CN101384173A - 使用微量养料作为三唑的安全剂以防治有害真菌的方法 - Google Patents
使用微量养料作为三唑的安全剂以防治有害真菌的方法 Download PDFInfo
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- CN101384173A CN101384173A CNA2007800055337A CN200780005533A CN101384173A CN 101384173 A CN101384173 A CN 101384173A CN A2007800055337 A CNA2007800055337 A CN A2007800055337A CN 200780005533 A CN200780005533 A CN 200780005533A CN 101384173 A CN101384173 A CN 101384173A
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- triazole
- micronutrient
- bacterium
- azoles
- acid
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- -1 metcona- 10 zole Chemical compound 0.000 claims abstract description 39
- PPDBOQMNKNNODG-NTEUORMPSA-N (5E)-5-(4-chlorobenzylidene)-2,2-dimethyl-1-(1,2,4-triazol-1-ylmethyl)cyclopentanol Chemical compound C1=NC=NN1CC1(O)C(C)(C)CC\C1=C/C1=CC=C(Cl)C=C1 PPDBOQMNKNNODG-NTEUORMPSA-N 0.000 claims abstract description 21
- 239000005859 Triticonazole Substances 0.000 claims abstract description 21
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000005785 Fluquinconazole Substances 0.000 claims abstract description 16
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- IJJVMEJXYNJXOJ-UHFFFAOYSA-N fluquinconazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1N1C(=O)C2=CC(F)=CC=C2N=C1N1C=NC=N1 IJJVMEJXYNJXOJ-UHFFFAOYSA-N 0.000 claims abstract description 16
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- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 claims abstract description 6
- PZBPKYOVPCNPJY-UHFFFAOYSA-N 1-[2-(allyloxy)-2-(2,4-dichlorophenyl)ethyl]imidazole Chemical compound ClC1=CC(Cl)=CC=C1C(OCC=C)CN1C=NC=C1 PZBPKYOVPCNPJY-UHFFFAOYSA-N 0.000 claims abstract description 6
- UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 claims abstract description 6
- RQDJADAKIFFEKQ-UHFFFAOYSA-N 4-(4-chlorophenyl)-2-phenyl-2-(1,2,4-triazol-1-ylmethyl)butanenitrile Chemical compound C1=CC(Cl)=CC=C1CCC(C=1C=CC=CC=1)(C#N)CN1N=CN=C1 RQDJADAKIFFEKQ-UHFFFAOYSA-N 0.000 claims abstract description 6
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- 239000002283 diesel fuel Substances 0.000 description 1
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- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- OSFBJERFMQCEQY-UHFFFAOYSA-N propylidene Chemical group [CH]CC OSFBJERFMQCEQY-UHFFFAOYSA-N 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
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- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
- A01N47/14—Di-thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/14—Boron; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
Abstract
本发明涉及一种使用选自Mg、Ca、B、Mn、Fe、Co、Zn和Mo的盐和加合物的微量养料作为选自戊环唑、双苯三唑醇、糠菌唑、环唑醇、噁醚唑、烯唑醇、烯菌灵、氧唑菌、腈苯唑、喹唑菌酮、氟硅唑、粉唑醇、己唑醇、酰胺唑、环戊唑醇、环戊唑菌、腈菌唑、戊菌唑、丙环唑、丙硫菌唑、硅氟唑、戊唑醇、氟醚唑、唑菌醇、三唑酮和戊叉唑菌或其盐或加合物的三唑的安全剂以防治有害真菌的方法。
Description
本发明涉及一种使用选自Mg、Ca、B、Mn、Fe、Co、Zn和Mo的盐和加合物的微量养料作为选自戊环唑(azaconazole)、双苯三唑醇(bitertanol)、糠菌唑(bromoconazole)、环唑醇(cyproconazole)、噁醚唑(difenoconazole)、烯唑醇(diniconazole)、烯菌灵(enilconazole)、氧唑菌(epoxiconazole)、腈苯唑(fenbuconazole)、喹唑菌酮(fluquinconazole)、氟硅唑(flusilazole)、粉唑醇(flutriafol)、己唑醇(hexaconazole)、酰胺唑(imibenconazole)、环戊唑醇(ipconazole)、环戊唑菌(metconazole)、腈菌唑(myclobutanil)、戊菌唑(penconazole)、丙环唑(propiconazole)、丙硫菌唑(prothioconazole)、硅氟唑(simeconazole)、戊唑醇(tebuconazole)、氟醚唑(tetraconazole)、唑菌醇(triadimenol)、三唑酮(triadimefon)和戊叉唑菌(triticonazole)或其盐或加合物的三唑的安全剂以防治有害真菌的方法。
此外，本发明涉及一种使用微量养料与三唑的混合物防治有害真菌的方法和微量养料和三唑在制备这种混合物中的用途，以及包含这些混合物的组合物。
Montford，F.等，Pesticide Science 46(4)，1996，1996，第315-322页公开了当三唑如戊叉唑菌(triticonazole)用于处理种子或作物植物时，可发生对植物生长的负面效果。用戊叉唑菌(triticonazole)处理期间的负面效果可例如为强烈降低的纵向生长。对于作物植物小麦已描述了此效果。
本发明的目的是提供一种消除三唑对于植物生长负面效果，同时具有杀真菌作用的安全剂。
我们已经发现此目的通过开头定义的微量养料作为三唑安全剂以防治有害真菌的方法实现。此外，我们已发现微量养料和三唑可同时，即联合或分开施用。此外，已发现微量养料和三唑可用于制备组合物。
微量养料如金属盐描述于Arnold Finck，Dünger und Düngung，VCHVerlagsgesellschaft mbH，Weinheim，1989中。
含金属的加合物还包括含金属化合物和络合物，且为已知的并且公开如下:
代森锰锌(mancozeb)(US 3 379 610)，
代森锰(maneb)，亚乙基双(二硫代氨基甲酸)锰(US 2 504 404)；
代森联(metiram)，亚乙基双(二硫代氨基甲酸)氨合锌(US 3 248 400)；
甲基代森锌(propineb)，亚丙基双(二硫代氨基甲酸)锌聚合物(BE 611960)；
福美铁(ferbam)，二甲基二硫代氨基甲酸铁(3+)(US 1 972 961)；
福美锌(ziram)，双(二甲基二硫代氨基甲酸)锌；CAS RN[137-30-4]
代森锌(zineb)，亚乙基双(二硫代氨基甲酸)锌(US 2 457 674)；
三唑、它们的制备方法和它们对有害真菌的作用通常为已知的(参见:http://www.hclrss.demon.co.uk/index.html)；它们为市售的。
戊环唑(azaconazole)，1-[[2-(2，4-二氯苯基)-1，3-二氧戊环-2-基]甲基]-1H-1，2，4-三唑CAS RN[50207-31-0]，
双苯三唑醇(bitertanol)，β-([1，1′-联苯基]-4-基氧基)-α-(1，1-二甲基乙基)-1H-1，2，4-三唑-1-乙醇(DE 23 24 020)，
糠菌唑(bromuconazole)，1-[[4-溴-2-(2，4-二氯苯基)四氢-2-呋喃基]甲基]-1H-1，2，4-三唑(Proc.1990 Br.Crop.Prot.Conf.-Pests Dis.第1卷，第459页)，
环唑醇(cyproconazole)，2-(4-氯苯基)-3-环丙基-1-[1，2，4]三唑-1-基丁-2-醇(US 4 664 696)；
噁醚唑(difenoconazole)，1-{2-[2-氯-4-(4-氯苯氧基)苯基]-4-甲基-[1，3]二氧戊环-2-基甲基}-1H-[1，2，4]三唑(GB-A 2 098 607)；
烯唑醇(diniconazole)，(βE)-β-[(2，4-二氯苯基)亚甲基]-α-(1，1-二甲基乙基)-1H-1，2，4-三唑-1-乙醇(Noyaku Kagaku，1983，第8卷，第575页)，
烯菌灵(enilconazole)(烯菌灵(imazalil))，1-[2-(2，4-二氯苯基)-2-(2-丙烯基氧基)乙基]-1H-咪唑(Fruits，1973，第28卷，第545页)；
氧唑菌(epoxiconazole)，(2RS，3SR)-1-[3-(2-氯苯基)-2，3-环氧基-2-(4-氟苯基)丙基]-1H-1，2，4-三唑(EP-A 196 038)；
喹唑菌酮(fluquinconazole)，3-(2，4-二氯苯基)-6-氟-2-[1，2，4]三唑-1-基-3H-喹唑啉-4-酮(Proc.Br.Crop Prot.Conf.-Pests Dis.，5-3，411(1992))；
腈苯唑(fenbuconazole)，α-[2-(4-氯苯基)乙基]-α-苯基-1H-1，2，4-三唑-1-丙腈(Proc.1988Br.Crop Prot.Conf.-Pests Dis.第1卷，第33页)，
氟硅唑(flusilazole)，1-{[双-(4-氟苯基)甲基硅烷基]甲基}-1H-[1，2，4]三唑(Proc.Br.Crop Prot.Conf.-Pests Dis.，1，413(1984))；
粉唑醇(flutriafol)，α-(2-氟苯基)-α-(4-氟苯基)-1H-1，2，4-三唑-1-乙醇(EP 15 756)，
己唑醇(hexaconazole)，2-(2，4-二氯苯基)-1-[1，2，4]三唑-1-基己-2-醇[CAS-RN 79983-71-4]；
酰胺唑(imibenconazole)，(4-氯苯基)甲基N-(2，4-二氯苯基)-1H-1，2，4-三唑-1-乙烷亚氨基硫代盐(Proc.1988 Br.Crop Prot.Conf.-Pests Dis.第2卷，第519页)，
环戊唑醇(ipconazole)，2-[(4-氯苯基)甲基]-5-(1-甲基乙基)-1-(1H-1，2，4-三唑-1-基甲基)环戊醇(EP 267 778)，
环戊唑菌(metconazole)，5-(4-氯苄基)-2，2-二甲基-1-[1，2，4]三唑-1-基甲基环戊醇(GB 857 383)；
腈菌唑(myclobutanil)，2-(4-氯苯基)-2-[1，2，4]三唑-1-基甲基戊腈[CASRN 88671-89-0]；
戊菌唑(penconazole)，1-[2-(2，4-二氯苯基)戊基]-1H-[1，2，4]三唑(Pesticide Manual，第12版(2000)，第712页)；
丙环唑(propiconazole)，1-[[2-(2，4-二氯苯基)-4-丙基-1，3-二氧戊环-2-基]甲基]-1H-1，2，4-三唑(BE 835 579)，
丙硫菌唑(prothioconazole)，2-[2-(1-氯环丙基)-3-(2-氯苯基)-2-羟基丙基]-2，4-二氢-[1，2，4]三唑-3-硫酮(WO 96/16048)；
硅氟唑(simeconazole)，α-(4-氟苯基)-α-[(三甲基甲硅烷基)甲基]-1H-1，2，4-三唑-1-乙醇[CAS RN 149508-90-7]；
三唑酮(triadimefon)，1-(4-氯苯氧基)-3，3-二甲基-1-(1H-1，2，4-三唑-1-基)-2-丁酮；
唑菌醇(triadimenol)，β-(4-氯苯氧基)-α-(1，1-二甲基乙基)-1H-1，2，4-三唑-1-乙醇；
戊唑醇(tebuconazole)，1-(4-氯苯基)-4，4-二甲基-3-[1，2，4]三唑-1-基甲基戊-3-醇(EP-A 40 345)；
氟醚唑(tetraconazole)，1-[2-(2，4-二氯苯基)-3-(1，1，2，2-四氟乙氧基)丙基]-1H-1，2，4-三唑(EP 234 242)，
戊叉唑菌(triticonazole)，(5E)-5-[(4-氯苯基)亚甲基]-2，2-二甲基-1-(1H-1，2，4-三唑-1-基甲基)环戊醇(FR 26 41 277)。
由于其碳原子的碱性性能，化合物II能分别与无机或有机酸和金属离子形成盐或加合物。
无机酸的实例为氢卤酸，例如氟化氢、氯化氢、溴化氢和碘化氢、碳酸、硫酸、磷酸和硝酸。
适合的有机酸例如为甲酸和链烷酸如乙酸、三氟乙酸、三氯乙酸和丙酸，以及羟基乙酸、硫氰酸、乳酸、琥珀酸、柠檬酸、苯甲酸、肉桂酸、草酸、烷基磺酸(具有1-20个碳原子的直链或支化烷基的磺酸)、芳基磺酸或二磺酸(带有1个或2个磺酸基团的芳族基如苯基和萘基)、烷基膦酸(具有1-20个碳原子的直链或支化烷基的膦酸)、芳基膦酸或二膦酸(带有1个或2个磷酸基团的芳族基如苯基和萘基)，其中烷基或芳基可带有其他取代基，例如对甲苯磺酸、水杨酸、对氨基水杨酸、2-苯氧基苯甲酸、2-乙酰氧基苯甲酸等。
适合的金属离子尤其是第二主族元素的离子，尤其是钙和镁，第三和第四主族元素的离子，尤其是铝、锡和铅，以及1-8过渡族元素的离子，尤其是铬、锰、铁、钴、镍、铜、锌等。特别优选第四周期的过渡族元素的金属离子。金属离子可以以它们可呈现的各种化合价存在。
适合的微量养料包括Mg、Ca、Mn、Fe、Co、Zn和Mo的金属阳离子与上述无机或有机酸阴离子的盐或加合物和以H2BO3 -和HBO3 2-金属盐形式的B、硼酸以及四硼酸盐和多硼酸盐的盐。
优选Mg、Ca、Mn和Zn阳离子与阴离子如氯离子、溴离子、硫酸根、碳酸根、碳酸氢根、磷酸根、亚磷酸根、磷酸氢根、亚磷酸氢根、甲酸根和乙酸根的金属盐。另外还有硼酸钠和硼酸钙、四硼酸钠(硼砂)、多硼酸钠和硼酸。
特别优选Mn和Zn阳离子与阴离子如氯离子、溴离子、碳酸根和磷酸根的金属盐和硼酸钠和硼酸钙、四硼酸钠和硼酸。
优选的金属加合物或络合物为代森锰锌(mancozeb)、代森锰(maneb)、代森联(metiram)、福美铁(ferbam)、甲基代森锌(propineb)、福美锌(ziram)和代森锌(zineb)。
特别优选代森锰锌、代森锰、代森联、甲基代森锌、福美锌和代森锌。
尤其优选代森锰锌和代森锰。
优选安全剂与三唑的如下组合。
代森锰锌作为氧唑菌(epoxiconazole)、喹唑菌酮(fluquinconazole)、环戊唑菌(metconazole)、丙硫菌唑(prothioconazole)、戊唑醇(tebuconazole)或戊叉唑菌(triticonazole)的安全剂。
代森锰作为氧唑菌、喹唑菌酮、环戊唑菌、丙硫菌唑、戊唑醇或戊叉唑菌的安全剂。
代森联作为氧唑菌、喹唑菌酮、环戊唑菌、丙硫菌唑、戊唑醇或戊叉唑菌的安全剂。
福美铁作为氧唑菌、喹唑菌酮、环戊唑菌、丙硫菌唑、戊唑醇或戊叉唑菌的安全剂。
代森锌作为氧唑菌、喹唑菌酮、环戊唑菌、丙硫菌唑、戊唑醇或戊叉唑菌的安全剂。
福美锌作为氧唑菌、喹唑菌酮、环戊唑菌、丙硫菌唑、戊唑醇或戊叉唑菌的安全剂。
优选与本发明安全剂组合的如下三唑。
氧唑菌、喹唑菌酮、环戊唑菌、丙硫菌唑、环戊唑菌、戊唑醇和戊叉唑菌。
尤其优选氧唑菌、喹唑菌酮、环戊唑菌、戊唑醇和戊叉唑菌。
另外优选环戊唑菌和戊叉唑菌。
特别优选环戊唑菌。
如开头所述，在许多作物中，用杀真菌剂拌种延缓或降低出苗并且当开始耕种时产生更差的群丛(stand)建立。
使用微量养料与三唑混合物，或同时，即联合或分开使用微量养料和三唑之一的方法特征在于三唑对于植物的负面效果不发生或不明显。另外，混合物对尤其选自子囊菌纲(Ascomycetes)、担子菌纲(Basidiomycetes)、半知菌纲(Deuteromycetes)和Peronosporomycetes(又名卵菌纲(Oomycetes))的宽范围植物病原性真菌具有极好活性。它们中一些内吸有活性并可以在作物保护中用作叶面杀真菌剂，作为杀真菌剂用于拌种，以及用作土壤杀真菌剂。
它们对在各种作物植物如香蕉、棉花、蔬菜品种(例如黄瓜、豆类、西红柿和葫芦科植物)、大麦、禾草、燕麦、咖啡、土豆、玉米、水果品种、稻、黑麦、豆类(如大豆、豌豆、菜豆、扁豆)、葡萄藤、小麦、观赏植物、甘蔗以及大量种子中防治大量真菌尤其重要。
它们可用于通过包括基因方法的栽培而对昆虫或真菌有耐受性的植物。
另外，它们适于防治对藤和它们的根具有活性的葡萄座腔菌(Botryosphaeria)属、柱孢属(Cylindrocarpon)属、葡萄顶枯病菌(Eutypalata)、Neonectria liriodendri和毛韧革菌(Stereum hirsutum)。
它们尤其适于防治如下植物病害:
-蔬菜、油籽油菜、糖用甜菜、水果、稻、大豆和马铃薯(例如早疫链格孢(A.solani)或链格孢(A.alternata))和西红柿(例如早疫链格孢(A.solani)或链格孢(A.alternata))上的链格孢(Alternaria)属，和小麦上的链格孢(Alternaria)属，
-糖用甜菜和蔬菜上的丝囊霉(Aphanomyces)属，
-禾谷类和蔬菜上的壳二孢(Ascochyta)属，例如小麦上的Ascochyta tritici，
-玉米、禾谷类、稻和草坪上的平脐蠕孢(Bipolaris)属和内脐蠕孢(Drechslera)属，例如玉米上的玉蜀黍平脐蠕孢(D.maydis)，
-禾谷类(例如小麦或大麦)上的禾白粉菌(Blumeria graminis)(白粉病)；
-草莓、蔬菜、花卉、葡萄藤和小麦上的灰葡萄孢(Botrytis cinerea)(灰霉病)，
-莴苣上的莴苣盘梗霉(Bremia lactucae)，
-玉米、大豆、稻、糖用甜菜上的尾孢(Cercospora)属，例如大豆上的大豆灰斑病菌(Cercospora sojina)或大豆紫斑病菌(Cercospora kikuchii)、小麦上的多主枝孢菌(cladosporium herbarum)，
-玉米、禾谷类、稻上的旋孢腔菌(Cochliobolus)属(例如禾谷类上的禾旋孢腔菌(Cochliobolus sativus)，稻上的宫部旋孢腔菌(Cochliobolusmiyabeanus))，
-大豆和棉花上的剌盘孢(Colletotricum)属，例如大豆上的炭疽病菌(Colletotrichum truncatum)，
-大豆上的主棒孢菌(Corynespora cassiicola)，
-大豆上的白纹羽束丝菌(Dematophora necatrix)，
-大豆上的大豆茎溃疡病菌(Diaporthe phaseolorum)，
-玉米、禾谷类、稻和草坪上的内脐蠕孢(Drechslera)属、核腔菌(Pyrenophora)属，大麦上(大麦网斑内脐蠕孢(D.teres))和小麦上(D.tritci-repentis)；
-由Phaeoacremonium chlamydosporium、Ph.Aleophilum和Formitiporapunctata(同义词斑孔木层孔菌(Phellinus punctatus))引起的葡萄上的埃斯卡(Esca)；
-葡萄上的痂囊腔菌(Elsinoe ampelina)，
-小麦上的附球菌属(Epicoccum ssp.)，
-玉米上的突脐蠕孢(Exserohilum)属，
-黄瓜上的二孢白粉菌(Erysiphe cichoracearum)和单丝壳白粉菌(Sphaerotheca fuliginea)，
-各种植物上的镰孢霉(Fusarium)属和轮枝孢(Verticillium)属，例如禾谷类(如小麦或大麦)上的禾本科镰孢(F.graminearum)或大刀镰孢(F.culmorum)或例如西红柿上的尖镰孢(F.oxysporum)和大豆上的茄镰孢(Fusarium solani)，
-禾谷类上的禾顶囊壳(Gaeumanomyces graminis)属，
-禾谷类和稻上的赤霉(Gibberella)属(例如稻上的藤仓赤霉(Gibberellafujikuroi))，
-葡萄和其他植物上的围小丛壳菌(Glomerella cingulata)，
-稻上的革兰氏染色配合物(Grain staining complex)；
-葡萄上的Guignardia budwelli，
-玉米和稻上的长蠕孢(Helminthosporium)属；
-葡萄上的褐斑拟棒束孢(Isariopsis clarispora)，
-大豆上的菜豆壳球孢(Macrophomina phaseolina)，
-禾谷类上的Michrodochium nivale；
-大豆上的大豆白粉病菌(Microsphaera diffusa)，
-禾谷类、香蕉和花生上的球腔菌(Mycosphaerella)属，例如小麦上的禾生球腔菌(M.graminicola)或香蕉上的斐济球腔菌(M.fijiensis)，
-卷心菜(例如芸苔霜霉(P.brassicae))、洋葱(例如大葱霜霉(P.destructor))上的霜霉(Peronospora)属，例如大豆上的霜霉病菌(Peronosporamanshurica)，
-大豆上的豆薯层锈菌(Phakopsora pachyrhizi)和山马蟥层锈菌(Phakopsara meibomiae)，
-大豆(例如Phomopsis phaseoli)、向日葵和葡萄(例如葡萄生单轴霉(P.Viticola))上的拟茎点霉(Phomopsis)属，
-不同植物上的疫霉(Phytophthora)属，例如柿子椒上的辣椒疫霉(P.capsici)、大豆上的大豆疫霉病菌(P.megasperma)、马铃薯和西红柿上的致病疫霉(Phytophthora infestans)，
-葡萄藤上的葡萄生单轴霉(Plasmopara viticola)，
-苹果上的苹果白粉病菌(Podosphaera leucotricha)，
-禾谷类(小麦或大麦)上的小麦基腐病菌(Pseudocercosporellaherpotrichoides)，
-啤酒花(例如葎草假霜(P.Humili))和黄瓜(例如古巴假霜霉(P.Cubensis))上的假霜霉(Pseudoperonospora)属，
-葡萄上的Pseudopezicula tracheiphilai，
-不同植物上的柄锈菌(Puccinia)属，例如禾谷类(例如小麦或大麦)上的小麦柄锈菌(P.triticina)、条形柄锈病(P.striformis)、大麦柄锈病(P.hordei)或禾柄锈菌(P.graminis)，或芦笋上的(天门冬属柄锈病(P.asparagi))，-稻上的稻瘟病菌(Pyricularia oryzae)、笹木伏革菌(Corticium sasakii)、帚梗柱孢属(Sarocladium oryzae)、稻叶鞘腐败病(S.attenuatum)、稻叶黑粉菌(Entyloma oryzae)，
-小麦上的小麦褐麦病菌(Pyrenophora tritici-repentis)或大麦上的大麦网斑病菌(Pyrenophora teres)，
-草坪和禾谷类上的稻梨孢菌(Pyricularia grisea)，
-草坪、小麦、稻、玉米、棉花、油籽油菜、向日葵、马铃薯、糖用甜菜、蔬菜和其他植物上的腐霉(Pythium)属(例如终极腐霉菌(P.ultiumum)或瓜果腐霉(P.aphanidermatum))，
-大麦上的Rumularia collo-cygni，
-棉花、稻、土豆、草坪、玉米、油籽油菜、糖用甜菜、蔬菜和其他植物上的丝核菌(Rhizoctonia)属，例如大豆上的立枯丝核病菌(Rhizoctoniasolani)或小麦或大麦上的禾谷丝核菌(Rhizoctonia cerealis)，大麦、黑麦和黑小麦上的黑麦喙孢(Rhynchosporium secalis)，
-油籽油菜和向日葵上的核盘菌(Sclerotinia)属，例如大豆上的核盘菌(Sclerotinia sclerotiorum)或齐整小菌核菌(Sclerotinia rolfsii)，大豆上的Septoria glycine，
-小麦上的小麦壳针孢(Septoria tritici)和颖枯壳多孢(Stagonosporanodorum)，
-葡萄藤上的葡萄钩丝壳(Erysiphe(同义词Uncinula)necator)，
-玉米和草坪上的Setospaeria属，
-玉米上的丝轴黑粉菌(Sphacelotheca reilinia)，
-小麦上的颖枯壳多孢(Stagonospora nodorum)，
-大豆和棉花上的根串珠霉(Thievaliopsis)属，
-禾谷类上的腥黑粉菌(Tilletia)属，
-小麦或大麦上的Typhula incarnata，
-禾谷类、玉米和糖用甜菜上的黑粉菌(Ustilago)属，和
-苹果和梨上的黑星菌(Venturia)属(黑星病)。
微量养料和三唑也可用于在材料(例如木材、纸、油漆分散体、纤维或织物)保护中和储存产品保护中防治有害真菌如拟青霉(Paecilomycesvariotii)。
微量养料和三唑可同时，即一起或分开，或依次施用，在分开施用的情况下，顺序通常对植物生长和防治措施的结果不具有任何影响。
在本发明使用期间，优选使用纯微量养料和三唑，可根据需要向其中加入对有害真菌或其他害虫如昆虫、蜘蛛或线虫有活性的其他化合物，或除草或生长调节活性化合物或肥料。
通常使用微量养料和三唑的混合物。然而，在某种情况下也可有利地使用微量养料和三唑与如果合适的话多种活性组分的混合物，例如微量养料和三唑与其他杀真菌剂的混合物。
微量养料与三唑的混合比(重量比)的选择使得发生所述安全剂作用，例如微量养料:三唑如100:1-1:100，特别是10:1-1:10，例如5:1-1:5，特别是3:1-1:3，优选2:1-1:2。混合物的安全剂作用本身表明三唑对植物生长的负面效果不存在或不明显。
如果需要的话，其他活性组分以20:1-1:20的比加入微量养料和三唑中。
取决于化合物类型和所需效果，所用混合物的施用率，尤其基于农作物面积为5-2000g/ha，优选20-900g/ha，尤其是50-750g/ha。
相应地，微量养料的施用率通常为1-1000g/ha，优选10-900g/ha，尤其是20-750g/ha。
相应地，三唑的施用率通常为1-1000g/ha，优选10-900g/ha，尤其是40-750g/ha。
在种子处理中，所用微量养料与三唑的混合物的施用率通常为1-1000g/100kg种子，优选1-750g/100kg种子，尤其是5-500g/100kg种子。
根据本发明，微量养料与三唑在防治有害真菌的方法中的使用通过在植物播种之前或之后或在植物出苗之前或之后对种子、植物或土壤喷雾或撒粉分开或联合施用微量养料和三唑或微量养料与三唑的混合物而进行。
当使用本发明微量养料和三唑时，可将它们转化成常规配制剂，例如溶液、乳液、悬浮液、粉剂、粉末、糊和颗粒。使用形式取决于特定的意欲目的；在每种情况下，应确保微量养料和三唑精细且均匀地分布。
配制剂以已知方式制备，例如通过将活性化合物与溶剂和/或载体混合而制备，若需要的话使用乳化剂和分散剂。适于该目的的溶剂/助剂主要为:
-水、芳族溶剂(如Solvesso产品、二甲苯)、石蜡(如矿物油馏分)、醇类(如甲醇、丁醇、戊醇、苄醇)、酮类(如环己酮、γ-丁内酯)、吡咯烷酮(NMP、NOP)、乙酸酯(乙二醇二乙酸酯)、二元醇、脂肪酸二甲基酰胺、脂肪酸和脂肪酸酯。原则上还可以使用溶剂混合物。
-载体如磨碎的天然矿物(如高岭土、粘土、滑石、白垩)和磨碎的合成矿物(如高度分散的硅石、硅酸盐)；乳化剂如非离子和阴离子乳化剂(如聚氧乙烯脂肪醇醚、烷基磺酸盐和芳基磺酸盐)以及分散剂如木素亚硫酸盐废液和甲基纤维素。
适用作表面活性剂的有木素磺酸、萘磺酸、苯酚磺酸、二丁基萘磺酸的碱金属盐、碱土金属盐和铵盐，烷基芳基磺酸盐，烷基硫酸盐，烷基磺酸盐，脂肪醇硫酸盐，脂肪酸和硫酸化脂肪醇乙二醇醚，还有磺化萘和萘衍生物与甲醛的缩合物，萘或萘磺酸与苯酚和甲醛的缩合物，聚氧乙烯辛基苯基醚，乙氧基化异辛基酚，辛基酚，壬基酚，烷基苯基聚乙二醇醚，三丁基苯基聚乙二醇醚，三硬脂基苯基聚乙二醇醚，烷基芳基聚醚醇，醇和脂肪醇/氧化乙烯缩合物，乙氧基化蓖麻油，聚氧乙烯烷基醚，乙氧基化聚氧丙烯，月桂醇聚乙二醇醚缩醛，山梨醇酯，木素亚硫酸盐废液和甲基纤维素。
适于制备可直接喷雾溶液、乳液、糊或油分散体的物质为中至高沸点的矿物油馏分如煤油或柴油，还有煤焦油和植物或动物来源的油，脂族、环状和芳族烃如甲苯、二甲苯、石蜡、四氢化萘、烷基化萘或它们的衍生物，甲醇，乙醇，丙醇，丁醇，环己醇，环己酮，异佛尔酮，高度极性溶剂如二甲亚砜、N-甲基吡咯烷酮和水。
粉末、撒播用材料和可撒粉产品可以通过将活性物质与固体载体混合或一起研磨来制备。
颗粒如涂敷颗粒、浸渍颗粒和均质颗粒可以通过使活性化合物与固体载体粘附而制备。固体载体实例为矿土如硅胶、硅酸盐、滑石、高岭土、活性粘土(attaclay)、石灰石、石灰、白垩、红玄武土、黄土、粘土、白云石、硅藻土、硫酸钙、硫酸镁、氧化镁，磨碎的合成材料，肥料如硫酸铵、磷酸铵、硝酸铵、尿素以及植物来源的产品如谷粉、树皮粉、木粉和坚果壳粉，纤维素粉和其它固体载体。
配制剂通常包含0.01-95重量％，优选0.1-90重量％微量养料和三唑。微量养料和三唑以90-100％，优选95-100％的纯度(根据NMR谱)使用。
下列为配制剂实例:
1.用水稀释的产品
A)水溶性浓缩物(SL)
将10重量份本发明微量养料和三唑溶于90重量份水或水溶性溶剂中。作为选择，加入湿润剂或其它助剂。活性化合物经水稀释溶解。这样得到具有10重量％活性化合物含量的配制剂。
B)分散性浓缩物(DC)
将20重量份本发明微量养料和三唑随着加入10重量份分散剂如聚乙烯基吡咯烷酮而溶于70重量份环己酮中。用水稀释得到分散体。活性化合物含量为20重量％。
C)可乳化浓缩物(EC)
将15重量份本发明微量养料和三唑随着加入十二烷基苯磺酸钙和蓖麻油乙氧基化物(每种情况下5重量份)而溶于75重量份二甲苯中。用水稀释得到乳液。配制剂的活性化合物含量为15重量％。
D)乳液(EW、EO)
将25重量份本发明微量养料和三唑随着加入十二烷基苯磺酸钙和蓖麻油乙氧基化物(每种情况下5重量份)而溶于35重量份二甲苯中。通过乳化机(例如Ultraturrax)将该混合物引入30重量份水中并制成均匀乳液。用水稀释得到乳液。配制剂的活性化合物含量为25重量％。
E)悬浮液(SC、OD)
在搅拌球磨机中，将20重量份本发明微量养料和三唑随着加入10重量份分散剂和润湿剂和70重量份水或有机溶剂而粉碎以得到细活性化合物悬浮液。用水稀释得到活性化合物的稳定悬浮液。配制剂中活性化合物含量为20重量％。
F)水分散性颗粒和水溶性颗粒(WG、SG)
将50重量份本发明微量养料和三唑随着加入50重量份分散剂和润湿剂而精细磨碎并通过技术应用(例如挤出机、喷雾塔、流化床)而制得水分散性或水溶性颗粒。用水稀释得到活性化合物的稳定分散体或溶液。配制剂的活性化合物含量为50重量％。
G)水分散性和水溶性粉末(WP、SP)
将75重量份本发明微量养料和三唑在转子-定子研磨机中随着加入25重量份分散剂、润湿剂和硅胶而磨碎。用水稀释得到活性化合物的稳定分散体或溶液。配制剂的活性化合物含量为75重量％。
2.不经稀释而施用的产品
H)可撒粉粉末(DP)
将5重量份本发明微量养料和三唑细碎研磨并与95重量份的细碎高岭土充分混合。这得到活性化合物含量为5重量％的可撒粉产品。
J)颗粒(GR、FG、GG、MG)
将0.5重量份本发明微量养料和三唑细碎研磨并结合99.5重量份载体。现行方法是挤出、喷雾干燥或流化床方法。这得到活性化合物含量为0.5重量％的不经稀释而施用的颗粒。
K)ULV溶液(UL)
将10重量份本发明微量养料和三唑溶于90重量份有机溶剂如二甲苯中。这得到活性化合物含量为10重量％的不经稀释而施用的产物。
微量养料和三唑可以直接、以其配制剂形式或由其制备的使用形式，例如可直接喷雾溶液、粉末、悬浮液或分散体、乳液、油分散体、糊、可撒粉产品、撒播用材料或颗粒形式，借助喷雾、雾化、撒粉、撒播或浇灌而使用。使用形式完全取决于意欲的目的；它们意欲在每种情况下确保本发明活性化合物的最佳可能分布。
含水使用形式可通过加入水由乳液浓缩物、糊或可湿性粉末(可喷雾粉末、油分散体)制备。为制备乳液、糊或油分散体，可借助湿润剂、增粘剂、分散剂或乳化剂将微量养料和三唑直接或溶于油或溶剂中后在水中均化。然而，也可制备包含微量养料和三唑、湿润剂、增粘剂、分散剂或乳化剂和如果合适的话溶剂或油的浓缩物且这种浓缩物适于用水稀释。
即用制剂中微量养料和三唑的浓度可在相对宽范围内变化。通常为0.0001-10％，优选0.01-1％。
微量养料和三唑也可成功用于超低容量法(ULV)，其中可以施用包含超过95重量％微量养料和三唑的配制剂，或甚至施用不含添加剂的微量养料和三唑。
可将各种类型的油、湿润剂或辅助剂加入微量养料和三唑中，甚至如果合适的话，恰在紧邻使用前加入(桶混合)。这些试剂通常与本发明组合物以1:100-100:1，优选1:10-10:1的重量比混合。
微量养料和三唑或混合物或对应的配制剂通过用杀真菌有效量的混合物，或在分开施用的情况下微量养料和三唑处理有害真菌或待保护以防它们的植物、种子、土壤、区域、材料或空间而施用。施用可以在有害真菌侵染之前或之后进行。
微量养料和三唑的安全剂作用通过以下试验证实。
将种子单独用微量养料和三唑或用微量养料与三唑的混合物处理，然后观察植物的发展。当使用混合物时，在单独施用的情况下一种或两种混合伙伴的负面效果，如果有的话以降低的水平观察到。
试验1
测试大豆植物的植物毒性
将几种大豆在温室中在约93F度下种植6周直至它们达到约5三叶的大小。然后将它们用环戊唑菌(Caramba)、代森锰锌(Fore(Dow)80DF)的商业配制剂和它们的混合物以给定比率喷雾。4周以后以％中间叶的叶面积萎黄率(chlorosis)评价植物损害。
变种GH3946
| 萎黄率(％叶面积) |
| 未处理 | 0 | |
| 环戊唑菌 | 100g/ha | 20 |
| 环戊唑菌&代森锰锌 | 100g/ha & 2.24kg/ha | 10 |
变种USG 7443
| 萎黄率(％叶面积) | ||
| 未处理 | 0 | |
| 环戊唑菌 | 100g/ha | 5 |
| 环戊唑菌&代森锰锌 | 100g/ha & 2.24kg/ha | 0 |
变种DKB 36-52
| 萎黄率(％叶面积) | ||
| 未处理 | 0 | |
| 环戊唑菌 | 100g/ha | 10 |
| 环戊唑菌&代森锰锌 | 100g/ha & 2.24kg/ha | 3 |
试验2
测试大豆植物的植物毒性
将几种大豆在温室中在约93F度下种植6周直至它们达到约5三小叶的大小。然后将它们用环戊唑菌(Caramba)、代森锰锌(Fore(Dow)80 DF)的商业配制剂和它们的混合物以给定比率喷雾。4周以后以％中间叶的叶面积坏死率评价植物损害。
变种RC 3624
| 坏死率(％叶面积) | ||
| 未处理 | 0 | |
| 环戊唑菌 | 100g/ha | 9 |
| 环戊唑菌&代森锰锌 | 100g/ha 2.24kg/ha | 1 |
变种DKB 38-52
| 坏死率(％叶面积) | ||
| 未处理 | 0 | |
| 环戊唑菌 | 100g/ha | 7 |
| 环戊唑菌&代森锰锌 | 100g/ha & 2.24kg/ha | 1 |
Claims (12)
1.一种使用选自Mg、Ca、B、Mn、Fe、Co、Zn和Mo的盐和加合物的微量养料作为选自戊环唑、双苯三唑醇、糠菌唑、环唑醇、噁醚唑、烯唑醇、烯菌灵、氧唑菌、腈苯唑、喹唑菌酮、氟硅唑、粉唑醇、己唑醇、酰胺唑、环戊唑醇、环戊唑菌、腈菌唑、戊菌唑、丙环唑、丙硫菌唑、硅氟唑、戊唑醇、氟醚唑、唑菌醇、三唑酮和戊叉唑菌或其盐或加合物的三唑的安全剂以防治有害真菌的方法。
2.根据权利要求1的方法，其中所述微量养料选自代森锰锌、代森锰、代森联、福美铁、甲基代森锌、代森锌和福美锌。
3.根据权利要求2的方法，其中所述微量养料选自代森锰锌、代森锰、代森联、甲基代森锌、代森锌和福美锌。
4.根据权利要求3的方法，其中所述微量养料选自代森锰锌和代森锰。
5.根据权利要求1的方法，其中所述三唑选自氧唑菌、喹唑菌酮、环戊唑菌、丙硫菌唑、戊唑醇和戊叉唑菌。
6.根据权利要求1的方法，其中微量养料与三唑的重量比为100:1-1:100。
7.根据权利要求1的方法，其包括用所述微量养料和所述三唑处理真菌、它们的栖息地或待保护以防它们的植物、种子、土壤、区域、材料或空间。
8.根据权利要求7的方法，其中根据权利要求1的微量养料和三唑同时，即一起或分开，或依次施用。
9.根据权利要求7或8的方法，其中根据权利要求1的微量养料和三唑以5-2000g/ha的量施用。
10.根据权利要求7或8的方法，其中根据权利要求1的微量养料和三唑以1-1000g每100kg种子的量施用。
11.一种使用微量养料和三唑制备适于防治有害真菌的组合物的方法。
12.根据权利要求11的方法，其中除微量养料和三唑外，所述组合物还包含固体或液体载体。
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| CN105764342B (zh) * | 2013-09-20 | 2021-07-02 | 拜耳作物科学股份公司 | 活性化合物结合物 |
| BR102014031252A2 (pt) * | 2014-12-12 | 2016-06-14 | Upl Do Brasil Ind E Com De Insumos Agropecuarios S A | método para reduzir a fitotoxicidade de fungicidas |
| BR102017010745A2 (pt) * | 2016-05-24 | 2018-02-27 | Adama Makhteshim Ltd. | Formulação líquida de óleo fungicida, suspoemulsão fungicida e uso da formulação líquida de óleo fungicida |
| JOP20190228A1 (ar) * | 2017-03-31 | 2019-09-30 | Mosaic Co | أسمدة تحتوي على مصادر سريعة و بطيئة لاطلاق البورون |
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| US1972961A (en) * | 1931-05-26 | 1934-09-11 | Du Pont | Disinfectant |
| US2457674A (en) * | 1944-12-02 | 1948-12-28 | Rohm & Haas | Fungicidal compositions |
| US2504404A (en) * | 1946-06-12 | 1950-04-18 | Du Pont | Manganous ethylene bis-dithiocarbamate and fungicidal compositions containing same |
| DE1076434B (de) * | 1957-08-17 | 1960-02-25 | Badische Anilin- S. Soda-Fabrik Aktiengesellschaft, Ludwigshafen/Rhein | Fungizide Mittel |
| BE617407A (zh) * | 1961-05-09 | |||
| AU554648B2 (en) * | 1982-05-27 | 1986-08-28 | Sumitomo Chemical Company, Limited | Fungicidal composition comprising |
| DE3221700A1 (de) * | 1982-06-09 | 1983-12-15 | Bayer Ag, 5090 Leverkusen | Pflanzenwuchshemmende mittel |
| US4933166A (en) * | 1987-10-13 | 1990-06-12 | American Cyanamid Company | Method of safening fungicidal compositions |
| FR2663195A1 (fr) * | 1990-06-13 | 1991-12-20 | Rhone Poulenc Agrochimie | Procede de traitement fongicide foliaire au moyen d'un triazole et composition fongicide pour mettre en óoeuvre le procede. |
| FR2675663A1 (fr) * | 1991-04-24 | 1992-10-30 | Sandoz Agro | Procede ameliore pour combattre les mildious des vegetaux. |
| DE19716257A1 (de) * | 1997-04-18 | 1998-10-22 | Bayer Ag | Fungizide Wirkstoffkombination |
| US7927616B2 (en) * | 2004-01-16 | 2011-04-19 | Thomas T. Yamashita | Pesticide compositions and methods for their use |
-
2007
- 2007-02-07 US US12/223,879 patent/US20090048319A1/en not_active Abandoned
- 2007-02-07 CN CNA2007800055337A patent/CN101384173A/zh active Pending
- 2007-02-07 BR BRPI0707651-7A patent/BRPI0707651A2/pt not_active IP Right Cessation
- 2007-02-07 CA CA002640001A patent/CA2640001A1/en not_active Abandoned
- 2007-02-07 KR KR1020087022351A patent/KR20080095285A/ko not_active Application Discontinuation
- 2007-02-07 EP EP07704411A patent/EP1986496A1/en not_active Withdrawn
- 2007-02-07 EA EA200801774A patent/EA200801774A1/ru unknown
- 2007-02-07 AU AU2007216558A patent/AU2007216558A1/en not_active Abandoned
- 2007-02-07 WO PCT/EP2007/051153 patent/WO2007093535A1/en active Application Filing
- 2007-02-07 JP JP2008553756A patent/JP2009526772A/ja not_active Withdrawn
- 2007-02-13 TW TW096105330A patent/TW200800024A/zh unknown
- 2007-02-13 AR ARP070100611A patent/AR059485A1/es not_active Application Discontinuation
- 2007-02-13 PE PE2007000152A patent/PE20071268A1/es not_active Application Discontinuation
-
2008
- 2008-07-22 IL IL192958A patent/IL192958A0/en unknown
- 2008-08-04 EC EC2008008661A patent/ECSP088661A/es unknown
- 2008-08-21 CR CR10232A patent/CR10232A/es unknown
- 2008-09-10 ZA ZA200807785A patent/ZA200807785B/xx unknown
- 2008-09-10 MA MA31224A patent/MA30270B1/fr unknown
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102334490A (zh) * | 2010-07-23 | 2012-02-01 | 青岛奥迪斯生物科技有限公司 | 一种含有代森锰锌和环丙唑醇的高效杀菌组合物 |
| CN101971839A (zh) * | 2010-11-21 | 2011-02-16 | 陕西美邦农药有限公司 | 一种含环唑醇的杀菌组合物 |
| CN101971840A (zh) * | 2010-11-22 | 2011-02-16 | 陕西美邦农药有限公司 | 一种含环唑醇与代森联的杀菌组合物 |
| CN102027956A (zh) * | 2011-01-07 | 2011-04-27 | 陕西美邦农药有限公司 | 一种含联苯三唑醇与硫代氨基甲酸酯类的杀菌组合物 |
| CN102047904A (zh) * | 2011-01-08 | 2011-05-11 | 陕西美邦农药有限公司 | 一种含联苯三唑醇与三唑类化合物的杀菌组合物 |
| CN102047904B (zh) * | 2011-01-08 | 2014-06-18 | 陕西美邦农药有限公司 | 一种含联苯三唑醇与三唑类化合物的杀菌组合物 |
| CN102057930A (zh) * | 2011-01-24 | 2011-05-18 | 陕西美邦农药有限公司 | 一种含有腈苯唑与硫代氨基甲酸酯类化合物的杀菌组合物 |
| CN102057930B (zh) * | 2011-01-24 | 2014-03-19 | 陕西美邦农药有限公司 | 一种含有腈苯唑与硫代氨基甲酸酯类化合物的杀菌组合物 |
| CN102067859A (zh) * | 2011-02-19 | 2011-05-25 | 陕西美邦农药有限公司 | 一种含有种菌唑与硫代氨基甲酸酯类化合物的杀菌组合物 |
| CN103957703A (zh) * | 2011-11-14 | 2014-07-30 | 江苏龙灯化学有限公司 | 处理真菌感染的方法、杀真菌组合物及其用途 |
| TWI622350B (zh) * | 2011-11-14 | 2018-05-01 | 龍燈農業化工國際有限公司 | 處理真菌感染的方法－殺菌組合物及其用途 |
| CN108849888A (zh) * | 2011-11-14 | 2018-11-23 | 江苏龙灯化学有限公司 | 处理真菌感染的方法、杀真菌组合物及其用途 |
| CN108849888B (zh) * | 2011-11-14 | 2022-05-03 | 江苏龙灯化学有限公司 | 处理真菌感染的方法、杀真菌组合物及其用途 |
| CN107353080A (zh) * | 2017-06-30 | 2017-11-17 | 陕西标正作物科学有限公司 | 含有丙硫菌唑的药肥颗粒剂及应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2640001A1 (en) | 2007-08-23 |
| EP1986496A1 (en) | 2008-11-05 |
| JP2009526772A (ja) | 2009-07-23 |
| TW200800024A (en) | 2008-01-01 |
| PE20071268A1 (es) | 2008-03-02 |
| IL192958A0 (en) | 2009-02-11 |
| AR059485A1 (es) | 2008-04-09 |
| US20090048319A1 (en) | 2009-02-19 |
| ZA200807785B (en) | 2009-11-25 |
| KR20080095285A (ko) | 2008-10-28 |
| EA200801774A1 (ru) | 2009-02-27 |
| ECSP088661A (es) | 2008-09-29 |
| AU2007216558A1 (en) | 2007-08-23 |
| BRPI0707651A2 (pt) | 2011-05-10 |
| WO2007093535A1 (en) | 2007-08-23 |
| CR10232A (es) | 2008-09-22 |
| MA30270B1 (fr) | 2009-03-02 |
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