CN101389304A - 油包水型乳化防晒化妆品 - Google Patents
油包水型乳化防晒化妆品 Download PDFInfo
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- CN101389304A CN101389304A CNA2007800061323A CN200780006132A CN101389304A CN 101389304 A CN101389304 A CN 101389304A CN A2007800061323 A CNA2007800061323 A CN A2007800061323A CN 200780006132 A CN200780006132 A CN 200780006132A CN 101389304 A CN101389304 A CN 101389304A
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Abstract
本发明提供了一种充分发挥优异的紫外线遮挡效果、且防止·抑制随时间发臭的稳定性也优异的油包水型乳化防晒化妆品。本发明油包水型乳化防晒化妆品，其特征在于，含有：(a)0.2～10质量％的奥克立林、(b)0.2～30质量％的实施了疏水化处理的二氧化钛和/或氧化锌、(c)0.02～8质量％的苯基苯并咪唑磺酸以及(d)上述(c)成分的中和剂，还根据期望含有(e)0.01～20质量％的有机硅类表面活性剂。
Description
相关申请
本申请要求2006年2月20日申请的日本专利申请2006-041831号的优先权，其包含在本申请中。
技术领域
本发明涉及油包水型乳化防晒化妆品。更详细地说，涉及充分发挥优异的防紫外线的能力、且防止·抑制随时间发臭的稳定性优异的油包水型乳化防晒化妆品。
背景技术
通常，为了阻挡紫外线对皮肤的照射以获得高的SPF(太阳保护因子)值，在防晒化妆品中配合紫外线吸收剂，或者配合紫外线散射剂(氧化锌、二氧化钛等)(参见例如专利文献1～2)。
奥克立林(octocrylene)是常用的紫外线吸收剂，由于在油包水型防晒化妆品中组合使用实施了疏水化处理的紫外线散射剂，会产生随时间发臭的问题。
专利文献1：日本特开平10-120543号公报(段落编号[0037]、[0041]、[0045]等)
专利文献2：日本特表2002-521417号公报(权利要求书一栏等)
发明内容
发明要解决的问题
本发明的目的是消除上述现有的问题点，提供一种能充分发挥优异的紫外线阻断效果、且防止·抑制随时间发臭的稳定性优异的油包水型乳化防晒化妆品。
解决问题的方法
本发明人为了解决上述课题，实施了精心的研究，发现在油相(外相)中组合使用配合奥克立林和实施了疏水化处理的紫外线散射剂(氧化锌、二氧化钛等)的油包水型乳化系的水相(内相)中，中和特定的水溶性紫外线吸收剂，以盐的形式配合，从而能稳定地获得优异的紫外线阻断效果和防止·抑制随时间发臭的效果，从而完成本发明。
即，本发明提供了一种油包水型乳化防晒化妆品，其含有：(a)0.2～10质量％的奥克立林、(b)0.2～30质量％的实施了疏水化处理的二氧化钛和/或氧化锌、(c)0.02～8质量％的苯基苯并咪唑磺酸以及(d)上述(c)成分的中和剂。
此外，本发明提供上述油包水型乳化防晒化妆品，其含有10.1～25质量％(b)成分。
此外，本发明提供上述油包水型乳化防晒化妆品，其中，(b)成分是实施了疏水化处理的氧化锌。
此外，本发明提供上述油包水型乳化防晒化妆品，其中，(d)成分是三乙醇胺。
此外，本发明提供上述油包水型乳化防晒化妆品，其中，还含有(e)0.01～20质量％的有机硅类表面活性剂。
根据本发明，提供能充分发挥优异的紫外线阻断效果、且防止·抑制随时间发臭的稳定性也优异的油包水型乳化防晒化妆品。
具体实施方式
以下，对本发明的油包水型乳化防晒化妆品进行详细说明。
作为本发明中使用的(a)成分的奥克立林(别名：2-氰基-3，3-二苯基-2-丙烯酸-2-乙基己酯)是防紫外线剂，以例如作为“ユビヌルN539”(バスフ(BASF)公司)、“パルソ-ル340”(DSMニュ-トリションジヤパン(株))等市售，可以适合使用这些。
(a)成分的配合量相对于本发明化妆品为0.2～10质量％，优选为1～7质量％。配合量不足0.2质量％的话，无法获得足够的防紫外线能力，另一方面，超过10质量％的话，随时间的发臭增强，可能会导致发粘、发油等使用性恶化。
作为(b)成分的实施了疏水化处理的二氧化钛和/或氧化锌是紫外线散射剂，通过进行疏水化处理，能有效地在油相(外相)中分散。
从紫外线散射效果的观点出发，二氧化钛、氧化锌优选制备成微粒状。作为微粒二氧化钛，可以优选列举平均一次粒径为1～30nm、更优选为20nm以下的材料。此外，作为微粒氧化锌，可以列举平均一次粒径为1～40nm、更优选为30nm以下的材料。然而，并不限定于其中。
对疏水化处理的方法没有特别的限制，可以通过公知的方法处理。可以列举例如使用甲基氢聚硅氧烷、甲基氢聚硅氧烷·二甲基聚硅氧烷共聚物、二甲基聚硅氧烷等有机硅类的处理；使用辛基三乙氧基硅烷、己基三甲氧基硅烷等硅烷化合物的处理；使用棕榈酸、硬脂酸等脂肪酸的处理；使用前述脂肪酸的碱金属盐或碱土类金属盐等的金属皂化处理；使用全氟烷基磷酸二乙醇胺盐、全氟烷基三甲氧基硅烷等的氟处理等。
作为实施了疏水化处理的二氧化钛，市售品可以列举例如“TTO-S-4”、“TTO-V-4”(均为石原产业(株)制造)、“MT-100TV”、“MT-014V”(均为テイカ(株)制造)等，此外，作为实施了疏水化处理的氧化锌，市售品可以列举例如“FZO-50”(石原产业(株)制造)、“WSX-MZ-700”(テイカ(株)制造)、“Z-Cote HP-1”(バスフ(BASF)公司制造)等，可以适合使用这些。
(b)成分的配合量相对于本发明化妆品为0.2～30质量％，优选为1～30质量％，更优选为10.1～25质量％。配合量不足0.2质量％的话，无法获得足够的防紫外线效果，另一方面，超过30质量％的话，可能会导致以随时间的发臭和粗糙(smoothlessness)为代表的使用性恶化。另外，(b)成分的配合量为10.1质量％的话，能获得非常高的防紫外线效果，但发臭也变得显著。在本发明中，通过配合(c)成分和(d)成分(后述)，即使在配合多的(b)成分的情况下，仍然能稳定地防止由于组合使用上述(a)成分和(b)成分引起的发臭。此外，在作为(b)成分使用疏水化锌的情况下，与使用疏水化二氧化钛的情况相比，虽然组合使用(a)成分的随时间发臭更强烈，但在本发明中，即使在该情况下，通过配合(c)成分和(d)成分，可以稳定有效地防止·抑制发臭。
作为(c)成分的苯基苯并咪唑磺酸是水溶性的防紫外线剂，以例如“ネオ·ヘリパン·ハイド口(Neo Heliopan Hydro)”(シムライズ(Symrise)公司制造)、“ユ—ソレツクス232(Eusolex232)”(メルク(Merck)公司制造)等市售，可以适合使用这些。
(c)成分的配合量相对于本发明化妆品为0.02～8质量％，优选为0.2～5质量％，更优选为1～4质量％。配合量不足0.02质量％的话，无法获得足够的防止·抑制随时间发臭的效果，另一方面，超过8质量％的话，担忧在水相中的溶解性。
(d)成分是上述(c)成分的中和剂，可以优选使用氢氧化钠、氢氧化钾、三乙醇胺、2-氨基-2-甲基-1-丙醇、2-氨基-2-甲基-1，3-丙二醇、N-甲基牛磺酸钠等。然而，并不限定于这些例示中。其中，从防止·抑制随时间发臭的观点出发，特别优选使用三乙醇胺。
(d)成分的配合量只要是足以中和(c)成分的量，就没有特别的限定，通常，相对于(c)成分，优选为50质量％以上，更优选为55质量％以上，尤其是为60质量％以上。如果配合量相对于(c)成分过少，则无法充分中和(c)成分，结晶析出存在担忧。对(d)成分配合量的上限值没有特别限定，只要仅能中和(c)成分，则考虑pH上升等的观点，通常优选相对于(c)成分为65质量％以下左右。
在本发明中，进而作为乳化剂，优选配合(e)有机硅类表面活性剂，作为有机硅类表面活性剂，只要能在油包水型乳化型体系内使用，就没有特别限定，可以列举例如聚(氧乙烯·氧丙烯)甲基聚硅氧烷共聚物、聚氧乙烯甲基聚硅氧烷共聚物、有机硅链支链型甲基聚硅氧烷共聚物、烷基链支链型聚氧乙烯甲基聚硅氧烷共聚物、烷基链·有机硅链支链型聚氧乙烯甲基聚硅氧烷共聚物、交联型聚氧乙烯甲基聚硅氧烷、含有烷基的交联型聚氧乙烯甲基聚硅氧烷、支链型聚甘油改性有机硅、交联型聚甘油改性有机硅、含有烷基的交联型聚甘油改性有机硅、烷基支链型聚甘油改性有机硅等。然而，并不限定于这些。
作为上述聚(氧乙烯·氧丙烯)甲基聚硅氧烷共聚物，可以列举PEG/PPG-20/22丁基醚二甲硅油(“KF-6012”；信越化学工业(株)制造)、PEG/PPG-20/20二甲硅油(“BY22-008M”；東レ·ダウコ-ニング·シリコ-ン(株)制造)、月桂基PEG/PPG-18甲基硅油(“5200 Formulation Aid”；東レ·ダウコ-ニング(株)制造)、PEG/PPG-19/19二甲硅油(“5330Fluid”；東レ·ダウコ-ニング(株)制造)、PEG/PPG-15/15二甲硅油(“5330 Fluid”；東レ·ダウコ-ニング(株)制造)等。
作为聚氧乙烯甲基聚硅氧烷共聚物，可以列举PEG-11甲基醚二甲硅油(“KF-6011”；信越化学工业(株)制造)、PEG-9二甲硅油(“KF-6013”；信越化学工业(株)制造)、PEG-3二甲硅油(“KF-6015”；信越化学工业(株)制造)、PEG-9甲基醚二甲硅油(“KF-6016”；信越化学工业(株)制造)、PEG-10二甲硅油(“KF-6017”；信越化学工业(株)制造)、PEG-11甲基醚二甲硅油(“KF-6018”；信越化学工业(株)制造)、PEG-9二甲硅油(“KF-6019”；信越化学工业(株)制造)、PEG-12二甲硅油(“SH3771M”、“SH3772M”、“SH3773M”、“SH3775M”等。東レ·ダウコ-ニング(株)制造)等。
作为有机硅链支链型甲基聚硅氧烷共聚物，可以列举PEG-9聚二甲基甲硅烷氧基乙基二甲硅油(“KF-6026”；信越化学工业(株)制造)。
作为烷基链支链型聚氧乙烯甲基聚硅氧烷共聚物，可以列举PEG/PPG-10/3油基醚二甲硅油(“KF-6028”；信越化学工业(株)制造)等。
作为烷基链·有机硅链支链型聚氧乙烯甲基聚硅氧烷共聚物，可以列举月桂基PEG-9聚二甲基甲硅烷氧基乙基二甲硅油(“KF-6038”；信越化学工业(株)制造)等。
作为交联型聚氧乙烯甲基聚硅氧烷，可以列举二甲硅油(二甲硅油/(PEG-10/15))交联聚合物(“KSG-210”；信越化学工业(株)制造)、环二甲硅油·PEG-12二甲硅油二甲硅油交联聚合物(“9011有机硅弹性体混合物”；東レ·ダウコ-ニング·シリコ-ン(株)制造)。
作为含烷基的交联型聚氧乙烯甲基聚硅氧烷，可列举矿物油·PEG-15月桂基二甲硅油交联聚合物(“KSG-310”；信越化学工业(株)制造)、异十二烷·PEG-15月桂基二甲硅油交联聚合物(“KSG-320”；信越化学工业(株)制造)、三乙基己酸精(Triethylhexanoin)·PEG-15月桂基二甲硅油交联聚合物(“KSG-330”；信越化学工业(株)制造)、角鲨烯·PEG-15月桂基二甲硅油交联聚合物·PEG-10月桂基二甲硅油交联聚合物(“KSG-340”；信越化学工业(株)制造)等。
作为支链型聚甘油改性有机硅，可列举聚甘油-3二硅氧烷二甲硅油(“KF-6100”；信越化学工业(株)制造)、聚甘油-3聚二甲基甲硅烷氧基乙基二甲硅油(“KF-6104”；信越化学工业(株)制造)等。
作为交联型聚甘油改性有机硅，可列举二甲硅油·(二甲硅油/聚甘油-3)交联聚合物(“KSG-710”；信越化学工业(株)制造)等。
作为含烷基的交联型聚甘油改性有机硅，可列举矿物油·(月桂基二甲硅油/聚甘油3)交联聚合物(“KSG-810”；信越化学工业(株)制造)、异十二烷·(月桂基二甲硅油/聚甘油3)“KSG-820”；信越化学工业(株)制造)、三乙基己酸精(月桂基二甲硅油/聚甘油3)交联聚合物(“KSG-830”；信越化学工业(株)制造)、角鲨烯·(月桂基二甲硅油/聚甘油3)交联聚合物(“KSG-840”；信越化学工业(株)制造)等。
作为烷基支链型聚甘油改性有机硅，可以列举月桂基聚甘油-3聚二甲基甲硅烷氧基乙基二甲硅油(“KF-6105”；信越化学工业(株)制造)等。
其中，适合使用聚氧乙烯甲基聚硅氧烷共聚物、聚(氧乙烯·氧丙烯)甲基聚硅氧烷共聚物、有机硅链支链型甲基聚硅氧烷共聚物、烷基链·有机硅链支链型聚氧乙烯甲基聚硅氧烷共聚物等。
(e)成分的配合量在本发明防晒化妆品中，优选下限值为0.01质量％，更优选为0.1质量％以上，特别优选为0.5质量％以上。此外，上限值优选为20质量％以下，更优选为10质量％以下。配合量不足0.01质量％的话，化妆品的稳定性存在变恶化的倾向，另一方面，在配合量大于20质量％的情况下，会产生表面发粘感，使用感存在恶化的倾向。
本发明的油包水型乳化防晒化妆品优选油相(外相)为20～80质量％，水相(内相)为80～20质量％。
在本发明的化妆品中，除了上述成分以外，在不损害本发明的目的·效果的范围内，还可以根据需要适当配合通常化妆品中使用的其它成分。作为该成分，可以列举水溶性高分子、油溶性高分子、高分子粉末、乳化剂(除了上述(e)成分以外)、蜡类、醇类、液体油脂、酯油、烃油、有机硅油、脂肪酸、高级醇、脂肪酸酯、药剂、紫外线吸收剂(除了上述(a)成分、(c)成分以外)、紫外线散射剂(除了上述(b)成分以外)、有机改性粘土矿物等。然而，并不限定于这些例示中。
作为水溶性高分子，可以列举2-丙烯酰胺-2-甲基丙磺酸(以下，简称为“AMPS”)的均聚物、或共聚物。共聚物是由乙烯基吡咯烷酮、丙烯酸酰胺、丙烯酸钠、丙烯酸羟乙酯等共聚物单体构成的共聚物。即，可以例示AMPS均聚物、乙烯基吡咯烷酮/AMPS共聚物、二甲基丙烯酰胺/AMPS共聚物、丙烯酸酰胺/AMPS共聚物、丙烯酸钠/AMPS共聚物等。
此外，可以例示羧基乙烯基聚合物、聚丙烯酸铵、聚丙烯酸钠、丙烯酸钠/丙烯酸烷基酯/甲基丙烯酸钠/甲基丙烯酸烷基酯共聚物、角叉菜胶、果胶、甘露聚糖、凝胶多糖、软骨素硫酸、淀粉、糖原、阿拉伯树胶、透明质酸钠、黄蓍胶、黄原胶、硫酸粘多糖、羟乙基瓜尔胶、羧甲基瓜尔胶、瓜尔胶、葡聚糖、硫酸角质、槐树豆胶、琥珀酸葡聚糖(succinoglucan)、壳多糖、壳聚糖、羧甲基壳多糖、琼脂等。
作为油溶性高分子，可以例示三甲基甲硅烷氧基硅酸、烷基改性有机硅、聚酰胺改性有机硅等。
作为高分子粉末，可以例示二甲硅油交联聚合物、(二甲硅油/乙烯基二甲硅油)交联聚合物、聚甲基倍半硅氧烷、聚乙烯、聚甲基丙烯酸甲酯等。
作为蜡类，可以例示例如蜂蜡、小烛树蜡、巴西棕榈蜡、羊毛脂、液态羊毛脂、希蒙得木蜡(JOJOBA WAX)等。
作为乳化剂(除了上述(e)成分以外)，可以例示甘油脂肪酸酯、聚甘油脂肪酸酯、聚氧乙烯甘油脂肪酸酯、脱水山梨糖醇脂肪酸酯、聚氧乙烯脱水山梨糖醇脂肪酸酯等。
作为醇类，可以例示乙醇、异丙醇等低级醇、异硬脂醇、辛基十二烷醇、己基癸醇等高级醇、乙二醇、丙二醇、1，3-丁二醇、二丙二醇、聚丁二醇等多元醇等。
作为液体油脂，可以例示例如鳄梨油、山茶油、鳖油、澳洲坚果油、玉米油、貂油、橄榄油、菜籽油、蛋黄油、芝麻油、桃仁油、小麦胚芽油、山茶花油、蓖麻油、亚麻子油、红花油、棉籽油、紫苏子油、大豆油、花生油、茶籽油、椰子油(kaya oil)、米糠油、泡桐油、日本桐油、霍霍巴油、胚芽油、三甘油等。
作为酯油，可以例示例如肉豆蔻酸异丙酯、辛酸鲸蜡酯、肉豆蔻酸辛基十二烷基酯、棕榈酸异丙酯、硬脂酸丁酯、月桂酸己酯、肉豆蔻酸肉豆蔻酯、油酸癸酯、二甲基辛酸己基癸酯、乳酸鲸蜡酯、乳酸肉豆蔻酯、乙酸羊毛脂、硬脂酸异鲸蜡酯、异硬脂酸异鲸蜡酯、异壬酸异壬酯、12-羟基硬脂酸胆甾醇酯、二-2-乙基己酸乙二醇酯、二季戊四醇脂肪酸酯、单异硬脂酸N-烷基二醇酯、二癸酸新戊二醇酯、苹果酸二异硬脂酰酯、二-2-庚基十一烷酸甘油酯、三-2-乙基己酸三羟甲基丙烷、三异硬脂酸三羟甲基丙烷、四-2-乙基己酸季戊四醇酯、三-2-乙基己酸甘油酯、三辛酸甘油酯、三异棕榈酸甘油酯、三异硬脂酸三羟甲基丙烷、2-乙基己酸鲸蜡酯、棕榈酸2-乙基己酯、三肉豆蔻酸甘油酯、三-2-庚基十一烷酸甘油酯、蓖麻油脂肪酸甲酯、油酸油基酯、乙酰甘油酯、棕榈酸2-庚基十一烷基酯、己二酸二异丁基酯、N-月桂酰基-L-谷氨酸-2-辛基十二烷基酯、己二酸二-2-庚基十一烷基酯、月桂酸乙酯、癸二酸二-2-乙基己酯、肉豆蔻酸2-己基癸酯、棕榈酸2-己基癸酯、己二酸2-己基癸酯、癸二酸二异丙酯、琥珀酸2-乙基己酯、柠檬酸三乙酯等。
作为烃油，可以例示液体石蜡、地蜡(ozocerite)、角鲨烷、姥鲛烷、石蜡、纯地蜡(ceresin)、角鲨烯、凡土林、微晶蜡、聚乙烯蜡、费-托蜡等。
作为有机硅油，可列示二甲基聚硅氧烷、八甲基硅氧烷、十甲基四硅氧烷、甲基氢聚硅氧烷、甲基苯基聚硅氧烷、六甲基环三硅氧烷、八甲基环四硅氧烷、十甲基环五硅氧烷等。
作为脂肪酸，可以例示月桂酸、肉豆蔻酸、棕榈酸、硬脂酸、山嵛酸、花生四烯酸等。
作为高级醇，可以例示月桂醇、肉豆蔻醇、鲸蜡醇、硬脂醇、山嵛醇、花生醇(arachidyl alcohol)、鲨肝醇、鲛肝醇、廿四醇、蜡醇、二十八烷醇(koryanyl alcohol)、蜂花醇(myricylalcohol)、虫蜡醇(lacceryl alcohol)、反油醇(elaidyl alcohol)、异硬脂酰基甘油醚、辛醇、三十烷醇(triacontyl alcohol)、鲨油醇、十六十八烷醇(cetostearyl alcohol)、油醇、羊毛脂醇、氢化羊毛脂醇、己基癸醇、辛基癸醇等。
作为脂肪酸酯，可以例示肉豆蔻酸肉豆蔻酯、棕榈酸鲸蜡酯、硬脂酸胆甾醇酯、蜂蜡脂肪酸2-辛基十二烷基酯等。
作为药剂，可以例示L-抗坏血酸及其衍生物的盐，甘草酸二钾、甘草酸单铵等甘草酸及其衍生物、甘草酸硬脂酰酯等甘草酸及其衍生物、尿囊素、凝血酸及其衍生物的盐、烷氧基水杨酸及其衍生物的盐、谷胱甘肽及其衍生物的盐、甘菊环等。
作为紫外线吸收剂(除了上述(a)成分、(c)成分以外)，可以例示例如甲氧基肉桂酸乙基己酯、甲氧基肉桂酸异丙酯、甲氧基肉桂酸异戊酯等肉桂酸衍生物；对氨基安息香酸(以下，简称为“PABA“)、乙基PABA、乙基-二羟丙基PABA、乙基己基-二甲基PABA、甘油基PABA等PABA衍生物；水杨酸三甲环己酯(homosalate)、水杨酸乙基己酯、水杨酸二丙二醇酯、TEA水杨酸酯等水杨酸衍生物；二苯甲酮-1、二苯甲酮-2、二苯甲酮-3或氧苯酮、二苯甲酮-4、二苯甲酮-5、二苯甲酮-6、二苯甲酮-8、二苯甲酮-9、二苯甲酮-12等二苯甲酮衍生物；3-苯亚甲基樟脑、4-甲基苯亚甲基樟脑、苯亚甲基樟脑磺酸、甲基硫酸樟脑苄烷铵、对苯二亚甲基樟脑磺酸、聚丙烯酰胺甲基苯亚甲基樟脑等苯亚甲基樟脑衍生物；异三嗪(anisotriazine)、乙基己基三嗪、二乙基己基丁酰胺三嗪酮、2，4，6-三(二异丁基-4’-氨基亚苄基丙二酸酯)均三嗪等三嗪衍生物；苯基二苯并咪唑四磺酸二钠等苯基苯并咪唑衍生物；苯并三唑基甲基苯酚(Drometrizole)三硅氧烷、亚甲基双(苯并三唑四甲基丁基苯酚)等苯基苯并三唑衍生物；氨茴酸薄荷酯等氨茴内酐衍生物；乙基己基二甲氧基苯亚甲基二氧代咪唑啉丙酸酯等咪唑啉衍生物；具有苯亚甲基丙二酸酯官能团的聚有机硅氧烷等苯亚甲基丙二酸酯衍生物；1，1-二羧基(2，2’-二甲基丙基)-4，4-二苯基丁二烯等4，4-二芳基丁二烯衍生物等。
作为紫外线散射剂(除了上述(b)成分以外)，可以例示实施了疏水化处理的高岭土、碳酸钙等无机颜料等。
作为有机改性粘土矿物，可以例示季铵盐型阳离子改性粘土矿物等。
本发明的油包水型乳化防晒化妆品是乳液态制品或乳状制品。这些制品可以将通常配合于前述必须成分和化妆品中的成分混合、通过常规方法制造。
实施例
下面，基于实施例对本发明进行更详细的说明，但本发明并不限定于以下的实施例中。另外，配合量全部以质量％表示。
[实施例1～8，比较例1～3]
根据下表1～2所示的配方，制备防晒化妆品。
具体地说，在(1)～(7)[A部分]中添加(8)[B部分]，均匀分散，再向其中添加(9)～(11)[C部分]，均匀分散，然后缓慢添加(12)～(19)[D部分]、乳化而进行制备。
[防止·抑制发臭稳定性]
对于所得防晒化妆品(试样)，根据下述评价标准评价各自的防止·抑制发臭稳定性。结果在表1～2中示出。
(试验方法)
将在50℃下静置1个月的各试样在女性小组(10名)中实际使用，根据下述评价标准评价涂布时的臭味。
(评价标准)
◎：10名中有9名以上回答存在可接受的臭味。
○：10名中有6～8名回答存在可接受的臭味。
△：10名中有3～5名回答存在可接受的臭味。
×：10名中有不到3名回答存在可接受的臭味。
表1
| 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 | |
| (1)十甲基环五硅氧烷 | 剩余 | 剩余 | 剩余 | 剩余 | 剩余 | 剩余 |
| (2)二甲基聚硅氧烷(*1) | 2 | 2 | 2 | 2 | 2 | 2 |
| (3)异壬酸异壬酯 | 3 | 3 | 3 | 3 | 3 | 3 |
| (4)三甲基甲硅烷氧基硅酸 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 |
| (5)甲氧基肉桂酸乙基己酯(*2) | 5 | 5 | 5 | 5 | 5 | 5 |
| (6)奥克立林(*3)[(a)成分] | 5 | 5 | 5 | 5 | 5 | 5 |
| (7)烷基链·硅氧烷链支链型聚氧乙烯甲基聚硅氧烷共聚物(*4)[(e)成分] | 1 | 1 | 1 | 1 | 1 | 1 |
| (8)有机改性粘土矿物(*5) | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| (9)棕榈酸糊精处理氧化锌(*6)[(b)成分] | 15 | 15 | 25 | - | ||
| (10)硬脂酸处理二氧化钛(*7)[(b)成分] | - | 15 | - | 15 | - | 25 |
| (11)聚甲基倍半硅氧烷 | 6 | 6 | 6 | 6 | 6 | 6 |
| (12)离子交换水 | 24.3 | 24.3 | 25.65 | 25.65 | 14.3 | 14.3 |
| (13)苯基苯并咪唑磺酸(*8)[(c)成分] | 3 | 3 | 3 | 3 | 3 | 3 |
| (14)三乙醇胺[(d)成分] | 1.8 | 1.8 | - | - | 1.8 | 1.8 |
| (15)氢氧化钠[(d)成分] | - | - | 0.45 | 0.45 | - | - |
| (16)甘油 | 1 | 1 | 1 | 1 | 1 | 1 |
| (17)依地酸三钠盐 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
| (18)乙醇(95度) | 5 | 5 | 5 | 5 | 5 | 5 |
| (19)苯氧基乙醇 | 0.35 | 0.35 | 0.35 | 0.35 | 0.35 | 0.35 |
| 防止·抑制发臭稳定性 | ◎ | ◎ | ○ | ◎ | ○ | ◎ |
表2
| 实施例7 | 实施例8 | 比较例1 | 比较例2 | 比较例3 | |
| (1)十甲基环五硅氧烷 | 剩余 | 剩余 | 剩余 | 剩余 | 剩余 |
| (2)二甲基聚硅氧烷(*1) | 2 | 2 | 2 | 2 | 2 |
| (3)异壬酸异壬基酯 | 3 | 3 | 3 | 3 | 3 |
| (4)三甲基甲硅烷氧基硅酸 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 |
| (5)甲氧基肉桂酸乙基己酯(*2) | 5 | 5 | 5 | 5 | 5 |
| (6)奥克立林(*3)[(a)成分] | 5 | 5 | 5 | 5 | 5 |
| (7)烷基链·有机硅链支链型聚氧乙烯甲基聚硅氧烷共聚物(*4)[(e)成分] | 1 | 1 | 1 | 1 | 1 |
| (8)有机改性粘土矿物(*5) | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| (9)棕榈酸糊精处理氧化锌(*6)[(b)成分] | 15 | - | 15 | 31 | 15 |
| (10)硬脂酸处理二氧化钛(*7)[(b)成分] | - | 15 | - | - | |
| (11)聚甲基倍半硅氧烷 | 6 | 6 | 6 | - | 6 |
| (12)离子交换水 | 26.7 | 26.7 | 29.1 | 14.3 | 24.3 |
| (13)苯基苯并咪唑磺酸(*8)[(c)成分] | 1.5 | 1.5 | - | 3 | 3 |
| (14)三乙醇胺[(d)成分] | 0.9 | 0.9 | - | 1.8 | 1.8 |
| (15)氢氧化钠[(d)成分] | - | - | - | - | - |
| (16)甘油 | 1 | 1 | 1 | 1 | 1 |
| (17)依地酸三钠盐 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
| (18)乙醇(95度) | 5 | 5 | 5 | 5 | 5 |
| (19)苯氧基乙醇 | 0.35 | 0.35 | 0.35 | 0.35 | 0.35 |
| 防止·抑制发臭稳定性 | ○ | ◎ | × | △ | △ |
另外，在表1～2中，以下示出的化合物使用以下产品。
二甲基聚硅氧烷(*1)：“KF96A-6T”(信越化学工业(株)制造)、甲氧基肉桂酸乙基己酯(*2)：“パルソ-ルMCX”(DSMニュ-トリションジヤパン(株)制造)、奥克立林(*3)“パルソ-ル340”(DSMニュ-トリションジヤパン(株)制造)、烷基链·有机硅链支链型聚氧乙烯甲基聚硅氧烷共聚物(*4)：“KF6038”(信越化学工业(株)制造)、有机改性粘土矿物(*5)“ベントン38VCG”(エレメンテイススペシヤリテイ-ズ)、棕榈酸糊精处理氧化锌(*6)：“WSX-MZ-700”(テイカ(株)制造)、硬脂酸处理二氧化钛(*7)“TTO-V-4”(石原产业(株)制造)、苯基苯并咪唑磺酸(*8)：“Eusolex232”(メルク社制造)。
由表1～2的结果所示，确认本发明的油包水型乳化防晒化妆品的防止·抑制发臭效果的稳定性优异。
Claims (5)
1.一种油包水型乳化防晒化妆品，其含有:(a)0.2～10质量％的奥克立林、(b)0.2～30质量％的实施了疏水化处理的二氧化钛和/或氧化锌、(c)0.02～8质量％的苯基苯并咪唑磺酸、以及(d)上述(c)成分的中和剂。
2.根据权利要求1所述的油包水型乳化防晒化妆品，其含有10.1～25质量％的(b)成分。
3.根据权利要求1或2所述的油包水型乳化防晒化妆品，(b)成分是实施了疏水化处理的氧化锌。
4.根据权利要求1～3任一项所述的油包水型乳化防晒化妆品，(d)成分是三乙醇胺。
5.根据权利要求1～4任一项所述的油包水型乳化防晒化妆品，其还含有(e)0.01～20质量％的有机硅类表面活性剂。
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| JP3984892B2 (ja) * | 2002-08-30 | 2007-10-03 | 株式会社資生堂 | 油中水型乳化組成物 |
| JP2004224757A (ja) * | 2003-01-24 | 2004-08-12 | Kao Corp | 油中水型乳化化粧料 |
| US7368105B2 (en) * | 2004-07-02 | 2008-05-06 | L'oreal | Photostabilization of dibenzoylmethane UV-screening agents with arylalkyl benzoate/bis-resorcinyl triazine compounds and photoprotective compositions comprised thereof |
| JP4551710B2 (ja) | 2004-07-26 | 2010-09-29 | アイホン株式会社 | ナースコールシステム |
| JP4447541B2 (ja) * | 2005-09-13 | 2010-04-07 | 株式会社資生堂 | 日焼け止め化粧料 |
| JP5240967B2 (ja) * | 2006-02-20 | 2013-07-17 | 株式会社 資生堂 | 油中水型乳化日焼け止め化粧料 |
-
2006
- 2006-02-20 JP JP2006041831A patent/JP5288521B2/ja active Active
-
2007
- 2007-02-16 TW TW096106189A patent/TWI394589B/zh not_active IP Right Cessation
- 2007-02-19 AU AU2007218767A patent/AU2007218767A1/en not_active Abandoned
- 2007-02-19 CN CNA2007800061323A patent/CN101389304A/zh active Pending
- 2007-02-19 US US12/224,152 patent/US20090041817A1/en not_active Abandoned
- 2007-02-19 EP EP07714467A patent/EP2002822A4/en not_active Withdrawn
- 2007-02-19 KR KR1020087020223A patent/KR20080096777A/ko not_active Application Discontinuation
- 2007-02-19 WO PCT/JP2007/052941 patent/WO2007097274A1/ja active Application Filing
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107028777A (zh) * | 2015-11-25 | 2017-08-11 | 拜尔斯道夫股份有限公司 | 含有二氧化钛的防晒剂 |
| CN107028777B (zh) * | 2015-11-25 | 2021-06-08 | 拜尔斯道夫股份有限公司 | 含有二氧化钛的防晒剂 |
| CN110099670A (zh) * | 2016-12-21 | 2019-08-06 | 莱雅公司 | 含有油性连续相、液体β，β-二苯基丙烯酸酯UV遮蔽剂、液体水杨酸酯UV遮蔽剂和非环状挥发性硅油的组合物 |
| CN107958734A (zh) * | 2017-12-21 | 2018-04-24 | 颍上贝斯特电子科技有限公司 | 一种防水防晒的连接线 |
| CN109589277A (zh) * | 2018-12-20 | 2019-04-09 | 广州欧盛化妆品有限公司 | 一种防晒霜及其制备方法 |
| CN110897955A (zh) * | 2019-12-12 | 2020-03-24 | 芭贝拉化妆品(浙江)有限公司 | 一种防晒组合物及其制备方法及应用 |
| CN110897955B (zh) * | 2019-12-12 | 2022-04-19 | 芭贝拉化妆品(浙江)有限公司 | 一种防晒组合物及其制备方法及应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI394589B (zh) | 2013-05-01 |
| JP2007217379A (ja) | 2007-08-30 |
| EP2002822A4 (en) | 2012-09-05 |
| AU2007218767A1 (en) | 2007-08-30 |
| TW200744649A (en) | 2007-12-16 |
| EP2002822A9 (en) | 2009-04-15 |
| KR20080096777A (ko) | 2008-11-03 |
| US20090041817A1 (en) | 2009-02-12 |
| WO2007097274A1 (ja) | 2007-08-30 |
| EP2002822A2 (en) | 2008-12-17 |
| JP5288521B2 (ja) | 2013-09-11 |
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