CN101426830B - 纤维强化复合材料用环氧树脂组合物 - Google Patents
纤维强化复合材料用环氧树脂组合物 Download PDFInfo
- Publication number
- CN101426830B CN101426830B CN200780014731XA CN200780014731A CN101426830B CN 101426830 B CN101426830 B CN 101426830B CN 200780014731X A CN200780014731X A CN 200780014731XA CN 200780014731 A CN200780014731 A CN 200780014731A CN 101426830 B CN101426830 B CN 101426830B
- Authority
- CN
- China
- Prior art keywords
- epoxy resin
- fiber
- resin
- reinforced composite
- composite material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003822 epoxy resin Substances 0.000 title claims abstract description 147
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 147
- 239000000203 mixture Substances 0.000 title claims abstract description 85
- 239000003733 fiber-reinforced composite Substances 0.000 title claims abstract description 36
- 239000000463 material Substances 0.000 title claims abstract description 33
- 229920005989 resin Polymers 0.000 claims abstract description 135
- 239000011347 resin Substances 0.000 claims abstract description 135
- 150000001875 compounds Chemical class 0.000 claims abstract description 44
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 37
- 150000007524 organic acids Chemical class 0.000 claims abstract description 37
- 150000001412 amines Chemical class 0.000 claims abstract description 23
- 239000011159 matrix material Substances 0.000 claims abstract description 21
- 229920000768 polyamine Polymers 0.000 claims abstract description 14
- 125000003118 aryl group Chemical group 0.000 claims abstract description 9
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 7
- 125000002723 alicyclic group Chemical group 0.000 claims abstract description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 25
- 229920005992 thermoplastic resin Polymers 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 13
- 239000000835 fiber Substances 0.000 claims description 12
- 241001676573 Minium Species 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 10
- 238000005728 strengthening Methods 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000005259 measurement Methods 0.000 claims description 7
- 239000012783 reinforcing fiber Substances 0.000 claims description 7
- 230000006378 damage Effects 0.000 claims description 6
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 claims description 4
- LJGHYPLBDBRCRZ-UHFFFAOYSA-N 3-(3-aminophenyl)sulfonylaniline Chemical compound NC1=CC=CC(S(=O)(=O)C=2C=C(N)C=CC=2)=C1 LJGHYPLBDBRCRZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004697 Polyetherimide Substances 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 claims description 3
- 150000002513 isocyanates Chemical class 0.000 claims description 3
- 229920001601 polyetherimide Polymers 0.000 claims description 3
- 239000004695 Polyether sulfone Substances 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 229920003192 poly(bis maleimide) Polymers 0.000 claims description 2
- 229920006393 polyether sulfone Polymers 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- 238000003475 lamination Methods 0.000 claims 1
- 238000003860 storage Methods 0.000 abstract description 4
- 230000008018 melting Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 28
- 239000011162 core material Substances 0.000 description 27
- 238000006243 chemical reaction Methods 0.000 description 26
- 238000010438 heat treatment Methods 0.000 description 24
- 239000011248 coating agent Substances 0.000 description 11
- 238000000576 coating method Methods 0.000 description 11
- -1 glycidyl group amine Chemical class 0.000 description 8
- 230000001464 adherent effect Effects 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 4
- 239000010419 fine particle Substances 0.000 description 4
- 230000009975 flexible effect Effects 0.000 description 4
- 230000000630 rising effect Effects 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 3
- 238000009998 heat setting Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000004321 preservation Methods 0.000 description 3
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 239000011499 joint compound Substances 0.000 description 2
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 2
- 235000013923 monosodium glutamate Nutrition 0.000 description 2
- 239000004223 monosodium glutamate Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 2
- 229940038384 octadecane Drugs 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 239000009719 polyimide resin Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N 1,3-Dimethylbenzene Natural products CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920000271 Kevlar® Polymers 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006664 bond formation reaction Methods 0.000 description 1
- XEVRDFDBXJMZFG-UHFFFAOYSA-N carbonyl dihydrazine Chemical compound NNC(=O)NN XEVRDFDBXJMZFG-UHFFFAOYSA-N 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- ZWLIYXJBOIDXLL-UHFFFAOYSA-N decanedihydrazide Chemical compound NNC(=O)CCCCCCCCC(=O)NN ZWLIYXJBOIDXLL-UHFFFAOYSA-N 0.000 description 1
- 150000007520 diprotic acids Chemical class 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical group 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000004761 kevlar Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000090 poly(aryl ether) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
Landscapes
- Reinforced Plastic Materials (AREA)
- Epoxy Resins (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006120706A JP4141480B2 (ja) | 2006-04-25 | 2006-04-25 | 繊維強化複合材料用エポキシ樹脂組成物 |
| JP120707/2006 | 2006-04-25 | ||
| JP120704/2006 | 2006-04-25 | ||
| JP120706/2006 | 2006-04-25 | ||
| JP2006120704A JP4141479B2 (ja) | 2006-04-25 | 2006-04-25 | 繊維強化複合材料用エポキシ樹脂組成物 |
| JP2006120707A JP4141481B2 (ja) | 2006-04-25 | 2006-04-25 | 繊維強化複合材料用エポキシ樹脂組成物 |
| PCT/JP2007/058882 WO2007125929A1 (ja) | 2006-04-25 | 2007-04-24 | 繊維強化複合材料用エポキシ樹脂組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101426830A CN101426830A (zh) | 2009-05-06 |
| CN101426830B true CN101426830B (zh) | 2012-03-21 |
Family
ID=38762178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200780014731XA Expired - Fee Related CN101426830B (zh) | 2006-04-25 | 2007-04-24 | 纤维强化复合材料用环氧树脂组合物 |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP4141479B2 (enrdf_load_stackoverflow) |
| CN (1) | CN101426830B (enrdf_load_stackoverflow) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2013119741A (ru) * | 2010-09-28 | 2014-11-10 | Торэй Индастриз, Инк. | Композиция эпоксидной смолы, препрег и армированные волокнами композитные материалы |
| CN103732659B (zh) * | 2011-08-18 | 2017-03-08 | 蓝立方知识产权公司 | 可固化树脂组合物 |
| CN102555302B (zh) * | 2011-12-16 | 2014-01-22 | 沈阳飞机工业（集团）有限公司 | 复合材料纸蜂窝夹芯结构整体共固化成型工艺方法 |
| EP2695903B1 (en) * | 2012-08-08 | 2018-09-26 | Siemens Aktiengesellschaft | Method of modifying the rate of temperature change of an epoxy resin composition in a resin container during a casting process |
| JP6131332B2 (ja) * | 2013-11-26 | 2017-05-17 | 東邦テナックス株式会社 | 熱硬化性樹脂組成物、プリプレグ及びこれらを用いる繊維強化複合材料の製造方法 |
| US10351700B2 (en) * | 2014-11-17 | 2019-07-16 | Toray Industries, Inc. | Epoxy resin composition, prepreg, cured resin, and fiber reinforced composite material (as amended) |
| WO2016088528A1 (ja) * | 2014-12-03 | 2016-06-09 | Dic株式会社 | エポキシ樹脂用硬化剤、及びこれを用いてなるエポキシ樹脂組成物 |
| CN107922591A (zh) * | 2015-09-03 | 2018-04-17 | 东丽株式会社 | 环氧树脂组合物、预浸料坯以及碳纤维增强复合材料 |
| CN106926516B (zh) * | 2015-12-31 | 2019-07-26 | 比亚迪股份有限公司 | 复合蜂窝夹芯板及其制备方法 |
| CN110520497A (zh) * | 2017-02-26 | 2019-11-29 | 陶氏环球技术有限责任公司 | 含有潜伏性固化剂混合物的单组分增韧的环氧粘合剂 |
| CN109054290A (zh) * | 2018-06-12 | 2018-12-21 | 苏州洛特兰新材料科技有限公司 | 一种环氧树脂基复合材料的制备方法及其应用 |
| CN110591292B (zh) * | 2019-09-29 | 2022-05-13 | 烟台德邦科技股份有限公司 | 一种表面绝缘电阻高的底部填充胶及其制备方法 |
| EP4314108A4 (en) | 2021-03-31 | 2025-02-19 | Toray Industries, Inc. | Epoxy resin composition, prepreg, and fiber-reinforced composite material |
| CN116003988A (zh) * | 2023-02-07 | 2023-04-25 | 四川大学 | 一种环氧碳纤维增强复合材料及其制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6596373B1 (en) * | 1999-10-13 | 2003-07-22 | Toray Industries, Inc. | Epoxy resin composition for fiber-reinforced composite material prepreg, and fiber-reinforced composite material |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003026768A (ja) * | 2001-07-13 | 2003-01-29 | Toray Ind Inc | エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料 |
| JP2004075914A (ja) * | 2002-08-21 | 2004-03-11 | Toray Ind Inc | エポキシ樹脂組成物及びプリプレグ |
| JP4314845B2 (ja) * | 2003-03-06 | 2009-08-19 | 東レ株式会社 | エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料 |
-
2006
- 2006-04-25 JP JP2006120704A patent/JP4141479B2/ja active Active
-
2007
- 2007-04-24 CN CN200780014731XA patent/CN101426830B/zh not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6596373B1 (en) * | 1999-10-13 | 2003-07-22 | Toray Industries, Inc. | Epoxy resin composition for fiber-reinforced composite material prepreg, and fiber-reinforced composite material |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4141479B2 (ja) | 2008-08-27 |
| JP2007291236A (ja) | 2007-11-08 |
| CN101426830A (zh) | 2009-05-06 |
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| C14 | Grant of patent or utility model | ||
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120321 |