CN101242895B - 用于氢化含有能被氢化的基团的有机化合物的催化剂和方法 - Google Patents

用于氢化含有能被氢化的基团的有机化合物的催化剂和方法 Download PDF

Info

Publication number
CN101242895B
CN101242895B CN2006800305342A CN200680030534A CN101242895B CN 101242895 B CN101242895 B CN 101242895B CN 2006800305342 A CN2006800305342 A CN 2006800305342A CN 200680030534 A CN200680030534 A CN 200680030534A CN 101242895 B CN101242895 B CN 101242895B
Authority
CN
China
Prior art keywords
catalyst
hydrogenation
ruthenium
substituted
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2006800305342A
Other languages
English (en)
Chinese (zh)
Other versions
CN101242895A (zh
Inventor
F·范拉尔
M·贝克尔
E·施瓦布
J·亨克尔曼
P·波拉内科
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN101242895A publication Critical patent/CN101242895A/zh
Application granted granted Critical
Publication of CN101242895B publication Critical patent/CN101242895B/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/462Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/64Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656Manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0205Impregnation in several steps
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B35/00Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2006800305342A 2005-06-22 2006-06-20 用于氢化含有能被氢化的基团的有机化合物的催化剂和方法 Expired - Fee Related CN101242895B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102005029200.3 2005-06-22
DE102005029200A DE102005029200A1 (de) 2005-06-22 2005-06-22 Katalysator und Verfahren zur Hydrierung von hydrierbare Gruppen enthaltenden organischen Verbindungen
PCT/EP2006/063323 WO2006136541A2 (de) 2005-06-22 2006-06-20 Ru-katalysator und verfahren zur hydrierung von hydrierbare gruppen enthaltenden organischen verbindungen

Publications (2)

Publication Number Publication Date
CN101242895A CN101242895A (zh) 2008-08-13
CN101242895B true CN101242895B (zh) 2012-01-11

Family

ID=37433856

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2006800305342A Expired - Fee Related CN101242895B (zh) 2005-06-22 2006-06-20 用于氢化含有能被氢化的基团的有机化合物的催化剂和方法

Country Status (8)

Country Link
US (1) US8207327B2 (enExample)
EP (1) EP1899051A2 (enExample)
JP (1) JP2008543550A (enExample)
KR (1) KR101354236B1 (enExample)
CN (1) CN101242895B (enExample)
CA (1) CA2612435C (enExample)
DE (1) DE102005029200A1 (enExample)
WO (1) WO2006136541A2 (enExample)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005049568A1 (de) 2005-10-17 2007-04-19 Basf Ag Verfahren zur kontinuierlichen Hydrierung oder hydrierenden Aminierung
EP2049254B1 (de) 2006-07-31 2010-12-15 Basf Se Verfahren zur regenerierung von rutheniumkatalysatoren für die kernhydrierung von phthalaten
US8889936B2 (en) 2006-07-31 2014-11-18 Basf Se Method of regenerating ruthenium catalysts for the hydrogenation of benzene
ES2759627T3 (es) 2006-07-31 2020-05-11 Basf Se Procedimiento integrado consistente en la hidrogenación con catalizadores de rutenio y regeneración de los mismos
DE102007025223A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025362A1 (de) 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025315A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung
DE102007025443A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025356A1 (de) * 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025442B4 (de) 2007-05-31 2023-03-02 Clariant International Ltd. Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE202008017277U1 (de) 2008-11-30 2009-04-30 Süd-Chemie AG Katalysatorträger
ES2602116T3 (es) 2008-12-17 2017-02-17 Basf Se Procedimiento continuo de producción de ciclohexilmetanoles sustituidos
US20110144398A1 (en) 2009-12-11 2011-06-16 Basf Se Process for regenerating a ruthenium-containing supported hydrogenation catalyst
WO2011072992A1 (en) 2009-12-15 2011-06-23 Exxonmobil Chemical Patents Inc. Temperature control of an oligomerisation process and reactor
KR101833077B1 (ko) 2009-12-15 2018-02-27 바스프 에스이 방향족 화합물의 수소화를 위한 촉매 및 방법
EP2534281B1 (de) 2010-02-12 2019-01-09 Basf Se Verfahren zur herstellung von 4-isopropylcyclohexylmethanol
US8889920B2 (en) 2010-02-12 2014-11-18 Basf Se Process for preparing 4-isopropylcyclohexylmethanol
MX2012010715A (es) 2010-03-24 2012-10-05 Basf Se Proceso para la preparacion de 4 - ciclohexil - 2 - metil - 2- butanol.
US8450534B2 (en) 2010-03-24 2013-05-28 Basf Se Process for preparing 4-cyclohexyl-2-methyl-2-butanol
DE102010026462A1 (de) * 2010-07-08 2012-01-12 Süd-Chemie AG Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator
US9056812B2 (en) 2011-09-16 2015-06-16 Basf Se Process for preparing 4-cyclohexyl-2-methyl-2-butanol
CN103796980B (zh) 2011-09-16 2016-08-31 巴斯夫欧洲公司 制备4-环己基-2-甲基-2-丁醇的方法
US9340754B2 (en) 2012-11-27 2016-05-17 Basf Se Process for the preparation of cyclohexyl-substituted tertiary alkanols
CN106338551B (zh) * 2015-07-07 2019-03-08 中国石油化工股份有限公司 重整催化剂中不同形态硫元素含量的分析方法
EP3359290B1 (de) * 2015-10-05 2025-01-01 Basf Se Verfahren zur herstellung von ruthenium/eisen/kohlenstoffträger-katalysatoren
JP6131370B1 (ja) * 2016-06-10 2017-05-17 千代田化工建設株式会社 合成ガス製造触媒用担体及びその製造方法、合成ガス製造触媒及びその製造方法、並びに合成ガスの製造方法
CN109790101A (zh) * 2016-09-09 2019-05-21 埃克森美孚化学专利公司 邻苯二甲酸酯的氢化方法
KR102324239B1 (ko) * 2017-11-06 2021-11-08 한화솔루션 주식회사 방향족 화합물의 수소화 반응용 촉매 및 이의 제조방법
GB2613281B (en) * 2020-09-29 2025-01-29 Resonac Corp Method for producing ethyl acetate production catalyst
ES3014723T3 (en) 2020-12-18 2025-04-24 Evonik Oxeno Gmbh & Co Kg Method for regenerating hydrogenation catalysts
US11918989B2 (en) * 2020-12-18 2024-03-05 Evonik Operations Gmbh Process for regeneration of hydrogenation catalysts
CN114602463B (zh) * 2022-04-13 2023-12-05 宏业生物科技股份有限公司 一种对羟基苯甲酸乙酯加氢催化剂及其制备方法
GB2630272B (en) 2023-05-15 2025-07-02 Johnson Matthey Plc Ruthenium eggshell catalyst
CN117101676A (zh) * 2023-07-12 2023-11-24 安徽香枫新材料股份有限公司 催化剂、制备工艺以及dinp制备dinch的工艺

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1081664A (zh) * 1992-04-02 1994-02-09 法国石油公司 烃的选择性氢化方法
CN1174753A (zh) * 1996-06-19 1998-03-04 巴斯福股份公司 在载体上的钌催化剂存在下使有机化合物反应的方法
CN1355066A (zh) * 2000-11-23 2002-06-26 中国科学院生态环境研究中心 汽车尾气净化三效催化剂及其制备方法
US20040176549A1 (en) * 2001-06-11 2004-09-09 Arnd Bottcher Method for the production of cycloaliphatic compounds (1) having side chains with epoxy groups
US20040199033A1 (en) * 2001-06-11 2004-10-07 Arnd Bottcher Method for hydrogenating organic compounds by means of ru/sio2 catalysts

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4072628A (en) 1974-11-05 1978-02-07 Ici Americas Inc. Regeneration of supported ruthenium catalyst
BE882279A (fr) 1980-03-18 1980-07-16 Raffinerie Tirlemontoise Sa Procede de reactivation d'un catalyseur, a base de metaux du groupe du platine, pour l'hydrogenation des sucres
US4431750A (en) 1982-05-19 1984-02-14 Phillips Petroleum Company Platinum group metal catalyst on the surface of a support and a process for preparing same
ATE89260T1 (de) * 1988-01-14 1993-05-15 Huels Chemische Werke Ag Verfahren zur produktion von 4,4'diaminodicyclohexylmethan mit niedrigem transtrans-isomergehalt durch katalytische hydrogenierung von 4,4'-diaminodiphenylmethan.
US4923842A (en) * 1988-10-11 1990-05-08 Allied-Signal Inc. Lanthanum containing catalyst for treating automotive exhaust
US5102850A (en) * 1990-10-17 1992-04-07 W. R. Grace & Co. - Conn. Catalyst supports having promoter oxide gradient, resulting catalyst and method of making the supports
US5399535A (en) * 1993-08-17 1995-03-21 Rohm And Haas Company Reticulated ceramic products
DE4328007A1 (de) * 1993-08-20 1995-02-23 Huels Chemische Werke Ag Katalysator zur Herstellung von Bis-Para-aminocyclohexylmethan mit niedrigem Anteil an trans-trans-Isomer durch Hydrierung von Methylendiamin
EP0813906A3 (de) * 1996-06-19 1998-11-18 Basf Aktiengesellschaft Verfahren zur Umsetzung einer organischen Verbindung in Gegenwart eines geträgerten Rutheniumkatalysators
US6852667B2 (en) * 1998-02-16 2005-02-08 Sumitomo Chemical Company Limited Process for producing chlorine
JPH11222447A (ja) * 1998-02-04 1999-08-17 Mitsubishi Chemical Corp 芳香族化合物の部分水素添加によるシクロオレフィン類の製造方法
DE19827844A1 (de) 1998-06-23 1999-12-30 Aventis Res & Tech Gmbh & Co Verfahren zur Herstellung von Schalenkatalysatoren durch CVD-Beschichtung
DE19832087A1 (de) * 1998-07-16 2000-01-20 Basf Ag Verfahren zur Umsetzung von organischen Verbindungen mit boroxidhaltigen, makroporösen Trägerkatalysatoren
DE10128205A1 (de) 2001-06-11 2002-12-12 Basf Ag Ruthenium-Katalysatoren
ATE422962T1 (de) * 2002-05-31 2009-03-15 Evonik Degussa Gmbh Geträgerter rutheniumkatalysator und verfahren zur hydrierung eines aromatischen amins in gegenwart dieses katalysators
DE10253803A1 (de) 2002-11-18 2004-05-27 Degussa Ag Verfahren zur Herstellung von aliphatischen Isocyanaten aus aromatischen Isocyanaten
DE10253802A1 (de) * 2002-11-18 2004-06-03 Degussa Ag Verfahren zur Hydrierung von aromatischen Urethanen in Gegenwart eines geträgerten Rutheniumkatalysators
US7230035B2 (en) 2002-12-30 2007-06-12 Conocophillips Company Catalysts for the conversion of methane to synthesis gas
DE10361157A1 (de) 2003-12-22 2005-07-21 Basf Ag Ruthenium-Heterogenkatalysator und Verfahren zur Herstellung eines Bisglycidylethers der Formel I
WO2005061106A1 (de) 2003-12-22 2005-07-07 Basf Aktiengesellschaft Ruthenium-heterogenkatalysator, verfahren zur hydrierung einer carbocyclischen aromatischen gruppe und kernhydrierte bisglycidylether der bisphenole a und f
DE10361151A1 (de) 2003-12-22 2005-07-14 Basf Ag Ruthenium-Heterogenkatalysator und Verfahren zur Hydrierung einer carbocyclischen aromatischen Gruppe, insbesondere zur Herstellung eines Bisglycidylethers der Formel I

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1081664A (zh) * 1992-04-02 1994-02-09 法国石油公司 烃的选择性氢化方法
CN1174753A (zh) * 1996-06-19 1998-03-04 巴斯福股份公司 在载体上的钌催化剂存在下使有机化合物反应的方法
CN1355066A (zh) * 2000-11-23 2002-06-26 中国科学院生态环境研究中心 汽车尾气净化三效催化剂及其制备方法
US20040176549A1 (en) * 2001-06-11 2004-09-09 Arnd Bottcher Method for the production of cycloaliphatic compounds (1) having side chains with epoxy groups
US20040199033A1 (en) * 2001-06-11 2004-10-07 Arnd Bottcher Method for hydrogenating organic compounds by means of ru/sio2 catalysts

Also Published As

Publication number Publication date
EP1899051A2 (de) 2008-03-19
CA2612435C (en) 2015-02-24
KR101354236B1 (ko) 2014-01-22
KR20080027871A (ko) 2008-03-28
DE102005029200A1 (de) 2006-12-28
WO2006136541A3 (de) 2007-04-12
CA2612435A1 (en) 2006-12-28
WO2006136541A2 (de) 2006-12-28
US20100152436A1 (en) 2010-06-17
CN101242895A (zh) 2008-08-13
US8207327B2 (en) 2012-06-26
JP2008543550A (ja) 2008-12-04

Similar Documents

Publication Publication Date Title
US8207327B2 (en) Catalyst and process for hydrogenating organic compounds comprising hydrogenatable groups
CN102753266B (zh) 用于氢化芳族化合物的催化剂和方法
CN101522300B (zh) 适用于氢化的钌催化剂的再生方法
ES2602116T3 (es) Procedimiento continuo de producción de ciclohexilmetanoles sustituidos
US20110196181A1 (en) Process for reacting an aromatic hydrocarbon in the presence of hydrogen
US10245583B1 (en) Use of charge-containing molecules linked with covalent bonds to enhance acetylene hydrogenation catalysts
US20070149793A1 (en) Heterogeneous ruthenium catalyst, nucleus-hydrogenated diglycidyl ether of bisphenols a and f, and method for the production thereof
Bachiller-Baeza et al. Ruthenium-supported catalysts for the stereoselective hydrogenation of paracetamol to 4-trans-acetamidocyclohexanol: effect of support, metal precursor, and solvent
US20070112210A1 (en) Heterogeneous ruthenium catalyst, methods for hydrogenating a carbocyclic aromatic group, and nucleus-hydrogenated diglycidyl ether of bisphenols a and f
US8889936B2 (en) Method of regenerating ruthenium catalysts for the hydrogenation of benzene
KR101017905B1 (ko) 아세트산 제조용 담지촉매의 제조방법
CN119701961B (zh) 一种基于碳球载体的dinp加氢催化剂及其制备方法和应用
US11572330B2 (en) Method for oxidation of cycloalkanes
Gallezot et al. Liquid Phase Oxidation of Glyoxal to Glyoxylic ACID by AIR on Platinum Catalysts
Nadgeri Studies on mono-, bi-metallic and nano catalysts of nickel, palladium and platinum metals and their applications in selective hydrogenation of acetylenic compounds and nitroaromatics of industrial relevance
DE10361151A1 (de) Ruthenium-Heterogenkatalysator und Verfahren zur Hydrierung einer carbocyclischen aromatischen Gruppe, insbesondere zur Herstellung eines Bisglycidylethers der Formel I

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120111

Termination date: 20170620

CF01 Termination of patent right due to non-payment of annual fee