CN101348500B - 一种双酚a双(二苯基磷酸酯)的制备方法 - Google Patents
一种双酚a双(二苯基磷酸酯)的制备方法 Download PDFInfo
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- CN101348500B CN101348500B CN2008101392419A CN200810139241A CN101348500B CN 101348500 B CN101348500 B CN 101348500B CN 2008101392419 A CN2008101392419 A CN 2008101392419A CN 200810139241 A CN200810139241 A CN 200810139241A CN 101348500 B CN101348500 B CN 101348500B
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- Prior art keywords
- dihydroxyphenyl propane
- pocl3
- preparation
- diphenyl phosphoester
- phenol
- Prior art date
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- 235000010290 biphenyl Nutrition 0.000 title claims description 18
- 239000004305 biphenyl Substances 0.000 title claims description 18
- 125000006267 biphenyl group Chemical group 0.000 title claims description 18
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 title claims description 18
- 238000002360 preparation method Methods 0.000 title claims description 14
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 title abstract 8
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 claims abstract description 78
- 238000006243 chemical reaction Methods 0.000 claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 22
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002841 Lewis acid Substances 0.000 claims abstract description 8
- 150000007517 lewis acids Chemical class 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 238000005406 washing Methods 0.000 claims abstract description 5
- 238000010521 absorption reaction Methods 0.000 claims abstract description 4
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 42
- 229910019213 POCl3 Inorganic materials 0.000 claims description 35
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 32
- 229910052757 nitrogen Inorganic materials 0.000 claims description 16
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 12
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 11
- 238000010792 warming Methods 0.000 claims description 8
- 230000035484 reaction time Effects 0.000 claims description 7
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 5
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 238000004821 distillation Methods 0.000 claims description 4
- 238000007701 flash-distillation Methods 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 8
- 238000009835 boiling Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229940106691 bisphenol a Drugs 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- -1 dichloro SULPHOSUCCINIC ACID ESTER Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000004128 high performance liquid chromatography Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229920002449 FKM Polymers 0.000 description 1
- 229920004935 Trevira® Polymers 0.000 description 1
- BHIIGRBMZRSDRI-UHFFFAOYSA-N [chloro(phenoxy)phosphoryl]oxybenzene Chemical compound C=1C=CC=CC=1OP(=O)(Cl)OC1=CC=CC=C1 BHIIGRBMZRSDRI-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- NESLWCLHZZISNB-UHFFFAOYSA-M sodium phenolate Chemical compound [Na+].[O-]C1=CC=CC=C1 NESLWCLHZZISNB-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Abstract
Description
Claims (9)
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CN2008101392419A CN101348500B (zh) | 2008-08-19 | 2008-08-19 | 一种双酚a双(二苯基磷酸酯)的制备方法 |
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CN2008101392419A CN101348500B (zh) | 2008-08-19 | 2008-08-19 | 一种双酚a双(二苯基磷酸酯)的制备方法 |
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CN101348500A CN101348500A (zh) | 2009-01-21 |
CN101348500B true CN101348500B (zh) | 2012-02-22 |
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Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101831308A (zh) * | 2010-04-19 | 2010-09-15 | 江苏大明科技有限公司 | 一种高分子量固体磷酸酯阻燃剂及其制备方法和应用 |
CN105061497A (zh) * | 2015-08-12 | 2015-11-18 | 中国科学院兰州化学物理研究所 | 一种双酚af基磷酸酯类化合物及其制备方法和应用 |
CN106496264B (zh) * | 2016-09-27 | 2017-10-10 | 浙江万盛股份有限公司 | 一种双酚a‑双(二苯基磷酸酯)的连续化制备方法 |
CN106699805B (zh) * | 2016-12-15 | 2019-02-01 | 衢州普信新材料有限公司 | 一种双酚a双(二苯基磷酸酯)的制备方法 |
CN108558942A (zh) * | 2018-04-03 | 2018-09-21 | 吉林市银联科技有限公司 | 一种双酚单二苯基亚磷酸酯化合物及制备方法 |
CN111662530A (zh) * | 2019-03-07 | 2020-09-15 | 华东理工大学华昌聚合物有限公司 | 一种预浸料用无卤阻燃的环氧树脂体系及其制备方法 |
CN111205318A (zh) * | 2020-01-10 | 2020-05-29 | 江苏雅克科技股份有限公司 | 一种非均相催化合成双酚a-双(二苯基磷酸酯)的方法 |
CN112409404B (zh) | 2020-12-07 | 2022-08-09 | 浙江万盛股份有限公司 | 一种高纯双酚a-双(二苯基磷酸酯)的连续工业化生产方法 |
CN114907400B (zh) * | 2022-05-07 | 2023-12-19 | 万华化学集团股份有限公司 | 一种bdp中间体的制备工艺 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6031035A (en) * | 1998-02-13 | 2000-02-29 | Great Lakes Chemical Corporation | Process for making and using bisaryl diphosphates |
CN1355808A (zh) * | 1999-06-11 | 2002-06-26 | 阿尔伯麦尔公司 | 基于双酚a双(磷酸二苯酯)的阻燃剂 |
CN1361786A (zh) * | 1999-06-28 | 2002-07-31 | 大八化学工业株式会社 | 制备缩聚磷酸酯的方法 |
CN1367788A (zh) * | 1999-07-27 | 2002-09-04 | 大八化学工业株式会社 | 制备缩合磷酸酯的方法 |
-
2008
- 2008-08-19 CN CN2008101392419A patent/CN101348500B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6031035A (en) * | 1998-02-13 | 2000-02-29 | Great Lakes Chemical Corporation | Process for making and using bisaryl diphosphates |
CN1355808A (zh) * | 1999-06-11 | 2002-06-26 | 阿尔伯麦尔公司 | 基于双酚a双(磷酸二苯酯)的阻燃剂 |
CN1361786A (zh) * | 1999-06-28 | 2002-07-31 | 大八化学工业株式会社 | 制备缩聚磷酸酯的方法 |
CN1367788A (zh) * | 1999-07-27 | 2002-09-04 | 大八化学工业株式会社 | 制备缩合磷酸酯的方法 |
Non-Patent Citations (2)
Title |
---|
卢林刚 等.阻燃剂双酚-A双(磷酸二苯酯)的合成.《精细化工中间体》.2007,第7卷(第4期),59-62. * |
姜丹蕾 等.阻燃剂BDP的合成及应用研究.《塑料助剂》.2007,(第1期),21-24. * |
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CN101348500A (zh) | 2009-01-21 |
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Address after: 262714 west of Yanglin Road north of Donghai Road, Yangkou Town, Shouguang City, Weifang City, Shandong Province Patentee after: SHANDONG MORIS TECHNOLOGY Co.,Ltd. Address before: 262714 Bohai chemical industry park, Shouguang City, Shandong Province Patentee before: SHANDONG MORIS CHEMICAL Co.,Ltd. |
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Effective date of registration: 20220207 Address after: 262700 Bohai Industrial Park, Yangkou Town, Shouguang City, Weifang City, Shandong Province Patentee after: SHANDONG SUNRIS CO.,LTD. Address before: 262714 west of Yanglin Road north of Donghai Road, Yangkou Town, Shouguang City, Weifang City, Shandong Province Patentee before: SHANDONG MORIS TECHNOLOGY Co.,Ltd. |
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Address after: 262714 Yangkou Chemical Industrial Park, Shouguang City, Weifang City, Shandong Province (West of Yanglin road and north of Donghai Road) Patentee after: Shandong XURUI New Material Co.,Ltd. Address before: 262700 Bohai Industrial Park, Yangkou Town, Shouguang City, Weifang City, Shandong Province Patentee before: SHANDONG SUNRIS CO.,LTD. |
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Denomination of invention: A preparation method of bisphenol A bis (diphenyl phosphate) Effective date of registration: 20230815 Granted publication date: 20120222 Pledgee: Zhejiang Commercial Bank Co.,Ltd. Weifang branch Pledgor: Shandong XURUI New Material Co.,Ltd. Registration number: Y2023980052362 |
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