CN100534649C - Cleansed handling domestic garbage - Google Patents

Cleansed handling domestic garbage Download PDF

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CN100534649C
CN100534649C CNB2005100257810A CN200510025781A CN100534649C CN 100534649 C CN100534649 C CN 100534649C CN B2005100257810 A CNB2005100257810 A CN B2005100257810A CN 200510025781 A CN200510025781 A CN 200510025781A CN 100534649 C CN100534649 C CN 100534649C
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water
sewage
filter tank
gas
handled
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CN1727085A (en
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刘文治
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Abstract

A technique for treating life garbage without environmental pollution includes such steps as using deodoring agent and microwave for removing odor smell and killing bacteria, cyclically treating the seeped liquid, separating organic substance from inorganic one, high-temp high-pressure degradation of organic substance to kill microbes and obtain clean raw material, preparing fuel blocks from the inorganic substance, stabilizing fly ash, mixing it with fuel cinder, making building material, treating sewage by magnetized biologic filter pool and magnetized chemical flocculating pool for cyclic use, and reclaiming sludge.

Description

House refuse cleans processing method
Technical field
The invention belongs to organic solid castoff and clean processing and comprehensive utilization of resources field, particularly house refuse cleans processing method.
Background technology
At present, three kinds of methods are adopted in domestic rubbish disposal both at home and abroad basically: burning, compost, sanitary landfill method, also have the 4th kind of method, and be exactly the comprehensive treatment method of so-called above-mentioned three kinds or two kinds method combinations.Burning method is innoxious more thorough through high temperature incineration, but the flying dust that produces 3%-4% contains the dangerous material discarded objects such as dioxin and heavy metal that exceed standard, need after-treatment, the method method of after-treatment has the high-temperature fusion that surpasses 1000 ℃ to make it vitrifying, plastics fusion embedding, adds the cement embedding behind the stabilizing agent, in a word, after the processing, need the secondary landfill disposal, cost is very high.Burn the lime-ash that produces 15%-20% and need landfill disposal, or transport outside the factory, do other utilization.It is strong carcinogenic substance that the flue gas that burning method produces contains dioxin, needs the high temperature through 1200 ℃ through the dual firing chamber of incinerator, and the time of staying is not less than 2S, and the dioxin branch is taken off.So far the dioxin that exceeds standard both at home and abroad discharging, burning method is quite a lot.Burning method also wastes energy, and the employing burning electricity generation that has reclaims electric energy, but has only 30% just to be converted into electric energy in the heat energy, and 70% heat energy is not utilized, and has slatterned.Original useful resource can directly be recycled in the rubbish, or handles the back and recycle, and can burn but to have wasted.The burning method investment is very high, and operating cost is also very high.
Composting process was carried out compost fermentation with 20 days-30 day time with rubbish exactly.Aerobic compost and anaerobic composting are arranged; Also have aerobic and the compost anaerobism combination; Static compost and dynamic compost are arranged.In a word, utilize the natural microorganisms in the house refuse to carry out lengthy fermentation exactly, the high temperature that produces more than 55 ℃ is killed most of disease bacterium and worm's ovum, but resistant to elevated temperatures bacillus is not gone out.It is dead to give birth to life and death through natural microorganisms, the long-time compost fermentation that goes round and begins again, most nutriments in the rubbish have been exhausted, the only remaining difficult humus that utilizes again and the inhibitory substance of microbial death thalline and generation are microbial toxin, make microorganism can not continue the heat production of fermenting again, so-called stabilisation that Here it is has been finished the whole process of compost fermentation.Because the perishable organic matter in the rubbish consumes in a large number, become the greenhouse gases volatilization, make about waste reduction to three/one.But heavy metal wherein can not be decomposed by microorganism, and volatilization and is stayed in the garbage compost, make it to be concentrated, increment nearly about three times.Compost contains heavy metal amount height, contains the microbial toxin height, contains the harmful bacillus category that is difficult for being killed, and can not do agricultural fertilizer.For a long time, garbage compost is used as the nutrition soil or the soil conditioner of greening usefulness both at home and abroad.But in recent years, the U.S., the soil conditioner of greening usefulness is not advocated to make of garbage compost in Europe.For avoiding ecological risk, can only be used as the overburden soil of landfill factory.Just carry out landfill disposal.Also produce a large amount of toxic and harmfuls in the composting process, as greenhouse gases and foul gas, make mosquitos and flies parasitic in a large number, environmental sanitation is very poor, and epidemic infectious diseases very easily takes place.Compost easily produces fuel gas, CO, H 2, CH 4, burning and blast often take place.
Sanitary landfill method is the another kind of form of compost fermentation method, and its Biological Principles is similar with fermentation method.Produce not easily biological-degradable of percolate, need with materialization and biochemical Combined Treatment, operating cost is very high.Landfill produces inflammable biogas and often burns, blast.Landfill method takies a large amount of soils, waste land resource.Because security consideration, after the closing, except that greening, can not do any utilization in 10 years.The same in the landfill process with compost, produce a large amount of toxic and harmfuls, greenhouse gases and foul gas have a large amount of mosquitos and flies parasitisms, easily produce epidemic infectious diseases.
Summary of the invention:
Technical problem to be solved by this invention is to overcoming the drawback of above three kinds of methods, and adopts the processing method that cleans, thoroughly sterilization and deodorization.In processing procedure, adopt and clean circulation process method, do not produce the mosquitos and flies parasitism.Adopt the processing method that cleans of resource, the recycling of energy thing, reach at last, the result of no emission, no residue.
Technical problem to be solved by this invention can be achieved through the following technical solutions:
House refuse cleans processing method, comprises that rubbish is toppled over, the stench when keeping in is handled; The recycling treatment of organic matter, inorganic matter after the sorting; Clean the generation of combustion gas heat energy; The recycling treatment of sewage, flue gas, tail gas, flying dust, slag, all adopt the method that cleans, circulates, recycles, reach no residue at last, it is characterized in that, topple at rubbish, the stench when temporary comprises that microwave dryer carries out the rapid draing processed in handling; Described rubbish is toppled over, the stench when keeping in is handled, and adopts the sour ferrous sulfate waste liquid that contains of pickled plate to do deodorant; Its concentration that contains acid is 15%-18%, contains Fe + 2At 5%-8%, between temporary, establish deodorant basin and ejecting device, the processing of spraying of the rubbish between temporary, spray amount is the 2%-10% of rubbish volume, and deodorant is reinstated the chemical degradation jar that pump is transported to HTHP with percolate one.
Wherein rubbish is toppled over, the stench when temporary handles and be: house refuse is transported to treatment plant after the car load weighing by the sealing transport vehicle, through seal channel, enter rubbish dump temporary between, again rubbish is dumped to broken bag, temporary hole with sealing car tipping bucket, dump in the process after the bag-breaking machine broken bag, open the deodorant spray pump, deodorant is released from the shower nozzle spraying through pump pressure, and the microorganism in the rubbish is by the H in the deodorant +And Fe + 2Institute kills.Deodorant is the ferrous acid waste liquid of sulfur acid that mechanical industry pickled plate produces, and containing acid concentration is 15%-18%, contains Fe + 2At 5%-8%, spray amount is the 2%-10% of rubbish volume.Fe in the deodorant + 2Generate FeS and eliminated stench with the sulfide generation chemical reaction that produces stench.Acid effect makes the pH of rubbish reach 4-5.5, has suppressed to produce most microorganisms of stench.The deodorant residue that this kind method produces is transported in the organic high-temperature high-pressure chemical catalytic degradation jar as catalyst through pump together with percolate.Also reached simultaneously treatment of wastes with processes of wastes against one another purpose.Lower than the organic deodorant cost that adopts at present, reduce investment outlay than biofilter deodorizing, save operating cost.Because the rubbish water content after the deodorizing is higher, influence sorting, therefore need dewater through the ripple drying machine rapid draing that declines of crawler belt or gallery; Be 1min-5min drying time.Temperature is 60 ℃-100 ℃.Because the alternation electrostatic field of microwave from the inner frictional heat that produces the alternation electrostatic field of rubbish, also plays degradation simultaneously to organic matter.Further sterilization effect is also played in the fast dewatering effect simultaneously.The microwave dryer discharge end is transported to that magnetic deironing device, screening machine, artificial separation platform, winnowing machine, sorting tap a blast furnace, copper, aluminium reclaim.
Clean the generation of combustion gas heat energy: inorganic matters such as the silt particle that screening, selection by winnowing go out, stone, glass, pottery are with the inflammable plastics and the bamboo wood that sub-elect, after pulverizing, preparing burden, add again and add water furnishing lime white with lime and make adhesive and mix, the dosage of adhesive is the 1%-6% of combustibles plastics and bamboo wood and inorganic matter total amount, and wherein inorganic matter is no more than the 15%-35% of total amount.Use the pressure forming machine moulding, pressure is 20T/cm 3-200T/cm 3, fuel slug is of a size of diameter 6mm-100mm.Water content 30%-50%.Make the drying machine of thermal source with waste heat, fuel slug is dried to water content≤30%, enter gas producer, carry out pyrolysis, gasification, destructive distillation and handle, produce thick fuel gas.Fuel slug enters from the gas producer upper top, hot-air and water vapour respectively from gas producer furnace bottom stove add into, fuel gas is gone out from gas producer top, boiler ash sediment is discharged from the furnace bottom of gas producer.Hot water or steam that body of heater is done interlayer water flowing cooling generation outward advance waste heat boiler.Thick fuel gas purifies respectively through the electric fishing storage that electric precipitation flies, electricity removes tar, and this is ripe public technology.Thick fuel gas purifies the NH that last water absorption itself produces 3, it is with hydrogen sulfide generation neutralization reaction, generates that sulphur hydrogenation ammonium adds 1 again, 4-naphthoquinones-2-ichthyodin is made catalyst, regenerates ammoniacal liquor and separates out sulphur with the former reaction.Catalyst is through drum air oxidation regeneration, recycling.Air capacity is 1-5 a times of amount of liquid.NH 3/ H 2S is the unnecessary NH of 0.5-0.9 accumulation 3The water evaporation and concentration becomes liquefied ammonia to be used for composting.The sulfur recovery utilization of taking off can join and replenish moderate-element sulphur in the fertilizer.
The flying dust of dedusting contains heavy metal to be handled with 5% vulcanized sodium, and dosage is in sulphion, be total metals 1-5 doubly, make vulcanized sodium generate the sulfide of heavy metal with the reaction of the heavy metal in the flying dust, be insoluble in water and be in stable state.Fuel gas after the purification mainly contains inflammable CO and H 2, CH 4On a small quantity, enter waste heat boiler and burn, burning produces hot-air and superheated steam or saturated vapor, is used further to gas producer as thermal source and vaporization agent.Hot air temperature is 150 ℃-800 ℃, superheat steam temperature is 150 ℃-450 ℃, the gas producer temperature is controlled at 800 ℃-1800 ℃, pressure is controlled at 0.1MPa-4.0MPa, the water vapour consumption be in the fuel slug every 1Kg pure carbon to need saturated vapor be 0.3Kg-0.8Kg, as being 0.2Kg-0.6Kg with superheated steam.Another part of superheated steam and hot-air is used for the chemical catalysis degraded jar of HTHP; Superheated steam pressure is 0.3MPa-2.0MPa, and temperature is 120 ℃-400 ℃, makes the organic matter macromolecules degradation become little molecule again through molecular rearrangement, take place, and the solid ammonia of Maillard reaction reaches chemical stabilization.Cleaning material after the processing, ordorless, have only burnt the paste or coffee formula fragrance; Can be as organic nitrogenous fertilizer, organic nitrogen composite fertilizer; Can be as fiber feedstuff; Also can be as wood-based plate; Cement, concrete excite, reinforcing agent; Many-sided purposes such as ecological pigment.
The chemical catalysis degradation process method comprises chemical catalysis hydrolysis process, the solid ammonia treatment of chemical catalysis hydrolysis, the solid ammonia treatment of steam catalytic pyrolysis, the expanding treatment of HTHP catalyse pyrolysis, HTHP catalytic pyrolysis percussion flow processing, the solid ammonia treatment of high-temperature and high pressure electrochemistry catalyzing hydrolysis etc.The tail gas that the chemical catalysis degraded takes place contains formic acid, acetate, is neutralized into calcium formate, the recyclable utilization of calcium acetate with lime.Specifically see patent of invention: " a kind of high nutrient composite fertilizer and production method thereof " patent No. 2L961.20682.9, application patent of invention: " the chemical stabilization treatment technology of house refuse " number of patent application: 200510025613.1.
The tar that the electricity consumption trap separated during fuel gas purified is incorporated in the fuel as combustion adjuvant.The flying dust of stabilized processing and boiler ash sediment mixed and do construction material during fuel gas purified: as non-burning brick, building block, floor tile, kerb.Adhesive therefor is a sodium metasilicate, and modulus is 10-30, and dosage is the 10%-30% of solid portion, and the modifier polyacrylamide is 1 ‰ of a sodium metasilicate-5 ‰, and curing agent is a prodan, and dosage is the 5%-30% of sodium metasilicate, and the required pressure of extrusion forming is 50T/cm 3-1000T/cm 3, be 1h-24h hardening time, can replace cement to realize solidifying fast, without health 28 days, but only needs to solidify just construction application of 5h-12h, saves occupation area of equipment, improves output.
The sewage that junk-free treatment plant is produced has the sewage and the sanitary sewage that wash vehicle, flushing device container, flushing ground.The processing method that adopts magnetic field-intensification BAF and magnetic field-intensification flocculation basin to combine is handled the reclaimed water standard of national regulation, recycles as flushing water fire demand water, greening water; The mud that produces is failed circular treatment in the chemical catalysis degraded jar of getting back to HTHP.The entire sewage treatment system is handled the generation that has alleviated stench significantly through magnetization.Whole system is for for sealing system, and each treatment facility is provided with passage, draws blast pipe from high 20m, high altitude discharge with air-introduced machine through negative pressure.Do not have stench around the sewage disposal system, do not have mosquitos and flies to occur.Flushing sewage and sanitary sewage enter the regulating reservoir homogeneous.Magnetize processing through first magnetizer, enter the mud filter tank then, replace sedimentation basin with the mud filter tank, top, mud filter tank is equipped with and is adopted polystyrene foam plastics is the showy filtrate of material, and particle diameter is 1mm-5mm, the thick 2m-5m of filtering layer.There is the perforation pressing plate showy filtrate top, and function is that showy filtrate can not be taken out of with water, plays and holds back and force the contact flocculation effect.Because sludge microbe concentration height, but anti impulsion load, the mud filter tank has simultaneously aerobic, hold concurrently oxygen and three kinds of effects of anaerobism are not only removed COD, BOD, SS is effective, denitrogenation, and phosphor-removing effect is also fine.Magnetic field-intensification is handled; The one, strengthen dissolved oxygen concentration; The 2nd, stimulate microbial activity in the mud, make it quick breeding, strengthen the ability of decomposing organic matter, strengthen the sludge absorption activity, clean-up effect is improved.Mud filter tank water conservancy load is 1m 3/ m 2H-6m 3/ (m 2H).The mud order is 5 days-10 days.The water outlet of mud filter tank is advanced the one-level BAF behind second magnetizer, water outlet behind the 3rd magnetizer, enters the secondary BAF again, and secondary BAF water conservancy load is all 1m 3/ (m 2H)-6m 3/ (m 2H).The water outlet of secondary BAF adds iron, aluminium, silicon ternary polymerization inorganic polymer flocculation agent, the mode of taking the preceding dosing of pump, mixing is through the laggard flocculation tank of the 4th magnetizer, the time of staying is 0.3h-1h, dosage is 80mg/L-200mg/L, theory of evolution flocculation filter tank then, water conservancy load in chemical flocculation filter tank is 5m 3-10m 3/ (m 2H), through holding back absorption, building bridge the water purification, its water outlet is sterilized, is sterilized with the high-pressure electrostatic disinfection sterilization device.The high-pressure electrostatic AC-DC of high-pressure electrostatic disinfection sterilization device: voltage is 1 Wan Fu-30,000 volt, and current strength is 1 milliampere-0.001 milliampere, and flow velocity is 1m/S-50m/S.Water outlet total number of bacteria, colititer all meet the miscellaneous water standard of national regulation, can be as wash water, and fire demand water, greening water.First, second, third and fourth grade magnetizer magnetic field intensity is 1000 Gausses-8000 Gausses, and the magnetic field number of transitions is 3-20 time; Flow velocity is 1m/S-50m/S; Aeration adopts molecular sieve oxygen-enriched aeration machine, and oxygen-enriched content is 〉=90%, and aeration rate is 1-7 with the ratio of sewage quantity: 1; Micro porous aeration head bottom mud filter tank, firsts and seconds BAF is to mud filter tank, the air inlet of firsts and seconds BAF respectively.The mud filter tank and the secondary BAF cycle of operation are all 〉=48h, stop into water during the filtrate backwash, reduce water level, filtrate is loose thereupon to be opened, contained flocculation mud rapid precipitation is to the bottom, pond, and the secondary BAF washes filtrate from bottom to top with vapour, aquapulse mode; Flushing water adopts handles back water, and washing water quantity seldom is the 1%-5% of the water yield after handling.Because of polystyrene foam plastics is hydrophobic, do not adhere to mud, backwash is easy to.Secondary BAF backwash mud is after concentration basin concentrates, supernatant advances regulating reservoir, thickened sludge is squeezed into the mud filter tank with sludge pump: the mud in the mud filter tank is because of underrun, meeting is decomposed most of voluntarily, carries out circular treatment in the chemical catalysis degraded jar of residual active sludge with sludge pump input HTHP.The chemical flocculation basin cycle of operation is 24h-48h, and backwash is adopted and handled back water, the same BAF of washing water quantity and backwashing manner.The chemical sludge of backwash is after concentrating, supernatant advances regulating reservoir, thickened sludge is with containing sour ferrous sulfate waste liquid dissolved iron, aluminium, silicon, the pH value was controlled at 3 o'clock, advance centrifuge, dissolved iron, aluminium, silicon supernatant advance waste liquor storage tank, and the chemical sludge that mud cake promptly separates flocculant is with two kinds of method circular treatment: the one, and same flying dust, slag mix and do building material; The 2nd, can advance circular treatment in the chemical catalysis degraded jar of HTHP.
House refuse clean treatment technology because to sewage, tail gas, thick fuel gas, waste residue all adopts and cleans processing, and recycling, the result does not have residue, do not efflux and let alone what pollutant and residue to factory.
The treatment technology that cleans of house refuse also is applicable to and processing to people, animal, poultry manure is applicable to stalk, residue, the offal treatment of agricultural, forestry; Be applicable to animal and plant to be the processing that raw material is processed the organic waste that is produced; Be applicable to the processing of the organic waste that fermentation industry produces, be applicable to the processing of sewage treatment plant residual active sludge.
Description of drawings
Fig. 1 handles total technological process figure for house refuse of the present invention cleans.
Fig. 2 handles fuel gas generator system process chart for house refuse of the present invention cleans.
Fig. 3 purifies and inorganic matter system building materials system process figure for the thick fuel gas that house refuse of the present invention cleans in the processing method.
Fig. 4 handles the recycling system process chart for the effluent cycle that house refuse of the present invention cleans in the processing method.
The specific embodiment
Describe embodiments of the invention in detail below in conjunction with accompanying drawing.
Referring to Fig. 1, house refuse is transported to treatment plant by the sealing transport vehicle, weigh through truck scale earlier, pass through garbage shaft then, to rubbish dump temporary between, at once by the bag-breaking machine broken bag, open the deodorant spray pump, dump stainless steel shower nozzle between temporary and spray from what ferrous sulfate contained the acid waste liquid basin to temporary rubbish and contain acid concentration 17% through being arranged on rubbish, contain Fe + 26% deodorant, sprinkling is vaporific, and spray amount is 3% of a rubbish volume.Behind the rubbish contact deodorant, stink disappears at once.Pump be located at rubbish dump temporary between in the bottom pump hole.After having sprayed, close the liquid flowing valve of basin to pump.A rubbish deodorant residual liquid part is delivered to replenishing as catalyst in the chemical catalysis degraded jar of HTHP through pump together with the original percolate of rubbish.Through the temporary rubbish of deodorant processing, for the next part choosing creates conditions.For the horse back drying is taken off moisture content, be transported to the crawler type microwave dryer with conveyer belt and carry out quick dewatering drying, temperature is 80 ℃, be 5min drying time.Drying also plays the effect of sterilization simultaneously.After the microwave drying, be sent to separation system with conveyer, magneticly elect iron and steel earlier and reclaim, screening again, selection by winnowing copper aluminium reclaim, and screening, selection by winnowing go out the battery recovery and send special disposal mechanism.Screening, selection by winnowing are told the bamboo wood and the plastics of inorganic matter such as silt, stone, glass, pottery and inflammable large-size, are transported to the fuel gas generator system, the system fuel slug; Screening, selection by winnowing go out to contain organic matter 90% with enterprising basin, enter HTHP catalytic degradation system then, carry out the chemical catalysis degradation treatment, go to the composting system through blowdown, screening, drying again; Tail gas through the absorption tower, the neutralization reaction treatment system.Specifically see patent of invention: " a kind of high nutrient composite fertilizer and production method thereof " patent No. 2L961.20682.9, application patent of invention: " the chemical stabilization treatment technology of house refuse " number of patent application: 200510025613.1.
HTHP catalytic degradation system gets superheated steam and the drying and dehydrating waste heat boiler of hot-air from the series connection of fuel purifying gas producer.
Referring to Fig. 2, put from the silt list under the inorganic matter sieve of sorting, degeneration system.Stone, glass, pottery enter pulverizer after crusher in crushing becomes to be not more than the fritter of 10mm, be ground into 〉=powder of 50 sieve meshes; Advance the inorganic matter feed bin together with silt particle.Big part bamboo and wood from separation system advances big part disintegrating machine, is broken into the fritter bamboo wood that is not more than 10mm; Advance flour mill then; Be milled to 〉=the bamboo wood powder of 60 sieve meshes, advance bamboo wood powder feed bin.Plastics from separation system enter shear crusher, are broken into to be not more than the wide plastic strip of 3mm; Through fine crusher, be ground into the fragment of about 2mm * 2mm again, advance the plastics feed bin.The lime water is adjusted to the pulpous state material of thickness as bonding agent, and the ratio of mud is 3: 1.Four kinds of compositions advance the computer proportioning machine by weight proportion: inorganic matter accounts for 15%, plastics 65%, and bamboo wood accounts for 10%, and lime accounts for 10%, accounts for 2% from the tar of the tar basin of fuel gas cleaning system, and laggard pressure forming machine stirs; Pressure is 200T/cm 2, behind punch forming Φ 20mm * 20mm, drying machine drying after water content is not more than 30%, is advanced the screening machine screening, and oversize and each fuel slug advance bunker.Screenings returning pressure make-up machine is briquetting again.
Fuel slug is sent the gas producer top from bunker to conveyer, enters gas producer: the high 3m of the material of gas producer, body of heater external diameter are 1.5m, and height is 7.5m, with 285 #Carbon steel is made housing, and the two-layer iron refractory liner of casting, and thickness is 200mm, and operating pressure is 2.5MPa, and the outlet external diameter is 0.9m, air preheat to 200 ℃.Fire grate has rotation and stirs cake, can move vertically, on coaxial a revolving scraper is arranged, and can scrape the ash charge lock hopper to lime-ash.Whole fuel gas producer is told ash bed, gasification layer, destructive distillation layer, drying layer from bottom to top.From logical hot-air of furnace bottom fire grate and water vapour.The weight ratio of water vapour and hot-air is 1: 2, and operating pressure is 1.6MPa.Keep stove internal combustion layer temperature to be minimum 900 ℃, the highest 1600 ℃.Fuel gas is extracted out from suitable for reading and gasification layer two, advances the fuel gas cleaning system, and electrostatic precipitator is taken off flying dust; The detar of static trap; After water absorption tower deamination, the desulfurization, enter waste heat boiler, second-time burning produces superheated steam and hot-air; A part is supplied with gas producer; A part is supplied with the chemical catalysis degraded jar of the HTHP of organic matter processing.The flying dust that gas producer produces comes along building materials system system building materials with boiler ash sediment after the vulcanized sodium stabilization processes.
Referring to Fig. 3, flying dust can be removed totally through double helix deduster and the series operation of board-like static trap from the thick fuel gas of gas producer, this is more ripe disclosed technology.Containing heavy metal in the flying dust need carry out stabilization processes and make it to be difficult for by water and acid rain dissolving.Flying dust advances the stabilization reactions jar, and 5% vulcanized sodium sprays stirring, reaction time 1h with pump to retort in jar, and dosage is 3 times of amounts that bright sulfur is counted total metals in the flying dust, and heavy metal is formed sulfide, is difficult for dissolving.Advance the flying dust basin of stabilisation then.After board-like static trap is removed flying dust, enter tubular type static trap and capture tar, this also is ripe disclosed technology.After removing tar, tar advances basin, for the combustion-supporting usefulness of fuel slug additive.The tubular type static trap into high temperature resistant sack cleaner that comes out is further removed micro-flying dust.Flying dust advances the stabilization reactions jar, the laggard basin of stabilisation.Pearl filler is arranged, with micro-H in the plastics 2The S reaction generates a part of CaS and enters in the flying dust, after last one cloth bag removes flying dust, enters the absorption tower, and water absorbs the ammonia in the fuel gas, generates ammoniacal liquor and absorbs hydrocyanic acid.With in the ammoniacal liquor nature and hydrogen sulfide generate sulphur hydracid ammonium and cyanogen hydrogen ammonium under catalyst 1,4-naphthoquinones-2-ichthyodin effect, regenerate ammoniacal liquor and separate out sulphur.Catalyst 1,4-naphthoquinones-2-ichthyodin consumption are 2% of sulfur content.Sulfur recovery is incorporated in the organic fertilizer.The catalyst air aeration, oxidation, regeneration cycle play catalytic action again.NH 3/ H 2S is 0.7.The surplus ammonia of desulphurization reaction jar runs up at 15% o'clock, enters surplus ammonia evaporation and concentration jar and heats 90 ℃, and surplus ammonia evaporation is compressed into liquefied ammonia with ammonia compressor and goes the solid ammonia system of composting.Fuel gas after the purification advances the waste heat boiler combustion heat supplying.After flying dust still carries out stabilization processes with pre-treatment with 5% sulfuration, advance the computer proportioning machine together with lime-ash, the Autoadhesive basin adds sodium silicate binder simultaneously, the sodium metasilicate dosage is 18% of a solid amount, the sodium metasilicate modulus is 30, adding adhesive modifier is PAMC, and dosage is 1 ‰ of an adhesive sodium metasilicate.Add the curing agent prodan, dosage is 16% of a sodium metasilicate, and after the weighing by the computer proportioning machine, pure mixing time is 3min.Enter pressure forming machine, pressure is 100T/cm 2, this is ripe open equipment, after the moulding, enters between temporary temporary.3h promptly solidifies.By stacking machine, piling is put in storage again.Make-up machine is produced different product with different moulds; Can produce non-burning brick, building block, floor tile, kerb, partition plate etc.The feature of this kind construction material is to make adhesive without health 28 days without cement, and 3h solidifies, and 10h reaches maximum intensity, reaches state-set standard.
Referring to Fig. 4, the sewage that junk-free treatment plant produces all enters regulating reservoir as flushing vehicle sewage, equipment container flushing sewage, ground flushing sewage and sanitary sewage, homogenizes.Regulating reservoir time of staying 4h enters the mud filter tank by first magnetizer, does not establish sedimentation basin.The water conservancy load in mud filter tank is 1m 3/ (m 2H), enter second magnetizer then.After the magnetization, advance the one-level BAF; After the magnetization of the 3rd magnetizer, advance the secondary BAF again.One-level, the water conservancy load of secondary BAF is 3m 3/ (m 2H).The magnetization of the 4th magnetizer is advanced in one secondary BAF water outlet again, advances the flocculation reaction groove then.Flocculant is iron, aluminium, silicon ternary polymerization inorganic polymer flocculation agent, after the metering, drops into before pump, after pump is mixed fast, after the magnetizer magnetization, advances the flocculation reaction groove.Dosage is 20min for the 100mg/L. reaction time, and the theory of evolution flocculation basin filters then; The water conservancy load is 5m 3/ (m 2H).Clean-up effect is from regulating reservoir water outlet CODcr500mg/L, SS150mg/L, chemical flocculation filter tank water outlet CODcr<10mg/L, BOD 5<8mg/L, NH 4-N<10mg/L, turbidity are 2 degree, meet the miscellaneous water standard of national regulation fully.The chemical flocculation basin water outlet is through the sterilization of high-pressure electrostatic disinfection sterilization device, and DC voltage is 10,000 volts, and DC current is 10 microamperes, and flow velocity is 20m/s, total number of bacteria, and colititer all meets the miscellaneous water standard of national regulation; Mud filter tank, secondary BAF, the chemical flocculation filter tank, filtrate is all the showy filtrate that polystyrene foam plastics is a material, and particle diameter is 3mm40%, 2mm60%, filter material layer height 4m, total height is 7.5m.Backwashing system is established in the filter tank, and the backwash water level is handled back water, and washing water quantity is for handling 2% of the water yield, and adding tolerance is 30% of washing water quantity.During flushing, reduce water level earlier, make the filtrate that floats loose downwards, the mud that is adsorbed is bulk and drops to bottom, biofilter sludge bucket rapidly.Squeeze into the mud filter tank with sludge pump then.Because of polystyrene foam plastics is a hydrophobic type, foundry loam not, fine flushing.The secondary BAF cycle of operation is all 48h.The mud filter tank is because of underrun, and mud can major part decompose voluntarily, and surplus a small amount of activated sludge can be got back to chemical catalysis degeneration system circular treatment, does not efflux mud.Handle back water and can do flushing water, fire demand water again, greening water, not outer draining.After chemical sludge in the chemistry filter tank concentrated, supernatant advanced regulating reservoir, and thickened sludge advances centrifuge with containing sour ferrous sulfate waste liquid dissolving, and centrifugal mud cake advances dissolving tank.Dosage ammonium pH value is controlled to be 3, and the iron of dissolving, aluminium, silicon inorganic polymer flocculant are returned the flocculant groove with pump and made flocculant again and replenish, and be recycling.Regularly add flocculant.The mud of precipitation enters the chemical catalysis degeneration system, also can join in flying dust, the boiler ash sediment and make building materials.
Molecular sieve oxygen-enriched aeration machine aeration is all used in mud filter tank, I and II biofilter, and oxygen content is 90%, and aeration rate is 1: 1 with the ratio of sewage quantity; The magnetizer magnetic field intensity is 2500 Gausses, and the magnetic field number of alternations is 8 times; Flow velocity is 20m/s.The mud filter tank, secondary BAF and chemical flocculation filter tank all seal, and all are provided with passage, and with the 20m height, the blast pipe of Dg300 is connected, the static pressure exhaust of 20mm high-altitude.Making does not have around the treating apparatus stench to produce, and does not have the mosquitos and flies parasitism yet, reaches fully to clean, recycling, not externally discharged waste water river mud.

Claims (7)

  1. House refuse clean processing method, comprise that rubbish is toppled over, the stench when temporary is handled; The recycling treatment of organic matter, inorganic matter after the sorting; Clean the generation of combustion gas heat energy; The recycling treatment of sewage, flue gas, tail gas, flying dust, slag, all adopt the method that cleans, circulates, recycles, reach no residue at last, it is characterized in that, topple at rubbish, the stench when temporary comprises that microwave dryer carries out the rapid draing processed in handling; Described rubbish is toppled over, the stench when keeping in is handled, and adopts the sour ferrous sulfate waste liquid that contains of pickled plate to do deodorant; Its concentration that contains acid is 15%-18%, contains Fe + 2At 5%-8%, between temporary, establish deodorant basin and ejecting device, the processing of spraying of the rubbish between temporary, spray amount is the 2%-10% of rubbish volume, and deodorant is reinstated the chemical degradation jar that pump is transported to HTHP with percolate one.
  2. 2. house refuse as claimed in claim 1 cleans processing method, it is characterized in that, the described organic recycling treatment that sub-elects: the organic matter that sub-elects comprises that the kitchen is surplus, paper, woody and draft class plant, the fruit skin, the nuclear slag, animal skin, leather, the natural fiber of dry goods, staple fibre, the chemical synthetic fiber of non-plastics, adopt the chemical catalysis biodegrading process of HTHP to handle, temperature is greater than 120 ℃, pressure is greater than 0.2MPa, processing time is greater than 2min, wherein the chemical catalysis degradation process method is the chemical catalysis hydrolysis, the solid ammonia treatment of chemical catalysis hydrolysis, the solid ammonia treatment of steam catalytic pyrolysis, the expanding treatment of HTHP catalyse pyrolysis, the percussion flow of HTHP catalytic pyrolysis is handled, a kind of in the solid ammonia treatment of high-temperature and high pressure electrochemistry hydrolysis.
  3. 3. house refuse as claimed in claim 1 cleans processing method, it is characterized in that, describedly clean being produced as of combustion gas heat energy with the plastics after the sorting, bamboo wood and inorganic matter, through pulverizing, batching, mix, fuel slug is made in extrusion forming, inorganic matter comprises silt particle, stone, glass, pottery, fuel slug enters gas producer and carries out pyrolysis, gasification, destructive distillation is handled, produce thick fuel gas, thick fuel gas is through purifying electric precipitation, electricity removes tar, water absorbs in the ammonia and the desulfurization under hydrogen sulfide and the catalyst action is handled, form sulphur hydracid ammonium, wherein catalyst is 1,4-naphthoquinones-2-ichthyodin, dosage are 1-5 times of sulphion total amount; In thick fuel gas processing procedure, be blown into air simultaneously, air capacity is 1-5 a times of amount of liquid, Recovered sulphur and excess ammonia produce clean fuel gas; Clean fuel gas is through the waste heat boiler clean burning, produce steam and hot-air as supplying with gas producer and handling the organic energy, the flying dust of dedusting contains heavy metal to carry out hybrid reaction with spray pattern with flying dust with 5% vulcanized sodium and makes heavy metal in the flying dust form sulfide and be the indissoluble state and reach stabilisation, the vulcanized sodium dosage is with the bright sulfur ionometer, for the 1-5 of total metals doubly, tar mixes in the fuel slug, cooks combustion adjuvant.
  4. 4. house refuse as claimed in claim 3 cleans processing method, it is characterized in that, described fuel slug enters gas producer and carries out pyrolysis, gasification, destructive distillation processing, produce thick fuel gas, fuel slug is of a size of diameter 6mm-100mm, enter from the gas producer furnace roof, hot-air and water vapour that waste heat boiler produces enter from the fire grate of gas producer furnace bottom respectively, and ashes are discharged from the gas producer bottom; Gas producer reaction in furnace temperature is controlled at 800 ℃-1800 ℃, and pressure is controlled at 0.1MPa-4.0MPa, and water vapour is saturated vapor or superheated steam, and its consumption is every 1Kg pure carbon in the vaporising fuel piece, and the amount of required saturated vapor is 0.3Kg-0.8Kg.
  5. 5. house refuse as claimed in claim 1 cleans processing method, it is characterized in that, described flying dust, slag recycling treatment are the flying dust of stabilized processing, and the slag that produces with gas producer mixes as construction material again; Adhesive therefor is a sodium metasilicate, and the modulus of sodium metasilicate is 10-30, and dosage is the 10%-30% of solid portion, modifier polyacrylamide dosage is 1 ‰ of a sodium metasilicate-5 ‰, curing agent is a prodan, and dosage is the 5%-30% of sodium metasilicate, and the required pressure of extrusion forming is 50T/cm 2-100T/cm 2, be 1h-24h hardening time.
  6. 6. house refuse as claimed in claim 1 cleans processing method, it is characterized in that, described sewage recycling is handled: the kind of sewage has flushing vehicle, equipment, container, the sewage on ground, sanitary sewage to enter the regulating reservoir in the entire sewage treating apparatus respectively, the regulating reservoir volume is 4-5 a times of sewage quantity, the water that regulating reservoir comes out is after first magnetizer is handled, enter the mud filter tank, mud filter tank volume is 4-7 a times of sewage quantity, and the water conservancy load is 1m 3-6m 3/ (m 2H), wherein the filtrate in mud filter tank employing polystyrene foam is the floating filter material of material, the thick 2m-5m of filtering layer, particle diameter is 1mm-5mm, the water outlet of mud filter tank after second magnetizer is handled, is advanced the one-level BAF again, and the water outlet of one-level BAF is behind the 3rd magnetizer, enter the secondary BAF again, the concrete parameter of secondary BAF is fully with the one-level BAF; Adopt molecular sieve oxygen-enriched aeration mode, carry out aeration to mud filter tank, I and II BAF respectively, oxygen-enriched content 〉=90%, aeration rate is 1-7 with the ratio of sewage quantity: 1; The cycle of operation is 24h-48h, and the backwash water yield adopts the backwash mode of carbonated drink mixing for handling the 1%-3% of the back water yield, and air capacity is the 10%-50% of the water yield, and the backwashing water precipitation concentrates, and supernatant returns regulating reservoir, and thickened sludge enters the mud filter tank; The filtrate size of secondary BAF, thickness of filter bed are with the filtrate in mud filter tank; The water outlet of secondary BAF adds iron, aluminium, silicon ternary polymerization inorganic polymer flocculation agent, dosage is 80mg/L-200mg/L, mix before the pump, after the 4th magnetizer is handled, advance flocculation tank, time of staying 0.3h-1h, theory of evolution flocculation filter tank, chemical flocculation filter tank technique parameter is same, the secondary BAF, difference, without oxygen-enriched aeration, the water conservancy load is 5m 3-10m 3/ (m 2H), the water outlet of chemical flocculation filter tank is advanced clear water reserviors after sterilizing with the high-pressure electrostatic disinfection sterilization device, and the residual active sludge in the mud filter tank turns back in the high-temperature high-pressure chemical catalytic degradation jar, and is recycling; First to fourth magnetizer magnetic field intensity is 1000 Gausses-8000 Gausses, and the magnetic field number of transitions is 3-20 time; Flow velocity is 1m/s-50m/s; The voltage of high-pressure electrostatic disinfection sterilization device is 1 Wan Fu-30,000 volt, and electric current is 1 milliampere-0.001 milliampere of a direct current, and flow velocity is 1m/s-50m/s; The entire sewage treating apparatus is hermetically sealed, and each device is established passage, receives the high blast pipe of 20m, to handling the gas high altitude discharge that produces, does not have stench to produce around the sewage-treatment plant, does not have the mosquitos and flies parasitism.
  7. 7. house refuse as claimed in claim 1 cleans processing method, it is characterized in that, except that handling house refuse, also comprises organic solid castoff, and it comprises people, domestic animal, poultry manure; With plant, animal is the industrial organic waste residues of raw material converted products, the organic waste residues of fermentation industry, agricultural, forestry, discarded object and residue, the residual active sludge of sewage treatment plant.
CNB2005100257810A 2005-05-12 2005-05-12 Cleansed handling domestic garbage Expired - Fee Related CN100534649C (en)

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CN101314163B (en) * 2008-06-16 2010-06-09 费爱民 Reclamation processing method for poor garbage
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CN102500607A (en) * 2011-10-28 2012-06-20 北京建筑材料科学研究总院有限公司 Method for performing pyrolysis uniting building-material utilization to rubbish oversize products
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WO2013086742A1 (en) * 2011-12-16 2013-06-20 Lin Xiumei Sludge magnetization pyrolyzing treatment device and sludge treatment method
CN106269777A (en) * 2015-05-19 2017-01-04 深圳市易达环保创新科技有限公司 One way of life waste disposal method and device
CN105195501B (en) * 2015-11-03 2017-06-13 青岛市固体废弃物处置有限责任公司 A kind of microwave handling method of house refuse
CN105598139A (en) * 2016-03-07 2016-05-25 谢泽明 Household-garbage classifying, treating and recycling device
CN106111662A (en) * 2016-06-24 2016-11-16 浦北县科学技术开发中心 Preprocess method before one way of life garbage loading embeading
CN106363010A (en) * 2016-08-31 2017-02-01 芜湖广仁慧环保科技有限公司 Method for classification and resource utilization of municipal solid waste
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JP6384846B1 (en) * 2018-03-15 2018-09-05 エンヴィテック・エンジニアリング株式会社 Separation of metals from shredder dust, conversion of organic combustible residues into fuel, effective utilization of inorganic residues, and treatment equipment
CN108611147B (en) * 2018-05-22 2020-07-14 新奥科技发展有限公司 Formed coke and preparation method thereof
CN109909262B (en) * 2019-02-20 2020-07-24 辽宁海天阁环保科技有限公司 Treatment method for synergistically solidifying waste incineration fly ash and waste concentrated solution
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