CN101296863B - 制备LiMnPO4的方法 - Google Patents

制备LiMnPO4的方法 Download PDF

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Publication number
CN101296863B
CN101296863B CN2006800400811A CN200680040081A CN101296863B CN 101296863 B CN101296863 B CN 101296863B CN 2006800400811 A CN2006800400811 A CN 2006800400811A CN 200680040081 A CN200680040081 A CN 200680040081A CN 101296863 B CN101296863 B CN 101296863B
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China
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solution
source
limnpo
dispersion
preparing
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Chinese (zh)
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CN101296863A (zh
Inventor
矶野基史
蒂埃里·德列津
伊万·埃克斯纳尔
伊沃·特林克
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Toyota Motor Corp
Dow Global Technologies LLC
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Toyota Motor Corp
Dow Global Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/37—Phosphates of heavy metals
    • C01B25/377—Phosphates of heavy metals of manganese
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Secondary Cells (AREA)
CN2006800400811A 2005-10-28 2006-10-27 制备LiMnPO4的方法 Expired - Fee Related CN101296863B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP314054/2005 2005-10-28
JP2005314054A JP5084131B2 (ja) 2005-10-28 2005-10-28 ＬｉＭｎＰＯ４の製造方法
PCT/JP2006/322037 WO2007049815A2 (en) 2005-10-28 2006-10-27 Method for manufacturing limnpo4

Publications (2)

Publication Number Publication Date
CN101296863A CN101296863A (zh) 2008-10-29
CN101296863B true CN101296863B (zh) 2011-06-01

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CN2006800400811A Expired - Fee Related CN101296863B (zh) 2005-10-28 2006-10-27 制备LiMnPO4的方法

Country Status (6)

Country Link
US (1) US7749658B2 (https=)
EP (1) EP1957404B1 (https=)
JP (1) JP5084131B2 (https=)
KR (1) KR100984421B1 (https=)
CN (1) CN101296863B (https=)
WO (1) WO2007049815A2 (https=)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1889314A2 (en) * 2005-06-06 2008-02-20 High Power Lithium S.A. Lithium rechargeable electrochemical cell
EP1989747B1 (en) * 2006-02-14 2017-04-12 Dow Global Technologies LLC Lithium manganese phosphate positive material for lithium secondary battery
EP1901388A1 (en) * 2006-09-14 2008-03-19 High Power Lithium S.A. Overcharge and overdischarge protection in lithium-ion batteries
US20080303004A1 (en) * 2007-06-08 2008-12-11 Conocophillips Company Method for producing lithium transition metal polyanion powders for batteries
EP2015382A1 (en) * 2007-07-13 2009-01-14 High Power Lithium S.A. Carbon coated lithium manganese phosphate cathode material
JP5272756B2 (ja) * 2008-02-12 2013-08-28 株式会社Ｇｓユアサ リチウム二次電池用正極活物質、リチウム二次電池用正極及びリチウム二次電池、並びに、その製造方法
TWI474970B (zh) 2008-12-29 2015-03-01 Basf Se 於水熱條件下合成鋰－金屬－磷酸鹽
US20110008233A1 (en) 2009-07-10 2011-01-13 Semiconductor Energy Laboratory Co., Ltd. Positive electrode active material
KR101748406B1 (ko) * 2009-08-07 2017-06-16 가부시키가이샤 한도오따이 에네루기 켄큐쇼 양극 활물질의 제작 방법
US7931985B1 (en) * 2010-11-08 2011-04-26 International Battery, Inc. Water soluble polymer binder for lithium ion battery
US8076026B2 (en) * 2010-02-05 2011-12-13 International Battery, Inc. Rechargeable battery using an aqueous binder
JP5820566B2 (ja) * 2010-02-17 2015-11-24 株式会社Ｇｓユアサ 正極材料の製造方法
JP5917027B2 (ja) 2010-06-30 2016-05-11 株式会社半導体エネルギー研究所 電極用材料の作製方法
US20110143206A1 (en) * 2010-07-14 2011-06-16 International Battery, Inc. Electrode for rechargeable batteries using aqueous binder solution for li-ion batteries
KR101219395B1 (ko) * 2010-07-15 2013-01-11 전자부품연구원 리튬이차전지용 양극재료 및 그의 제조방법
US8102642B2 (en) * 2010-08-06 2012-01-24 International Battery, Inc. Large format ultracapacitors and method of assembly
KR101484015B1 (ko) 2010-09-03 2015-01-19 쇼와 덴코 가부시키가이샤 리튬 금속 인산염의 제조 방법
JP5557715B2 (ja) * 2010-12-06 2014-07-23 株式会社日立製作所 リチウムイオン二次電池用正極材料およびその製造方法，リチウムイオン二次電池用正極活物質，リチウムイオン二次電池用正極，リチウムイオン二次電池
JP5673275B2 (ja) * 2011-03-23 2015-02-18 住友大阪セメント株式会社 リチウムイオン電池用正極活物質とその製造方法及びリチウムイオン電池用電極並びにリチウムイオン電池
EP2693538A4 (en) 2011-03-28 2015-05-06 Univ Hyogo ELECTRODE MATERIAL FOR A SECONDARY BATTERY, METHOD FOR PRODUCING THE ELECTRODE MATERIAL FOR A SECONDARY BATTERY AND SECONDARY BATTERY
JP6143216B2 (ja) * 2012-08-29 2017-06-07 株式会社デンソー 非水電解質二次電池用正極活物質の製造方法
EP2919303A4 (en) 2012-11-12 2016-06-15 Mitsui Shipbuilding Eng ELECTRODE MATERIAL AND METHOD FOR PRODUCING AN ELECTRODE MATERIAL
US9673454B2 (en) 2013-02-18 2017-06-06 Semiconductor Energy Laboratory Co., Ltd. Sodium-ion secondary battery
KR101624317B1 (ko) 2014-09-01 2016-06-07 한국생산기술연구원 이차전지용 양극소재 제조방법
CN110371940A (zh) * 2019-09-04 2019-10-25 井冈山大学 一种LiMnPO4前驱体模板Li3PO4空心微球及其制备方法和应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1322023A (zh) * 2000-04-25 2001-11-14 索尼株式会社 正极活性材料和非水电解质电池
CN1571195A (zh) * 2004-05-13 2005-01-26 复旦大学 用于薄膜锂离子电池的纳米阴极材料及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1125983A (ja) 1997-07-04 1999-01-29 Japan Storage Battery Co Ltd リチウム電池用活物質
EP1094532A1 (en) 1999-04-06 2001-04-25 Sony Corporation Method for manufacturing active material of positive plate and method for manufacturing nonaqueous electrolyte secondary cell
EP1261050A1 (en) * 2001-05-23 2002-11-27 n.v. Umicore s.a. Lithium transition-metal phosphate powder for rechargeable batteries
JP4475882B2 (ja) 2003-03-31 2010-06-09 国立大学法人九州大学 ２次電池用正極材料の製造方法、および２次電池

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1322023A (zh) * 2000-04-25 2001-11-14 索尼株式会社 正极活性材料和非水电解质电池
CN1571195A (zh) * 2004-05-13 2005-01-26 复旦大学 用于薄膜锂离子电池的纳米阴极材料及其制备方法

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
C.Delacourt et al..One-Step Low-Temperature Route for the Preparation of Electrochemically Active LiMnPO4 Powders.《Chem. Mater.》.2003,第16卷(第1期),93-99. *
Charles Delacourt et al..Low temperature preparation of optimized phosphates for Li-battery applications.《Solid State Ionics》.2004,第173卷113-118. *
白莹 等.新型锂离子电池正极材料LiMPO4（M=Fe，Mn）的谱学和电化学研究.《光散射学报》.2004,第15卷(第4期),231-236.
白莹等.新型锂离子电池正极材料LiMPO4(M=Fe,Mn)的谱学和电化学研究.《光散射学报》.2004,第15卷(第4期),231-236. *

Also Published As

Publication number Publication date
JP2007119304A (ja) 2007-05-17
EP1957404A2 (en) 2008-08-20
JP5084131B2 (ja) 2012-11-28
KR20080065676A (ko) 2008-07-14
WO2007049815A3 (en) 2007-11-15
US7749658B2 (en) 2010-07-06
CN101296863A (zh) 2008-10-29
KR100984421B1 (ko) 2010-09-30
US20090184296A1 (en) 2009-07-23
WO2007049815A2 (en) 2007-05-03
EP1957404B1 (en) 2011-08-03

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