CN101314163A - Reclamation processing method for poor garbage - Google Patents

Reclamation processing method for poor garbage Download PDF

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Publication number
CN101314163A
CN101314163A CNA2008100389917A CN200810038991A CN101314163A CN 101314163 A CN101314163 A CN 101314163A CN A2008100389917 A CNA2008100389917 A CN A2008100389917A CN 200810038991 A CN200810038991 A CN 200810038991A CN 101314163 A CN101314163 A CN 101314163A
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sterilization
heavy metal
garbage
pollution
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CNA2008100389917A
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CN101314163B (en
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刘文治
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费爱民
刘文治
费杰
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • Y02W30/523
    • Y02W30/622
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/78Recycling of wood or furniture waste

Abstract

The invention provides a completely innocent and utmost resource treatment method for old garbage, which comprises the following steps that: a wood-plastic man-made board is produced after pretreatments such as disinfection, sterilization, screening and air separation of waste bamboo wood and plastics; and septic soil and concentrated waste liquid are prepared into a main raw material of high-quality organic fertilizer. The method used to treat the old garbage has the advantages that: 1. the method eliminates foul odor, foreign odor, and pollution to the environment which are produced by the prior treatment of the old garbage, and avoids the problems of greenhouse pollution and heavy metal pollution as well as flammability and explosibility due to produced inflammable gas when the old garbage is added with fresh organic matters and is prepared into compost through secondary fermentation; 2. the method avoids the atmospheric pollution produced by incineration treatment, particularly dioxin pollution; 3. the method can reclaim and reuse useful substances in the old garbage to the utmost extent, and produces good social benefit, economic benefit and ecological environment benefit.

Description

Reclamation processing method for poor garbage

Technical field:

The present invention relates to organic solid castoff handles and comprehensive utilization field, particularly reclamation processing method for poor garbage.

Background technology

The alleged poor garbage of the present invention mainly is at without the rubbish after the natural heap garbage of any processing and the envelope factory of landfill factory, the decrement rubbish that compost is ended.

Statistics according to Ministry of Construction's issue in 2002: 1.36 hundred million tons of China's 660 organizational system cities house refuse generations, wherein the amount of focusing on is 7,404 ten thousand tons, there are 6,200 ten thousand tons without any processing, these house refuses or be deposited in the appointed place, or arbitrarily be deposited in river bank, pond and the combination area of city and country.House refuse " besieged city " phenomenon is very serious; County town in addition, 660 organizational system cities, organic town, about 3,600 ten thousand tons of year generation house refuse does not obtain handling substantially, is poured over swag, river bank, lake etc. nearby, environment is caused seriously pollute.By the end of the year 2003, build together and establish 575 in domestic rubbish disposal factory (field) in the whole nation, 7,545 ten thousand tons of disposal abilities, and wherein household refuse landfill sites is 457, disposal ability is 6,404 ten thousand tons, account for 79.5% and 84.5% respectively, 47 of municipal solid waste incinerators, 3,700,000 tons of disposal abilities, account for 8.2% and 4.9% respectively, 70 in consumer garbage compost factory, 7,170,000 tons of disposal abilities account for 12% and 9.5% respectively.

State Environmental Protection Administration investigated 30 province, district and city, 329 domestic rubbish disposal facilities in ground in calendar year 2001, the result: " what meet the sanitary landfills requirement in the household refuse landfill sites substantially accounts for 8.9%; what part met the sanitary landfills requirement accounts for 43.9%; simple and easy landfill yard accounts for 40.5%; " the severe contamination water body does not have essential distinction with untreated dumping.If by 457 disposal abilities of landfill yard in 2002 be 6,404 ten thousand tons 20% the estimation, simple and easy landfill account for 1280.8 ten thousand tons, add in the foregoing organizational system city 6,200 ten thousand tons without any processing, county, town do not obtain 3,600 ten thousand tons in the rubbish handled substantially, the whole nation amounts to: 11,081 ten thousand tons, add the decrement rubbish that composting plant is dropped, this and in recent years the rubbish of other statistics to remain 12,000 ten thousand tons data be approaching.

To the measuring and calculating of landfill waste 14 annual means, the mean calorie of landfill yard poor garbage is at 2800 kilocalories/kg according to Shanghai Lao Gang landfill yard, and 40mm oversize mean calorie is up to 6500 kilocalories/kg, and the energy, the utilization of resources are got up considerable.The organic overwhelming majority stable in the 40mm screenings is difficult for decomposing again, wherein contains the class humic acid substance or claims lignin derivative about about 15%.Except class humic acid substance or the title lignin derivative of the overwhelming majority for being difficult for decomposing again; The heavy metal that also exists a large amount of germs, virus and microbial toxin and be concentrated simultaneously.As directly doing farming fertile meeting contaminated soil and agricultural product.As abandon, can produce secondary pollution, also be the waste of resource simultaneously.China's major part is used as the nutrition soil or the landfill factory overburden soil of trees greening.The developed country that has, only repeats to have reduced the utilization rate of landfill yard as the landfill yard overburden soil no longer as greening nutrition soil for fear of ecological risk.Outside the poor garbage depollution environment, take a large amount of soils, wasted land resource.Through the rainwater leaching, ooze drop liquid and can cause water pollution.The landfill waste that closes has a lot of cities to clear out a gathering place to do after-treatment, so that do the secondary landfill yard, save land used.Continue to select new landfill place, to a lot of cities, not easy.To the processing of poor garbage, significant.If can only handle with burning method with conventional art, the problem of existence is that cost height, investment are big, and serious to the atmosphere secondary pollution, the cost that solves secondary pollution is very high, and is the waste resource.Do not do the poor garbage of any processing, waste land resource, waste regenerative resource resource is wasted renewable physical resources, and continues contaminated environment.

Domestic waste is meant in city dweller's daily life or the solid waste that produces in the activity of service is provided for daily life.China's domestic waste adopts the method for stacking and landfill to handle always for a long time.Stack or the domestic waste of landfill 〉=2 year is called outmoded house refuse at landfill yard.Outmoded house refuse is basicly stableization after degraded for many years, is characterized in that the microbial death body burden is abundant, and content of organics is lower, and ash content is big, and calorific value is low.Domestic waste adopts the method for stacking and landfill not only to pollute environment, has also caused the waste of resource.

Existing poor garbage has only traditional composting technology, relies on adding new refuse or straw kind, industrial organic waste class to carry out aerobic secondary fermentation, and fermentation time is long, has heavy metal and microbial toxin residual.

Chinese patent application number is that 200510090096.6 to disclose a kind of be the method that raw material is produced active nutritional fertilizer with outmoded house refuse, it is for utilizing nitrogen-fixing bacteria, light and bacterium, saccharomycete, lactic acid bacteria, composite bacteria agent capable and earthworm that little aerobic or aerobic bacteria such as functional bacillus is formed, outmoded house refuse being added the rice chaff of 2-5% and the straw of long 30mm ferments as raising agent, the organic component content of the fertilizer that obtains is measured, if can not reach: full nitrogen 〉=0.3%, quick-acting nitrogen 〉=0.04%, full phosphorus 〉=0.1%, full potassium 〉=0.2% o'clock, carry out nitrogen, phosphorus, the balance of potassium promptly adds nitrogenous fertilizer, feed with balanced nutrients such as phosphate fertilizer and potash fertilizer is to reach standard.But it is separated that the heavy metal that is concentrated in the outmoded rubbish does not have, and directly does fertilizer or add fresh organic matter.Carrying out secondary fermentation does fertilizer and all can cause ecological risk.

In addition, the present invention finds that also poor garbage is through long-term nature or artificial compost's fermentation process, long-term landfill disposal, and perishable organic matter all decomposition changes into greenhouse gases, CO 2, CO, CH 4, H 2, NO X, H 2Foul gas such as S and organic sulfur compound organic amine, remaining is to be difficult for the cell membrane of the humic acid material of fermentation and heavy metal that is concentrated and dead thalline and microbial toxin, bamboo wood class, artificial synthetic fibers class, plastics class, metal species, mineral-type such as sandstone, earth, glass-ceramic class.Reached stabilisation, secondary fermentation adds fresh organic matter and ferments again, lacks practical significance, and heavy metal in the poor garbage and microbial toxin can influence the quality of secondary fermentation fertilizer.

Summary of the invention

Technical problem to be solved by this invention is the characteristics at poor garbage, and proposes a kind of reclamation processing method for poor garbage, to solve the existing existing deficiency of poor garbage processing method.

Technical problem to be solved by this invention can be achieved through the following technical solutions:

A kind of reclamation processing method for poor garbage comprises following steps:

1) screening: poor garbage is screened, filter out size and carry out fragmentation, be broken into the fragment rubbish of size below 20mm greater than the Bulky Waste more than the 300mm;

2) sterilization: the fragment rubbish of step 1) fragmentation is transported in sterilization, the disinfection tank together with all the other rubbish that screen, in the sterilization jar, feed temperature more than 120 ℃, saturated vapor or the superheated steam of pressure more than 0.2Mpa, retention time is at 2-4 hour, so that microorganisms all in the rubbish is thoroughly knocked out; Isolate solid portion and liquid part after the sterilization;

3) screening: will be through step 2) solid portion after the sterilization screens with the screening machine of 10mm-15mm sieve aperture earlier; The screenings that screens is transported in the water dissolving tank, adds the vitriolated aqueous solution that screenings 6-10 doubly measures, and hydrolysis was at normal temperatures and pressures soaked 1-3 hour, makes the heavy metal dissolving in the screenings, and the sulfuric acid concentration that uses during dissolving is 2-5%; After hydrolysis is soaked and is finished, isolate the acid non-soluble substance that contains earth foreign material and humic acid material with centrifuge, the centrifuge revolution is-6000 rev/mins of 2000 commentaries on classics, the aqueous sulfuric acid that will be dissolved with heavy metal simultaneously is transported to and contains in the heavy metal solution jar, wait to collect when a certain amount of, adopt the ferrite method to handle; The amount that adds ferrous sulfate is 10-20 a times of total metals, and PH adjusts to 8-9, and the forced air that produces with air compressor machine carries out oxidation reaction, and air capacity is 2-6 a times of solution amount, and reaction temperature is 50 ℃-100 ℃.After reaction is finished, isolate wet ferrite with centrifuge, the centrifuge revolution is-6000 rev/mins of 2000 commentaries on classics, then with the heated-air drying more than 150 ℃ to water content 2%-5%, after being cooled to normal temperature again, the metering, the packing contain the heavy metal ferrite, content is more than 90%.

4) insoluble matter that contains earth foreign material and humic acid material in the step 3) is transported in the alkali dissolving tank, adding the 2%-5% aqueous slkali soaks, immersion process maintained 0.5 hour-3 hours, the aqueous slkali consumption is dissolved out the humic acid material in the insoluble matter for the whole immersion process pH value of control is 8-10 fully; The molten thing of alkali after the dissolving neutralizes with the sulfuric acid of 2-8%, and control pH value is 1-5 in the N-process, makes the humic acid material in the molten thing of alkali be precipitated out standby; Contain earth and foreign material landfill disposal in the alkali insoluble matter;

5) oversize in the step 3) is carried out selection by winnowing, with the bamboo in oversize wood class material, sandstone class material, category of glass material and plastics class material respectively selection by winnowing come out; Then bamboo wood class material is ground into 0.1mm-1mm and 60 orders-200 purpose bamboo wood powder two parts are standby; Plastics class material is isolated cleaner plastics after washing, after drying, it is standby to be ground into 20 orders-100 purpose molding powder; Sandstone class material, category of glass material and ceramic-like material landfill disposal or recovery are done the building materials use;

6) with step 2) to become concentration be the concentrate of 20%-60% for liquid partial concentration after the sterilization treatment, the humic acid material that obtains with step 4) mixes, under 150 ℃ of-300 ℃ of conditions, obtain generating the primary raw material of organic high-quality fertilizer of the active organic matter contain activity (containing pentose, hexose class) and nonactive (containing humic acids) after the spray-drying.

In the present invention, the 0.01mm-1mm bamboo wood powder that described step 5) obtains is pressed into fuel slug with make-up machine, carries out pyrolytic gasification through the thermal decomposition vaporization stove and produces fuel gas, as the fuel use of steam boiler.

In the present invention, described step 5) obtains 60 orders-200 order bamboo wood powder and 20 orders-100 order molding powder, according to weight ratio is the ratio mixing of bamboo wood powder: molding powder=3-4: 7-6, mixes the back and adopts forcing press or extruder to make wooden plastic man-made board material (belonging to known public technology).

Owing to adopted technical scheme as above, adopted method of the present invention to handle poor garbage and have following advantage:

1, stench and smell pollution and greenhouse gases pollution problem that the conventional treatment poor garbage produces have been eliminated, especially mosquito, fly parasitism, carry germ, virus and propagate everywhere communicable disease very easily takes place, saved long-time 2 fermentations of present poor garbage compost.

2, avoided compost, landfill disposal to produce fuel gas in a large number and cause inflammable and explosive harm.

3, secondary pollution, the especially dioxin contamination of having avoided burning method to produce.

4, solve poor garbage and occupied a large amount of land resources for a long time.

5, can the utility in the poor garbage be reclaimed to greatest extent, obtained obvious social, economic benefit and ecological environment benefit.

Description of drawings

Fig. 1 is the process chart of reclamation processing method for poor garbage of the present invention.

The specific embodiment

Referring to Fig. 1, reclamation processing method for poor garbage specifically comprises the steps:

1, screening: poor garbage is screened, filter out size and carry out fragmentation, become the fragment rubbish of size below 20mm through high-power, screw die formula crusher in crushing greater than the Bulky Waste more than the 300mm; In this step, it mainly is to consider smooth delivery of power to arrive the sterilization jar that size is carried out fragmentation greater than the Bulky Waste more than the 300mm, prevents to block;

2, sterilization: the fragment rubbish of step 1 fragmentation is transported in the sterilization jar together with all the other rubbish that screen, in the sterilization jar, feed 130 ℃ of temperature, pressure saturated vapor or superheated steam at 0.3Mpa, retention time is about 2 hours, so that microorganisms all in the rubbish is thoroughly knocked out; In sterilization process, bulky plastic sheeting can be shrunk to irregular spherical.Make poor garbage volume decrement to 1/3.In sterilization process, the pentose class of the different molecular weight that hemicellulose in the poor garbage decomposes is discharged earlier, and the concentrate that is condensed into solid content 60% through the heat of tail gas recycle is standby;

3, screening: will screen with the screening machine of 10mm-15mm sieve aperture earlier through the solid portion after step 2 sterilization; The screenings that screens is transported in the dissolving tank, and the aqueous sulfuric acid hydrolysis at normal temperatures and pressures that adds 8 times of amounts of screenings was soaked 2 hours, makes the heavy metal dissolving in the screenings, and the sulfuric acid concentration that uses during dissolving is 2%; After hydrolysis soak to finish, isolate the insoluble matter that contains earth foreign material and humic acid material with centrifuge, the aqueous sulfuric acid that will be dissolved with heavy metal simultaneously enters and contains in the heavy metal solution jar, waits to collect when a certain amount of, adopts the ferrite method to handle; The ferrous sulfate dosage is 20 times of heavy metal, PH adjusts to 8, the drum air capacity is 2 times of solution amount, and reaction temperature is 70 ℃, after the reaction time is 30 minutes, carry out centrifugation with centrifuge, the centrifuge revolution is 3000 rev/mins, the wet ferrite that centrifugation goes out with 150 ℃ heated-air drying to water content 5%, be cooled to normal temperature again after, measure, pack, generation contains the product of heavy metal ferrite more than 90%.

4, the acid non-soluble substance that contains earth foreign material and humic acid material in the step 3 is transported in the alkali dissolving tank, adding 2% aqueous slkali soaks, immersion process stirs simultaneously, revolution is 60 rev/mins and maintains 2 hours, the aqueous slkali consumption is dissolved out the humic acid material in the insoluble matter for the whole immersion process pH value of control is 9 fully; The molten thing weight percent concentration of alkali after the dissolving is that 5% sulfuric acid neutralizes, and control pH value is 3 in the N-process, makes the humic acid material in the molten thing of alkali be dissolved out standby; Contain earth in the alkali insoluble matter after the dissolving and foreign material carry out landfill disposal;

5, the oversize in the step 3 is carried out selection by winnowing, with wherein bamboo wood class material, sandstone class material, category of glass material and plastics class material respectively selection by winnowing come out; Then bamboo wood class material is ground into 0.3mm and 200 orders, two parts with pulverizer; Carry out pyrolytic gasification 0.3mm the bamboo wood powder is pressed into fuel slug through the thermal decomposition vaporization stove, the fuel gas of generation uses as the fuel of steam boiler.200 order bamboo wood powders are done Wood plastic boards and are used.Isolate cleaner plastics after washing, being ground into 100 purpose molding powders after drying is the bamboo wood powder with 200 order bamboo wood powders according to weight ratio: the ratio of molding powder=3: 7 is mixed, and mixes the back and adopts extruder to make wooden plastic man-made board material.Building materials are done in sandstone class material, category of glass material and ceramic-like material landfill disposal or recovery in the poor garbage to be used;

6, the liquid partial concentration after step 2 sterilization treatment is become the concentrate of solid content 60%, the humic acid material that obtains with step 4 mixes, under 250 ℃ of conditions, obtain generating the primary raw material of the high-quality fertilizer that contains activity (containing pentose, hexose class) organic composition and nonactive (containing humic acids) organic composition after the spray-drying.

Claims (3)

1, a kind of reclamation processing method for poor garbage is characterized in that, comprises following steps:
1) screening: poor garbage is screened, filter out size and carry out fragmentation, be broken into the fragment rubbish of size below 20mm greater than the Bulky Waste more than the 300mm;
2) sterilization: the fragment rubbish of broken step all the other rubbish after together with the Bulky Waste that screens are transported in the sterilization jar, in the sterilization jar, feed temperature more than 120 ℃, saturated vapor or the superheated steam of pressure more than 0.2Mpa, retention time is at 2-4 hour, so that microorganisms all in the rubbish is thoroughly knocked out; Isolate solid portion and liquid part after the sterilization;
3) screening: will be through step 2) solid portion after the sterilization screens with the screening machine of 10mm-15mm sieve aperture earlier; The screenings that screens is transported in the water dissolving tank, adds the vitriolated aqueous solution that screenings 6-10 doubly measures, and hydrolysis was at normal temperatures and pressures soaked 1-3 hour, makes the heavy metal dissolving in the screenings, and the aqueous sulfuric acid concentration of using during dissolving is 2-5%; After hydrolysis is soaked and is finished, isolate the acid non-soluble substance that contains earth foreign material and humic acid material with centrifuge, the centrifuge revolution is-6000 rev/mins of 2000 commentaries on classics, the aqueous sulfuric acid that will be dissolved with heavy metal simultaneously is transported to and contains in the heavy metal solution jar, wait to collect when a certain amount of, adopt the ferrite method to handle; The ferrous sulfate dosage is 10-20 a times of total metals, pH adjusts to 8-9, the forced air that produces with air compressor machine carries out oxidation reaction, air capacity is 2-6 a times of solution amount, reaction temperature is 50 ℃-90 ℃, after reaction time is 20 minutes-2 hours, formation contains the wet ferrite of heavy metal, isolate wet ferrite with centrifuge, the centrifuge revolution is-6000 rev/mins of 2000 commentaries on classics, then with the heated-air drying more than 150 ℃ to water content 2%-5%, be cooled to normal temperature again after, it is more than 90% that metering, packing promptly generate its content of stable ferrite contain heavy metal;
4) acid non-soluble substance that contains earth foreign material and humic acid material in the step 3) is transported in the alkali dissolving tank, adding concentration is that the aqueous slkali of 2%-5% soaks dissolving, immersion process stirs simultaneously, revolution changes-100 rev/mins 20, maintained 0.5 hour-3 hours, the aqueous slkali consumption is 4-8 a times of solid volume, controls whole immersion course of dissolution pH value and is 8-10, and the humic acid material in the insoluble matter is dissolved out fully; Separate with the earth foreign material, the molten thing of the alkali after the dissolving neutralizes with the aqueous sulfuric acid of 2-8%, and control pH value is 1-5 in the N-process, makes the humic acid material in the molten thing of alkali be precipitated out standby; Contain earth and foreign material in the alkali insoluble matter and carry out landfill disposal;
5) oversize in the step 3) is carried out selection by winnowing, with the bamboo in oversize wood class material, sandstone class material, category of glass material and plastics class material respectively selection by winnowing come out; Then bamboo wood class material is ground into 0.1mm-1mm and 60 orders-200 purpose bamboo wood powder two parts are standby; The plastics class is isolated cleaner plastics after wet concentration, washing, it is standby to be ground into 20 orders-100 purpose molding powder after drying; Sandstone class material, category of glass material and ceramic-like material landfill disposal or recovery are done the building materials use;
6) with step 2) the liquid partial concentration after the sterilization treatment becomes the concentrate of solid content 20%-60%, the humic acid material that obtains with step 4) mixes, under 150 ℃ of-300 ℃ of conditions, obtain generating the primary raw material of the high-quality fertilizer that contains the organic composition of activity (containing pentose and hexose class) and nonactive (containing humic acids) organic composition after the spray-drying.
2, reclamation processing method for poor garbage as claimed in claim 1, it is characterized in that, the part of the bamboo wood powder 0.1mm-1mm that described step 5) obtains is pressed into fuel slug with make-up machine and carries out pyrolytic gasification generation fuel gas through the thermal decomposition vaporization stove, as the clean fuel use of steam boiler;
3, reclamation processing method for poor garbage as claimed in claim 1, it is characterized in that, 60 orders-200 order bamboo wood powder that described step 5) obtains and 20 orders-100 purpose molding powder, according to weight ratio is the ratio mixing of bamboo wood powder: molding powder=3-4: 7-6, mixes the back and adopts forcing press or extruder to make wooden plastic man-made board material.
CN2008100389917A 2008-06-16 2008-06-16 Reclamation processing method for poor garbage CN101314163B (en)

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CN101879761A (en) * 2010-05-12 2010-11-10 扬州天富龙汽车内饰纤维有限公司 Preparation method of high-purity masterbatches
CN101891512A (en) * 2010-07-02 2010-11-24 北京桑德环保集团有限公司 Method for preparing cultivation medium from urban sludge and refuse compost
CN102041127A (en) * 2011-01-18 2011-05-04 杨健 Preparation method for preparing derived fuel by utilizing combustible materials in garbage
CN102153376A (en) * 2010-11-23 2011-08-17 桐庐天翼电子科技有限公司 Full-function closed cyclic treatment and utilization system for comprehensive waste
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CN102476129A (en) * 2010-11-29 2012-05-30 周仁福 Integrated converting and utilizing co-production method for agricultural waste
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CN103861863A (en) * 2014-03-21 2014-06-18 广州保绿环保科技有限公司 Urban domestic garbage comprehensive utilization treatment method
CN103981219A (en) * 2014-05-13 2014-08-13 天津大学 Method of preparing humic acid by biological sludge composting
CN105175033A (en) * 2015-09-22 2015-12-23 崇州市地龙海龙生物制品开发研究所 Green garbage disposal method
CN105921498A (en) * 2016-06-17 2016-09-07 北京神雾环境能源科技集团股份有限公司 Household garbage resourceful comprehensive treatment method and treatment system
CN105921497A (en) * 2016-06-17 2016-09-07 北京神雾环境能源科技集团股份有限公司 Resourceful comprehensive treatment method and system for household garbage
CN105964650A (en) * 2013-08-27 2016-09-28 天紫环保投资控股有限公司 Organic matter rubbish treatment system with limiting and protecting springs
CN106077029A (en) * 2016-06-17 2016-11-09 北京神雾环境能源科技集团股份有限公司 Domestic garbage resource integrated conduct method and processing system
CN106111657A (en) * 2016-06-17 2016-11-16 北京神雾环境能源科技集团股份有限公司 Domestic garbage resource integrated conduct method and processing system
CN106111675A (en) * 2016-08-12 2016-11-16 北京神雾环境能源科技集团股份有限公司 Domestic garbage resource integrated conduct method and processing system
CN106433686A (en) * 2016-09-19 2017-02-22 重庆冠虹环保能源股份有限公司 Method for preparing soil remediation agent through biomass charcoal and residual ashes

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US9193635B2 (en) 2009-03-13 2015-11-24 Asahi Group Holdings, Ltd. Reducing mixture derived from microorganisms which has an oxidation-reduction potential of 0 mV or less, and production method for same
CN102405292B (en) * 2009-03-13 2015-06-10 朝日集团控股株式会社 A reducing mixture derived from microorganisms which has an oxidation-reduction potential of 0mv or less, and production method for same
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