CN101522401A - 贴合方法以及贴合装置 - Google Patents

贴合方法以及贴合装置 Download PDF

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Publication number
CN101522401A
CN101522401A CNA2007800362551A CN200780036255A CN101522401A CN 101522401 A CN101522401 A CN 101522401A CN A2007800362551 A CNA2007800362551 A CN A2007800362551A CN 200780036255 A CN200780036255 A CN 200780036255A CN 101522401 A CN101522401 A CN 101522401A
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CN
China
Prior art keywords
substrate
bonding agent
coating
face
irradiation
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Granted
Application number
CNA2007800362551A
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English (en)
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CN101522401B (zh
Inventor
成田悠
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Shibaura Mechatronics Corp
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Shibaura Engineering Works Co Ltd
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Publication of CN101522401A publication Critical patent/CN101522401A/zh
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Publication of CN101522401B publication Critical patent/CN101522401B/zh
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/04Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving separate application of adhesive ingredients to the different surfaces to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C11/00Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
    • B05C11/02Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface
    • B05C11/08Spreading liquid or other fluent material by manipulating the work, e.g. tilting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C9/00Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important
    • B05C9/08Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material and performing an auxiliary operation
    • B05C9/12Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material and performing an auxiliary operation the auxiliary operation being performed after the application
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/1403Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation characterised by the type of electromagnetic or particle radiation
    • B29C65/1406Ultraviolet [UV] radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/1429Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation characterised by the way of heating the interface
    • B29C65/1435Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation characterised by the way of heating the interface at least passing through one of the parts to be joined, i.e. transmission welding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/1429Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation characterised by the way of heating the interface
    • B29C65/1448Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation characterised by the way of heating the interface radiating the edges of the parts to be joined, e.g. for curing a layer of adhesive placed between two flat parts to be joined, e.g. for making CDs or DVDs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/1477Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation making use of an absorber or impact modifier
    • B29C65/1483Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation making use of an absorber or impact modifier coated on the article
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/483Reactive adhesives, e.g. chemically curing adhesives
    • B29C65/4845Radiation curing adhesives, e.g. UV light curing adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/52Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the way of applying the adhesive
    • B29C65/521Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the way of applying the adhesive by spin coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/78Means for handling the parts to be joined, e.g. for making containers or hollow articles, e.g. means for handling sheets, plates, web-like materials, tubular articles, hollow articles or elements to be joined therewith; Means for discharging the joined articles from the joining apparatus
    • B29C65/7802Positioning the parts to be joined, e.g. aligning, indexing or centring
    • B29C65/7805Positioning the parts to be joined, e.g. aligning, indexing or centring the parts to be joined comprising positioning features
    • B29C65/7808Positioning the parts to be joined, e.g. aligning, indexing or centring the parts to be joined comprising positioning features in the form of holes or slots
    • B29C65/7811Positioning the parts to be joined, e.g. aligning, indexing or centring the parts to be joined comprising positioning features in the form of holes or slots for centring purposes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/78Means for handling the parts to be joined, e.g. for making containers or hollow articles, e.g. means for handling sheets, plates, web-like materials, tubular articles, hollow articles or elements to be joined therewith; Means for discharging the joined articles from the joining apparatus
    • B29C65/7858Means for handling the parts to be joined, e.g. for making containers or hollow articles, e.g. means for handling sheets, plates, web-like materials, tubular articles, hollow articles or elements to be joined therewith; Means for discharging the joined articles from the joining apparatus characterised by the feeding movement of the parts to be joined
    • B29C65/7879Means for handling the parts to be joined, e.g. for making containers or hollow articles, e.g. means for handling sheets, plates, web-like materials, tubular articles, hollow articles or elements to be joined therewith; Means for discharging the joined articles from the joining apparatus characterised by the feeding movement of the parts to be joined said parts to be joined moving in a closed path, e.g. a rectangular path
    • B29C65/7882Means for handling the parts to be joined, e.g. for making containers or hollow articles, e.g. means for handling sheets, plates, web-like materials, tubular articles, hollow articles or elements to be joined therewith; Means for discharging the joined articles from the joining apparatus characterised by the feeding movement of the parts to be joined said parts to be joined moving in a closed path, e.g. a rectangular path said parts to be joined moving in a circular path
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/001Joining in special atmospheres
    • B29C66/0012Joining in special atmospheres characterised by the type of environment
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    • B29C66/00145Vacuum, e.g. partial vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112Single lapped joints
    • B29C66/1122Single lap to lap joints, i.e. overlap joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/342Preventing air-inclusions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/40General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • B29C66/41Joining substantially flat articles ; Making flat seams in tubular or hollow articles
    • B29C66/45Joining of substantially the whole surface of the articles
    • B29C66/452Joining of substantially the whole surface of the articles the article having a disc form, e.g. making CDs or DVDs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/72General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
    • B29C66/723General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined being multi-layered
    • B29C66/7232General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined being multi-layered comprising a non-plastics layer
    • B29C66/72321General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined being multi-layered comprising a non-plastics layer consisting of metals or their alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/80General aspects of machine operations or constructions and parts thereof
    • B29C66/82Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps
    • B29C66/826Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps without using a separate pressure application tool, e.g. the own weight of the parts to be joined
    • B29C66/8266Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps without using a separate pressure application tool, e.g. the own weight of the parts to be joined using fluid pressure directly acting on the parts to be joined
    • B29C66/82661Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps without using a separate pressure application tool, e.g. the own weight of the parts to be joined using fluid pressure directly acting on the parts to be joined by means of vacuum
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    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/80General aspects of machine operations or constructions and parts thereof
    • B29C66/83General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
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    • B29C66/8322Joining or pressing tools reciprocating along one axis
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    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/90Measuring or controlling the joining process
    • B29C66/91Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux
    • B29C66/914Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux
    • B29C66/9161Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux by controlling or regulating the heat or the thermal flux, i.e. the heat flux
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
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    • B29C66/90Measuring or controlling the joining process
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    • B29C66/9161Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux by controlling or regulating the heat or the thermal flux, i.e. the heat flux
    • B29C66/91641Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux by controlling or regulating the heat or the thermal flux, i.e. the heat flux the heat or the thermal flux being non-constant over time
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    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
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    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/08Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
    • B29C35/0805Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
    • B29C2035/0822Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using IR radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
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    • B29C35/0805Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
    • B29C2035/0827Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using UV radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
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Abstract

本发明提供一种既可确保涂敷时粘接层的均匀性,又抑制制造中的粘接层的变化的贴合方法和贴合装置。具有向第一基板(P1)的一方的面上涂敷粘接剂(B1)的第一旋转涂敷装置(1)、向第二基板(P2)的一方的面涂敷比第一基板的粘接剂(B1)厚的粘接剂(B2)的第二旋转涂敷装置、使第二基板(P2)上的粘接剂(B2)临时硬化的前照射部(4)、贴合第一基板(P1)的涂敷了粘接剂(B1)的面和第二基板(P2)的涂敷了粘接剂(B2)的面的贴合部(5)、以及使第一基板(P1)和第二基板(P2)之间的粘接剂(B1)和(B2)硬化的后照射部(6)。

Description

贴合方法以及贴合装置
技术领域
本发明涉及一种贴合方法以及贴合装置,该贴合装置和贴合方法例如为了制造通过粘接剂贴合一对基板而形成的记录介质,对在贴合前向基板涂敷粘接剂进行改良。
背景技术
目前,对于光盘或光磁盘等的光学读取式的记录介质,再生专用的记录介质或可重写记录的信息的记录介质等各种各样规格的介质正在普及。例如,DVD等的光盘基本上是通过在两个基板的一方或双方上设置信息记录区域,并且经由粘接剂贴合而制造的。而且,为了正确地通过激光进行读写,要求用于贴合的粘接剂层的厚度具有非常高的精度。
参照图7对这样的贴合型盘片的制造顺序的一个例子进行说明。首先,预先注射模塑成形两张聚碳酸酯制的基板P,在喷溅室通过喷溅形成激光反射用的金属膜(记录膜)。然后,如图7(A)所示,将紫外线硬化型的粘接剂涂敷在两张基板P的接合面上,通过旋转涂敷来延展粘接剂。旋转涂敷是指,在利用涂敷装置K将粘接剂滴下涂敷到基板P的中心的周围之后,通过使基板P高速旋转,从而在基板P上形成粘接剂的薄膜(粘接层R),使多余的粘接剂飞散。
如图7(B)所示,这样形成粘接层R的一对基板P以彼此的粘接层R形成平行相对的状态的方式,由中心销G的卡盘E保持一方,并且另一方载置在转台或基座等的载置面F上,在该状态下,导入到真空室C的下部。然后,如图7(C)所示,通过真空室C下降并密封,形成减压室S,通过排气装置从该减压室S排气,由此,基板P周围的压力从大气压变成真空。
在该减压后的空间中,在保持一方的基板P的卡盘E闭合并且基板P落下的同时,推压部T通过汽缸等驱动源而下降并推压,由此,贴合于另一方的基板P。贴合时形成真空是为了尽可能地排除粘接的面之间的气体分子。
之后,如图7(D)所示,贴合后的基板P的周围导入大气而恢复到大气压,或者在加压到大气压以上之后恢复到大气压。通过这样被释放到大气压,残留在粘接层R的气泡通过与真空的压差而逐渐压缩。如图7(E)所示,通过光源U向放置在大气中几秒至几十秒的基板P整体照射紫外线,直到气泡被充分压缩为止,由此,粘接层R硬化。这样,两张基板P被牢固地粘接,制成盘片。
如上所述,对于贴合涂敷了粘接剂的基板而制造的盘片,在用于读写信息的激光照射到盘片上时,为了稳定地形成点,必须是没有翘曲或变形的平坦的盘片。因此,在该盘片上,希望贴合时的粘接层的膜厚尽量均匀。
但是,在通过所述的旋转涂敷而涂敷粘接剂的情况下,旋转的基板上的粘接剂通过离心力而延展。因此,相对于基板的内周部,外周部的膜厚变厚(例如10μm左右),难以使基板整体的膜厚均匀化。
为了解决该问题,作为通过旋转涂敷而将树脂均匀地涂敷的技术提出了以下方法,即,在旋转涂敷中,在停止盘片的旋转之前,通过向光盘上的树脂照射紫外线而改变整体的粘度,从而限制树脂向外周部的流动(参照专利文献1)。
专利文献1:日本特开2002-319192号公报
已知粘接层的膜厚的周内变化(标准离差)从盘片的内周开始越向外周越大。但是,随着如近年来的HD(高清晰度DVD)、BD(蓝光光盘)中所出现的记录密度的提高,最终的盘片所要求的粘接层的均匀性非常严格。例如,目前的DVD的标准离差范围为30μm左右,但HD或BD要求10μm左右的更高的精度。因此,抑制周内标准离差的必要性进一步提高。
尤其是在要求粘接层的厚度的情况下,容易产生周内标准离差,如专利文献1所示,在旋转涂敷中向树脂照射紫外线并使粘度发生变化,在该情况下,难以既抑制周内标准离差又控制涂敷膜的厚度。
并且,为了通过利用大气压的加压而将贴合时产生的气泡压碎,有时采用贴合后放置在大气中的方法。但是,当这样放置在大气中时,粘接层的周内变化扩大。这想必是由于从涂敷粘接剂后开始到硬化为止的时间变长,硬化中途的粘接剂流动的机会增加所致。例如,图8表示在贴合后不进行放置的情况和放置(20s)的情况下的各自的一个例子和测定平均周内变化率的结果。根据图8可知,在放置的情况下,周内变化整体变差,外周部的变化大。
而且,在进行基于旋转涂敷的涂敷时,如上所述,多余的粘接剂飞散。对这样飞散后的粘接剂进行回收并循环利用。但是,如专利文献1所示,如果在旋转期间全面照射紫外线,则飞散的粘接剂中含有照射紫外线而开始硬化的粘接剂。这样,为了循环利用,必须分离开始硬化的粘接剂和未硬化的粘接剂,但这是非常困难的。
发明内容
本发明就是为了解决所述现有的技术问题而提出的,其目的是提供一种既可确保涂敷时粘接层的均匀性,又可抑制制造中的粘接层的变化的贴合方法和贴合装置。
为了达成所述目的,本发明是一种贴合方法,经由通过照射电磁波而发生硬化的粘接剂贴合第一基板和第二基板,其特征在于,以分别不同的厚度向所述第一基板的一方的面和所述第二基板的一方的面涂敷粘接剂,向涂敷到所述第一基板的粘接剂和涂敷到所述第二基板的粘接剂中的薄的一方照射电磁波,贴合所述第一基板中的涂敷了粘接剂的面、和所述第二基板中的涂敷了粘接剂的面,向所述第一基板和所述第二基板之间的粘接剂照射电磁波。
其它的形式是一种贴合装置,经由通过照射电磁波而发生硬化的粘接剂贴合第一基板和第二基板,其特征在于,具有:以分别不同的厚度向所述第一基板的一方的面和所述第二基板的一方的面涂敷粘接剂的至少一个涂敷部,向涂敷到所述第一基板的粘接剂和涂敷到所述第二基板的粘接剂中的薄的一方照射电磁波的前照射部,贴合所述第一基板的涂敷了粘接剂的面、和所述第二基板的涂敷了粘接剂的面的贴合部,以及,向所述第一基板和所述第二基板之间的粘接剂照射电磁波的后照射部。
在以上的发明中,由于在使涂敷在贴合的基板上的粘接剂的厚度不同之后,在贴合之前向薄的粘接剂照射电磁波,因此,粘接剂硬化而防止流动,可抑制周内变化。并且,通过硬化能够抑制排气的产生,减少气泡的残留。
其它形式的特征在于,在贴合所述第一基板的涂敷了粘接剂的面和所述第二基板的涂敷了粘接剂的面之后,在照射电磁波之前放置在大气中。
其它形式的特征在于,具有放置部,该放置部在贴合所述第一基板的涂敷了粘接剂的面和所述第二基板的涂敷了粘接剂的面之后,在照射电磁波之前放置在大气中。
在以上的形式中,由于在贴合第一基板和第二基板之后,在使粘接剂硬化之前留有放置在大气中的时间,因此,可减少气泡的产生。
其它形式的特征是,所述涂敷部具有至少一个旋转涂敷装置,该旋转涂敷装置通过使所述第一基板和所述第二基板旋转而延展粘接剂,并且具有控制装置,该控制装置以在所述第一基板和所述第二基板上各自的旋转条件不同的方式控制所述旋转涂敷装置。
在所述的形式中,通过使转速等旋转条件不同,可控制粘接剂的涂敷厚度。
其他形式的特征是,所述涂敷部具有至少一个旋转涂敷装置,该旋转涂敷装置通过使所述第一基板和所述第二基板旋转而延展粘接剂,具有控制装置,该控制装置以在所述第一基板和所述第二基板上各自的延展次数不同的方式控制所述旋转涂敷装置。
在所述的形式中,由于通过改变延展次数,利用重叠涂敷的次数控制粘接剂的涂敷厚度,因此,即使具有厚度也容易确保均匀性。
如上所述,根据本发明,可提供既可确保涂敷时的粘接层的均匀性、又可抑制制造中的粘接层的变化的贴合方法和贴合装置。
附图说明
图1是表示本发明的贴合装置的一个实施方式的结构的说明图。
图2是表示图1的实施方式的第一旋转涂敷装置的简略纵截面图。
图3是表示图1的实施方式的处理顺序的流程图。
图4是表示根据本发明的实施方式制造的实施例和现有例的粘接层厚的周内分布的说明图。
图5是表示根据本发明的实施方式制造的膜厚比不同的盘片的周内变化程度的说明图。
图6是表示在本发明的贴合装置中设置放置部的情况下的一个实施方式的说明图。
图7是表示现有的基板贴合顺序的说明图,(A)是粘接剂的延展,(B)是向真空室的导入,(C)是贴合,(D)是大气开放,(E)是粘接剂硬化的工序。
图8是表示利用现有技术制造的盘片的粘接层厚度的周内分布的说明图。
具体实施方式
以下参照附图,就实施本发明的最佳方式(以下,称为实施方式)进行具体说明。在本实施方式中,以不同厚度向一对基板涂敷粘接剂,使粘结剂临时硬化,然后进行贴合,从而抑制粘结剂的周内变化。
[实施方式的结构]
首先,参照图1和图2说明本实施方式的贴合装置(以下称为“本装置”)的结构。另外,本装置构成盘片的制造装置的一部分,关于设置在本装置的上游工序中的基板的成形装置、金属膜的形成装置以及在各装置之间交接基板的机构等,可使用众所周知的所有技术,因此省略说明。
本装置具有第一旋转涂敷装置1、第二旋转涂敷装置2、构成于转台3上的前照射部4、贴合部5、后照射部6等。第一旋转涂敷装置1是通过旋转涂敷而对贴合的一方的基板P1涂敷紫外线硬化型粘接剂B1的装置。该第一旋转涂敷装置1具有载置基板P1的转台11和使转台11旋转的驱动源12,是通过使基板P1旋转从而使从粘接剂供给部(无图示)滴下的粘接剂B1延展的装置。
如图1所示,第二旋转涂敷装置2是通过旋转涂敷而对贴合的另一方的基板P2涂敷紫外线硬化型粘接剂的装置。该第二旋转涂敷装置2具有载置基板P2的转台21和使转台21旋转的驱动源22,是通过使基板P2旋转而将从粘接剂供给部(无图示)滴下的粘接剂B2延展的装置。
并且,如图2所示,第二旋转涂敷装置2具有向基板P2上的粘接剂B2照射紫外线(UV)的照射装置23、和进行加热的加热装置24。照射装置23是向基板P1的中心孔周围点状地照射紫外线的装置,以来自光源的紫外线被光纤引导的方式构成。也可以将紫外线LED用于光源、以能够调整照射强度的方式构成。加热装置24是对基板P1的外周附近进行加热的装置。作为该加热装置24,可以使用例如红外线(IR)照射单元或加热器。
在转台3上具有:对应于前照射部4而放入基板P1的第一放入位置31;放入基板P2的第二放入位置32,该基板P2通过翻转装置(无图示)以粘接面相对的方式翻转;与贴合部5对应的贴合位置33;与后照射部6对应的紫外线照射位置34;以及将完成的盘片D搬出到下一个工序的搬出位置35。该转台3通过无图示的驱动机构而与所述的各位置配合并间歇旋转。
前照射部4通过UV照射装置在大气中向涂敷在基板P1上的粘接剂B1照射紫外线、使其临时硬化。“大气中”是指妨碍硬化环境,例如,指含有氧的气体氛围。一般来说,处在大气中比较容易,但是,包含氧或其它的妨碍硬化的环境也可以。
贴合部5是在真空中贴合基板P1、P2的装置。另外,贴合部5具有通过升降机构而工作的真空室、对真空室内进行减压的真空源、通过升降机构而工作并且推压基板P1、P2的推压部等,因为是众所周知的技术,因此省略说明。
后照射部6是如下的装置,即,通过UV照射装置在真空中向贴合后的基板P1、P2照射紫外线,使基板P1、P2之间的粘接剂B1、B2完全硬化的装置。另外,后照射部6也具有通过升降机构而工作的真空室、对真空室内进行减压的真空源等,因为是众所周知的技术,因此省略说明。
另外,在真空中照射是为了排除氧等妨碍硬化的主要原因,但并不是必须要形成无氧环境。这是由于贴合后的基板P1、P2的粘接接触面几乎一体化而不受环境气体左右地进行硬化的缘故。在大气中进行贴合的情况下,虽然外周端面与大气接触,但对于这部分,在生产线上的保管时间内(几天)达到完全硬化。如果在所述的真空中进行照射,则对于该外周端面也具有可进一步可靠地硬化的优点。利用惰性气体(N2)排除氧(净化)也可得到同样的效果。
通过控制装置控制来自所述粘接剂供给部的粘接剂的供给量、转台的旋转及其速度、照射装置的发光、加热装置、升降机构以及真空源的工作等。该控制装置可通过例如以专用的电子电路或规定的程序进行动作的计算机等实现。因此,以以下说明的顺序控制本装置的动作的计算机程序以及对其进行记录的记录介质也是本发明的一个形式。
[实施方式的作用]
参照图1、图2以及图3的流程图就通过以上的本装置进行的基板贴合的顺序进行说明。另外,在前工序中,利用喷溅在一方的基板P1上形成半透明的反射膜,在另一方的基板P2上喷溅全反射的金属膜。
如图1所示,在第一旋转涂敷装置1中,将紫外线硬化型粘接剂滴下涂敷在基板P1的中心孔的周围,通过使转台11高速旋转,从而延展粘接剂(步骤301)。例如,使用粘度为430mPas的粘接剂,涂敷压为0.2MPa,涂敷时间为0.6sec,通过6000rpm的高速旋转将其甩动(振り切る)1sec。
之后,如图1所示,以如上所述地涂敷了粘接剂B1的面朝上的方式将基板P1放入转台3(步骤302)。然后,在前照射部4,通过UV照射装置在大气中全面照射紫外线,使粘接剂B1的涂敷形状临时硬化至不变形的程度(步骤303)。例如,与通常的真硬化的情况下的条件(50mW/cm2×5s)相比较,用同样的强度照射大约一半的照射时间(2s)。
另外,如果在大气中,一般的紫外线硬化型树脂(粘接剂)即使全面照射紫外线,在通常的照射强度下也不会完全硬化。这是因为,在树脂的表面附近,空气中的氧将阻碍硬化。即,如果在大气中进行紫外线照射,则能够在保持表面的粘接性的状态下进行临时硬化。例如,事实证明即使是1000mW×1~2s也不会全部硬化。因此,该临时硬化时的照射条件不局限于所述条件。
在另一方的基板P2上,在第二旋转涂敷装置2中涂敷粘接剂。例如,涂敷压为0.2MPa,涂敷时间为0.15sec,通过10000rpm的高速旋转甩动1sec(步骤304)。然后,如图2所示,使基板P2旋转到粘接剂不流动的程度(例如120rpm~300rpm),通过照射装置23向中心孔周围点状地照射紫外线。由此,在延展后的粘接剂上形成环形硬化的部分(硬化部)(步骤305)。此时,在UV光的强度强的部分完全硬化,但是,随着向外周移动,受到粘接剂的氧妨碍的影响,表面不凝固,内部凝固,朝向外周、内部也逐渐不硬化。
然后,再次向这样延展并形成了硬化部的基板P2的粘接剂上滴下涂敷紫外线硬化型的粘接剂,通过使转台11高速旋转从而使粘接剂延展(步骤306)。例如,使用与第一次相同的粘接剂,使涂敷压为0.2MPa,涂敷时间为0.6sec,通过4000rpm的高速旋转,甩动1sec。此时,通过使用加热装置24进行部分加热,进行延展。例如,使用点加热器作为热源,波长为700~3000nm,设定输出为350W,加热范围是基板P2的径方向40mm~60mm,加热时间为1sec。
被加热而粘度降低了的粘接剂,通过使基板P2旋转所产生的离心力而被甩动,容易向外周弹出。或者,得到热能而挥发量增大。因此,残留在外周的粘接剂变薄,可抑制其厚度增大,因此,可使整体厚度均匀化。另外,也可同时向外周喷吹热风,对粘接剂进行辅助加热。
如上所述,通过设定旋转涂敷的旋转条件和涂敷次数,基板P2的粘接剂B2变厚,基板P1的粘接剂B1变薄。然后,利用翻转装置翻转基板P2(步骤307),并将其以粘接剂B2的涂敷面朝下的方式放在基板P1的上方(步骤308)。
之后,将两张基板P1、P2搬运到贴合部5,与现有技术相同地在真空中进行贴合(步骤309)。将贴合后的基板P1、P2输送到后照射部6,在真空中全面地照射紫外线,粘接剂B1、B2完全硬化(步骤310)。此时,从喷溅了不透光(反透過)的金属膜的基板P1侧照射紫外线。从搬出位置35搬出通过粘接剂硬化而制成的盘片D(步骤311)。
[实施方式的效果]
根据以上的本实施方式,通过使涂敷在贴合的基板P1上的粘接剂B1比涂敷在基板P2上的粘接剂B2薄,并且使其临时硬化,可提高抑制粘接剂B1的流动的效果,抑制贴合基板P1、P2之后的粘接层厚度的周内变化。
图4表示这样的贴合后的粘接层的周内分布。这样,比较根据所述实施方式制成的实施例、和不进行临时硬化而贴合的现有例(其他条件与实施例相同)的一例和平均的周内变化率,发现实施例的周内变化比现有例小。而且,图5表示改变不照射紫外线侧的粘接剂的膜厚A与照射紫外线侧的粘接剂的膜厚B并测量周内平均变化的结果。另外,在膜厚比为1:1并且不进行临时硬化的现有的方式中,周内变化的平均值为1.8μm。由此可知,通过进行临时硬化,具有降低周内变化的效果,而且,如果使薄的一方的粘接剂临时硬化,则其效果可进一步提高。
并且,在使粘接剂B1临时硬化的情况下,由于一部分区域预先硬化,所以,在真空中贴合基板P1、P2时能够抑制排气的产生,减少残留的气泡。另外,由于用于临时硬化的紫外线照射是在旋转涂敷结束并且粘接剂B1的飞散消失后进行的,因此,在旋转涂敷时飞散的粘接剂不会开始硬化,可以循环使用回收后的粘接剂。另外,在与旋转涂敷不同的位置进行照射,也可得到相同的效果。对于一面旋转基板P2一面进行点照射,由于只不过照射限定的一部分区域,因此,不影响粘接剂的回收。
并且,通过改变粘接剂的涂敷量、旋转条件以及延展次数,可容易地调节涂敷厚度。尤其是在想增加涂敷厚度的情况下,如上所述,通过形成硬化部并一面加热一面进行重叠涂敷,可确保均匀的厚度,因此,可提高抑制周内变化的效果。
[其他实施方式]
本发明并不局限于所述的实施方式。例如,对贴合前的一方的粘接剂的硬化程度没有特别的限制。因此,通过在真空中进行照射、利用惰性气体进行净化并照射、提高照射强度、延长照射时间等各种方法,即使不使涂敷在一方的基板上的薄的一方的粘接剂临时硬化而是使其完全硬化,也能够得到抑制贴合后的周内变化的效果。在这种情况下,在贴合时,通过另一方的未硬化的粘接剂确保粘接性。
并且,由于可通过临时硬化抑制周内变化,因此,例如,通过在贴合后确保放置时间,可进一步抑制气泡的产生。例如,如图6所示,通过将放置位置36设置在转台3的从贴合位置33开始到紫外线照射位置34为止之间,并且在此确保用于放置在大气中的规定时间,可减少气泡。
另外,对于涂敷得薄的粘接剂,根据其厚度的程度而不容易流动。例如,如果将粘接剂涂敷得非常薄(几微米左右、通过点照射形成的硬化部的程度),则可得到抑制流动并且抑制贴合后的周内变化的效果。虽然假硬化可提高抑制该周内变化的效果,但是在非常薄地涂敷粘接剂的情况下,即使不进行临时硬化,有时也可与上述相同地抑制周内变化。
并且,对于所使用的粘接剂,并不局限于紫外线硬化型的树脂,也可使用其他通过电磁波(也包括激光)而硬化的树脂、热硬化型树脂等各种树脂。因此,根据树脂的种类,进行照射的电磁波的种类也可使用紫外线、红外线(包括热线)以及规定波长的激光等各种电磁波。在所述的实施方式中,为了涂厚粘接剂而形成硬化部并重叠涂敷,但是,也可以只进行重叠涂敷,也可增加粘接剂的滴下量而进行一次涂敷。也可省略延展时的加热。并且,贴合也可不在真空中进行。
用于涂敷粘接剂的涂敷部可以是单数也可以是复数。例如,第一基板和第二基板也可使用共同的旋转涂敷装置。也可用多台旋转涂敷装置进行重叠涂敷。涂敷部并不局限于旋转涂敷装置,只要是可涂敷粘接剂的装置即可,包括现在或将来可利用的所有装置。
并且,前照射部可以设置在旋转涂敷之后到贴合为止之间的任何位置。例如,可设置于旋转涂敷装置,也可设置于从旋转涂敷装置到转台为止的搬运中途。如上所述,可设置在转台上的基板P1、P2中的任何一方上,也可设置于双方。
基板的大小、形状、材质等是任意的,可适用于将来采用的所有基板。因此,可适用于任何规格的记录介质用的盘片,当然也能够适用于补写型的记录介质、写入型的记录介质中的任何一种。并且,不仅适用于作为记录介质的盘片,还可适用于通过粘接剂贴合的所有基板。即,权利要求中所述的“基板”的概念不局限于圆盘形等,还广泛地包括平面状的产品。

Claims (6)

1.一种贴合方法,经由通过照射电磁波而发生硬化的粘接剂贴合第一基板和第二基板,其特征在于,
以分别不同的厚度向所述第一基板的一方的面和所述第二基板的一方的面涂敷粘接剂,
向涂敷到所述第一基板的粘接剂和涂敷到所述第二基板的粘接剂中的薄的一方照射电磁波,
贴合所述第一基板中的涂敷了粘接剂的面、和所述第二基板中的涂敷了粘接剂的面,
向所述第一基板和所述第二基板之间的粘接剂照射电磁波。
2.如权利要求1所述的贴合方法,其特征在于,在贴合所述第一基板中的涂敷了粘接剂的面、和所述第二基板中的涂敷了粘接剂的面之后,在照射电磁波之前放置在大气中。
3.一种贴合装置,经由通过照射电磁波而发生硬化的粘接剂贴合第一基板和第二基板,其特征在于,具有:
以分别不同的厚度向所述第一基板的一方的面和所述第二基板的一方的面涂敷粘接剂的至少一个涂敷部,
向涂敷到所述第一基板的粘接剂和涂敷到所述第二基板的粘接剂中的薄的一方照射电磁波的前照射部,
贴合所述第一基板的涂敷了粘接剂的面、和所述第二基板的涂敷了粘接剂的面的贴合部,以及,
向所述第一基板和所述第二基板之间的粘接剂照射电磁波的后照射部。
4.如权利要求3所述的贴合装置,其特征在于,具有放置部,在贴合所述第一基板的涂敷了粘接剂的面、和所述第二基板的涂敷了粘接剂的面之后,在照射电磁波之前在大气中放置规定时间。
5.如权利要求3或4所述的贴合装置,其特征在于,所述涂敷部具有至少一个旋转涂敷装置,该旋转涂敷装置通过使所述第一基板和所述第二基板旋转而延展粘接剂,
并且具有控制装置,该控制装置以在所述第一基板和所述第二基板上各自的旋转条件不同的方式控制所述旋转涂敷装置。
6.如权利要求3或4所述的贴合装置,其特征在于,所述涂敷部具有至少一个旋转涂敷装置,该旋转涂敷装置通过使所述第一基板和所述第二基板旋转而延展粘接剂,
具有控制装置,该控制装置以在所述第一基板和所述第二基板上各自的延展次数不同的方式控制所述旋转涂敷装置。
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US20100043964A1 (en) 2010-02-25
JP4789282B2 (ja) 2011-10-12
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WO2008038413A1 (en) 2008-04-03
TWI384476B (zh) 2013-02-01

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