合物以及此类组合物的制备和使用方法。
发明背景
含有纤维的制品例如衣服和亚麻布由于使用和清洗而会起皱。为了减少褶皱，通常将此类衣服和亚麻布在清洁后熨烫或汽熨。遗憾的是，由于褶皱会在清洁、储存和/或使用/穿着期间再次出现，因此这种处理的功效不能持久保持。
因此，需要一种可供消费者用来向成品纺织物产品赋予持久抗皱特性的纺织物有益组合物。
发明概述
纺织物有益组合物包含聚氨酯和/或聚氨酯共聚物；交联剂；和载体。
本发明还涉及上述组合物的制备和使用方法，以及用上述组合物来处理纺织物的方法。
发明详述
定义
除非另外指明，如本文所用，术语“纺织消费品”包括纤维、纱、织物和/或衣服或包含它们的制品。
如本文所用，包括“一个/一种”在内的冠词被理解为是指一个/种或多个/种受权利要求书保护或描述的事物。
除非另外指明，所有组分或组合物含量均涉及所述组分或组合物的活性物质含量，并且不包括可能存在于市售来源中的杂质，例如残余溶剂或副产物。
除非另外指明，所有百分比和比率均按重量计算。除非另外指明，所有百分比和比率均基于总组合物计算。
应当理解，在整个该说明书中给出的每一最大数值限度包括每一较低数值限度，就像这样的较低数值限度在本文中是明确地写出一样。在整个该说明书中给出的每一最小数值限度包括每一较高数值限度，就像这样的较高数值限度在本文中是明确地写出一样。在整个该说明书中给出的每一数值范围包括落在该较宽数值范围内的每一较窄数值范围，就像这样的较窄数值范围在本文中是明确地写出一样。
组合物
在一个方面，公开了一种组合物，所述组合物包含按重量计约0.1％至约30％，约0.5％至约20％，约1％至约10％，约或甚至约1.5％至约8％的聚氨酯材料，所述聚氨酯材料选自由下列组成的组：聚氨酯、聚氨酯共聚物以及它们的混合物，所述聚氨酯和聚氨酯共聚物具有的Tg为约-50℃至约150℃，约-30℃至约100℃，约-10℃至约80℃，或甚至约20℃至约60℃；交联剂，所述交联剂的含量使聚氨酯与交联剂的比率为约100∶1至约1∶2，约50∶1至约1∶1，约20∶1至约3∶2，或甚至约10∶1至约2∶1；催化剂，所述催化剂的含量使交联剂与催化剂的比率为约100∶1至约1∶5，约50∶1至约1∶1，约20∶1至约3∶2，或甚至约10∶1至约2∶1；和任选辅助成分，所述组合物余量为载体，例如水。
在一个方面，公开了一种组合物，所述组合物具有上述参数，并且其中所述聚氨酯材料包括具有下式I结构的材料：
其中：
a.)R1和R2独立地选自可取代的或未取代的芳基、杂芳基、烷基或杂烷基；
b.)R3、R5和R6独立地选自H、聚合物或芳基、杂芳基、烷基或杂烷基；
c.)R4为OH、聚合物或芳基、杂芳基、烷基或杂烷基；并且
d.)R7和R8独立地选自H、可取代的或未取代的芳基、杂芳基或烷基；
e.)y为1至200，1至100，1至50，1至20，1至10或1至5的整数。
在一个方面中，公开了一种组合物，所述组合物具有上述参数，并且其中所述聚氨酯材料包括具有上式I结构的材料，其中：
a.)R1选自4，4’-二苯基甲烷、苯、碳二亚胺改性的4，4’-二苯基甲烷和环己烷；
b.)R2选自聚丙二醇、聚乙二醇、己二酸1，4-丁二醇酯、1，4-丁烷、1，3-丙烷、乙烷、4，4’-二羟基联苯和2，2’-二羟甲基丙酸；
c.)R3、R4、R5和R6独立地选自硅氧烷、聚乙烯、聚丙烯、官能化取代的蜡、脂肪族酯、聚胺、聚丙烯酸酯、羧酸和聚羧酸；和
d.)R7和R8独立地选自可取代的或未取代的芳基、杂芳基或烷基。
在本说明书公开的组合物的任何方面，所述交联剂包括选自由下列组成的组的物质：脲的羟甲基和烷氧基甲基衍生物以及亚乙基脲和亚丙基脲的羟甲基和烷氧基甲基衍生物、多官能羧酸、以及它们的混合物。
在本说明书公开的组合物任何方面，所述组合物可包含润滑剂。所述润滑剂包括选自由下列组成的组的物质：脂肪族酯、硅氧烷、聚乙烯乳液、以及它们的混合物。
在本说明书公开的组合物的任何方面，所述组合物可包含任选的辅助成分，所述辅助成分包括选自由下列组成的组的物质：香料、香料递送体系、润湿剂、软化剂、毛发调理剂、护肤剂、驱污剂、去污剂、抗静电剂、水分调节剂、染料固定剂、染料转移抑制剂、色彩增强剂、基质柔软剂(substrate hand builder)、抗磨蚀剂、以及它们的混合物。在一个方面中，按总组合物的重量计，所述任选成分在所述组合物中的含量为约0.001％至约30％，约0.01％至约20％，或甚至约0.05％至约10％。
在本说明书公开的组合物任何方面中，所述催化剂包括选自由下列组成的组的物质：酸、潜酸、金属盐、以及它们的混合物。
物质
适宜的聚氨酯和聚氨酯共聚物可依照本说明书和美国专利申请2005/0107563 A1中的教导。
适宜的交联剂可得自Sigma-Aldrich，St.Louis，Missouri，U.S.A.和Noveon，Inc.，Cleveland，Ohio，U.S.A.。
适宜的催化剂可得自Sigma-Aldrich，St.Louis，Missouri，U.S.A.。
适宜的润滑剂可得自Akzo Nobel，Velperweg 76，6824BM Arnhem，Netherlands和Dow Corning Corporation，Midland，Michigan，U.S.A.。
适宜的任选辅助成分可得自International Flavors & Fragrances，New York，New York，U.S.A.；BASF Aktiengesellschaft，Ludwigshafen，Germany；Ciba Specialty Chemicals Inc.，Basel，Switzerland；和Clariant International Ltd.，Muttenz，Switzerland。
制备组合物的方法
可通过将本说明书中公开的物质按本说明书中公开的量进行组合来制备本说明书中公开的组合物。该组合可通过任何组合方法来实现，包括批量、半批量和连续方法。
产品
在一个方面中，公开了成品消费品，所述成品消费品包括包装和本说明书中公开的任何组合物。在一个方面中，所述成品消费品可包括容器，所述容器至少部分地包含本说明书中公开的任何组合物。
处理方法
在一个方面，公开了处理纺织消费品、毛发或它们的组合的方法，所述方法包括以下步骤：
a.)使所述纺织消费品、毛发或它们的组合的至少一部分与本说明书中公开的任何组合物接触；
b.)使与本说明书中公开的任何组合物接触的所述纺织消费品、毛发或它们的组合的至少一部分干燥。
在一个方面中，可通过熨烫纺织消费品来实现所述干燥。
在一个方面中，可通过用本说明书中公开的任何组合物喷雾或浸泡所述纺织消费品来实现所述接触。
在一个方面中，在最终用户使用所述纺织品之前，对所述纺织消费品、毛发或它们的组合进行处理。
处理过的产品
在一个方面，公开了处理过的产品，所述处理过的产品通过依照本说明书中公开的处理方法处理所述产品来获得。
实施例
喷雾-熨烫用的产品组合物的实施例
  实施例1   实施例2   实施例3
  聚氨酯(％)   4.0   5.0   2.5
  聚氨酯的玻璃化转变温度(℃)   55   45   35
  聚氨酯共聚物(％)   1.5   2.0   2.0
  硅氧烷(％)   1.0   0.0   0.0
  聚乙烯蜡(％)   0.0   1.0   0.0
  改性的二羟甲基-4，5-二羟基亚乙基脲   1.0   0.0   0.0
  MgCl2   0.2   0.0   0.0
  丁烷四羧酸   0.0   1.0   0.0
  聚苹果酸   0.0   0.0   1.0
  次磷酸钠   0.0   0.3   0.4
  硅氧烷多羟基化合物   0.2   0.2   0.1
  香料   0.1   0.15   0.1
  水   余量   余量   余量
实施例4
喷雾-熨烫应用：
将由100％棉纤维构成的织物放置在熨衣板上，并且将实施例1中的组合物以足以获得约50％湿吸收的量均匀地喷雾在所述织物上。然后使用高温设置来熨烫所述织物直至其干燥。
实施例5
浸泡-熨烫应用：
将约200g的实施例2的组合物与1000g水混合。将所得混合物搅拌和/或搅动。将包括由100％棉纤维构成的衬衣在内的衣服置于包含该混合物的容器中，并且搅拌约5分钟。然后将所述衣服在洗衣机中旋转2分钟，然后熨烫直至其干燥。
实施例6
浸泡-熨烫应用：
将约200g的实施例2的组合物与1000g水混合。将所得的混合物搅拌和/或搅动。将包括由50％棉纤维和50％聚酯纤维构成的衬衣在内的衣服置于包含该混合物的容器中，并且搅拌约5分钟。然后将所述衣服在洗衣机中旋转2分钟，然后熨烫直至其干燥。
  化学物质   重量％
  聚氨酯   6.5
  二甲基二羟基亚乙基脲   2.0
  聚乙二醇   0.5
  MgCl2   0.5
  甲醇   0.3
  任选香料和/或染料*
  水   余量至100％
  化学物质   重量％
  聚氨酯   6.5
  DMDHEU*   2.0
  二甘醇   1.5
  聚乙二醇   0.5
  MgCl2   0.5
  甲醇   0.3
  任选香料和/或染料**
  水   88.7
·二羟甲基二羟基亚乙基脲
本文所公开的量纲和值不旨在被理解为严格地限于所述的精确值。相反，除非另外指明，每个这样的量纲是指所引用的数值和围绕该数值的功能上等同的范围。例如，公开为“40mm”的量纲旨在表示“约40mm”。
在发明详述中引用的所有文件都在相关部分中以引用方式并入本文中。对于任何文件的引用不应当解释为承认其是有关本发明的现有技术。当本发明中术语的任何含义或定义与引入以供参考的文件中术语的任何含义或定义矛盾时，应当服从在本发明中赋予该术语的含义或定义。
虽然已经举例说明和描述了本发明的具体实施方案，但是对于本领域技术人员来说显而易见的是，在不背离本发明实质和范围的情况下可以做出多个其他改变和变型。因此，权利要求书意欲包括在本发明范围内的所有这样的改变和变型。

Claims (11)

1.一种组合物，所述组合物包含：
(a)按重量计0.1％至30％，优选0.5％至20％，更优选1％至10％，最优选1.5％至8％的聚氨酯材料，所述聚氨酯材料选自由下列组成的组：聚氨酯、聚氨酯共聚物以及它们的混合物，所述聚氨酯和聚氨酯具有-50℃至150℃，优选-30℃至100℃，更优选-10℃至80℃，最优选20℃至60℃的玻璃化转变温度；
(b)交联剂，优选地所述交联剂包括选自由下列组成的组的物质：脲的羟甲基和烷氧基甲基衍生物以及亚乙基脲和亚丙基脲的羟甲基和烷氧基甲基衍生物、多官能羧酸以及它们的混合物，所述交联剂的含量使得聚氨酯与交联剂的比率为100∶1至1∶2，优选50∶1至1∶1，更优选20∶1至3∶2，最优选10∶1至2∶1；
(c)催化剂，优选地所述催化剂包括选自由下列组成的组的物质：酸、潜酸、金属盐以及它们的混合物，所述催化剂的含量使得交联剂与催化剂的比率为100∶1至1∶5，优选50∶1至1∶1，更优选20∶1至3∶2，最优选10∶1至2∶1；和
(d)任选的辅助成分，优选地所述组合物包含助剂，所述助剂包括选自由下列组成的组的物质：香料、香料递送体系、润湿剂、软化剂、毛发调理剂、护肤剂、驱污剂、去污剂、抗静电剂、水分调节剂、染料固定剂、染料转移抑制剂、色彩增强剂、基质柔软剂、抗磨蚀剂、以及它们的混合物，
所述组合物的余量为载体。
2.如权利要求1所述的组合物，其中所述聚氨酯材料包括具有下式I结构的物质：
其中：
a.)R1和R2独立地选自可取代的或未取代的芳基、杂芳基、烷基或杂烷基；
b.)R3、R5和R6独立地选自H、聚合物或芳基、杂芳基、烷基或杂烷基；
c.)R4为OH、聚合物或芳基、杂芳基、烷基或杂烷基；并且
d.)R7和R8独立地选自H、可取代的或未取代的芳基、杂芳基或烷基；
e.)y为1至200，优选1至100，更优选1至50，最优选1至5的整数。
3.如前述任一项权利要求所述的组合物，其中对于式I而言：
a.)R1选自4，4’-二苯基甲烷、苯、碳二亚胺改性的4，4’-二苯基甲烷和环己烷；
b.)R2选自聚丙二醇、聚乙二醇、己二酸1，4-丁二醇酯、1，4-丁烷、1，3-丙烷、乙烷、4，4’-二羟基联苯和2，2’-二羟甲基丙酸；
c.)R3、R4、R5和R6独立地选自硅氧烷、聚乙烯、聚丙烯、官能化取代的蜡、脂肪族酯、聚胺、聚丙烯酸酯、羧酸和聚羧酸；并且
d.)R7和R8独立地选自可取代的或未取代的芳基、杂芳基或烷基。
4.如前述任一项权利要求所述的组合物，所述组合物包含润滑剂，优选地所述润滑剂包括选自由下列组成的组的物质：脂肪族酯、硅氧烷、聚乙烯乳液以及它们的混合物。
5.一种包括包装和前述任一项权利要求的组合物的产品，所述产品为成品消费品。
6.如权利要求5所述的产品，所述包装包括容器，所述容器至少部分地包含所述组合物。
7.一种处理纺织消费品、毛发或它们的组合的方法，所述方法包括以下步骤：
a.)使所述纺织消费品、毛发或它们的组合的至少一部分与如权利要求1至4中任一项所述的组合物接触；
b.)使与权利要求1的所述组合物接触的所述纺织消费品、毛发或它们的组合的至少一部分干燥。
8.如权利要求11所述的方法，其中通过熨烫和/或挤压纺织消费品来实现所述纺织消费品、毛发或它们的组合的所述干燥。
9.如权利要求11所述的方法，其中通过用权利要求1的组合物喷雾或浸泡所述纺织消费品来实现所述纺织消费品、毛发或它们的组合的所述接触。
10.如权利要求11所述的方法，其中在最终用户使用所述纺织品之前，对所述纺织消费品、毛发或它们的组合进行处理。
11.一种纺织品，所述纺织品根据权利要求11处理过。
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