CN101516928B - 催化剂活化剂及其制备方法、以及其在催化剂和烯烃聚合中的应用 - Google Patents

催化剂活化剂及其制备方法、以及其在催化剂和烯烃聚合中的应用 Download PDF

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CN101516928B
CN101516928B CN200780034808XA CN200780034808A CN101516928B CN 101516928 B CN101516928 B CN 101516928B CN 200780034808X A CN200780034808X A CN 200780034808XA CN 200780034808 A CN200780034808 A CN 200780034808A CN 101516928 B CN101516928 B CN 101516928B
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bronsted acid
lewis base
silicon oxide
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CN101516928A (zh
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卢宾·罗
斯蒂文·P.·迪芬巴赫
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WR Grace and Co
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Albemarle Corp
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN200780034808XA 2006-09-20 2007-09-17 催化剂活化剂及其制备方法、以及其在催化剂和烯烃聚合中的应用 Active CN101516928B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US84606506P 2006-09-20 2006-09-20
US60/846,065 2006-09-20
US86996706P 2006-12-14 2006-12-14
US60/869,967 2006-12-14
PCT/US2007/078629 WO2008036594A2 (en) 2006-09-20 2007-09-17 Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins

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CN101516928A CN101516928A (zh) 2009-08-26
CN101516928B true CN101516928B (zh) 2012-05-23

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US (1) US8501655B2 (enExample)
EP (1) EP2099833B1 (enExample)
JP (1) JP6026716B2 (enExample)
KR (1) KR101430777B1 (enExample)
CN (1) CN101516928B (enExample)
CA (1) CA2663342C (enExample)
ES (1) ES2562434T3 (enExample)
WO (1) WO2008036594A2 (enExample)

Families Citing this family (10)

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Publication number Priority date Publication date Assignee Title
PT2099832T (pt) * 2006-12-14 2019-06-27 Grace W R & Co Ativadores de catalisador, processos para preparação dos mesmos, e sua utilização em catalisadores e polimerização de olefinas
WO2012071205A2 (en) 2010-11-22 2012-05-31 Albemarle Corporation Activator compositions, their preparation, and their use in catalysis
TWI555574B (zh) * 2011-03-09 2016-11-01 亞比馬利股份有限公司 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途
ES2805782T3 (es) 2012-04-27 2021-02-15 Grace W R & Co Composiciones de activador, su preparación y su uso en catalizadores
CN103539873A (zh) * 2012-07-11 2014-01-29 苏州亚培克生物科技有限公司 固体活化剂体系及其制备方法
CN104910021B (zh) * 2014-03-13 2018-02-13 双阳化工淮安有限公司 2‑甲基‑6‑乙基苯胺的制备工艺
KR102578006B1 (ko) 2015-05-11 2023-09-12 더블유.알. 그레이스 앤드 캄파니-콘. 개질된 점토, 지지된 메탈로센 중합 촉매의 제조 방법, 제조된 촉매, 및 이의 용도
BR112017024300A2 (pt) 2015-05-11 2018-07-24 Grace W R & Co processo para a produção de argila modificada, argila modificada produzida e uso da mesma
CN111408410B (zh) * 2019-01-04 2023-03-24 中国石油化工股份有限公司 一种催化剂组合物、其制备方法及其在乙烯选择性二聚化合成1-丁烯的反应中的应用
WO2021247244A2 (en) 2020-06-03 2021-12-09 Exxonmobil Chemical Patents Inc. Process for production of thermoplastic vulcanizates using supported catalyst systems and compositions made therefrom

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1427842A (zh) * 2000-05-24 2003-07-02 巴塞尔聚烯烃有限公司 适用作助催化剂的化学产物、其制备以及它们在制备聚烯烃用催化剂体系中的应用
WO2007005921A2 (en) * 2005-07-01 2007-01-11 Albemarle Corporation Bronsted acidic aluminoxane compositions and their use in olefin polymerization catalyst compositions
WO2007005676A2 (en) * 2005-07-01 2007-01-11 Albemarle Corporation Activator compositions and their use in catalysts and olefin polymerization
WO2007076398A2 (en) * 2005-12-21 2007-07-05 Albemarle Corporation Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins

Family Cites Families (5)

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Publication number Priority date Publication date Assignee Title
JP3196419B2 (ja) * 1993-05-20 2001-08-06 出光興産株式会社 アルミニウムオキシ化合物及びそれを含有する重合用触媒
AU1272100A (en) * 1998-11-25 2000-06-13 Targor Gmbh Metallocene monohalogenides
JP2001323009A (ja) * 2000-03-07 2001-11-20 Sumitomo Chem Co Ltd α−オレフィン重合用触媒およびα−オレフィン重合体の製造方法
JP2002179723A (ja) * 2000-12-08 2002-06-26 Asahi Kasei Corp オレフィン重合用触媒及び該触媒を用いるオレフィンの重合方法
EP1527108A2 (en) * 2002-07-15 2005-05-04 Basell Polyolefine GmbH Preparation of supported catalyst systems

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1427842A (zh) * 2000-05-24 2003-07-02 巴塞尔聚烯烃有限公司 适用作助催化剂的化学产物、其制备以及它们在制备聚烯烃用催化剂体系中的应用
WO2007005921A2 (en) * 2005-07-01 2007-01-11 Albemarle Corporation Bronsted acidic aluminoxane compositions and their use in olefin polymerization catalyst compositions
WO2007005676A2 (en) * 2005-07-01 2007-01-11 Albemarle Corporation Activator compositions and their use in catalysts and olefin polymerization
WO2007076398A2 (en) * 2005-12-21 2007-07-05 Albemarle Corporation Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins

Also Published As

Publication number Publication date
CN101516928A (zh) 2009-08-26
CA2663342C (en) 2015-01-27
JP2010504406A (ja) 2010-02-12
KR101430777B1 (ko) 2014-08-18
WO2008036594A2 (en) 2008-03-27
US20100029470A1 (en) 2010-02-04
US8501655B2 (en) 2013-08-06
EP2099833B1 (en) 2015-11-11
KR20090077917A (ko) 2009-07-16
WO2008036594A3 (en) 2008-07-24
ES2562434T3 (es) 2016-03-04
CA2663342A1 (en) 2008-03-27
EP2099833A2 (en) 2009-09-16
JP6026716B2 (ja) 2016-11-16

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