CN101343202B - Composite type micro-element liquid foliage fertilizer and preparation thereof - Google Patents
Composite type micro-element liquid foliage fertilizer and preparation thereof Download PDFInfo
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- CN101343202B CN101343202B CN2008100291567A CN200810029156A CN101343202B CN 101343202 B CN101343202 B CN 101343202B CN 2008100291567 A CN2008100291567 A CN 2008100291567A CN 200810029156 A CN200810029156 A CN 200810029156A CN 101343202 B CN101343202 B CN 101343202B
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- 239000007788 liquid Substances 0.000 title claims abstract description 42
- 239000003337 fertilizer Substances 0.000 title claims abstract description 34
- 239000002131 composite material Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000011701 zinc Substances 0.000 claims abstract description 18
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 13
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004615 ingredient Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 11
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 11
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 claims description 11
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 claims description 11
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 10
- 229930195725 Mannitol Natural products 0.000 claims description 10
- 235000010355 mannitol Nutrition 0.000 claims description 10
- 239000000594 mannitol Substances 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 9
- 235000005979 Citrus limon Nutrition 0.000 claims description 9
- 235000000177 Indigofera tinctoria Nutrition 0.000 claims description 9
- 229940022663 acetate Drugs 0.000 claims description 9
- 235000013305 food Nutrition 0.000 claims description 9
- 229940013688 formic acid Drugs 0.000 claims description 9
- 235000019253 formic acid Nutrition 0.000 claims description 9
- 229940097275 indigo Drugs 0.000 claims description 9
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 claims description 9
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 claims description 9
- 235000012141 vanillin Nutrition 0.000 claims description 9
- 229960004217 benzyl alcohol Drugs 0.000 claims description 8
- 239000013543 active substance Substances 0.000 claims description 6
- SFBHPFQSSDCYSL-UHFFFAOYSA-N n,n-dimethyltetradecan-1-amine Chemical compound CCCCCCCCCCCCCCN(C)C SFBHPFQSSDCYSL-UHFFFAOYSA-N 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 6
- BPTQPROSVJPWNL-UHFFFAOYSA-N [Na].[Na].C(C)NCC Chemical compound [Na].[Na].C(C)NCC BPTQPROSVJPWNL-UHFFFAOYSA-N 0.000 claims description 5
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 claims description 5
- ISPYRSDWRDQNSW-UHFFFAOYSA-L manganese(II) sulfate monohydrate Chemical compound O.[Mn+2].[O-]S([O-])(=O)=O ISPYRSDWRDQNSW-UHFFFAOYSA-L 0.000 claims description 5
- NHLUVTZJQOJKCC-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCN(C)C NHLUVTZJQOJKCC-UHFFFAOYSA-N 0.000 claims description 5
- 239000012466 permeate Substances 0.000 claims description 5
- 235000013599 spices Nutrition 0.000 claims description 5
- 230000000050 nutritive effect Effects 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims description 3
- 210000005053 lamin Anatomy 0.000 claims description 3
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 3
- 229960001855 mannitol Drugs 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 230000001954 sterilising effect Effects 0.000 claims description 3
- 238000004659 sterilization and disinfection Methods 0.000 claims description 3
- 229940117960 vanillin Drugs 0.000 claims description 3
- 244000248349 Citrus limon Species 0.000 claims 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract description 13
- 229910052796 boron Inorganic materials 0.000 abstract description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 11
- 229910052802 copper Inorganic materials 0.000 abstract description 11
- 239000010949 copper Substances 0.000 abstract description 11
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract description 9
- 235000015097 nutrients Nutrition 0.000 abstract description 7
- 235000016709 nutrition Nutrition 0.000 abstract description 3
- 230000002335 preservative effect Effects 0.000 abstract description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 239000006184 cosolvent Substances 0.000 abstract 1
- 230000000149 penetrating effect Effects 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 235000013399 edible fruits Nutrition 0.000 description 18
- 230000000694 effects Effects 0.000 description 8
- 239000011573 trace mineral Substances 0.000 description 8
- 235000013619 trace mineral Nutrition 0.000 description 8
- 244000131522 Citrus pyriformis Species 0.000 description 6
- 230000012010 growth Effects 0.000 description 5
- 235000013339 cereals Nutrition 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 240000007594 Oryza sativa Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
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- 230000018109 developmental process Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 210000000056 organ Anatomy 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000001850 reproductive effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
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- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000007914 freezing tolerance Effects 0.000 description 1
- 230000005078 fruit development Effects 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
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- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a composite microelement liquid foliar fertilizer, comprising a nutritional ingredient and an auxiliary concentration ingredient; the nutritional ingredient consists of sulfate and polymerizing sodium borate salt; and the auxiliary concentration ingredient is composed of a preservative, a cosolvent, a penetrating agent, a bactericide, a surface active agent and other supplementary materials. The invention meanwhile provides a simple, easy and low-cost preparation method of the foliar fertilizer. The composite microelement liquid foliar fertilizer has both good stability and unfolding property, and can provide enough zinc, manganese, copper and boron nutrients for crops in the meanwhile, all elements interact with one another, crops can absorb the nutrients rapidly, and the nutrient utilization rate is high. The liquid foliar fertilizer has rather low costs, and can save fertilizer and labor costs for peasants.
Description
Technical field
The invention belongs to field of agricultural production technologies, be specifically related to be applied to a kind of composite type micro-element liquid foliage fertilizer of fruit tree.
Background technology
As everyone knows, in the process of growth of crop, trace element zinc, manganese, copper, boron play an important role, and zinc, manganese, copper movability in making object is little, and boron is the difficult element that moves.Zinc plays an important role to promoting crop reproductive development and the quality that improves resistance and fruit.Manganese is that crop carries out the indispensable participant of photosynthesis, and the activity through regulatory enzyme promotes nitrate salt to be transformed into ammonium nitrogen, improves the freezing tolerance of crop.Copper has stabilization to chlorophyll and other pigments, can prevent that pigment is damaged, and copper can also promote the growth of floral organ, thereby improves setting percentage.Boron plays an important role to the formation of fruit yield and the raising of fruit quality.Especially in bloom early stage, bear fruit phase and the fruit expanding period of fruit tree, the boron important that just seems.Boron promotes building up of crop reproductive organ and grows, and improves setting percentage, reduces malformed fruit, and the fruit growth size evenly can also improve output simultaneously.In case do to lack wherein a kind of trace element in the object, all can cause corresponding physiological disease, thereby influence the normal growth of crop.This shows that zinc, manganese, copper and boron play an important role in the growth and development process of crop, is the essential trace element of plant growth.Can fruit tree well absorb and make good use of zinc, manganese, copper and boron is the important factor that influences fruit yield height and quality quality, and this also is the emphasis of fruit tree leaves leaven research.
The most microelement foliage fertilizer that provides in the market all is a single-element fertilizer, two kinds or more than three kinds all seldom, four kinds are little especially; Though can play certain effect through using single trace element fertilizer, the assimilated efficiency of element is not high, loses time and the labour yet; And the high-quality microelement foliage fertilizer that the peasant uses now is nearly all from external import; Because factor affecting such as its raw material and technology cost an arm and a leg, fertilizer cost is also higher.Because the limitation of technology, the microelement foliage fertilizer overwhelming majority that domestic manufacturer produces is a solid form, and liquid form few can not adapt to pressing for of China's planting fruit trees industry.
Summary of the invention
The objective of the invention is to overcome the deficiency of prior art, the composite type micro-element liquid type foliar nutrient of a kind of high-quality and efficient zinc, manganese, copper, boron is provided for crop.
A further object of the invention provides the preparation method of said composite type micro-element liquid foliage fertilizer.
The object of the invention is achieved through following technical scheme:
A kind of composite type micro-element liquid foliage fertilizer is provided, comprises nutritive ingredient and auxiliary concentration components; Said nutritive ingredient is made up of vitriol and polymerization boric acid sodium salt; Said auxiliary concentration components is made up of sanitas, solubility promoter, permeate agent, sterilant, tensio-active agent and other auxiliary materials.
The preferred Zinc vitriol of said vitriol, Manganous sulfate monohydrate, Salzburg vitriol and tetraacethyl diethylamine disodium.
Said sanitas optimization citric acid; The preferred Ucar 35 of said solubility promoter, phenylcarbinol, formic acid, acetate and diethylene glycol monoethyl ether; The preferred N.F,USP MANNITOL of said permeate agent; The preferred N of said sterilization and tensio-active agent, N-dimethyl-tetradecy lamine and N, N-dimethyl-cetylamine.
Said other auxiliary materials comprise spices, pigment, tinting material and water.The preferred vanillin food grade,1000.000000ine mesh of said spices; The indigo of said pigment preferred 1% and 1% lemon yellow; The preferred diethylene glycol monoethyl ether of said tinting material.
The present invention provides a preferred version of said composite type micro-element liquid foliage fertilizer moity, is made up of according to said parts by weight following component:
28 parts of Zinc vitriols;
15 parts of Manganous sulfate monohydrates;
8 parts of Salzburg vitriols;
3 parts of tetraacethyl diethylamine disodiums;
4 parts of polymerization boric acid sodium salts;
0.36 part of Hydrocerol A;
0.5 part in formic acid;
0.5 part of acetate;
2.2 parts of Ucar 35;
0.5 part in N.F,USP MANNITOL;
1.0 parts of phenylcarbinols;
0.36 part of diethylene glycol monoethyl ether;
1.2 parts of vanillin food grade,1000.000000ine meshs;
N, 1.5 parts of N-dimethyl-tetradecy lamines;
N, 1.4 parts of N-dimethyl-cetylamines;
0.1 part of 1% indigo;
1% lemon yellow 0.15 part;
Water surplus.
The present invention provides the preparation method of said composite type micro-element liquid foliage fertilizer simultaneously, specifically may further comprise the steps:
(1) earlier water is added reaction kettle, add tetraacethyl diethylamine disodium then and stir, add Zinc vitriol more successively until dissolving fully; Manganous sulfate monohydrate; Salzburg vitriol, polymerization boric acid sodium salt adds after waiting a kind of material of adding to dissolve fully a kind of down again; Treat after four kinds of salt dissolve fully solution to be filtered, form A liquid;
(2) will assist concentration components according to Hydrocerol A, formic acid, acetate, Ucar 35, N.F,USP MANNITOL, phenylcarbinol, diethylene glycol monoethyl ether, vanillin food grade,1000.000000ine mesh, N, N-dimethyl-tetradecy lamine, N, the order of N-dimethyl-cetylamine is dissolved in the water successively, forms B liquid;
(3) B liquid is slowly poured in the A liquid, the limit bevelling stirs, and stirs 15 minutes, mixedly can form C liquid after even;
(4) with the lemon yellow of 1% indigo and 1% C liquid is deployed into blue-greenish colour, can obtains finished product.
Beneficial effect of the present invention is discussed as follows:
The present invention, is dissolved in vitriol and polymerization boric acid sodium salt wherein as solubility promoter with Ucar 35, phenylcarbinol, formic acid and acetate successively, with Hydrocerol A as sanitas; Make permeate agent with N.F,USP MANNITOL; With N, N-dimethyl-tetradecy lamine and N, N-dimethyl-cetylamine is as sterilization and tensio-active agent; Make solubility promoter and tinting material with diethylene glycol monoethyl ether, form stable and sprawl effective liquid preparation.
Microelement foliage fertilizer staple among the present invention is vitriol and polymerization boric acid sodium salt; The applicant draws this foliage fertilizer through a large amount of field tests has good effect to crop; Various matter interactions in the concentrated assistant form a kind of particular structural, help crop more and well absorb zinc, manganese, copper, four kinds of elements of boron; Assimilated efficiency is all high than single use trace element fertilizer, for the peasant has saved manual work and fertilizer cost.Ucar 35 among the present invention, phenylcarbinol etc. are good solvents, do the stable performance that solvent can make formulation with Ucar 35 and phenylcarbinol.N.F,USP MANNITOL has good infiltration and diffusion, and it promotes infiltration and the diffusion of solution on blade, promotes crop to trace elements absorbed, the especially absorption of boron.N, N-dimethyl-tetradecy lamine and N, N-dimethyl-cetylamine is a kind of sterilant, it can help to kill the unwanted bacteria on crop blade face.N, N-dimethyl-tetradecy lamine and N, N-dimethyl-cetylamine or tensio-active agent, it has soup and well sprawls effect, the nutrition absorption excellent in efficiency.As sanitas, it makes this invention that good preservative effect arranged with Hydrocerol A in the present invention.The present invention also with vanillin food grade,1000.000000ine mesh as spices, it comes this product with other product differentiation from smell.Indigo with 1% and 1% lemon yellow furnishing blue-greenish colour are as the characteristic color of this invention.
In sum, the invention has the beneficial effects as follows:
(1) the present invention can provide the required zinc that grows, manganese, copper and boron nutrient for crop, has good stability and plate-out ability, and crop absorbs fast, and plant recovery of nutrient is high, well guarantees the needs that grow of fruit tree;
(2) the present invention can provide the required zinc that grows, manganese, copper and boron nutrient simultaneously for crop, has solved the time and the labour costs that use single-element fertilizer.
(3) the present invention has filled up the vacancy of home market, well imported product outside the subrogate country.
Embodiment
Come further explain the present invention below in conjunction with specific embodiment.
1 one kinds of composite type micro-element liquid foliage fertilizers of embodiment, mainly form according to said parts by weight by following component:
28 parts of Zinc vitriols;
15 parts of Manganous sulfate monohydrates;
8 parts of Salzburg vitriols;
3 parts of tetraacethyl diethylamine disodiums;
4 parts of polymerization boric acid sodium salts;
0.36 part of Hydrocerol A;
0.5 part in formic acid;
0.5 part of acetate;
2.2 parts of Ucar 35;
0.5 part in N.F,USP MANNITOL;
1.0 parts of phenylcarbinols;
0.36 part of diethylene glycol monoethyl ether;
1.2 parts of vanillin food grade,1000.000000ine meshs;
N, 1.5 parts of N-dimethyl-tetradecy lamines;
N, 1.4 parts of N-dimethyl-cetylamines;
0.1 part of 1% indigo;
1% lemon yellow 0.15 part;
Water surplus.
Concrete preparation method is following:
(1) earlier water is added reaction kettle, add tetraacethyl diethylamine disodium then and stir, add Zinc vitriol more successively until dissolving fully; Manganous sulfate monohydrate; Salzburg vitriol, polymerization boric acid sodium salt adds after waiting a kind of material of adding to dissolve fully a kind of down again; Treat after four kinds of salt dissolve fully solution to be filtered, form A liquid;
(2) will assist concentration components according to Hydrocerol A, formic acid, acetate, Ucar 35, N.F,USP MANNITOL, phenylcarbinol, diethylene glycol monoethyl ether, vanillin food grade,1000.000000ine mesh, N, N-dimethyl-tetradecy lamine, N, the order of N-dimethyl-cetylamine is dissolved in the water successively, forms B liquid;
(3) B liquid is slowly poured in the A liquid, the limit bevelling stirs, and stirs 15 minutes, mixedly can form C liquid after even;
(4) with the lemon yellow of 1% indigo and 1% C liquid is deployed into blue-greenish colour, can obtains finished product.
The test effect of embodiment 2 composite type micro-element liquid foliage fertilizers of the present invention on lichee
In beautiful fruit field, west, Shenzhen, spray the glutinous rice wrapped in lotus leaves of the age of tree about 13 years for 1000 times with composite type micro-element liquid foliage fertilizer dilution of the present invention, use at fruit development period, obtain good effect.Can find out that through table 1, table 2 yield increased increases by 13.8%, the pol comparison is according to increasing by 6.9%.
The contrast of table 1 output
| Handle | Single plant yield (Kg) | 30 fruit ear output (Kg) | Average simple grain is heavy (g) really | Stimulation ratio (%) | 30 fruit ear fruit quantity (grain) | The average setting amount of every fringe (grain) |
| Compound trace element fertilizer | 49.2 | 6.2 | 26.3 | 13.8 | 235 | 7.83 |
| Contrast (spray clear water) | 21.6 | 3.4 | 23.1 | -------- | 148 | 4.93 |
Table 2 pulp pol contrast (representing) with soluble solid
The test effect of embodiment 3 composite type micro-element liquid foliage fertilizers of the present invention on paddy rice
On Agricultural University Of South China education experiment farm, spray paddy rice for 1000 times with the fertile dilution of composite type micro-element liquid of the present invention, can find out that through table 3 yield increased increases by 8.3%, the comparison of the real grain of every fringe number is according to increasing by 6, and setting percentage also is significantly increased.
Table 3
The test effect of embodiment 4 composite type micro-element liquid foliage fertilizers of the present invention on vegetables
On Agricultural University Of South China education experiment farm, spray green cucumber for 1000 times with the fertile dilution of composite type micro-element liquid of the present invention, can find out that through table 4 yield increased increases by 19.6%, the income comparison increases 362 yuan according to mu.
Table 4
| Handle | Area (mu) | Gross output (Kg) | Folding per mu yield (Kg) | 7 average prices (unit) | Per mu yield value (unit) | Comparison is according to increasing (%) | Comparison increases (unit) according to mu |
| Compound trace element fertilizer | 0 .12 | 281.5 | 2345.9 | 0.94 | 2205.4 | 19.6 | 362.7 |
| Contrast | 0 .15 | 294.0 | 1960.0 | 0.94 | 1842.4 | ------ | ----------- |
Claims (4)
1. a composite type micro-element liquid foliage fertilizer is characterized in that comprising nutritive ingredient and auxiliary concentration components; Said nutritive ingredient is made up of vitriol and polymerization boric acid sodium salt, and said vitriol is Zinc vitriol, Manganous sulfate monohydrate, Salzburg vitriol and tetraacethyl diethylamine disodium; Said auxiliary concentration components is made up of sanitas, solubility promoter, permeate agent, sterilant, tensio-active agent and other auxiliary materials; Said sanitas is a Hydrocerol A; Said solubility promoter is Ucar 35, phenylcarbinol, formic acid, acetate and diethylene glycol monoethyl ether, and said permeate agent is a N.F,USP MANNITOL, and said sterilization and tensio-active agent are N; N-dimethyl-tetradecy lamine and N, N-dimethyl-cetylamine; Said other auxiliary materials comprise spices, pigment, tinting material and water.
2. composite type micro-element liquid foliage fertilizer according to claim 1 is characterized in that said spices is vanillin food grade,1000.000000ine mesh; Said pigment is the lemon yellow of 1% indigo and 1%; Said tinting material is a diethylene glycol monoethyl ether.
3. composite type micro-element liquid foliage fertilizer according to claim 1 and 2 is characterized in that being made up of according to said parts by weight following component:
28 parts of Zinc vitriols;
15 parts of Manganous sulfate monohydrates;
8 parts of Salzburg vitriols;
3 parts of tetraacethyl diethylamine disodiums;
4 parts of polymerization boric acid sodium salts;
0.36 part of Hydrocerol A;
0.5 part in formic acid;
0.5 part of acetate;
2.2 parts of Ucar 35;
0.5 part in N.F,USP MANNITOL;
1.0 parts of phenylcarbinols;
0.36 part of diethylene glycol monoethyl ether;
1.2 parts of vanillin food grade,1000.000000ine meshs;
N, 1.5 parts of N-dimethyl-tetradecy lamines;
N, 1.4 parts of N-dimethyl-cetylamines;
0.1 part of 1% indigo;
1% lemon yellow 0.15 part;
Water surplus.
4. the preparation method of the said composite type micro-element liquid foliage fertilizer of claim 3 is characterized in that may further comprise the steps:
(1) earlier water is added reaction kettle, add tetraacethyl diethylamine disodium then and stir, add Zinc vitriol more successively until dissolving fully; Manganous sulfate monohydrate; Salzburg vitriol, polymerization boric acid sodium salt adds after waiting a kind of material of adding to dissolve fully a kind of down again; Treat after four kinds of salt dissolve fully solution to be filtered, form A liquid;
(2) will assist concentration components according to Hydrocerol A, formic acid, acetate, Ucar 35, N.F,USP MANNITOL, phenylcarbinol, diethylene glycol monoethyl ether, vanillin food grade,1000.000000ine mesh, N, N-dimethyl-tetradecy lamine, N, the order of N-dimethyl-cetylamine is dissolved in the water successively, forms B liquid;
(3) B liquid is slowly poured in the A liquid, the limit bevelling stirs, and stirs 15 minutes, mixedly can form C liquid after even;
(4) with the lemon yellow of 1% indigo and 1% C liquid is deployed into blue-greenish colour, can obtains finished product.
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| CN101665390B (en) * | 2009-09-08 | 2012-08-22 | 华南农业大学 | Suspension type liquid compound fertilizer and preparation method thereof |
| CN103664359B (en) * | 2013-11-25 | 2015-04-08 | 华南农业大学 | High-phosphorus high-zinc liquid compound fertilizer and preparation method thereof |
| CN105110868B (en) * | 2015-07-24 | 2018-06-19 | 南宁宇益源农业科技发展有限公司 | A kind of environmental type foliar fertilizer and preparation method thereof |
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| CN107691139B (en) * | 2017-08-04 | 2019-10-15 | 农业部环境保护科研监测所 | Carry out the method that leaf is produced with rape safe and high quality in cadmium mild or moderate pollution vegetable plot |
| CN107628896A (en) * | 2017-09-12 | 2018-01-26 | 四川鑫圣生物科技有限公司 | A kind of garlic special fertilizer and preparation method thereof |
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| CN112174737B (en) * | 2020-10-10 | 2022-02-25 | 河南华智营养科技有限公司 | Micro-fertilizer for foliar spraying of unmanned aerial vehicle |
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| CN112715539B (en) * | 2021-01-28 | 2022-06-17 | 菲吉乐科(南京)生物科技有限公司 | Auxiliary penetrating agent suitable for bacteriophage to penetrate into tuber crops and preparation method and application thereof |
| CN114249618A (en) * | 2021-12-29 | 2022-03-29 | 鞍山绿泰佳葡萄主题公园有限公司 | Cultivation method for milk drip irrigation and grape spraying |
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