WO2010139408A2 - Flubendiamide-nützlings-kombinationen - Google Patents
Flubendiamide-nützlings-kombinationen Download PDFInfo
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- WO2010139408A2 WO2010139408A2 PCT/EP2010/003147 EP2010003147W WO2010139408A2 WO 2010139408 A2 WO2010139408 A2 WO 2010139408A2 EP 2010003147 W EP2010003147 W EP 2010003147W WO 2010139408 A2 WO2010139408 A2 WO 2010139408A2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/10—Animals; Substances produced thereby or obtained therefrom
- A01N63/14—Insects
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/20—Bacteria; Substances produced thereby or obtained therefrom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/40—Viruses, e.g. bacteriophages
Definitions
- the present invention relates to flubendiamide-beneficial combinations comprising 3-iodo-N '- (2-mesyl-1, 1-dimethyl-ethyl) -N- ⁇ 4- [1,2,2,2-tetrafluoro-1 - (Trifluoromethyl) ethyl] o-tolyl ⁇ phthalamides, known as flubendiamides, and at least one type of use for the effective and environmentally friendly control of animal pests such as insects and / or unwanted acarids.
- EP-A-1 380 209 and WO 2004/034786 describe the increase in activity of combinations comprising flubendiamides and further insecticides. Furthermore, the insecticidal and acaricidal activity enhancement for flubendiamides by means of addition of ammonium or phosphonium salts is described (WO 2007/068357).
- pest control uses are well known (e.g., from "Knowing and Recognizing", M. H. Malais, WJ, Ravensberg, published by Koppert B.V., Reed Business Information (2003)).
- Benefits are usually referred to as arachnids or insects that are useful to humans in some way, mainly because they need other insects, which in turn are called pests, as food or as hosts.
- the term “beneficials” is not limited to arachnids and insects. In the present case, it also includes fungi or bacterial or viral strains suitable for pest control.
- Beneficial insects are particularly suitable for pest control in greenhouses.
- the use of uses has the advantage that no resistance forms, that there are no waiting times for cultural and nursing measures as well as harvesting.
- the use of the beneficial organisms does not put any strain on users with pesticides.
- beneficial insects are usually used only when pest infestation (curative). Because beneficial insects are the natural enemies of the pests to be controlled, their spectrum of activity is often limited to the specific pest and sometimes even only to specific stages of development of these pests. Since, however, within a culture, several pests with different control requirements, such as time of use, Nauerlingsart and Nauerlingsrius can occur, the culture must be monitored regularly and requires infestation fast reaction. The user also needs intensive knowledge of the culture, pests and beneficials.
- the useful organisms which can be used in the combination according to the invention are microorganisms such as fungi (eg Metarhizium anisopliae or Beauveria bassiana) or bacterial or viral strains (eg Bacillus strains or baculoviruses such as granulosis viruses) as well as insects and arachnids from the orders or suborders of Araneae, Acari, Dermaptera , Hymenoptera, Coleoptera, Neuroptera, Thysanoptera, Heteroptera, Diptera, Hemiptera, Dermaptera and / or Parasitiformes, Plannipennia, more preferably from the families of Vespidae, Aphelinidae, Trichogrammatidae, Encyrtidae, Mymaridae, Eulophidae, Alloxystidae, Megaspilidae, Braconidae, Cantharidae, Cocci
- Hymenoptera from the orders Trichogramma spp., Aphidius spp. (Parasitic wasps) such as Aphidius colemani, A. aphidius ervi., Lariophagus spp. (Lagerzwespe) such as Lariophagus distinguendus, Lysiphlebus spp. such as Lysiphlebus testaceipes, Encarsia spp. (Parasitic wasp) such as Encarsia formosa, Dacnusa spp. such as Dacnusa sibirica, Aphelinus spp. such as Aphelinus abdominalis, Diglyphus spp.
- Leptomastix spp. such as, for example, Leptomastix abnormis, Dabnusa spp. such as Dabnusa sibirica, Trichogramma spp. (Parasitic wasp) such as Trichogramma brassicae, Trichogramma dendrolimi and Trichogramma evanescens. Campbird Lariophagus distinguendus;
- Bacillus thuringiensis Bacillus firmus, Bacillus subtilis, baculoviruses, Beauveria brongniartii and Beauveria bassiana, Metarhizium anisopliae, Metarhizium acridum and Thanasimus formicarius.
- Flubendiamide beneficial combinations containing flubendiamides and at least one type of use selected from the uses mentioned in Table 1 are preferred.
- Flubendiamide beneficial combinations for the purposes of the present invention are also those combinations in which the use of Flubendiamide on the one hand and the beneficial agent on the other hand takes place temporally and / or spatially separated.
- flubendiamide can be used in the soil or in a bottomless substrate and for use on the plant - or vice versa.
- Flubendiamide useful combinations according to the invention are also present if the use is already present on the plant before the treatment and by the treatment with Flubendiamide the balance between pest and use is shifted in favor of N ⁇ tzlings.
- the invention also relates to the use of flubendiamides in combination with uses, preferably with a use selected from one of the groups (1) to (7), for controlling animal pests.
- Flubendiamide is preferably used in combination with the uses mentioned in Table 1 for controlling the animal pests mentioned in the same line
- the flubendiamide beneficials combination can be used in annual or perennial crops.
- One-year crops are, for example: vegetables such as fruit vegetables and inflorescences (eg peppers, hot peppers, tomatoes, aubergines, cucumbers, pumpkins, zucchini, field beans, Runner beans, bush beans, peas, artichokes), leafy vegetables (eg lettuce, chicory, endives, kraken, ravens, lamb's lettuce, iceberg lettuce, leeks, spinach, chard), tubers, root and stem vegetables (eg celery, beetroot, carrots, radishes , Horseradish, salsify, asparagus, turnips, palm sprouts, bamboo shoots, as well as onions, for example onions, leeks, fennel, garlic), cabbage (eg cauliflower, broccoli, kohlrabi, red cabbage, cabbage, kale, savoy cabbage, Brussels sprouts, Chinese cabbage), ornamental plants, such as cut flowers (eg roses, carnations, gerberas, lilies, daisies, chrysanthemums, tulips,
- Perennial crops include citrus (eg orange, grapefruit, mandarin, lemon, lime, bitter orange, kumquat, satsumas), pome fruit (eg apples, pears and quince), stone fruit (eg peaches, nectarines, cherries, plums, plums, apricots), Wine, hops, olives, tea and tropical crops such as mangoes, papayas, figs, pineapples, dates, bananas, durians, kakis, coconuts, cocoa, coffee, avocados, lychees, passion fruits, guavas, almonds and nuts hazelnuts, walnuts, pistachios, cashew nuts, Brazil nuts, pecans, butternuts, chestnuts, hickory nuts, macadamia nuts, peanuts, berries (eg currants, gooseberries, raspberries, blackberries, blueberries, strawberries, cranberries, kiwis, cranberries), ornamentals such as cut flowers ( eg roses
- Roses Tagetes, Pansies, Geraniums, Fuchsias, Hibiscus, Chrysanthemums, Hardy Lichens, Cyclamen, African Violets, Sunflowers, Begonias), Shrubs and Conifers (eg Ficus, Rhododendron, Spruce, Fir, Pine, Yew, Juniper, Pine, Oleander), Spices (eg anise, chilli, paprika, pepper, vanilla, marjoram, thyme, cloves, juniper berries, cinnamon, tarragon, koryander, saffron, ginger).
- Shrubs and Conifers eg Ficus, Rhododendron, Spruce, Fir, Pine, Yew, Juniper, Pine, Oleander
- Spices eg anise, chilli, paprika, pepper, vanilla, marjoram, thyme, cloves, juniper berries, cinnamon, tarragon, koryander,
- the invention relates to the preventive or curative use of flubendiamides in combination with uses in the cultivation of annual or perennial crops, preferably of greenhouse crops.
- Flubendiamide is preferably used in combination with the uses mentioned in Table 2 in the cultivation of the cultures mentioned in the same line.
- the application rate of flubendiamide can be varied within a relatively wide range, depending on the mode of administration. It is in the treatment of parts of plants, e.g. Leaves from 0.1 to 1000 g / ha, preferably from 1 to 500 g / ha, particularly preferably from 10 to 300 g / ha.
- the application rate is from 0.01 to 50 mg / plant, preferably from 0.1 to 10 mg / plant, more preferably from 0.5 to 5 mg / plant.
- the flubendiamide-beneficial insect combination according to the invention is used to protect plants against attack by animal pests within a certain period of time after the treatment.
- the Flubendiamide-beneficials combination according to the invention is used to liberate plants from infestation by the animal pests.
- Flubendiamide is applied by treatment of the culture substrate.
- the Flubendiamide- Nönlingskombination invention is particularly easy and effective to use and Flubendiamide can be used in a lower dose.
- the culture substrate By application of the culture substrate is meant contacting flubendiamides with bottomless substrate. This can be done in particular by spraying, casting, side-dressing, shower-drenching, overhead-drenching or by drip irrigation, i. Application done in the context of an irrigation system.
- the addition of the active ingredient into the water phase enclosing the plant roots can be carried out, for example, in the floating, boxing or paddy field method.
- Bottomless substrates are understood to mean, in particular, those substrates which are not grown naturally or are produced artificially from inorganic minerals and organic humus.
- Bottomless substrates are, for example, special substrates based on peat moss, coconut fibers, rock wool (eg Grodan®), pumice, expanded clay (eg Lecaton® or Lecadan®), clay granules (eg Seramis®), foams (eg Baystrat®), vermiculite, perlite, artificial Soils (eg Hygromull®), or combinations thereof.
- Preferred substrates are perlite and rock wool.
- the flubendiamide beneficial insecticidal combinations according to the invention are suitable for the protection of plants and plant organs with good plant tolerance and in particular good environmental compatibility. This can increase crop yields and improve the quality of the crop.
- the combination is preferably used in crop protection. Especially in agriculture, horticulture, forests, gardens and recreational facilities. Likewise, the combination can be used in stock and material protection. The combination is effective against normally sensitive and resistant species as well as against all or individual stages of development.
- Heliopeltis spp. Horcias nobilellus, Leptocorisa spp., Leptoglossus phyllopus, Lygus spp., Macropes excavatus, Miridae, Monalonion atratum, Nezara spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., Psallus spp., Pseudacysta persea, Rhodnius spp., Sahlbergella singularis, Scaptocoris castanea, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp.
- Aonidiella spp. Aphanostigma piri, Aphis spp., Arboridia apicalis, Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacorthum solani, Bemisia spp., Brachycaudus helichrysii, Brachycolus spp., Brevicoryne brassicae, Calligypona marginata, Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii, Chromaphis juglandicola, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., Cryptomyzus ribis, Dalbulus
- Orthoptera e.g. Acheta domesticus, Blatta orientalis, Blattella germanica, Gryllotalpa spp., Leucophaea maderae, Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria.
- Flubendiamide can be converted into the usual formulations, such as solutions, emulsions, wettable powders, water- and oil-based suspensions, powders, dusts, pastes, soluble powders, soluble granules, scattering granules, suspension-emulsion concentrates, flubendiamide-impregnated natural products, flubendiamide-impregnated synthetic substances, fertilizers and microencapsulation in polymeric substances.
- solutions such as solutions, emulsions, wettable powders, water- and oil-based suspensions, powders, dusts, pastes, soluble powders, soluble granules, scattering granules, suspension-emulsion concentrates, flubendiamide-impregnated natural products, flubendiamide-impregnated synthetic substances, fertilizers and microencapsulation in polymeric substances.
- formulations are prepared in a known manner, e.g. by mixing the active compounds with extenders, ie liquid solvents and / or solid carriers, if appropriate using surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents.
- extenders ie liquid solvents and / or solid carriers
- surface-active agents ie emulsifiers and / or dispersants and / or foam-forming agents.
- Excipients which can be used are those which are suitable for imparting special properties to the composition itself and / or preparations derived therefrom (for example spray liquor, seed dressing), such as certain technical properties and / or specific biological properties.
- Typical auxiliaries are: extenders, solvents and carriers.
- polar and non-polar organic chemical liquids e.g. from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins,
- Alkylbenzenes alkylnaphthalenes, chlorobenzenes
- alcohols and polyols which may also be substituted, etherified and / or esterified
- ketones such as acetone, cyclohexanone
- Esters (including fats and oils) and (poly) ethers, of simple and substituted amines, amides,
- Lactams such as N-alkyl pyrrolidones
- lactones such as N-alkyl pyrrolidones
- sulfones such as dimethyl sulfoxide
- organic solvents can also be used as auxiliary solvents.
- liquid solvents are essentially in question: Aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatic hydrocarbons and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols, such as butanol or glycol, and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strong polar solvents such as dimethyl sulfoxide, and water.
- Aromatics such as xylene, toluene, or alkylnaphthalenes
- chlorinated aromatic hydrocarbons and chlorinated aliphatic hydrocarbons such as chlorobenzen
- the carrier means a natural or synthetic, organic or inorganic substance which may be solid or liquid, with which the active ingredients are mixed or combined for better applicability, in particular for application to plants or plant parts or seeds.
- the solid or liquid carrier is generally inert and should be useful in agriculture.
- Suitable solid or liquid carriers are:
- Ammonium salts and ground natural minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as fumed silica, alumina and silicates, as solid carriers for granules are suitable: e.g. crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as paper, sawdust, coconut shells, corn cobs and tobacco stems; suitable emulsifying and / or foaming agents are: e.g.
- nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates;
- suitable dispersants are non-ionic and / or ionic substances, e.g.
- adhesives such as carboxymethylcellulose, natural and synthetic powdery, granular or latex-like polymers, such as rubbers. arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids.
- Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
- inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
- additives may be fragrances, mineral or vegetable optionally modified oils, waxes and nutrients (also trace nutrients), such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
- Stabilizers such as cold stabilizers, preservatives, antioxidants, light stabilizers or other chemical and / or physical stability-improving agents may also be present.
- the active substance content of the application forms prepared from the commercial formulations can vary within wide ranges.
- the total active ingredient concentration or the active ingredient concentration of the individual active substances of the use forms is in the range from 0.000001 to 97% by weight of active compound, preferably in the range from 0.0001 to 80% by weight, particularly preferably in the range from 0.001 to 65% by weight. -% and most preferably in the range of 0.01 to 50 wt .-%.
- flubendiamide-beneficial agent combinations according to the invention can be used in their commercial formulations and in the formulations prepared from these formulations in admixture with other active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth regulators, herbicides, safeners, fertilizers or semiochemicals available.
- active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth regulators, herbicides, safeners, fertilizers or semiochemicals available.
- a mixture with other known active ingredients, such as herbicides, fertilizers, growth regulators, safeners, semiochemicals, or with agents for improving the plant properties is possible.
- Flubendiamide can be present in the flubendiamide-beneficial insect combination according to the invention in its commercial formulations as well as in the formulations prepared from these formulations in admixture with synergists.
- Synergists are compounds that increase the effect of the active ingredients without the added synergist itself having to be active.
- the inventive FIubendiamide-beneficial combinations may also be present when used as insecticides in their commercial formulations as well as in the formulations prepared from these formulations in mixtures with inhibitors which degradation of the active ingredient after application in the environment of the plant, on the surface of plant parts or in plant tissues.
- the application is done in a custom forms adapted to the application forms.
- plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
- Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights.
- Preferably one- or perennial crops are treated.
- Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, examples of which include leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, as well as roots, tubers and rhizomes.
- the plant parts also include crops and vegetative and generative propagation material, for example fruits, seeds, cuttings, tubers, rhizomes, offshoots, seeds, bulbs, sinkers and shoots.
- the treatment according to the invention of the plants and plant parts with the flubendiamide beneficial insects combinations takes place directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, evaporating, atomizing, spreading, brushing, inoculating or applying the beneficial insect or injecting.
- wild species or plant species obtained by conventional biological breeding methods such as crossing or protoplast fusion and plant cultivars and parts thereof are treated.
- transgenic plants and plant cultivars which have been obtained by genetic engineering methods such as antisense or cosuppression technology, RNA interference RNAi technology, optionally in combination with conventional methods (Genetically Modified Organisms), and parts thereof treated.
- the terms "parts” or “parts of plants” or “plant parts” have been explained above. It is particularly preferred according to the invention to treat plants of the respective commercially available or in use plant cultivars.
- Plant varieties are understood to be plants with new traits which have been bred either by conventional breeding, by mutagenesis or by recombinant DNA techniques. Crop plants can therefore be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties protectable or non-protectable plant varieties.
- the treatment method according to the invention can thus also for the treatment of genetically modified organisms (GMOs), z.
- GMOs genetically modified organisms
- Genetically modified plants are plants in which a heterologous gene has been stably integrated into the genome.
- heterologous gene essentially refers to a gene that is provided or assembled outside the plant and that when introduced into the nuclear genome, chloroplast genome or mitochondrial genome imparts new or improved agronomic or other properties to the transformed plant Protein or polypeptide expressed or that it is another gene that in the
- RNAi for example by antisense technology, co-suppression technology or RNAi
- a heterologous gene present in the genome is also referred to as a transgene.
- a transgene defined by its specific presence in the plant genome is referred to as a transformation or transgenic event.
- Plants and plant varieties which are preferably treated according to the invention include all plants which have genetic material conferring on these plants particularly advantageous, useful features (whether obtained by breeding and / or biotechnology).
- Plants and plant varieties which can also be treated according to the invention are those plants which are resistant to one or more abiotic stress factors.
- Abiotic stress conditions may include, for example, drought, cold and heat conditions, osmotic stress, waterlogging, increased soil salinity, increased exposure to minerals, ozone conditions, high light conditions, limited availability of nitrogen nutrients, limited availability of phosphorous nutrients, or avoidance of shade.
- Plants and plant varieties which can also be treated according to the invention are those plants which are characterized by increased yield properties.
- An increased yield can in these plants z. B. based on improved plant physiology, improved plant growth and improved plant development, such as water efficiency, water retention efficiency, improved nitrogen utilization, increased carbon assimilation, improved photosynthesis, increased germination and accelerated Abreife.
- Yield can be further influenced by improved plant architecture (under stress and non-stress conditions), including early flowering, control of flowering for hybrid seed production, germination, plant size, internode count and distance, root growth, seed size, Fruit size, pod size, pod or ear number, number of seeds per pod or ear, seed mass, increased seed filling, reduced seed drop, reduced pod popping and stability.
- Other yield-related traits include seed composition such as carbohydrate content, protein content, oil content and composition, nutritional value, reduction in nontoxic compounds, improved processability, and improved shelf life.
- Plants which can be treated according to the invention are hybrid plants which already express the properties of the heterosis or the hybrid effect, which generally leads to higher yield, higher vigor, better health and better resistance to biotic and abiotic stress factors.
- Such plants are typically produced by crossing an inbred male sterile parental line (the female crossbred partner) with another inbred male fertile parent line (the male crossbred partner).
- the hybrid seed is typically harvested from the male sterile plants and sold to propagators.
- Pollen sterile plants can sometimes be produced (eg in maize) by delaving (ie mechanical removal of the male reproductive organs or the male flowers); however, it is more common for male sterility to be due to genetic determinants in the plant genome.
- cytoplasmic male sterility have been described, for example, for Brassica species (WO 1992/005251, WO 1995/009910, WO 1998/27806, WO 2005/002324, WO 2006/021972 and US 6,229,072).
- pollen sterile plants can also be used with methods of vegetable biotechnology, such as genetic engineering.
- a particularly convenient means of producing male-sterile plants is described in WO 89/10396, wherein, for example, a ribonuclease such as a barnase is selectively expressed in the tapetum cells in the stamens. The fertility can then be restorated by expression of a ribonuclease inhibitor such as barstar in the tapetum cells (eg WO 1991/002069).
- Plants or plant varieties obtained by methods of plant biotechnology, such as genetic engineering which can be treated according to the invention are herbicide-tolerant plants, i. H. Plants tolerant to one or more given herbicides. Such plants can be obtained either by genetic transformation or by selection of plants containing a mutation conferring such herbicide tolerance.
- Herbicide-tolerant plants are, for example, glyphosate-tolerant plants, i. H. Plants tolerant to the herbicide glyphosate or its salts.
- glyphosate-tolerant plants can be obtained by transforming the plant with a gene encoding the enzyme 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS).
- EPSPS 5-enolpyruvylshikimate-3-phosphate synthase
- EPSPS 5-enolpyruvylshikimate-3-phosphate synthase
- AroA gene mutant CT7 of the bacterium Salmonella typhimurium (Comai et al., Science (1983), 221, 370-371)
- the CP4 gene of the bacterium Agrobacterium sp. Barry et al., Curr Topics Plant Physiol.
- Glyphosate-tolerant plants can also be obtained by expressing a gene coding for a glyphosate oxidoreductase enzyme as described in US 5,776,760 and US 5,463,175. Glyphosate-tolerant plants can also be obtained by expressing a gene encoding a glyphosate acetyltransferase enzyme as described in e.g. As WO 2002/036782, WO 2003/092360, WO 2005/012515 and WO 2007/024782 is encoded. Glyphosate-tolerant plants can also be obtained by selecting plants containing naturally-occurring mutations of the above-mentioned genes, as described, for example, in WO 2001/024615 or WO 2003/013226.
- herbicide-resistant plants are, for example, plants which have been tolerated to herbicides which inhibit the enzyme glutamine synthase, such as bialaphos, phosphinotricin or glufosinate.
- Such plants can be obtained by having an enzyme which detoxifies the herbicide or a mutant of the enzyme glutamine synthase, which is resistant to inhibition.
- an effective detoxifying enzyme is, for example, an enzyme encoding a phosphinotricin acetyltransferase (such as the bar or pat protein of Streptomyces species).
- Plants expressing an exogenous phosphinotricin acetyltransferase are described, for example, in US 5,561,236; US 5,648,477; US 5,646,024; US 5,273,894; US 5,637,489; US 5,276,268; US 5,739,082; US 5,908,810 and US 7,112,665.
- hydroxyphenylpyruvate dioxygenase HPPD
- HPPD hydroxyphenylpyruvate dioxygenases
- HPPD inhibitors may be treated with a gene encoding a naturally occurring resistant HPPD enzyme or a gene encoding an mimetic HPPD enzyme as described in WO 1996/038567, WO 1999/024585 and WO 1999 / 024586, are transformed.
- Tolerance to HPPD inhibitors can also be achieved by transforming plants with genes encoding certain enzymes that allow the formation of homogentisate despite inhibition of the native HPPD enzyme by the HPPD inhibitor. Such plants and genes are described in WO 1999/034008 and WO 2002/36787.
- the tolerance of plants to HPPD inhibitors can also be improved by transforming plants in addition to a gene coding for an HPPD-tolerant enzyme with a gene coding for a prephenate dehydrogenase enzyme, as described in WO 2004 / 024928 is described.
- ALS inhibitors include sulfonylurea, imidazolinone, triazolopyrimidines, pyrimidinyloxy (thio) benzoates and / or sulfonylaminocarbonyltriazolinone herbicides.
- ALS also known as acetohydroxy acid synthase, AHAS
- AHAS acetohydroxy acid synthase
- plants which are tolerant to imidazolinone and / or sulfonylurea can be obtained by induced mutagenesis, selection in cell cultures in the presence of the herbicide or by mutation breeding, as for example for the soybean in US 5,084,082, for rice in WO 1997/41218, for the sugar beet in US 5,773,702 and WO 1999/057965, for salad in US 5,198,599 or for the sunflower in WO 2001/065922.
- Plants or plant varieties obtained by plant biotechnology methods such as genetic engineering which can also be treated according to the invention are insect-resistant transgenic plants, i. Plants that have been made resistant to attack by certain target insects. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such insect resistance.
- insect-resistant transgenic plant includes any plant containing at least one transgene comprising a coding sequence encoding:
- an insecticidal crystal protein from Bacillus thuringiensis or an insecticidal portion thereof such as the insecticidal crystal proteins described by Crickmore et al., Microbiology and Molecular Biology Reviews (1998), 62, 807-813, by Crickmore et al. (2005) in the Bacillus // zwr / wg / e "s / s toxin nomenclature, online at:
- a crystal protein from Bacillus thuringiensis or a part thereof which is insecticidal in the presence of a second, different crystal protein than Bacillus thuringiensis or a part thereof, such as the binary toxin consisting of the crystal proteins Cy34 and Cy35 (Moellenbeck et al., Nat Biotechnol. (2001), 19, 668-72; Schnepf et al., Applied Environment Microb. (2006), 71, 1765-1774); or
- an insecticidal hybrid protein comprising parts of two different insecticidal crystal proteins from Bacillus thuringiensis, such as a hybrid of the
- Proteins of 1) above or a hybrid of the proteins of 2) above e.g.
- VIP vegetative insecticidal proteins
- a secreted protein from Bacillus thuringiensis or Bacillus cereus which is insecticidal in the presence of a second secreted protein from Bacillus thuringiensis or B. cereus, such as the binary toxin consisting of the proteins VIPlA and VIP2A (WO 1994/21795); or
- a hybrid insecticidal protein comprising parts of various secreted proteins of Bacillus thuringiensis or Bacillus cereus, such as a hybrid of the proteins of 1) or a hybrid of the proteins of 2) above; or
- Coding DNA were induced during cloning or transformation (preserving the coding for an insecticidal protein), such as the protein VIP3Aa in cotton event COT 102.
- insect-resistant transgenic plants in the present context also include any plant comprising a combination of genes encoding the proteins of any of the above classes 1 to 8.
- insect resistant transgenic plants in the present context also include any plant comprising a combination of genes encoding the proteins of any of the above classes 1 to 8.
- an insect resistant transgenic plant in the present context also include any plant comprising a combination of genes encoding the proteins of any of the above classes 1 to 8.
- an insect resistant transgenic plants in the present context also include any plant comprising a combination of genes encoding the proteins of any of the above classes 1 to 8.
- an insect resistant transgenic plants in the present context also include any plant comprising a combination of genes encoding the proteins of any of the above classes 1 to 8.
- Plants or plant varieties obtained by plant biotechnology methods such as genetic engineering), which can also be treated according to the invention, are tolerant to abiotic stress factors. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such stress resistance. Particularly useful plants with stress tolerance include the following:
- Plants which contain a transgene capable of reducing the expression and / or activity of the gene for the poly (ADP-ribose) polymerase (PARP) in the plant cells or plants, as described in WO 2000/004173 or EP 04077984.5 or EP 06009836.5 is described.
- Plants or plant varieties obtained by plant biotechnology methods such as genetic engineering which can also be treated according to the invention have a changed amount, quality and / or storability of the harvested product and / or altered characteristics of certain components of the harvested product, such as:
- Plants or plant varieties obtained by plant biotechnology methods such as genetic engineering
- Plants or plant varieties which can also be treated according to the invention are plants such as cotton plants with altered fiber properties.
- Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such altered fiber properties; these include:
- plants such as cotton plants, which contain an altered form of rsw2 or rsw3 homologous nucleic acids, as described in WO 2004/053219;
- plants such as cotton plants having increased expression of sucrose phosphate synthase as described in WO 2001/017333;
- plants such as cotton plants with an increased expression of sucrose synthase, as described in WO 02/45485;
- plants such as cotton plants with modified reactivity fibers, e.g. By expression of the N-acetylglucosamine transferase gene, including nodC, and chitin synthase genes, as described in WO 2006/136351.
- Plants or plant varieties obtained by plant biotechnology methods such as genetic engineering which can also be treated according to the invention are plants such as oilseed rape or related Brassica plants with altered oil composition properties. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such altered oil properties; these include:
- plants such as rape plants producing oil of high oleic acid content, as described, for example, in US 5,969,169, US 5,840,946 or US 6,323,392 or US 6,063,947;
- plants such as oilseed rape plants which produce low linolenic acid oil, as described in US 6,270,828, US 6,169,190 or US 5,965,755.
- plants such as oilseed rape plants which produce oil with a low saturated fatty acid content, such as e.g. As described in US 5,434,283.
- transgenic plants which can be treated according to the invention are plants with one or more genes coding for one or more toxins, the transgenic plants offered under the following commercial names: YIELD GARD® (for example maize, cotton, Soybeans), KnockOut® (for example corn), BiteGard® (for example maize), BT-Xtra® (for example corn), StarLink® (for example maize), Bollgard® (cotton), Nucotn® (cotton), Nucotn 33B® (cotton), NatureGard® (for example corn), Protecta® and NewLeaf® (potato).
- YIELD GARD® for example maize, cotton, Soybeans
- KnockOut® for example corn
- BiteGard® for example maize
- BT-Xtra® for example corn
- StarLink® for example maize
- Bollgard® cotton
- Nucotn® cotton
- Nucotn 33B® cotton
- NatureGard® for example corn
- Protecta® and NewLeaf® pot
- Herbicide-tolerant crops to be mentioned are, for example, corn, cotton and soybean varieties sold under the following tradenames: Roundup Ready® (glyphosate tolerance, for example corn, cotton, soybean), Liberty Link® (phosphinotricin tolerance, for example rapeseed) , IMI® (imidazolinone tolerance) and SCS® (sylphonylurea tolerance), for example corn.
- Herbicide-resistant plants (plants traditionally grown for herbicide tolerance) to be mentioned include the varieties sold under the name Clearfield® (for example corn).
- transgenic plants that can be treated according to the invention are plants that contain transformation events, or a combination of transformation events, and that are listed, for example, in the files of various national or regional authorities (see, for example, http: // /gmoinfo.jrc.it/gmp_browse.aspx and http://www.agbios.com/dbase.php).
- Flubendiamide-beneficial combinations are also suitable for controlling animal pests in household, hygiene and storage protection, in particular of insects, arachnids and mites, which are used in enclosed spaces, such as apartments, factory buildings, offices, vehicle cabins u.a. occurrence. They are effective against sensitive and resistant species and against all stages of development. These pests include:
- Scorpionidea eg Buthus occitanus.
- Acarina eg Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.
- Araneae eg Aviculariidae, Araneidae.
- Opiliones eg Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
- Isopoda eg Oniscus asellus, Porcellio scaber.
- Diplopoda eg Blaniulus guttulatus, Polydesmus spp.
- Chilopoda eg Geophilus spp.
- Zygentoma eg Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
- Psocoptera eg Lepinatus spp.
- Liposcelis spp. From the order of Coleoptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum.
- Hymenoptera for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
- Anoplura for example, Pediculus humanus capitis, Pediculus humanus corporis, Pemphigus spp., Phylloera vastatrix, Phthirus pubis. From the order of Heteroptera eg Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.
- flubendiamide can be carried out in aerosols, non-pressurized sprays, e.g. Pump and atomizer sprays, misting machines, foggers, foams, gels, evaporator products with cellulose or plastic evaporator plates, liquid evaporators, gel and membrane evaporators, propeller driven evaporators, energyless or passive evaporation systems, moth papers, moth cakes and moth gels, as granules or dusts, in litter or bait stations.
- non-pressurized sprays e.g. Pump and atomizer sprays, misting machines, foggers, foams, gels, evaporator products with cellulose or plastic evaporator plates, liquid evaporators, gel and membrane evaporators, propeller driven evaporators, energyless or passive evaporation systems, moth papers, moth cakes and moth gels, as granules or dusts, in litter or bait stations.
- a dust is obtained by mixing 10 parts by weight of flubendiamide and 90 parts by weight of talc as an inert material and comminuting in a hammer mill.
- a wettable powder readily dispersible in water is obtained by mixing 25 parts by weight of flubendiamide, 64 parts by weight of kaolin-containing quartz as inert substance, 10 parts by weight of lignosulfonic acid potassium and 1 part by weight of oleoylmethyltaurine sodium as wetting and dispersing agent and in a Pin mill grinds.
- a dispersion concentrate readily dispersible in water is obtained by reacting 20 parts by weight of flubendiamides with 6 parts by weight of alkylphenol polyglycol ether (®Triton X 207), 3 parts by weight of isotridecanol polyglycol ether (8 EO) and 71 parts by weight of paraffinic mineral oil (boiling range eg about 255 to about 277 C) and ground in a ball mill to a fineness of less than 5 microns.
- An emulsifiable concentrate is obtained from 15 parts by weight of flubendiamide, 75 parts by weight of cyclohexanone as solvent and 10 parts by weight of ethoxylated nonylphenol as emulsifier.
- a water-dispersible granules are obtained by mixing 75 parts by weight Flubendiamide, 10 parts by weight of calcium lignosulfonate, 5 parts by weight of sodium lauryl sulfate, 3 parts by weight of polyvinyl alcohol and 7 parts by weight of kaolin mixed on a Grinds pin mill and the powder granulated in a fluidized bed by spraying water as Granulier crampkeit.
- a water-dispersible granule is also obtained by adding 25 parts by weight of flubendiamide, 5 parts by weight of sodium 2,2'-dinaphthylmethane-6,6'-disulfonate, 2 parts by weight of oleoylmethyltaurinate sodium, 1 wt Part of polyvinyl alcohol, 17
- Parts by weight of calcium carbonate and 50 parts by weight of water were homogenized on a colloid mill and pre-comminuted, then ground on a bead mill and the suspension thus obtained in a spray tower by means of a Einstoffdüse atomized and dried.
- a synergistic effect is always present in the case of insecticides and acaricides whenever the effect of the flubendiamide-beneficial agent combinations is greater than the sum of the effects of the individually applied active substances or beneficials.
- the expected effect for a given combination of two drugs can be calculated according to SR Colby, Weeds (1967), 20-22 as follows:
- X the degree of killing, expressed in% of the untreated control, when using the active substance A at a rate of m g / ha, m mg ai / plant or in a
- Y is the degree of killing, expressed in% of the untreated control, when using the beneficial insect at a rate of n animals or n units, and
- E is the kill rate, expressed in% of the untreated control, when using the active substance A and the beneficial agent B at application rates of m ppm, mgm ai / plant or g / ha and n means animals or units,
- the combination in its killing is over-additive, i. there is a synergistic effect.
- the actually observed kill rate must be greater than the expected kill rate (E) value calculated from the above formula.
- Emulsifier parts by weight of alkylaryl polyglycol ether
- active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
- Cabbages (Brassica oleracea) that are strongly of the green peach aphid (Myzus persicae) are treated by casting with the preparation of active compound in the desired concentration.
- the predatory bugs (Macrolophus caliginosus) are added after the application in a defined amount. After the desired time, the kill of the pest is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
- the determined mortality values are calculated according to the Colby formula (see above).
- Emulsifier parts by weight of alkylaryl polyglycol ether
- active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration.
- Cabbage plants (Brassica oleracea) are cast with a preparation of active compound in the desired concentration and infected with larvae of the cabbage moth ⁇ Plutella xylostella).
- the kill of the pest is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
- flubendiamide when applied to bottomless substrates, shows surprisingly good systemic potency
Abstract
Description
Claims
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CN2010800244519A CN102480946A (zh) | 2009-06-03 | 2010-05-21 | 氟虫双酰胺和有益生物的结合物 |
BRPI1011982A BRPI1011982A2 (pt) | 2009-06-03 | 2010-05-21 | combinações de flubendiamidas e organismos úteis. |
EP10722615A EP2437597A2 (de) | 2009-06-03 | 2010-05-21 | Flubendiamide-nützlings-kombinationen |
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US (1) | US20100310518A1 (de) |
EP (1) | EP2437597A2 (de) |
KR (1) | KR20120046122A (de) |
CN (1) | CN102480946A (de) |
BR (1) | BRPI1011982A2 (de) |
TW (1) | TW201108938A (de) |
WO (1) | WO2010139408A2 (de) |
Cited By (2)
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WO2013178664A1 (en) * | 2012-05-30 | 2013-12-05 | Bayer Cropscience Ag | Compositions comprising a biological control agent and an insecticide |
CN104872203A (zh) * | 2015-06-01 | 2015-09-02 | 吴迪 | 一种防治草莓病害的植物源生物农药 |
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BR112015026129A2 (pt) * | 2013-04-19 | 2017-10-17 | Bayer Cropscience Ag | método para combater pragas |
CN112931533B (zh) * | 2021-02-02 | 2022-03-11 | 中国林业科学研究院森林生态环境与保护研究所 | 一种林业昆虫核型多角体病毒可湿性粉剂及其制备方法 |
AR126212A1 (es) | 2021-06-24 | 2023-09-27 | Pi Industries Ltd | Una combinación de flubendiamida y extracto de algas |
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US4761373A (en) * | 1984-03-06 | 1988-08-02 | Molecular Genetics, Inc. | Herbicide resistance in plants |
US5359807A (en) * | 1993-05-28 | 1994-11-01 | The United States Of America As Represented By The Secretary Of Agriculture | Method and apparatus for autodissemination of insect pathogens |
AU2005306363B2 (en) * | 2004-11-18 | 2012-08-09 | E. I. Du Pont De Nemours And Company | Anthranilamide insecticides |
DE102006027732A1 (de) * | 2006-06-16 | 2008-01-10 | Bayer Cropscience Ag | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
DE102006027730A1 (de) * | 2006-06-16 | 2007-12-20 | Bayer Cropscience Ag | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
DE102006027731A1 (de) * | 2006-06-16 | 2007-12-20 | Bayer Cropscience Ag | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
JP2010505752A (ja) * | 2006-09-30 | 2010-02-25 | バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト | 栽培基質に施用されたときの農薬組成物の生物学的効果の改善、適切な製剤及びその使用 |
BR112012018108A2 (pt) * | 2010-01-22 | 2015-10-20 | Bayer Ip Gmbh | combinações acaricidas e/ou inseticidas de ingredientes ativos |
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2010
- 2010-05-21 KR KR1020117031384A patent/KR20120046122A/ko not_active Application Discontinuation
- 2010-05-21 CN CN2010800244519A patent/CN102480946A/zh active Pending
- 2010-05-21 WO PCT/EP2010/003147 patent/WO2010139408A2/de active Application Filing
- 2010-05-21 EP EP10722615A patent/EP2437597A2/de not_active Withdrawn
- 2010-05-21 BR BRPI1011982A patent/BRPI1011982A2/pt not_active IP Right Cessation
- 2010-06-02 TW TW099117693A patent/TW201108938A/zh unknown
- 2010-06-03 US US12/793,078 patent/US20100310518A1/en not_active Abandoned
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013178664A1 (en) * | 2012-05-30 | 2013-12-05 | Bayer Cropscience Ag | Compositions comprising a biological control agent and an insecticide |
CN104507310A (zh) * | 2012-05-30 | 2015-04-08 | 拜尔农作物科学股份公司 | 包括生物防治剂和杀昆虫剂的组合物 |
US10306889B2 (en) | 2012-05-30 | 2019-06-04 | Bayer Cropscience Ag | Compositions comprising a biological control agent and an insecticide |
CN104872203A (zh) * | 2015-06-01 | 2015-09-02 | 吴迪 | 一种防治草莓病害的植物源生物农药 |
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TW201108938A (en) | 2011-03-16 |
CN102480946A (zh) | 2012-05-30 |
EP2437597A2 (de) | 2012-04-11 |
KR20120046122A (ko) | 2012-05-09 |
WO2010139408A3 (de) | 2011-06-16 |
BRPI1011982A2 (pt) | 2015-09-22 |
US20100310518A1 (en) | 2010-12-09 |
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