CN101230176A - 含多元醇的聚(乙烯醇)组合物 - Google Patents
含多元醇的聚(乙烯醇)组合物 Download PDFInfo
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- CN101230176A CN101230176A CNA2008100856191A CN200810085619A CN101230176A CN 101230176 A CN101230176 A CN 101230176A CN A2008100856191 A CNA2008100856191 A CN A2008100856191A CN 200810085619 A CN200810085619 A CN 200810085619A CN 101230176 A CN101230176 A CN 101230176A
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- Prior art keywords
- ester
- vinyl alcohol
- composition
- pvoh
- film
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 69
- -1 Poly(vinyl alcohol) Polymers 0.000 title claims abstract description 65
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- 238000000034 method Methods 0.000 claims abstract description 17
- 229920001519 homopolymer Polymers 0.000 claims abstract description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 9
- 125000004185 ester group Chemical group 0.000 claims abstract description 8
- 238000006460 hydrolysis reaction Methods 0.000 claims description 65
- 230000007062 hydrolysis Effects 0.000 claims description 64
- 239000004902 Softening Agent Substances 0.000 claims description 60
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 33
- 239000000463 material Substances 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 claims description 24
- 235000019442 glyceryl monoacetate Nutrition 0.000 claims description 19
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- MNKRTDOUBUSQHX-UHFFFAOYSA-N 2,4-dihydroxy-2-methyl-3-oxopentanoic acid Chemical compound CC(O)C(=O)C(C)(O)C(O)=O MNKRTDOUBUSQHX-UHFFFAOYSA-N 0.000 claims description 2
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- 238000012667 polymer degradation Methods 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 238000001149 thermolysis Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000010977 unit operation Methods 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F16/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
- C08F16/04—Acyclic compounds
- C08F16/06—Polyvinyl alcohol ; Vinyl alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
Description
实施例 | 基础PVOH | 增塑剂 | 温度1 | 温度2 |
均聚物实施例 | ||||
实施例1 | 均聚物1 | 单乙酸甘油酯 | 25℃ | 56℃ |
对比例A | 均聚物1 | 甘油 | 64℃ | 73℃ |
共聚物实施例 | ||||
实施例2 | 共聚物1 | 单乙酸甘油酯 | 19℃ | 27℃ |
对比例B | 共聚物1 | 甘油 | 38℃ | 50℃ |
实施例3 | 共聚物1 | 单乙酸甘油酯 | 17℃ | 35℃ |
实施例4 | 共聚物1 | 二乙酸甘油酯 | 17℃ | 38℃ |
对比例C3 | 共聚物1 | 三乙酸甘油酯 | 21℃ | 40℃ |
实施例 | 增塑剂 | 熔点 | 焓 | %水解 | 薄膜强度 |
均聚物(熔点228℃,焓69J/g)# | |||||
实施例1 | 单乙酸甘油酯 | 221℃ | 62J/g | 99.0% | 好 |
对比例A | 甘油 | 229℃ | 94J/g | 99.7% | 好 |
共聚物(熔点210℃,焓66J/g)实施例 | |||||
实施例2 | 单乙酸甘油酯 | 195℃ | 39J/g | 98.0% | 好 |
对比例B | 甘油 | 212℃ | 60J/g | 99.7% | 好 |
实施例3 | 单乙酸甘油酯 | 191℃ | 26J/g | 97.3% | 好 |
实施例4 | 二乙酸甘油酯 | 191℃ | 23J/g | 97.2% | 好 |
对比例C | 三乙酸甘油酯 | 204℃ | 49J/g | 98.8% | 差* |
Claims (10)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/698,428 US7781506B2 (en) | 2007-01-26 | 2007-01-26 | Poly(vinyl alcohol) composition comprising a polyol |
US11/698428 | 2007-01-26 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101230176A true CN101230176A (zh) | 2008-07-30 |
CN101230176B CN101230176B (zh) | 2012-09-05 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN2008100856191A Active CN101230176B (zh) | 2007-01-26 | 2008-01-25 | 含多元醇的聚(乙烯醇)组合物 |
Country Status (4)
Country | Link |
---|---|
US (1) | US7781506B2 (zh) |
JP (1) | JP5645346B2 (zh) |
CN (1) | CN101230176B (zh) |
GB (1) | GB2446068B (zh) |
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CN104294390A (zh) * | 2014-07-14 | 2015-01-21 | 江苏六甲科技有限公司 | 一种高强高模聚乙烯醇纤维的熔融制备方法 |
CN104294390B (zh) * | 2014-07-14 | 2017-01-04 | 江苏六甲科技有限公司 | 一种高强高模聚乙烯醇纤维的熔融制备方法 |
CN112110816A (zh) * | 2020-09-02 | 2020-12-22 | 山东吉青化工有限公司 | 一种多元醇脂肪酸酯增塑剂的制备方法 |
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US8759279B2 (en) | 2008-06-30 | 2014-06-24 | Kimberly-Clark Worldwide, Inc. | Fragranced biodegradable film |
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-
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- 2008-01-28 GB GB0801558A patent/GB2446068B/en active Active
- 2008-01-28 JP JP2008043577A patent/JP5645346B2/ja active Active
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JP2008184614A (ja) | 2008-08-14 |
GB2446068A (en) | 2008-07-30 |
GB0801558D0 (en) | 2008-03-05 |
JP5645346B2 (ja) | 2014-12-24 |
US7781506B2 (en) | 2010-08-24 |
GB2446068B (en) | 2011-02-09 |
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US20080182937A1 (en) | 2008-07-31 |
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