CN101273001A - 从羧酸混合物制备混合酮的选择性催化剂 - Google Patents

从羧酸混合物制备混合酮的选择性催化剂 Download PDF

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Publication number
CN101273001A
CN101273001A CNA2006800351622A CN200680035162A CN101273001A CN 101273001 A CN101273001 A CN 101273001A CN A2006800351622 A CNA2006800351622 A CN A2006800351622A CN 200680035162 A CN200680035162 A CN 200680035162A CN 101273001 A CN101273001 A CN 101273001A
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CN
China
Prior art keywords
catalyst composition
mixture
carboxylic acid
zirconium dioxide
surface area
Prior art date
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Pending
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CNA2006800351622A
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English (en)
Chinese (zh)
Inventor
A·V·伊纳琴科
M·M·曼尼钱
刘铸舫
C·W·怀顿
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Eastman Chemical Co
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Eastman Chemical Co
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Publication of CN101273001A publication Critical patent/CN101273001A/zh
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B01J27/1806—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with alkaline or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/48—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation involving decarboxylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNA2006800351622A 2005-09-23 2006-09-22 从羧酸混合物制备混合酮的选择性催化剂 Pending CN101273001A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US71987105P 2005-09-23 2005-09-23
US60/719,871 2005-09-23

Publications (1)

Publication Number Publication Date
CN101273001A true CN101273001A (zh) 2008-09-24

Family

ID=37670649

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2006800351622A Pending CN101273001A (zh) 2005-09-23 2006-09-22 从羧酸混合物制备混合酮的选择性催化剂

Country Status (6)

Country Link
US (2) US7452841B2 (enExample)
EP (1) EP1943206A1 (enExample)
JP (1) JP2009509729A (enExample)
KR (1) KR20080053306A (enExample)
CN (1) CN101273001A (enExample)
WO (1) WO2007038371A1 (enExample)

Cited By (1)

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CN109422630A (zh) * 2017-08-31 2019-03-05 中国科学院大连化学物理研究所 乙酸与乙醇两段法制备酮类化合物

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WO2016177842A1 (en) * 2015-05-07 2016-11-10 Rhodia Operations Process for the decarboxylative ketonization of fatty acids or fatty acid derivatives
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BR112019009170B1 (pt) 2016-11-08 2022-09-13 Rhodia Operations Método m para a preparação de pelo menos um composto final a partir de pelo menos uma cetona interna
US10239812B2 (en) 2017-04-27 2019-03-26 Sartec Corporation Systems and methods for synthesis of phenolics and ketones
US10696923B2 (en) 2018-02-07 2020-06-30 Sartec Corporation Methods and apparatus for producing alkyl esters from lipid feed stocks, alcohol feedstocks, and acids
US10544381B2 (en) 2018-02-07 2020-01-28 Sartec Corporation Methods and apparatus for producing alkyl esters from a reaction mixture containing acidified soap stock, alcohol feedstock, and acid
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CN113559843B (zh) * 2021-07-09 2023-08-11 江苏恒兴新材料科技股份有限公司 一种合成2-戊酮用催化剂的制备方法与用途
CN114558571A (zh) * 2022-03-08 2022-05-31 润泰化学（泰兴）有限公司 用于异丁酸与乙酸反应生成甲基异丙基酮的球形复合催化剂及制备方法
CN115739098B (zh) * 2022-11-21 2024-03-01 中国科学院山西煤炭化学研究所 一种催化剂及其制备方法和应用
CN115837272B (zh) * 2022-12-07 2024-08-16 江苏扬农化工股份有限公司 一种用于合成甲基异丙基酮的催化剂及其制备方法

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109422630A (zh) * 2017-08-31 2019-03-05 中国科学院大连化学物理研究所 乙酸与乙醇两段法制备酮类化合物
CN109422630B (zh) * 2017-08-31 2021-12-14 中国科学院大连化学物理研究所 乙酸与乙醇两段法制备酮类化合物

Also Published As

Publication number Publication date
US7659432B2 (en) 2010-02-09
JP2009509729A (ja) 2009-03-12
US20090182173A1 (en) 2009-07-16
EP1943206A1 (en) 2008-07-16
US7452841B2 (en) 2008-11-18
US20070093679A1 (en) 2007-04-26
KR20080053306A (ko) 2008-06-12
WO2007038371A1 (en) 2007-04-05

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Open date: 20080924