CN101330977B - 形成全同立构聚丙烯的催化剂组合物和方法 - Google Patents

形成全同立构聚丙烯的催化剂组合物和方法 Download PDF

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Publication number
CN101330977B
CN101330977B CN2006800472326A CN200680047232A CN101330977B CN 101330977 B CN101330977 B CN 101330977B CN 2006800472326 A CN2006800472326 A CN 2006800472326A CN 200680047232 A CN200680047232 A CN 200680047232A CN 101330977 B CN101330977 B CN 101330977B
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China
Prior art keywords
isotactic polypropylene
group
isotactic
alkyl
flu
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Expired - Fee Related
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CN2006800472326A
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English (en)
Chinese (zh)
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CN101330977A (zh
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V·马林
A·拉扎维
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Fina Technology Inc
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Fina Technology Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN2006800472326A 2005-12-16 2006-10-27 形成全同立构聚丙烯的催化剂组合物和方法 Expired - Fee Related CN101330977B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/305,704 US7514509B2 (en) 2005-12-16 2005-12-16 Catalyst compositions and methods of forming isotactic polyproyplene
US11/305,704 2005-12-16
PCT/US2006/041686 WO2007078387A1 (en) 2005-12-16 2006-10-27 Catalyst compositions and methods of forming isotactic polypropylene

Publications (2)

Publication Number Publication Date
CN101330977A CN101330977A (zh) 2008-12-24
CN101330977B true CN101330977B (zh) 2012-07-04

Family

ID=38174573

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2006800472326A Expired - Fee Related CN101330977B (zh) 2005-12-16 2006-10-27 形成全同立构聚丙烯的催化剂组合物和方法

Country Status (6)

Country Link
US (1) US7514509B2 (https=)
EP (1) EP1971433A4 (https=)
JP (1) JP2009520052A (https=)
KR (1) KR20080074987A (https=)
CN (1) CN101330977B (https=)
WO (1) WO2007078387A1 (https=)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100491458C (zh) 2006-04-20 2009-05-27 中国石油化工股份有限公司 高性能聚丙烯组合物的制备方法
EP2397509A1 (en) * 2010-06-18 2011-12-21 Stichting Dutch Polymer Institute Functionalized materials by catalyzed carbene copolymerization
JP2012020761A (ja) * 2010-07-14 2012-02-02 Japan Polypropylene Corp 電気電子機器部品搬送用ケース
JP5972056B2 (ja) * 2012-06-06 2016-08-17 三井化学株式会社 オレフィン重合体の製造方法
MX366147B (es) 2013-11-22 2019-06-28 Borealis Ag Homopolimero de propileno de baja emision.
MX368147B (es) * 2013-11-22 2019-09-20 Borealis Ag Homopolímero de propileno de baja emisión con alto flujo de masa fundida.
US11732067B2 (en) * 2017-06-27 2023-08-22 Exxonmobil Chemical Patents Inc. High stiffness polypropylene impact copolymer
EP3572441B1 (en) 2017-12-26 2023-06-07 Lg Chem, Ltd. Homopolypropylene and method for preparing the same

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Publication number Priority date Publication date Assignee Title
US5436305A (en) * 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
US5401817A (en) * 1991-05-09 1995-03-28 Phillips Petroleum Company Olefin polymerization using silyl-bridged metallocenes
US5191132A (en) * 1991-05-09 1993-03-02 Phillips Petroleum Company Cyclopentadiene type compounds and method for making
ES2107548T3 (es) * 1991-07-23 1997-12-01 Schering Corp Compuestos de beta-lactama sustituidos utiles como agentes hipocolesterolemicos y procedimientos para su preparacion.
US5416228A (en) * 1991-10-07 1995-05-16 Fina Technology, Inc. Process and catalyst for producing isotactic polyolefins
US5308817A (en) * 1992-05-18 1994-05-03 Fina Technology, Inc. Metallocene catalyst component with good catalyst efficiency after aging
JPH072935A (ja) * 1993-06-15 1995-01-06 Showa Denko Kk ポリオレフィン製造用触媒成分およびポリオレフィンの製造方法
DE19606510A1 (de) * 1996-02-22 1997-08-28 Hoechst Ag Hochmolekulares Polypropylen mit breiter Molmassenverteilung
US6114480A (en) * 1996-04-19 2000-09-05 Fina Technology, Inc. Process and catalyst for producing polyolefins having low molecular weight
DE69710838T2 (de) * 1996-04-22 2002-10-31 Japan Polyolefins Co. Ltd., Tokio/Tokyo Katalysator zur polyolefinherstellung und polyolefinherstellungsverfahren
US6090325A (en) * 1997-09-24 2000-07-18 Fina Technology, Inc. Biaxially-oriented metallocene-based polypropylene films
US6784269B2 (en) * 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
US6469188B1 (en) * 1999-01-20 2002-10-22 California Institute Of Technology Catalyst system for the polymerization of alkenes to polyolefins
US6515086B1 (en) * 1999-02-19 2003-02-04 Fina Research, S.A. Polyolefin production
US6372847B1 (en) * 2000-05-10 2002-04-16 Exxon Mobil Chemical Patents, Inc. Polyolefin compositions having improved low temperature toughness
AU2000262096A1 (en) * 2000-07-12 2002-01-21 E.I. Du Pont De Nemours And Company Metallocene polymerization catalyst
DE60211444T2 (de) * 2001-03-15 2006-11-30 Mitsui Chemicals, Inc. Automobilteile aus einer polypropylenharzzusammensetzung
US6943215B2 (en) * 2001-11-06 2005-09-13 Dow Global Technologies Inc. Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
JP2004027163A (ja) * 2002-06-28 2004-01-29 Mitsui Chemicals Inc オレフィン重合用触媒及び該触媒を用いたオレフィンの重合方法
US6683150B1 (en) * 2002-12-19 2004-01-27 Equistar Chemicals, Lp High molecular weight polypropylene process
US20050148460A1 (en) * 2004-01-02 2005-07-07 Vladimir Marin Catalyst components and their use in the polymerization of olefins
KR20070061567A (ko) * 2004-03-31 2007-06-13 미쓰이 가가쿠 가부시키가이샤 올레핀 중합체의 제조 방법
JP4389071B2 (ja) * 2004-04-14 2009-12-24 三井化学株式会社 プロピレン系重合体
US7241850B2 (en) * 2004-12-15 2007-07-10 Fina Technology, Inc. Polypropylene having improved clarity and articles prepared therefrom
US7094938B1 (en) * 2005-05-20 2006-08-22 Fina Technology, Inc. Process for the preparation of substituted fluorenes
US7335711B2 (en) * 2005-08-17 2008-02-26 Fina Technology, Inc. Preparation and use of tetrasubstituted fluorenyl catalysts for polymerization of olefins
US7538167B2 (en) * 2006-10-23 2009-05-26 Fina Technology, Inc. Syndiotactic polypropylene and methods of preparing same

Also Published As

Publication number Publication date
KR20080074987A (ko) 2008-08-13
WO2007078387A1 (en) 2007-07-12
EP1971433A1 (en) 2008-09-24
US7514509B2 (en) 2009-04-07
CN101330977A (zh) 2008-12-24
EP1971433A4 (en) 2009-08-26
JP2009520052A (ja) 2009-05-21
US20070142578A1 (en) 2007-06-21

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Granted publication date: 20120704

Termination date: 20121027