CN101466267A - 具有杀昆虫和杀螨虫特性的活性物质结合物 - Google Patents
具有杀昆虫和杀螨虫特性的活性物质结合物 Download PDFInfo
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- CN101466267A CN101466267A CNA2007800221765A CN200780022176A CN101466267A CN 101466267 A CN101466267 A CN 101466267A CN A2007800221765 A CNA2007800221765 A CN A2007800221765A CN 200780022176 A CN200780022176 A CN 200780022176A CN 101466267 A CN101466267 A CN 101466267A
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Classifications
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- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/58—One oxygen atom, e.g. butenolide
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Abstract
由环状酮烯醇和有利物种(天敌)组成的新的活性物质结合物具有良好的杀昆虫和/或杀螨特性。
Description
本发明涉及新的活性化合物结合物(combination)，其首先包括已知的环状酮烯醇，其次还包括有利的物种(天敌)，该结合物非常适合于防治诸如昆虫和/或不想要的螨虫等的动物类害虫。
已知某些环状酮烯醇具有杀昆虫和杀螨虫特性(EP-A-528 156)。WO 95/01971、EP-A-647 637、WO 96/16061、WO 96/20196、WO 96/25395、WO 96/35664、WO 97/02243、WO 97/01535、WO 97/36868、WO 97/43275、WO 98/05638、WO 98/06721、WO 99/16748、WO 99/43649、WO 99/48869、WO 99/55673、WO 00/42850、WO 01/17972、WO 01/23354、WO 01/74770、WO 03/013249、WO 04/024688、WO 04/080962、WO 04/111042、WO05/092897、WO 06/000355、WO 06/002824和WO 06/029799描述了其它具有杀昆虫和/或杀螨虫特性的酮烯醇。这些物质的活性良好，然而有时在低施用率下活性不能令人满意。
另外还已知多种有利的物种被用于防治昆虫和叶螨(spider mite)：“Knowing and recognizing”；M.H.Malais，W.J.Ravensberg，published by Koppert B.V.，Reed Business Information(2003)。然而，单独使用有利物种并不总是令人满意的。
现已发现式(I)化合物与来源于蜘蛛目(Araneae)、蜱螨亚纲(Acari)、膜翅目(Hymenoptera)、鞘翅目(Coleoptera)、脉翅目(Neuroptera)、缨翅目(Tysanoptera)、异翅目(Heteroptera)、双翅目(Diptera)、半翅目(Hemiptera)、革翅目(Dermaptera)和寄螨目(Parasitiformes)的目或亚目的有利物种结合使用具有非常好的杀昆虫和/或杀螨虫特性，
其中，
X 代表C1-C6烷基、卤素、C1-C6烷氧基或C1-C3卤代烷基，
Y 代表氢、C1-C6烷基、卤素、C1-C6烷氧基或C1-C3卤代烷基，
Z 代表C1-C6烷基、卤素或C1-C6烷氧基，
n 代表数字0-3，
A 代表氢或各自任选地被卤素取代的直链或带支链的C1-C12烷基、C3-C8烯基、C3-C8炔基、C1-C10烷氧基-C2-C8烷基、C1-C8聚烷氧基-C2-C8烷基、C1-C10烷硫基-C2-C8烷基或者可被氧和/或硫间隔的具有3-8个环原子的环烷基，以及各自任选被卤素、C1-C6烷基，C1-C6-卤代烷基，C1-C6烷氧基，C1-C6卤代烷氧基或硝基取代的苯基或苯基-C1-C6烷基，
B 代表氢、C1-C6烷基或C1-C6烷氧基-C2-C4烷基，
或者其中
A和B与它们所连接的碳原子一起形成一个饱和的或不饱和的3至8元环，所述环任选地被氧和/或硫间隔，并任选地被卤素、C1-C6烷基、C1-C6烷氧基、C1-C4卤代烷基、C1-C4卤代烷氧基、C1-C4烷硫基或任选被取代的苯基取代或任选地与苯稠合，
G 代表氢(a)或代表以下基团，
其中
R1 代表各自任选被卤素取代的C1-C20烷基、C2-C20烯基、C1-C8烷氧基-C2-C8烷基、C1-C8烷硫基-C2-C8烷基、C1-C8聚烷氧基-C2-C8烷基或可被氧和/或硫原子间隔的具有3-8个环原子的环烷基，
代表任选被卤素、硝基，C1-C6烷基、C1-C6烷氧基、C1-C6卤代烷基或C1-C6卤代烷氧基取代的苯基，
代表任选被卤素、C1-C6烷基、C1-C6烷氧基、C1-C6卤代烷基或C1-C6卤代烷氧基取代的苯基-C1-C6烷基，
代表各自任选被卤素和/或C1-C6烷基取代的吡啶基、嘧啶基、噻唑基或吡唑基，
代表任选被卤素和/或C1-C6烷基取代的苯氧基-C1-C6烷基，
R2 代表各自任选被卤素取代的C1-C20烷基、C2-C20烯基、C1-C8烷氧基-C2-C8烷基或C1-C8聚烷氧基-C2-C8烷基，
代表各自任选被卤素、硝基、C1-C6烷基、C1-C6烷氧基或C1-C6卤代烷基取代的苯基或苯甲基，
R3 代表任选被卤素取代的C1-C8烷基，代表各自任选被C1-C4烷基、卤素、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、硝基或氰基取代的苯基或苯甲基，
R4和R5彼此独立地代表各自任选被卤素取代的C1-C8烷基、C1-C8烷氧基、C1-C8烷基氨基、二(C1-C8)烷基氨基、C1-C8烷硫基、C2-C5烯硫基、C2-C5炔硫基或C3-C7环烷基硫基，代表各自任选地被卤素、硝基、氰基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷硫基、C1-C4卤代烷硫基、C1-C4烷基或C1-C4卤代烷基取代的苯基、苯氧基或苯硫基，
R6和R7彼此独立地代表各自任选被卤素取代的C1-C10烷基、C1-C10烷氧基、C3-C8烯基或C1-C8烷氧基-C1-C8烷基，代表任选被卤素、C1-C6卤代烷基、C1-C6烷基或C1-C6烷氧基取代的苯基，代表任选被卤素、C1-C6烷基、C1-C6卤代烷基或C1-C6烷氧基取代的苯甲基，或者两者一起代表一个任选被C1-C6烷基取代的且任选被氧或硫间隔的5至6元环。
令人惊奇的是，本发明的活性化合物/有利物种结合物的杀昆虫和/或杀螨虫活性比单独的活性化合物和有利物种的活性更好。存在不可预料的活性的增加。
此外，已发现，通过使用本发明的活性化合物/有利物种的结合物，可代替毒理学上和/或生态学上较为不利的活性化合物的施用，并取得相当的活性，这尤其有利于对使用者和/或环境的安全性。另外，已发现可减少喷雾的施用。除了至少一种式(I)的活性化合物以外，本发明的活性化合物/有利物种结合物还包括至少一种来源于上文所述的目或亚目的有利物种。
优选使用包括基团如下定义的式(I)化合物的活性化合物/有利物种结合物：
X 优选代表C1-C4烷基、卤素、C1-C4烷氧基或C1-C2卤代烷基，
Y 优选代表氢、C1-C4烷基、卤素、C1-C4烷氧基或C1-C2卤代烷基，
Z 优选代表C1-C4烷基、卤素或C1-C4烷氧基，
n 优选代表0或1，
A和B与它们所连接的碳原子一起优选代表一个任选被C1-C4烷基或C1-C4烷氧基取代的饱和的5至6元环，
G 优选代表氢(a)或代表下述基团，
其中
R1 代表各自任选被卤素取代的C1-C16烷基、C2-C16烯基、C1-C6烷氧基-C2-C6烷基或可被1至2个氧和/或硫原子间隔的具有3-7个环原子的环烷基，代表任选被卤素、硝基、C1-C4烷基、C1-C4烷氧基、C1-C3卤代烷基或C1-C3卤代烷氧基取代的苯基，
R2 代表各自任选被卤素取代的C1-C16烷基、C2-C16烯基或C1-C6烷氧基-C2-C6烷基，
代表各自任选被卤素、硝基、C1-C4烷基、C1-C4烷氧基或C1-C4卤代烷基取代的苯基或苯甲基。
特别优选地使用包括式(I-b-1)的二氢呋喃酮(dihydrofuranone)衍生物的活性化合物/有利物种结合物，
此外，活性化合物/有利物种结合物还可包括其它合适的具有杀真菌、杀螨虫或杀昆虫活性的添加组分。
优选将来自胡蜂科(Vespidae)、蚜小蜂科(Aphelinidae)、赤眼蜂科(Trichogrammatidae)、跳小蜂科(Encyrtidae)、缨小蜂科(Mymaridae)、姬小蜂科(Eulophidae)、长背瘦蜂科(Alloxystidae)、大痣细蜂科(Megaspilidae)、茧蜂科(Braconidae)、花萤科(Cantharidae)、瓢虫科(Coccinellidae)、郭公虫科(Cleridae)、草蛉科(Chrysopidae)、褐蛉科(Hemerobiidae)、花蝽科(Anthocoridae)、盲蝽科(Miridae)、球螋科(Forficulidae)、植绥螨科(Phytoseiidae)、步甲科(Carabidae)、隐翅虫科(Staphylenidae)、姬蜂科(Ichneumonidae)、蚜茧蜂科(Aphidiidae)、蜾赢科(Eumenidae)、泥蜂科(Sphecidae)、寄蝇科(Tachnidae)、食蚜蝇科(Syrphidae)、瘿蚊科(Cecidomyiidae)、长须螨科(Stigmaeidae)、Angstidae、绒螨科(Trombidiidae)、姬蝽科(Nabidae)、蝽科(Pentatomidae)、猎蝽科(Reduviidae)、粉蛉科(Coniopterygidae)、斑腹蝇科(Chameiidae)、食虫虻科(Asilidae)、土螨、植缨螨科(Phytoseidae)的科的有利物种用于一年生作物例如蔬菜、瓜类、观赏植物、玉米，以及多年生植物例如柑橘类水果、仁果和核果，香料植物、松柏类植物和其他观赏植物以及绿化植物中。
对于待保护作物，只对其进行了宽泛的描述，下文中将以更加细化及更加具体的方式进行描述。因此，就用途而言，蔬菜的含义应理解为例如果实类蔬菜和花头类蔬菜，例如甜椒(bell pepper)、辣椒、番茄、茄子、黄瓜、葫芦、小西葫芦、蚕豆、红花菜豆、矮菜豆、豌豆、朝鲜蓟；
还应理解为叶类蔬菜，例如莴笋、菊苣(chicory)、苣荬菜(endive)、水芹、芝麻菜(rocket salad)、作沙拉青菜用的匙形菜叶(field salad)、卷心莴苣、韭葱、菠菜、唐莴苣；
此外还应理解为块茎类蔬菜、根类蔬菜和茎类蔬菜，例如块根芹、甜菜根、胡萝卜、红萝卜、辣根、鸦葱、芦笋、菜用甜菜(table beet)、棕榈芽(palm shoot)、竹笋，以及鳞茎类蔬菜例如洋葱、韭葱、茴香、大蒜；
此外还应理解为苔芸类蔬菜，例如花椰菜、球花甘蓝(broccoli)、撇蓝(kohlrabi)、红球甘蓝、白球甘蓝、绿球甘蓝(green cabbage)、皱叶甘蓝(Savoy cabbage)、抱子甘蓝(Brussels sprouts)、白菜(Chinese cabbage)。
就用途而言，多年生作物的含义应理解为柑橘类水果，例如橙(orange)、葡萄柚、柑橘、柠檬、莱蒙、苦橙(bitter orange)、金橘、小蜜橘(satsuma)；
还应理解为仁果，例如苹果、梨和榅桲，以及核果，例如桃、油桃、樱桃、李、普通李(common plum)、杏；
还应理解为葡萄藤、酒花、橄榄、茶，以及热带作物例如芒果、木瓜、无花果、菠萝、枣椰、香蕉、榴莲、柿子、椰子、可可、咖啡、鳄梨、荔枝、maracujas、番石榴，
还应理解为杏仁和坚果，例如榛子、核桃、阿月浑子(pistachio)、腰果、巴西坚果、美洲山核桃(pecan nut)、灰胡桃、栗子、毡毛山核桃(hickory nut)、澳洲坚果(macadamia nut)、花生，
此外还应理解为无核小水果，例如黑醋栗、圆醋栗、覆盆子(raspberry)、黑莓、蓝莓、草莓、红越桔(red bilberry)、猕猴桃、酸果蔓(cranberry)。
就用途而言，观赏植物的含义应理解为一年生植物和多年生植物，例如切花(cut flower)，如玫瑰、康乃馨、大丁草、百合、雏菊、菊花、郁金香、水仙、银莲花、罂粟、孤挺花、大丽花、杜鹃花、malve，
还应理解为例如花坛植物(bedding plant)、盆栽植物和灌木，例如玫瑰、万寿菊、紫罗兰、天竺葵、倒挂金钟(fuchsia)、木槿、菊花、凤仙花、仙客来、非洲堇(African violet)、向日葵、秋海棠，
还应理解为例如灌木和松柏类植物，例如无花果树、杜鹃花、云杉、冷杉、松树、紫杉、杜松、石松、夹竹桃(rose bay)。
就用途而言，香料的含义应理解为一年生植物和多年生植物，例如大茴香、辣椒、甜椒、胡椒、香草、马郁兰、百里香、丁香、杜松、肉桂、龙蒿(tarragon)、芫荽、藏红花、姜。
蜾赢科，特别优选：蜾蠃属(Eumenes spp.)、Oplomerus spp.，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
泥蜂科，特别优选：沙蜂(Ammophila sabulos)、节腹泥蜂(Cercerisarenaria)，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
胡蜂科，特别优选：长足胡蜂属(Polistes spp.)、胡蜂属(Vespaspp.)、长黄胡蜂属(Dolichovespula spp.)、黄胡蜂属(Vespula spp.)、Paravespula spp.，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
蚜小蜂科，特别优选：Coccophagus spp.、恩蚜小蜂属种(Encarsia spp.)例如丽蚜小蜂(Encarsia formosa)、黄蚜小蜂属(Aphytis spp.)、蚜小蜂属种(Aphelinus spp.)例如苹果绵蚜蚜小蜂(Aphelinus mali)、Aphelinus abdominalis，浆角蚜小蜂属(Erelmocerus spp.)例如Erelmocerus erimicus、Erelmocerus mundus，黄色跳小蜂属(Prospaltella spp.)，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
赤眼蜂科，特别优选：赤眼蜂属(Trichogramma spp.)例如甘蓝夜蛾赤眼蜂(Trichogamma brassicae)，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
跳小蜂科，特别优选：Encyrtus fuscicollis、蚜虫跳小蜂属(Aphidencyrtrus spp.)，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物、香料和绿化植物中。
缨小蜂科，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
姬蜂科(Ichneumoidae)，特别优选：Coccigomymus spp.、弯尾姬蜂属(Diadegma spp.)、雕背姬蜂属(Glypta spp.)、瘦姬蜂属(Ophionspp.)、Pimpla spp.，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
姬小蜂科，特别优选：潜蝇姬小蜂属(Dyglyphus spp.)例如豌豆潜蝇姬小蜂(Dyglyphus isaea)、Eulophus viridula、Colpoclypeusflorus，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物、玉米和香料中。
长背瘦蜂科，特别优选：光背瘿蜂属(Alloxysta spp.)，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
大痣细蜂科，特别优选：盾痣细蜂属(Dendrocerus spp.)，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
茧蜂科(Bracconidae)，特别优选：茧蜂属(Aphidrus spp.)、蚜外茧蜂属(Praon spp.)、潜蝇茧蜂属(Opius spp.)、薾蜂属(Dacnusaspp.)例如西伯利亚离颚茧蜂(Dacnusa sibiria)，绒茧蜂属(Apantelesspp.)、革腹茧蜂属(Ascogaster spp.)、长体茧蜂属(Macrocentrusspp.)，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
蚜茧蜂科，特别优选：茧蜂属(Aphidius spp.)例如科列马·阿布拉小蜂(Aphidius colemani)、阿尔蚜茧蜂(Aphidius ervi)，蚜茧蜂属(Diaeretiella spp.)、Lysiphlebus spp.，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
瓢虫科，特别优选：异色瓢虫属(Harmonia spp.)、瓢虫属(Coccinella spp.)例如七星瓢虫(Coccinella septempunctata)、大丽瓢虫属(Adalia spp.)例如二星瓢虫(Adalia bipunctata)、裸瓢虫属(Calvia spp.)、盔唇瓢虫属(Chilocorus spp.)例如双斑唇瓢虫(Chilocorus bipustulatus)、小毛瓢虫属(Scymnus spp.)、孟氏隐唇瓢虫(Cryptolaemus montrouzieri)、光缘瓢虫属(Exochomusspp.)、小黑瓢虫属种(Stethorus spp.)例如Scymnus abietes、Scymnusinterruptus，眼斑瓢虫属(Anatis spp.)、暗色瓢虫属(Rhizobius spp.)、黑斑菌瓢虫属(Thea spp.)，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
隐翅虫科(Staphylemidae)，特别优选：前角隐翅虫属(Aleocharaspp.)、Aligota spp.、菲隐翅虫属(Philonthus spp.)、隐翅甲属(Staphylinus spp.)，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
草蛉科，特别优选：草蛉属(Chrysopa spp.)例如灰翅草蛉(Chrysopaoculata)、草蛉(Chrysopa perla)、普通草蛉(Chrysopa carnea)、Chrysopa flava、大草蛉(Chrysopa septempunctata)，通草蛉属(Chrysoperla spp.)、Chrysopidia spp.例如Chrysopidia ciliata，Hypochrysa spp.例如Hypochrysa elegans，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
褐蛉科，特别优选：褐蛉属(Hemerobius spp.)例如Hemerobiusfenestratus、全北褐蛉(Hemerobius humulinus)、Hemerobius micans、Hemerobius nitidulus、Hemerobius pini，丛褐蛉属(Wesmaelius spp.)例如Wesmaelius nervosus，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
花蝽科，特别优选：原花蝽属(Anthocoris spp.)例如Anthocorisnemoralis、欧原花蝽(Anthocoris nemorum)，小花蝽属(Orius spp.)例如Orius ma jusculus、微小花蝽(Orius minutus)、Orius laevigatus、狡诈花蝽(Orius insidiosus)、肩毛小花蝽(Orius niger)、邻小花蝽(Orius vicinus)，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
盲蝽科，特别优选：Atractotomus spp.例如苹果盲蝽(Atractotomusmali)，Blepharidopterus spp.例如Blepharidopterus angulatus，斑腿盲椿属(Campylomma spp.)例如显角微刺盲蝽(Camylommaverbasci)，齿爪盲蝽属(Deraeocoris spp.)、Macrolophus spp.例如盲蝽(Macrolophus caliginosus)，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
蝽科，特别优选：蠋蝽属(Arma spp.)、刺益蝽属(Podisus spp.)例如斑腹刺益蝽(Podisus maculiventris)，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
姬蝽科，特别优选：姬蝽属(Nabis spp.)例如Nabis apterus，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
猎蝽科，特别优选：白痣蚊猎蝽(Empicornis vagabundus)、伪装猎蝽(Reduvius personatus)、Rhinocoris spp.，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
寄蝇科(Tachinidae)，特别优选：Bessa fugax、Cyzeniusalbicans、康刺腹寄蝇(Compsileura concinnata)、黑伊乐寄蝇(Elodiatragica)、古毒蛾追寄蝇(Exorista larvarum)、Lyphia dubia，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
食蚜蝇科，特别优选：毛食蚜蝇属(Dasysyrphus spp.)、细扁食蚜蝇(Episyrphus balteatus)、Melangyna triangulata、墨蚜蝇属(Melanostoma spp.)、食蚜蝇属(Metasyrphus spp.)、宽跗食蚜蝇属(Platycheirus spp.)、蚜蝇属(Syrphus spp.)，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
瘿蚊科，特别优选：食蚜瘿蚊(Aphidoletes aphidimyza)、Feltiellaacarisuga，用于作物例如仁果、核果、蔬菜、观赏植物、松柏类植物和香料中。
植缨螨科，特别优选：钝绥螨属(Amblyseius spp.)、Typhlodromusspp.、植绥螨属(Phytoseiulus spp.)，用于作物例如仁果、核果、蔬菜、观赏植物和香料中。
本发明的活性化合物/有利物种结合物适合防治在葡萄栽培和水果栽培、农业和园艺以及绿化中发现的动物类害虫，优选节肢动物和线虫，特别是昆虫和/或蛛形纲动物。它们对通常敏感和抗性物种以及全部或某些发育阶段具有活性。上述害虫包括：
等足目(Isopoda)，例如，栉水虱(Oniscus asellus)、鼠妇(Armadilliudium vulgare)、球鼠妇(Porcellio scaber)。
倍足目(Diplopoda)，例如，Blaniulus guttulatus。
唇足目(Chilopoda)，例如，地蜈蚣(Geophilus carpophagus)、Scutigera spp.。
综合目(Symphyla)，例如，Scutigerella immaculata。
缨尾目(Thysanura)，例如，衣鱼(Lepisma saccharina)。
弹尾目(Collembola)，例如，武装棘跳虫(Onychiurus armatus)。
直翅目(Orthoptera)，例如，家蟋(Acheta domesticus)、蝼蛄属种(Gryllotalpa spp.)、亚洲飞蝗(Locusta migratoriamigratorioides)、黑蝗属种(Melanoplus spp.)、沙漠蝗(Schistocercagregaria)。
蜚蠊目(Blattaria)，例如，东方蜚蠊(Blatta orientalis)、美洲大蠊(Periplaneta americana)、马德拉蜚蠊(Leucophaea maderae)、德国小蠊(Blattella germanica)。
革翅目(Dermaptera)，例如，欧洲球螋(Forficula auricularia)。
等翅目(Isoptera)，例如，散白蚁属种(Reticulitermes spp.)。
虱目(Phthiraptera)，例如，人体虱(Pediculus humanus corporis)、血虱属种(Haematopinus spp.)、毛虱属种(Linognathus spp.)、嚼虱属种(Trichodectes spp.)、畜虱属种(Damalinia spp.)。
缨翅目(Thysanoptera)，例如，温室条篱蓟马(Hercinothripsfemoralis)、烟蓟马(Thrips tabaci)、棕榈蓟马(Thrips palmi)、西花蓟马(Frankliniella occidentalis)。
异翅目(Heteroptera)，例如，扁盾蝽属种(Eurygaster spp.)、Dysdercus intermedius、方背皮蝽(Piesma quadrata)、温带臭虫(Cimexlectularius)、长红锥蝽(Rhodnius prolixus)、锥猎蝽属种(Triatomaspp.)。
同翅目(Homoptera)，例如，白粉虱(Aleurodes brassicae)、烟粉虱(Bemisia tabaci)、温室粉虱(Trialeurodes vaporariorum)、棉蚜(Aphis gossypii)、甘蓝蚜(Brevicoryne brassicae)、茶藨隐瘤蚜(Cryptomyzus ribis)、黑豆蚜(Aphis fabae)、苹蚜(Aphispomi)、苹果绵蚜(Eriosoma lanigerum)、梅大尾蚜(Hyalopterusarundinis)、葡萄根瘤蚜(Phylloxera vastatrix)、瘿绵蚜属种(Pemphigus spp.)、麦长管蚜(Macrosiphum avenae)、瘤蚜属种(Myzusspp.)、忽布疣蚜(Phorodon humuli)、禾谷缢管蚜(Rhopalosiphumpadi)、小绿叶蝉属种(Empoasca spp.)、Euscelis bilobatus、黑尾叶蝉(Nephotettix cincticeps)、水木坚蚧(Lecanium corni)、蜡蚧(Saissetia oleae)、灰飞虱(Laodelphax striatellus)、褐飞虱(Nilaparvata lugens)、红园蚧(Aonidiella aurantii)、常春藤蚧(Aspidiotus hederae)、粉蚧属种(Pseudococcus spp.)、木虱属种(Psylla spp.)。
鳞翅目(Lepidoptera)，例如，红铃麦蛾(Pectinophoragossypiella)、松尺蠖(Bupalus piniarius)、冬尺蛾(Cheimatobiabrumata)、苹细蛾(Lithocolletis blancardella)、苹果巢蛾(Hyponomeuta padella)、菜蛾(Plutella xylostella)、黄褐天幕毛虫(Malacosoma neustria)、黄毒蛾(Euproctis chrysorrhoea)、毒蛾属种(Lymantria spp.)、棉潜蛾(Bucculatrix thurberiella)、桔潜蛾(Phyllocnistis citrella)、地老虎属种(Agrotis spp.)、切根虫属种(Euxoa spp.)、脏切夜蛾属种(Feltia spp.)、埃及金刚钻(Earias insulana)、实夜蛾属种(Heliothis spp.)、甘蓝夜蛾(Mamestra brassicae)、小眼夜蛾(Panolis flammea)、灰翅夜蛾属种(Spodoptera spp.)、粉纹夜蛾(Trichoplusia ni)、苹果皮小卷蛾(Carpocapsa pomonella)、菜粉蝶属种(Pieris spp.)、禾草螟属种(Chilo spp.)、玉米螟(Pyrausta nubilalis)、、地中海粉斑螟(Ephestia kuehniella)、大蜡螟(Galleria mellonella)、幕谷蛾(Tineola bisselliella)、袋谷蛾(Tinea pellionella)、褐织蛾(Hofmannophila pseudospretella)、亚麻黄卷蛾(Cacoeciapodana)、Capua reticulana、枞色卷蛾(Choristoneura fumiferana)、葡萄果蠹蛾(Clysia ambiguella)、茶长卷蛾(Homona magnanima)、栎绿卷蛾(Tortrix viridana)、Cnaphalocerus spp.、水稻负泥虫(Oulemaoryzae)。
鞘翅目(Coleoptera)，例如，家具窃蠹(Anobium punctatum)、谷蠹(Rhizopertha dominica)、恶条豆象(Bruchidius obtectus)、菜豆象(Acanthoscelides obtectus)、北美家天牛(Hylotrupesbajulus)、杨树萤叶甲(Agelastica alni)、马铃薯甲虫(Leptinotarsadecemlineata)、辣根猿叶虫(Phaedon cochleariae)、叶甲属种(Diabrotica spp.)、油菜金头跳甲(Psylliodes chrysocephala)、墨西哥豆瓢虫(Epilachna varivestis)、Atomaria spp.、锯谷盗(Oryzaephilus surinamensis)、花象属种(Anthonomus spp.)、谷象属种(Sitophilus spp.)、黑葡萄耳象(Otiorrhynchus sulcatus)、香蕉黑象虫(Cosmopolites sordidus)、白菜籽龟象(Ceuthorrhynchusassimilis)、紫苜蓿叶象(Hypera postica)、皮蠹属种(Dermestesspp.)、斑皮蠹属种(Trogoderma spp.)、圆皮蠹属种(Anthrenus spp.)、毛皮蠹属(Attagenus spp.)、粉蠹属种(Lyctus spp.)、油菜花露尾甲(Meligethes aeneus)、蛛甲属种(Ptinus spp.)、黄蛛甲(Niptushololeucus)、裸蛛甲(Gibbium psylloides)、拟谷盗属种(Triboliumspp.)、黄粉虫(Tenebrio molitor)、叩甲属种(Agriotes spp.)、宽胸叩头虫属种(Conoderus spp.)、西方五月鳃角金龟(Melolonthamelolontha)、马铃薯鳃角金龟(Amphimallon solstitialis)、褐新西兰肋翅鳃角金龟(Costelytra zealandica)、稻根象(Lissorhoptrusoryzophilus)。
膜翅目(Hymenoptera)，例如，松叶蜂属种(Diprion spp.)、实叶蜂属种(Hoplocampa spp.)、毛蚁属种(Lasius spp.)、小家蚁(Monomorium pharaonis)、胡蜂属种(Vespa spp.)。
双翅目(Diptera)，例如，伊蚊属种(Aedes spp.)、按蚊属种(Anopheles spp.)、库蚊属种(Culex spp.)、黑腹果蝇(Drosophilamelanogaster)、家蝇属种(Musca spp.)、厕蝇属种(Fannia spp.)、红头丽蝇(Calliphora erythrocephala)、绿蝇属种(Lucilia spp.)、金蝇属种(Chrysomyia spp.)、黄蝇属种(Cuterebra spp.)、胃蝇属种(Gastrophilus spp.)、Hyppobosca spp.、螫蝇属种(Stomoxysspp.)、狂蝇属种(Oestrus spp.)、皮蝇属种(Hypoderma spp.)、虻属种(Tabanus spp.)、Tannia spp.、花园毛蚊(Bibio hortulanus)、瑞典麦秆蝇(Oscinella frit)、草种蝇属种(Phorbia spp.)、藜泉蝇(Pegomyia hyoscyami)、地中海蜡实蝇(Ceratitis capitata)、橄榄大实蝇(Dacus oleae)、欧洲大蚊(Tipula paludosa)、黑蝇属种(Hylemyia spp.)、斑潜蝇属种(Liriomyza spp.)。
蚤目(Siphonaptera)，例如，印鼠客蚤(Xenopsylla cheopis)、角叶蚤属种(Ceratophyllus spp.)。
蛛形纲(Arachnida)，例如，中东金蝎(Scorpio maurus)、黑寡妇蜘蛛(Latrodectus mactans)、粗脚粉螨(Acarus siro)、锐缘蜱属种(Argas spp.)、钝缘蜱属种(Ornithodoros spp.)、鸡皮刺螨(Dermanyssus gallinae)、下心瘿螨(Eriophyes ribis)、桔芸锈螨(Phyllocoptruta oleivora)、牛蜱属种(Boophilus spp.)、扇头蜱属种(Rhipicephalus spp.)、花蜱属种(Amblyomma spp.)、璃眼蜱属种(Hyalomma spp.)、硬蜱属种(Ixodes spp.)、痒螨属种(Psoroptes spp.)、皮螨属(Chorioptes spp.)、疥螨属种(Sarcoptesspp.)、跗线螨属种(Tarsonemus spp.)、苜蓿苔螨(Bryobia praetiosa)、全爪螨属种(Panonychus spp.)、叶螨属种(Tetranychus spp.)、半跗线螨属种(Hemitarsonemus spp.)、短须螨属种(Brevipalpus spp.)。
植物寄生线虫类包括例如短体线虫属种(Pratylenchus spp.)、相似穿孔线虫(Radopholus similis)、起绒草茎线虫(Ditylenchusdipsaci)、半穿刺线虫(Tylenchulus semipenetrans)、异皮线虫属种(Heterodera spp.)、球异皮线虫属种(Globodera spp.)、根结线虫属种(Meloidogyne spp.)、滑刃线虫属种(Aphelenchoides spp.)、长针线虫属种(Longidorus spp.)、剑线虫属种(Xiphinema spp.)、毛刺线虫属种(Trichodorus spp.)、伞滑刃线虫属种(Bursaphelenchusspp.)。
本发明的活性化合物结合物可转化为常规制剂，例如溶液剂、乳剂、可湿性粉剂、悬浮剂、粉剂、粉末剂、膏剂、可溶性粉剂、颗粒剂、悬乳浓缩剂、经活性化合物浸渍的天然材料和合成材料，以及聚合物中的微胶囊剂。
这些制剂以已知的方式制成，例如将活性化合物与填充剂混合，即，与液体溶剂和/或固体载体混合，同时任选地使用表面活性剂，即乳化剂和/或分散剂和/或发泡剂。
如果使用水作为填充剂，还可使用例如有机溶剂作为助溶剂。基本适合的液体溶剂有：芳香族化合物，例如二甲苯、甲苯或烷基萘；氯代芳香族化合物和氯代脂族烃，例如氯苯、氯乙烯或二氯甲烷；脂族烃，例如环己烷或石蜡，例如矿物油馏分、矿物油和植物油；醇，例如丁醇或乙二醇，及它们的醚和酯；酮，例如丙酮、甲乙酮、甲基异丁基酮或环己酮；强极性溶剂如二甲基甲酰胺和二甲基亚砜；以及水。
适合的固体载体有：
例如，铵盐和磨碎的天然矿物，如高岭土、粘土、滑石、白垩、石英、凹凸棒石、蒙脱石或硅藻土，以及磨碎的合成矿物，如高度分散的二氧化硅、氧化铝和硅酸盐；适用于颗粒剂的固体载体为：例如粉碎并分级的天然岩石，如方解石、大理石、浮石、海泡石和白云石，及合成的无机及有机粉的颗粒，以及有机物质如锯屑、椰壳、玉米穗轴和烟草茎的颗粒；适合的乳化剂和/或发泡剂为：例如非离子和阴离子乳化剂，如聚氧乙烯脂肪酸酯、聚氧乙烯脂肪醇醚例如烷基芳基聚乙二醇醚、烷基磺酸盐、烷基硫酸盐、芳基磺酸盐及蛋白质水解产物；适合的分散剂为：例如亚硫酸盐废液和甲基纤维素。
制剂中可使用增粘剂，例如羧甲基纤维素；以及粉末、颗粒或胶乳形式的天然及合成聚合物，例如阿拉伯树胶、聚乙烯醇及聚乙酸乙烯酯；以及天然磷脂，例如脑磷脂和卵磷脂，以及合成磷脂。其它可能的添加剂为矿物油和植物油。
可使用着色剂，例如无机颜料，如氧化铁、氧化钛和普鲁士蓝，及有机着色剂，如茜素着色剂、偶氮着色剂和金属酞菁着色剂，以及微量营养物，如铁盐、锰盐、硼盐、铜盐、钴盐、钼盐和锌盐。
制剂通常包括0.1到95重量％的活性化合物，优选0.5至90％。
本发明的活性化合物结合物可在市售制剂及由所述制剂制备的使用形式中作为与其它活性化合物的混合物存在，所述其它活性化合物例如杀昆虫剂、引诱剂、消毒剂、杀细菌剂、杀螨剂、杀线虫剂、杀真菌剂、生长调节物质或除草剂。所述杀昆虫剂包括，例如磷酸酯类、氨基甲酸酯类、羧酸酯类、氯代烃类、苯基脲类、由微生物产生的物质等。
还可与其它已知活性化合物例如除草剂或肥料以及生长调节剂混合。
当用作杀昆虫剂时，本发明的活性化合物结合物还可在市售制剂及由所述制剂制备的使用形式中作为与增效剂的混合物存在。增效剂为可提高活性化合物作用的化合物，而所加入的增效剂本身不一定具有活性。
由市售制剂制备的使用形式的活性化合物含量可在较宽的范围内变化。使用形式的活性化合物浓度可为0.0000001至95重量％的活性化合物，优选0.0001至1重量％。
这些化合物以适合于使用形式的常规方式使用。
上述活性化合物结合物可以其原有形式、以浓液或普通的常规制剂形式使用，所述常规制剂例如粉剂、颗粒剂、溶液剂、悬浮剂、乳剂或膏剂。
上述制剂可通过本身已知的方式制备，例如将活性化合物与至少一种溶剂或稀释剂、乳化剂、分散剂和/或粘合剂或固定剂、防水剂，如果需要与干燥剂和UV稳定剂，以及如果需要与着色剂和颜料和其他加工助剂混合。
所有的植物及植物部位均可依据本发明予以处理。本发明中植物的含义应理解为所有的植物及植物种群，例如需要的及不需要的野生植物或作物植物(包括天然存在的作物植物)。作物植物可为可通过常规育种和优选法或通过生物技术和遗传工程方法或通过前述方法的结合而获得的植物，包括转基因植物，也包括受植物种苗权保护或不受其保护的植物栽培种。植物部位的含义应理解为植物所有的地上及地下部位及植物器官，例如枝条、叶、花和根，可提及的实例为叶、针叶、茎、干、花、子实体、果实和种子，以及根、块茎和根茎。植物部位还包括采收植物以及无性与有性繁殖物，例如插枝、块茎、根茎、幼枝和种子。
根据本发明的使用活性化合物对植物和植物部位进行的处理，根据常规处理方法直接进行或者通过使化合物作用于其所处环境、生境或储存空间来实现，所述常规处理方法例如浸液、喷雾、蒸发、弥雾、撒播、涂抹，并且对于繁殖材料尤其是种子，还可包衣一层或多层。
如上所述，可依据本发明处理所有的植物和其部位。在一个优选实施方案中，处理了野生的植物种和植物栽培种、或由常规生物育种方法例如杂交或原生质体融合获得的植物种和植物栽培种、以及所述植物种和植物栽培种的部位。在另一优选实施方案中，处理了由遗传工程方法、如果合适还可与常规方法相结合而获得的转基因植物和植物栽培种(遗传修饰生物)及其部位。术语“部位”或“植物的部位”或“植物部位”解释如上。
特别优选依据本发明对各自为市售或正在使用的植物栽培种的植物进行处理。
依据植物种或植物栽培种、其种植地点和生长条件(土壤、气候、植物生长期、营养(diet))，本发明的处理也可产生超加和性(superadditive)(“协同的”)效应。由此可获得例如如下超过实际预期的效果，可降低根据本发明使用的物质和组合物的施用率和/或拓宽其活性谱和/或提高其活性、改善植物生长状况、提高高温或低温耐受性、提高对干旱或者对水中或土壤中含盐量的耐受性、提高开花品质、使采收更简易、加速成熟、提高采收产率、提高采收产品的质量和/或提高其营养价值、改善采收产品的贮存稳定性和/或其加工性能。
优选的依据本发明处理的转基因植物或植物栽培种(即，通过遗传工程方法所获得的那些)包括通过遗传修饰而接受了遗传物质的所有植物，所述遗传物质将特别有利的、有用的特征赋予这些植物。这些特征的实例有改善植物生长状况、提高高温或低温耐受性、提高对干旱或者对水中或土壤中含盐量的耐受性、提高开花品质、使采收更简易、加速成熟、提高采收产率、提高采收产物的品质和/或提高其营养价值、改善采收产物的贮存稳定性和/或其加工性能。需特别强调的所述特征的其它实例有改善植物对动物类害虫和微生物有害物的抵抗力，例如对昆虫、螨虫、植物致病真菌、细菌和/或病毒的抵抗力，以及提高植物对某些除草活性化合物的耐受性。可提出的转基因植物的实例为重要的作物植物，例如谷物(小麦、稻)、玉米、大豆、马铃薯、棉花、油菜和果实植物(果实为苹果、梨、柑橘类果实和葡萄)，特别强调的是玉米、大豆、马铃薯、棉花和油菜。强调的特征具体为通过在植物体内形成毒素，特别是由苏云金杆菌(BacillusThuringiensis)的遗传物质(例如由基因Cry I A(a)、Cry I A(b)、Cry I A(c)、Cry II A、Cry III A、Cry III B2、Cry9c、Cry2Ab、Cry3Bb和Cry I F及其结合)在植物体内形成的毒素，来提高植物对昆虫的抵抗力(以下简称为“Bt植物”)。尤其强调的其它特征为提高植物对某些除草活性化合物例如咪唑啉酮类、磺酰脲类、草甘膦(glyphosate)或膦基麦黄酮(phosphinotricin)(例如“PAT”基因)的耐受性。所述赋予所想要特征的基因也可彼此在转基因植物体内相互结合存在。可提出的“Bt植物”的实例为市售的商标名称为YIELD (例如玉米、棉花、大豆)、
(例如玉米)、
(例如玉米)、
(棉花)、(棉花)和
(马铃薯)的玉米品种、棉花品种、大豆品种和马铃薯品种。可提出的具有除草剂耐受性的植物的实例为市售的商标名称为Roundup 
(具有草甘膦耐受性，例如玉米、棉花、大豆)、Liberty 
(具有膦基麦黄酮耐受性，例如油菜)、
(具有咪唑啉酮耐受性)和
(具有磺酰脲耐受性，例如玉米)的玉米品种、棉花品种和大豆品种。还可提出的抗除草剂的植物(以常规的除草剂耐受性方式育种的植物)包括名为的市售品种(例如玉米)。当然，以上叙述也适用于具有所述或待开发的遗传特征的植物栽培种，所述植物栽培种将在未来进行开发和/或上市。
依据本发明，所列植物可以一种特别有利的方式用本发明的活性化合物/有利物种结合物进行处理。结合物的上述优选范围也适用于这些植物的处理。特别强调的为用本发明明确提及的活性化合物/有利物种结合物对植物进行处理。
从以下实施例可看出本发明活性化合物/有利物种结合物的良好的杀昆虫和杀螨虫作用。虽然单个活性化合物的作用较弱，但活性化合物/有利物种结合物显示出超过了单一活性化合物作用的作用。
用途实施例
实施例A
在4组平行实验中，分别对五株约10年的“Braeburn”栽培种苹果树(冠高约为2.5m)进行处理，以防治红蜘蛛苹果全爪螨(Panonychusulmi)(PANOUL)。此处，活性化合物(I-b-1)(240SC)和市售的标准乙螨唑(etoxazole)(110SC)以所述施用率在捕食性螨Amblyseius andersoni(AMBLAN)的存在下使用背负式压力驱动喷雾器施用。水的施用率为400l/ha。两次施用之间的间隔为42天。
在第一次处理之前4天和之后的6、29、43和63天进行评估，对成年叶螨和捕食性螨在25片叶上的数量进行计数，并确定被捕食者/捕食者的比例，作为对有利物种辅助作用的量度。
两种活性化合物的结合物的灭杀率的计算公式
对于一种给定的两种活性化合物的结合物，其预期活性可如下计算(参见Colby，S.R.；“Calculating Synergistic and AntagonisticResponses of Herbicide Combinations”，Weeds 15，pages 20-22，1967)：
如果
X 是当活性化合物A以m ppm或g/ha的施用率使用时以未处理对照组的百分数表示的灭杀率，
Y 是当活性化合物B以n ppm或g/ha的施用率使用时以未处理对照组的百分数表示的灭杀率，并且
E 是当活性化合物A和B以m和n ppm或g/ha的施用率使用时以未处理对照组的百分数表示的灭杀率，
则
若实际的昆虫灭杀率高于计算值，则结合物的灭杀率具有超加和性，即存在协同效应。在这种情况下，实测的灭杀率必定高于用上式计算得到的预期灭杀率(E)值。
实施例B
苹果全爪螨测试
溶剂：7重量份的二甲基甲酰胺
乳化剂：2重量份的烷基芳基聚乙二醇醚
为了制备合适的活性化合物制剂，将1重量份的活性化合物与上述量的溶剂和乳化剂混合，并且用含有乳化剂的水将浓液稀释至所需浓度。
通过将被果树叶螨(苹果全爪螨)侵染的欧洲李插条(Prunusdomestica)的叶的上面用所需浓度的活性化合物制剂喷雾对其处理。
经过所需时间后，加入确定量的捕食性螨梨盲走螨(Typhlodromuspyri)。
经过所需时间后，确定以百分比计的灭杀率。100％表示全部叶螨被杀死；0％表示没有叶螨被杀死。将测得的灭杀率代入Colby公式。
在该测试中，例如，本申请的以下活性化合物/捕食性螨结合物，与单独施用的组分相比，表现出协同增效的活性：
表B
＊实测值＝检测到的活性
＊＊计算值＝使用Colby公式计算得到的活性。
实施例C
临界浓度测试/土壤昆虫-处理转基因植物
测试昆虫：土壤中的Diabrotica balteata幼虫
溶剂：7重量份的丙酮
乳化剂：1重量份的烷基芳基聚乙二醇醚
为产生合适的活性化合物制剂，将1重量份的活性化合物与所述量的溶剂混合，加入所述量的乳化剂，并用水将浓液稀释至所需浓度。
将活性化合物制剂倾倒在土壤上。在此，制剂中活性化合物的浓度实质上并不重要；仅每单位体积土壤中活性化合物以重量计的量(表示为ppm(mg/l))才至关重要。将土壤装入0.25L的盆中，并将其保留在20℃。
在制备后，立即将5粒已催芽的YIELD GUARD(Monsanto Comp.，USA的商标)栽培种的玉米放入各盆中。两天之后，将合适的测试昆虫放入被处理过的土壤中。再过七天之后，通过对已出芽的玉米植株进行计数来确定活性化合物的效力(1株植物＝20％活性)。
实施例D
烟芽夜蛾测试—处理转基因植物
溶剂：7重量份的丙酮
乳化剂：1重量份的烷基芳基聚乙二醇醚
为制备合适的活性化合物制剂，将1重量份的活性化合物与所述量的溶剂和所述量的乳化剂混合，并用水将浓液稀释至所需浓度。
通过将Roundup Ready(Monsanto Comp.，USA的商标)栽培种的大豆苗(Glycine max)浸泡到所需浓度的活性化合物制剂中来对其进行处理，并在叶依然潮湿时接种烟芽夜蛾(Heliothisvirescens)。
所需时间之后，确定对昆虫的灭杀情况。
Claims (9)
1.活性化合物/有利物种结合物，包括式(I)化合物
其中，
X 代表C1-C6烷基、卤素、C1-C6烷氧基或C1-C3卤代烷基，
Y 代表氢、C1-C6烷基、卤素、C1-C6烷氧基或C1-C3卤代烷基，
Z 代表C1-C6烷基、卤素或C1-C6烷氧基，
n 代表数字0-3，
A 代表氢或各自任选地被卤素取代的直链或带支链的C1-C12烷基、C3-C8烯基、C3-C8炔基、C1-C10烷氧基-C2-C8烷基、C1-C8聚烷氧基-C2-C8烷基、C1-C10烷硫基-C2-C8烷基或者可被氧和/或硫间隔的具有3-8个环原子的环烷基，以及各自任选被卤素、C1-C6烷基，C1-C6卤代烷基，C1-C6烷氧基，C1-C6卤代烷氧基或硝基取代的苯基或苯基-C1-C6烷基，
B 代表氢、C1-C6烷基或C1-C6烷氧基-C2-C4烷基，
或者其中
A和B与它们所连接的碳原子一起形成一个饱和的或不饱和的3至8元环，所述环任选地被氧和/或硫间隔，并任选地被卤素、C1-C6烷基、C1-C6烷氧基、C1-C4卤代烷基、C1-C4卤代烷氧基、C1-C4烷硫基或任选被取代的苯基取代或任选地与苯稠合，
G 代表氢(a)或代表以下基团，
—CO—R1 
(c)—SO2R3 (d)
其中
R1 代表各自任选被卤素取代的C1-C20烷基、C2-C20烯基、C1-C8烷氧基-C2-C8烷基、C1-C8烷硫基-C2-C8烷基、C1-C8聚烷氧基-C2-C8烷基或可被氧和/或硫原子间隔的具有3-8个环原子的环烷基，
代表任选被卤素、硝基，C1-C6烷基、C1-C6烷氧基、C1-C6卤代烷基或C1-C6卤代烷氧基取代的苯基，
代表任选被卤素、C1-C6烷基、C1-C6烷氧基、C1-C6卤代烷基或C1-C6卤代烷氧基取代的苯基-C1-C6烷基，
代表各自任选被卤素和/或C1-C6烷基取代的吡啶基、嘧啶基、噻唑基或吡唑基，
代表任选被卤素和/或C1-C6烷基取代的苯氧基-C1-C6烷基，
R2 代表各自任选被卤素取代的C1-C20烷基、C2-C20烯基、C1-C8烷氧基-C2-C8烷基或C1-C8聚烷氧基-C2-C8烷基，
代表各自任选被卤素、硝基、C1-C6烷基、C1-C6烷氧基或C1-C6卤代烷基取代的苯基或苯甲基，
R3 代表任选被卤素取代的C1-C8烷基，代表各自任选被C1-C4烷基、卤素、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、硝基或氰基取代的苯基或苯甲基，
R4和R5彼此独立地代表各自任选被卤素取代的C1-C8烷基、C1-C8烷氧基、C1-C8烷基氨基、二(C1-C8)烷基氨基、C1-C8烷硫基、C2-C5烯硫基、C2-C5炔硫基或C3-C7环烷基硫基，代表各自任选地被卤素、硝基、氰基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷硫基、C1-C4卤代烷硫基、C1-C4烷基或C1-C4卤代烷基取代的苯基、苯氧基或苯硫基，
R6和R7彼此独立地代表各自任选被卤素取代的C1-C10烷基、C1-C10烷氧基、C3-C8烯基或C1-C8烷氧基-C1-C8烷基，代表任选被卤素、C1-C6卤代烷基、C1-C6烷基或C1-C6烷氧基取代的苯基，代表任选被卤素、C1-C6烷基、C1-C6卤代烷基或C1-C6烷氧基取代的苯甲基，或者两者一起代表一个任选被C1-C6烷基取代的且任选被氧或硫间隔的5至6元环，
以及来源于以下目或亚目的有利物种：蜘蛛目、蜱螨亚纲、膜翅目、鞘翅目、脉翅目、缨翅目、异翅目、双翅目、半翅目、革翅目和/或寄螨目。
2.权利要求1的活性化合物/有利物种结合物，其中所述式(I)化合物的基团如下定义：
X 代表C1-C4烷基、卤素、C1-C4烷氧基或C1-C2卤代烷基，
Y 代表氢、C1-C4烷基、卤素、C1-C4烷氧基或C1-C2卤代烷基，
Z 代表C1-C4烷基、卤素或C1-C4烷氧基，
n 代表0或1，
A和B与它们所连接的碳原子一起代表一个任选被C1-C4烷基或C1-C4烷氧基取代的饱和的5至6元环，
G 代表氢(a)或代表下述基团，
—CO—R1 (b) 
其中
R1 代表各自任选被卤素取代的C1-C16烷基、C2-C16烯基、C1-C6烷氧基-C2-C6烷基或可被1至2个氧和/或硫原子间隔的具有3-7个环原子的环烷基，
代表任选被卤素、硝基、C1-C4烷基、C1-C4烷氧基、C1-C3卤代烷基或C1-C3卤代烷氧基取代的苯基，
R2 代表各自任选被卤素取代的C1-C16烷基、C2-C16烯基或C1-C6烷氧基-C2-C6烷基，
代表各自任选被卤素、硝基、C1-C4烷基、C1-C4烷氧基或C1-C4卤代烷基取代的苯基或苯甲基。
3.权利要求1的活性化合物/有利物种结合物，包括式(I-b-1)化合物
4.权利要求1中定义的活性化合物/有利物种结合物用于防治动物类害虫的用途。
5.防治动物类害虫的方法，其特征在于使权利要求1中定义的活性化合物/有利物种结合物作用于动物类害虫和/或其生境。
6.制备杀昆虫和/或杀螨虫组合物的方法，其特征在于将权利要求1中定义的活性化合物/有利物种结合物与填充剂和/或表面活性剂混合。
7.通过使用权利要求1的活性化合物/有利物种结合物来减少喷雾施用率(每季施用的数量)的方法。
8.通过使用权利要求1的活性化合物/有利物种结合物来减少采收物上和环境中总的杀昆虫剂和/或杀螨虫剂的残留的方法。
9.组合物，包括一种用于防治动物类害虫的权利要求1的活性化合物/有利物种结合物。
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| EP (1) | EP2034843A1 (zh) |
| JP (1) | JP2009539900A (zh) |
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| CN (1) | CN101466267A (zh) |
| DE (1) | DE102006027730A1 (zh) |
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-
2006
- 2006-06-16 DE DE102006027730A patent/DE102006027730A1/de not_active Withdrawn
-
2007
- 2007-06-05 WO PCT/EP2007/004971 patent/WO2007144089A1/de active Application Filing
- 2007-06-05 CN CNA2007800221765A patent/CN101466267A/zh active Pending
- 2007-06-05 KR KR1020097000779A patent/KR20090020699A/ko not_active Application Discontinuation
- 2007-06-05 JP JP2009514670A patent/JP2009539900A/ja not_active Withdrawn
- 2007-06-05 MX MX2008015840A patent/MX2008015840A/es not_active Application Discontinuation
- 2007-06-05 EP EP07725839A patent/EP2034843A1/de not_active Withdrawn
- 2007-06-05 US US12/304,958 patent/US20100056620A1/en not_active Abandoned
- 2007-06-15 TW TW096121633A patent/TW200814931A/zh unknown
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2024146571A1 (zh) * | 2023-01-03 | 2024-07-11 | 浙江同源康医药股份有限公司 | 用于预防和/或治疗神经退行性疾病的化合物 |
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| Publication number | Publication date |
|---|---|
| DE102006027730A1 (de) | 2007-12-20 |
| US20100056620A1 (en) | 2010-03-04 |
| WO2007144089A1 (de) | 2007-12-21 |
| KR20090020699A (ko) | 2009-02-26 |
| MX2008015840A (es) | 2009-01-09 |
| JP2009539900A (ja) | 2009-11-19 |
| TW200814931A (en) | 2008-04-01 |
| EP2034843A1 (de) | 2009-03-18 |
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Application publication date: 20090624 |