CN101402049A - 一种甲醇制丙烯催化剂的制备方法 - Google Patents
一种甲醇制丙烯催化剂的制备方法 Download PDFInfo
- Publication number
- CN101402049A CN101402049A CNA2008100439225A CN200810043922A CN101402049A CN 101402049 A CN101402049 A CN 101402049A CN A2008100439225 A CNA2008100439225 A CN A2008100439225A CN 200810043922 A CN200810043922 A CN 200810043922A CN 101402049 A CN101402049 A CN 101402049A
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- China
- Prior art keywords
- catalyst
- propylene
- methanol
- acid
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 84
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title claims abstract description 36
- 239000003054 catalyst Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title abstract description 10
- 230000008569 process Effects 0.000 title description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 16
- 239000010703 silicon Substances 0.000 claims abstract description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 30
- 238000005406 washing Methods 0.000 claims description 20
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 18
- 229910052782 aluminium Inorganic materials 0.000 claims description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 17
- 239000004411 aluminium Substances 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 238000002360 preparation method Methods 0.000 claims description 13
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 12
- 238000002425 crystallisation Methods 0.000 claims description 11
- 230000008025 crystallization Effects 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 11
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- 239000002808 molecular sieve Substances 0.000 claims description 9
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 239000006229 carbon black Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 claims description 8
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 6
- 238000009415 formwork Methods 0.000 claims description 6
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 5
- 239000013078 crystal Substances 0.000 claims description 5
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 4
- 230000005493 condensed matter Effects 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 22
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 10
- 239000005977 Ethylene Substances 0.000 abstract description 7
- 229910021536 Zeolite Inorganic materials 0.000 abstract description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract description 2
- 239000010457 zeolite Substances 0.000 abstract description 2
- 238000001354 calcination Methods 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 239000000047 product Substances 0.000 description 27
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000001704 evaporation Methods 0.000 description 9
- 230000008020 evaporation Effects 0.000 description 9
- -1 polypropylene Polymers 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 241000269350 Anura Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003348 petrochemical agent Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000012084 conversion product Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000011426 transformation method Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Catalysts (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNA2008100439225A CN101402049A (zh) | 2008-11-11 | 2008-11-11 | 一种甲醇制丙烯催化剂的制备方法 |
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CNA2008100439225A CN101402049A (zh) | 2008-11-11 | 2008-11-11 | 一种甲醇制丙烯催化剂的制备方法 |
Publications (1)
Publication Number | Publication Date |
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CN101402049A true CN101402049A (zh) | 2009-04-08 |
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CNA2008100439225A Pending CN101402049A (zh) | 2008-11-11 | 2008-11-11 | 一种甲醇制丙烯催化剂的制备方法 |
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CN (1) | CN101402049A (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102125866A (zh) * | 2010-12-16 | 2011-07-20 | 神华集团有限责任公司 | 一种用于甲醇制备丙烯的h-zsm-5分子筛催化剂及其用途 |
CN102989501A (zh) * | 2012-12-11 | 2013-03-27 | 神华集团有限责任公司 | H-zsm-5分子筛催化剂制备方法及制得的催化剂 |
CN103420753A (zh) * | 2012-05-16 | 2013-12-04 | 中国石油化工股份有限公司 | 甲醇转化制备丙烯的方法 |
CN107138175A (zh) * | 2017-05-15 | 2017-09-08 | 江苏有容催化技术研究所有限公司 | 一种高活性高选择性甲醇制丙烯催化剂的制备方法 |
CN107511167A (zh) * | 2016-06-17 | 2017-12-26 | 神华集团有限责任公司 | 有机含氧化合物制烯烃分子筛催化剂及其制备方法和有机含氧化合物制烯烃的方法 |
US9856183B2 (en) | 2013-01-31 | 2018-01-02 | Shanghai Bi Ke Clean Energy Technology Co., Ltd. | Catalyst with high C4 olefin selectivity for preparing olefin from methanol and preparation method thereof |
-
2008
- 2008-11-11 CN CNA2008100439225A patent/CN101402049A/zh active Pending
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102125866A (zh) * | 2010-12-16 | 2011-07-20 | 神华集团有限责任公司 | 一种用于甲醇制备丙烯的h-zsm-5分子筛催化剂及其用途 |
CN103420753A (zh) * | 2012-05-16 | 2013-12-04 | 中国石油化工股份有限公司 | 甲醇转化制备丙烯的方法 |
CN102989501A (zh) * | 2012-12-11 | 2013-03-27 | 神华集团有限责任公司 | H-zsm-5分子筛催化剂制备方法及制得的催化剂 |
US9856183B2 (en) | 2013-01-31 | 2018-01-02 | Shanghai Bi Ke Clean Energy Technology Co., Ltd. | Catalyst with high C4 olefin selectivity for preparing olefin from methanol and preparation method thereof |
CN107511167A (zh) * | 2016-06-17 | 2017-12-26 | 神华集团有限责任公司 | 有机含氧化合物制烯烃分子筛催化剂及其制备方法和有机含氧化合物制烯烃的方法 |
CN107511167B (zh) * | 2016-06-17 | 2021-11-05 | 国家能源投资集团有限责任公司 | 有机含氧化合物制烯烃分子筛催化剂及其制备方法和有机含氧化合物制烯烃的方法 |
CN107138175A (zh) * | 2017-05-15 | 2017-09-08 | 江苏有容催化技术研究所有限公司 | 一种高活性高选择性甲醇制丙烯催化剂的制备方法 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C53 | Correction of patent for invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Wang Jian Inventor after: Ji Xiangfei Inventor after: Guo Zhaomin Inventor after: Kong Ying Inventor after: Yao Min Inventor after: Zhou Guanghua Inventor after: Ai Yulian Inventor after: Jiao Hongqiao Inventor after: Luo Chuntao Inventor after: Zhang Kun Inventor after: Song Yan Inventor after: Dou Tao Inventor before: Song Yan Inventor before: Dou Tao Inventor before: Ji Xiangfei Inventor before: Kong Ying Inventor before: Guo Zhaomin |
|
COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: SONG YAN DOU TAO JI XIANGFEI KONG YING GUO ZHAOMIN TO: WANG JIAN YAO MIN ZHOU GUANGHUA AI YULIAN JIAO HONGQIAO LUO CHUNTAO ZHANG ZHANG SONG YAN DOU TAO JI XIANGFEI GUO ZHAOMIN KONG YING |
|
ASS | Succession or assignment of patent right |
Owner name: SHENHUA NINGXIA COAL INDUSTRY GROUP CO.,LTD. Free format text: FORMER OWNER: SHANGHAI FURUIDE CHEMICAL TECHNOLOGY CO., LTD. Effective date: 20100422 Owner name: SHANGHAI FURUIDE CHEMICAL TECHNOLOGY CO., LTD. |
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C41 | Transfer of patent application or patent right or utility model | ||
COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 200135 HOUSE 14, JUYANG BUILDING, NO.1200, PUDONG AVENUE, PUDONG NEW DISTRICT, SHANGHAI CITY TO: 750004 NO.168, BEIJING MIDDLE ROAD, YINCHUAN CITY, NINGXIA |
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TA01 | Transfer of patent application right |
Effective date of registration: 20100422 Address after: 750004 No. 168 middle Beijing Road, Ningxia, Yinchuan Applicant after: Shenhua Ningxia Coal Industry Group Co., Ltd . Applicant after: Shanghai Friend Chemical Technology Co.,Ltd. Address before: 200135, 14 floor, Ju Yang mansion, No. 1200 Pudong Avenue, Shanghai, Pudong New Area Applicant before: Shanghai Friend Chemical Technology Co.,Ltd. |
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C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20090408 |