CN101208073A - Makeup cosmetic - Google Patents
Makeup cosmetic Download PDFInfo
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- CN101208073A CN101208073A CNA2006800150248A CN200680015024A CN101208073A CN 101208073 A CN101208073 A CN 101208073A CN A2006800150248 A CNA2006800150248 A CN A2006800150248A CN 200680015024 A CN200680015024 A CN 200680015024A CN 101208073 A CN101208073 A CN 101208073A
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- makeup cosmetic
- powder body
- cosmetic
- partially crosslinked
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/98—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A makeup cosmetic that excels in nonsticky fresh sense upon use, elastic touch and soft feeling and impact resistance, and that can be charged in a metal dishlike or resin dishlike container and compression molded, and that ensures the simplicity and convenience of joint use of various colors through fitting of the dishlike container to a compact container. There is provided a makeup cosmetic comprising component (A) consisting of a partially crosslinked organopolysiloxane polymer containing a long-chain alkyl; component (B) consisting of a partially crosslinked organopolysiloxane polymer other than the component (A); component (C) consisting of silicone oil; component (D) consisting of one or two or more types of liquid oils selected from the group consisting of hydrocarbon oils and/or ester oils; and component (E) consisting of powder. A composition of these components (A) to (E) is charged in a dishlike container and compression molded into a makeup cosmetic.
Description
Technical field
The present invention relates to makeup cosmetic and preparation method thereof, more specifically, relate to a kind of composition (B) that contains the composition (A) formed by the partial cross-linked organopolysiloxane polymer that contains chain alkyl, forms by the partially crosslinked organopolysiloxane polymer except composition (A), the composition of forming by silicone oil (C), the composition of forming by one or more the unthickened fuel that is selected from hydrocarbon ils and/or ester oil (D) and the makeup cosmetic of the composition (E) formed by powder body and preparation method thereof.
Background technology
Because cosmetics such as makeup cosmetic are the article that directly spread upon face, fingernail etc., therefore use, ideally finish the usability of use, beautiful dressing with a light heart, result of use is very important, this has determined the value of cosmetics.Make the first step when applying some make up be, the bottle that at first tilts makes content flow in the palm, dig out in container, pour out content from metal tube or plastic tube with finger tip, and second step was to smear, spread out thinly and embrocate at skin surface.In such process, the flowability of cosmetics will change, and in cosmetics use from the beginning to the end, owing to reasons such as skin absorbs oil and water evaporates, the sensation of skin also will change.Therefore, physical property is very complicated.With hard, soft, water is tender, stretching, extension, wrinkle, be clamminess, vocabulary shows the evaluation to cosmetics like coarse, the powder etc.These performances are from bringing into use the sensorial reaction of cosmetics when use finishes.
Classify according to the flow behavior that makes the operational phase that applies some make up, usability etc.Evaluation before characteristic during the cosmetics that at first outward appearance, contact will be used, the easness etc. that takes out cosmetics in the container are used as using.The strength that characteristic during the contact cosmetics is pushed cosmetics with thumb or forefinger is estimated.In addition, flow resistance and the deformation state of the easness that takes out cosmetics in the container when taking out cosmetics in container waits and estimates.Secondly, with the cohesiveness that uses the position, sample on skin the stretching, extension difficulty or ease and percutaneous infiltrative sensation etc. as the evaluation in the use.Extensibility, permeability also carry out sensorial evaluation respectively.More specifically, after smearing with having smeared cosmetics or certain intervals, according to sense of touch and vision etc., the evaluation after the wiping difficulty etc. and be used as using of the skin appearance by using the position, residue cosmetics.Flow behavior, usability, the result of use of report in order to estimate cosmetics exactly arranged, must use rheol technology (for example, referring to non-patent literature 1).
Be called Newtonian fluid according to newton's rule flowable state liquid, its flow behavior is called newtonian flow; On the other hand, be not called non-Newtonian fluid, and its flow behavior is called non newtonian and flows according to newton's rule flowable state liquid.Most of Emulsion, suspension, macromolecular solution, semi-solid material etc. all are applicable to non-Newtonian fluid.Not with apply to cut off stress proportional, the liquid form of flows faster is called pseudoplasticity and flows; Not with apply cut off stress proportional, be difficult to mobile liquid form and be called (dialantancy) (for example, referring to the non-patent literature 2) that expand to flow.
Recently, develop the suitable material that the dilatancy compositions becomes to grade as cosmetic combinations such as wetting agent, massage agents that has of one of above-mentioned liquid form, known said composition is reached by following composition (A), (B) (C) to be formed, just, contain the poly(ethylene oxide) of (A) weight average molecular weight more than 100,000, (B) water swellable clays mineral and (C) water, dilatancy compositions (for example, referring to patent documentation 1); Or by following composition (A) and the dilatancy compositions (B) formed with identical characteristics, described compositions contains following O/W type emulsion that contains ceramide type or fatty acid of (A) oil droplet mean diameter 0.2 μ m and (B) water soluble polymer (for example, referring to patent documentation 2) of mean molecule quantity more than 300,000.
On the other hand, on makeup cosmetic, attempted improvement strategy aspect the multiple rheology.For example, oily solid cosmetics has made up more oil content, therefore seems greasy and glutinous, in order to overcome relatively poor extensibility, spreading property and stronger oil film sense, has developed the cosmetics that use silicone oil.Because therefore the good characteristic of silicone oil has adopted multiple silicone oil, particularly is extensive use of as oiliness composition useful in the cosmetics.This be because silicone oil have low viscosity, smooth, stretch, salubrious contiguous sense, be rich in the good feature and the condition of lubricity and hydrophobicity and tasteless odorless in addition.This silicone oil is representative with molecular weight and the different chain dimethyl polysiloxane of viscosity, can list ring-type octamethylcy-clotetrasiloxane and tolyl polysiloxanes.
In order to improve above-mentioned silicone oil, acquisition has the good safety cosmetics of usability, usability and long-time stability of smooth and salubrious thoughts and feelings, a kind of organopolysiloxane gel composition occurred,, can contain with benzene more than the weight identical weight own, by R though be insoluble to benzene
2SiO unit and RSiO
1.5The unit ratio is 1-30: 1 the silicon polymer with three-dimensional crosslinking structure form with the following low viscosity silicone of 50cs, and the part by weight of described silicon polymer and silicone oil with low viscosity is 5: 95-30: 70 (for example referring to patent documentations 3); The compositions that has also occurred a kind of oily solid cosmetics in addition, its film that can not cause making up is wrinkling or the fusion fillibility low, can remove cosmetic film gloss, have liner texture; It is applicable to oily solid cosmetics, by composition (A)-(D) form, just contain (A) partially crosslinked organopolysiloxane polymer 0.5-10 weight %, (B) silicone oil with low viscosity 5-50 weight %, (C) spherical powder body 10-50 weight %, (D) solid oil and/or lard 1-50 weight % (for example, referring to patent documentation 4).
In addition, aspect powdered cosmetic, in order to have the homogeneity and the ageing stability of good adaptation and slick spreadability, raisingization shape film, the known following composition (a)-(e) of containing, just contain composition (a) partially crosslinked organopolysiloxane, the aqueous silicone oil of composition (b), composition (c) unthickened fuel except composition (b) and the powdered cosmetic (for example, referring to patent documentation 5) of composition (e) powder body; Also knownly in addition contain the powdered cosmetic composition that at least a particle reaches at least a fatty phase mutually, it contains at least a gelating agent in the silicone elastomer type with surface active properties further, and particle is with respect to total composition to be 50-98 weight % (for example, referring to patent documentation 6) in said composition.
In addition, the known compositions of forming by the oil preparation outside cross-lined organic polyorganosiloxane polymer and the silicone oil, and the cosmetics (for example, referring to patent documentation 7) that contain said composition.
Patent documentation 1: the spy opens flat 10-182403 patent gazette
Patent documentation 2: the spy opens the 2002-317124 patent gazette
Patent documentation 3: special fair 8-6035 patent gazette
Patent documentation 4: the spy opens the 2000-281532 patent gazette
Patent documentation 5: the spy opens the 2001-278730 patent gazette
Patent documentation 6: the spy opens the 2003-55150 patent gazette
Patent documentation 7:WO2003/024413 number publication communique again
Non-patent literature 1: the Japanese cosmetic operator can compile " cosmetics topical reference book ", put down into 25, second brushes of 16 on JIUYUE, the distribution of the kind Co., Ltd. of ball, p215-216 page or leaf
Non-patent literature 2: the Japanese cosmetic operator can compile " cosmetics topical reference book ", put down into 25, second brushes of 16 on JIUYUE, the distribution of the kind Co., Ltd. of ball, p217 page or leaf
Summary of the invention
Makeup cosmetics such as oiliness type in the past and powder solid type eye shadow all are to be filled in the ware shape container, it is contained in has Portability in the compact container, and the multiple color of can packing in a compact container, thereby become the product with convenience.Yet it still is short of the salubrious sense of touch and the usability of soft feeling, also is short of elasticity.On the other hand, water system gel type cosmetics have salubrious sense of touch and soft feeling but are difficult to be packed in the ware shape container, the multiple color of therefore can not packing in a compact container, inconvenience.The problem to be solved in the present invention provide a kind of that be not clamminess, have salubrious usability and resilient sense of touch and soft feeling, a good resistance to impact, and this can be packed in metallic or the resinous ware shape container, these ware shape containers are contained in the compact container use, the multiple color of packing in a compact container has the coloured silk dress cosmetics of simplicity and convenience.
The inventor has noted the characteristic of the multiple organopolysiloxane polymer that makeup cosmetics such as eye shadow always use, the combination of studying the different multiple organopolysiloxane polymer of rerum natura with keen determination obtains following result, discovery will contain specific 2 kinds of organopolysiloxane polymers and one or more the unthickened fuel that is selected from hydrocarbon ils and/or ester oil, silicone oil, the component of powder body and solvent are (for example, silicone oil such as simethicone as the straight chain dimethyl polysiloxane of oligomerization) be added on and obtain pasty masses together, in lyosoption with its compression forming, with what be not clamminess, have salubrious usability and softish sense of touch, better elastic and resistance to impact, and can be filled in the makeup cosmetic in the container, and confirm that it also has simplicity and convenience in use, finishes the present invention thus.
In other words, the present invention relates to: (1) a kind of makeup cosmetic is characterized in that these cosmetics contain: the composition of being made up of the partially crosslinked organopolysiloxane polymer that contains chain alkyl (A), the composition of being made up of the partially crosslinked organopolysiloxane polymer except composition (A) (B), the composition of being made up of silicone oil (C), the composition of being made up of one or more the unthickened fuel that is selected from hydrocarbon ils and/or ester oil (D) and the composition of being made up of powder body (E); (2), it is characterized in that these cosmetics are butyrous as above-mentioned (1) described makeup cosmetic; (3), it is characterized in that composition (A) is (vinyl-dimethyl silicone oil/dodecyl simethicone) cross linked polymer (crosspolymer) as above-mentioned (1) or (2) described makeup cosmetic; (4), it is characterized in that composition (B) is (simethicone/vinyl-dimethyl silicone oil) cross linked polymer as each described makeup cosmetic of above-mentioned (1)-(3); (5), it is characterized in that composition (C) is a simethicone as each described makeup cosmetic of above-mentioned (1)-(4); (6), it is characterized in that containing the composition (C) of 30-70 quality % as each described makeup cosmetic of above-mentioned (1)-(5); (7), it is characterized in that containing the composition (D) of 0.5-10 quality % as each described makeup cosmetic of above-mentioned (1)-(6); (8), it is characterized in that composition (E) contains glossiness tabular powder body as each described makeup cosmetic of above-mentioned (1)-(7); (9), it is characterized in that composition (E) contains spherical powder body as each described makeup cosmetic of above-mentioned (1)-(8); (10) as each described makeup cosmetic of above-mentioned (1)-(9), it is characterized in that being packed in the ware shape container and compression forming, at least one of this ware shape container is loaded in the compact container; (11) as each described makeup cosmetic of above-mentioned (1)-(10), the contact pin load value that it is characterized in that the cosmetics of compression forming is 20-120gf; (12), it is characterized in that the elasticity number (L2/L1) that the cosmetics of the compression forming TPA (texture profile analysis) by texture analyser is measured is 0.48-0.99 as each described makeup cosmetic of above-mentioned (1)-(11); (13), it is characterized in that described makeup cosmetic is an eye shadow as each described makeup cosmetic of above-mentioned (1)-(12).
The invention still further relates to the preparation method of (14) makeup cosmetic in addition, it is characterized in that to contain the composition of forming by the partially crosslinked organopolysiloxane polymer that contains chain alkyl (A), the composition of forming by the partially crosslinked organopolysiloxane polymer except composition (A) (B), the composition of forming by silicone oil (C), the compositions of composition of being made up of one or more the unthickened fuel that is selected from hydrocarbon ils and/or ester oil (D) and the composition of being made up of powder body (E) is dispersed in the silicone oil equal solvent, be packed in the ware shape container compression forming when absorbing above-mentioned solvent after the dispersion.
Description of drawings
[Fig. 1] is the figure of measurement result of the dynamic viscoelastic of expression product of the present invention (embodiment 1).Transverse axis is represented distortion (%), and longitudinal axis G ' represents energy storage elastic modelling quantity (elasticity item), G " expression loss elastic modulus (viscosity term).
[Fig. 2] is the TPA measurement result of the product of the present invention (embodiment 1) that obtains by texture analyser of expression.
The specific embodiment
Makeup cosmetic of the present invention is so long as contain: the composition of forming by the partially crosslinked organopolysiloxane polymer that contains chain alkyl (A), by except composition (A), promptly do not contain composition (B) that the partially crosslinked organopolysiloxane polymer of chain alkyl forms, the composition of forming by silicone oil (C), the composition of forming by one or more the unthickened fuel that is selected from hydrocarbon ils and/or ester oil (D) and the composition of forming by powder body (E) and get final product, do not have other special restriction, but the compositions that more preferably contains above-mentioned each composition is butyrous.Further, preferably in containing the compositions of above-mentioned each composition, add the silicone oil equal solvent, in lyosoption with its compression forming; Further preferably after compression forming, be packed into the goods in the ware shape container.This ware shape container can be packed in the compact container, can pack into a plurality ofly to make it become suits in a compact container.The implication of ware shape container is meant the thin small-sized metallic or the plastic ware shape container that can be housed in degree in the compact container herein.According to the present invention, described oil-based cosmetic preparation is meant the goods that disperse powder body in oleaginous base, and it is different from powder solid cosmetics, water system gel cosmetic, emulsified make-up.Above-mentioned makeup cosmetic also can list eye shadow, foundation cream, concealer, make ground material, rouge, lipstick, mascara, informer, eyebrow pencil etc.
As mentioned component partially crosslinked organopolysiloxane polymer (A), that contain chain alkyl, get final product so long as on the polysiloxane-based rubber that partly presents three dimensional structure, contain the chemical compound of chain alkyl, do not have other special restriction with cross-bond; Above-mentioned chain alkyl is carbon atom number 8-30 straight chained alkyl preferably.This composition (A) is by obtaining organic hydride diene polysiloxanes and organopolysiloxane addition polymerization; Described organic hydride diene polysiloxanes is by being selected from for example SiO
2Unit, HSiO
1.5Unit, RSiO
1.5Unit, RHSiO unit, R
2SiO unit, R
3SiO
0.5Unit and R
2HSiO
0.5At least a construction unit of unit (wherein, R removes the monovalence alkyl aliphatic unsaturated group, that replace or do not have the carbon number 1-30 of replacement) constitutes, and contains in the molecule at bonded number of hydrogen atoms on the silicon atom on average more than 1.5; Described organopolysiloxane is by being selected from SiO
2Unit, (CH
2=CH) SiO
1.5Unit, RSiO
1.5Unit, R (CH
2=CH) SiO unit, R
2SiO unit, R
3SiO
0.5Unit and R
2(CH
2CH) SiO
0.5The construction unit of unit (wherein, R is a monovalence alkyl of removing the carbon number 1-30 aliphatic unsaturated group, replacement or non-replacement) constitutes, and contains at bonded ethylene radix on the silicon atom on average more than 1.5 in the molecule simultaneously.
This partially crosslinked organopolysiloxane that contains chain alkyl, for example can listing, INCI name (International Nomenclature Cosmetic Ingredient labeling names) is (vinyl-dimethyl silicone oil/lauryl simethicone) cross linked polymer.Commercially available product can list the organopolysiloxane gel that has cooperated hydrocarbon ils or ester oil in containing the partially crosslinked organopolysiloxane polymer of chain alkyl.For example, can specifically list the KSG-41 that contains 65-75 quality % (below be abbreviated as " % ") mineral oil; The KSG-42 that contains the 70-80% Fancol ID; The KSG-43 that contains 65-75% three octanes (three-2 ethyl hexanoic acid glyceride); Contain the KSG-44 (all being SHIN-ETSU HANTOTAI's chemical industry (strain) system) of the squalane of 65-75% etc.
According to purpose, but one or more compositions of the present invention (A) used, though the not restriction especially of its amount, 0.001-15% preferably in cosmetics, contained, preferred especially 0.1-10%.After having cooperated composition (A), can improve the overall compatibility of oils and make oils and the mixing of powder body class homogeneous.In addition, can with the relatively poor silicone oil of skin adaptation in cooperate and use the oil preparation higher with the skin adaptation.
The partially crosslinked organopolysiloxane polymer except composition (A) as mentioned component (B), as long as it is the polysiloxane-based elastomer that presents the three dimensional structure with partial cross-linked key, there is not other special restriction, the example that can enumerate is the polymer that the crosslinked bonding of organopolysiloxane is obtained, part contains three-dimensional crosslinking structure, and it is by R
2SiO unit and RSiO
1.5The unit is formed, and also can contain R
3SiO
0.5Unit and/or SiO
2(still, each R that constitutes in the unit for example contains hydrogen atom to unitary chemical compound; Alkyl such as methyl, ethyl, propyl group; Aliphatic unsaturated groups such as aryl such as phenyl, tolyl and vinyl; The substituent group of groups such as fluoro base, Oxyranyle, it can be identical or different kind), more specifically, can enumerate the polymer that special fair 8-6035 communique, spy are opened record such as 2001-342255 communique.
This composition (B) for example can be enumerated, and INCI name (International Nomenclature CosmeticIngredient labeling names) is (simethicone/vinyl-dimethyl silicone oil) cross linked polymer.And, though composition (B) can be even polymers, mix use usually more for a long time with silicone oil with low viscosity.This mixture for example can specifically be enumerated KSG-15 (95 parts of 5 parts of partially crosslinked methyl polysiloxanes and decamethyl Pentamethylene. siloxanes), KSG-16 (partially crosslinked methyl polysiloxane 20-30 part and methyl polysiloxane 70-80 part), KSG-17 (95 parts in 5 parts of partially crosslinked methyl polysiloxanes and prestox ring tetramethyl silica alkane), KSG-18 (partially crosslinked methyl polysiloxane 10-20 part and methyl phenyl silicone 80-90 part) commercially available products such as (all by chemical industrial company of SHIN-ETSU HANTOTAI systems).
Can use one or more composition (B) according to purpose,, preferably in cosmetics, contain 1-20%, special preferred 5-15% though its amount is not particularly limited.The elasticity of cosmetics can be kept by gradation composition (B), and the structure of compression forming in the ware shape container can be remained on.
As the silicone oil of mentioned component (C) can be straight chain or cyclic any one, for example below the viscosity 50cs; Never be clamminess and the purpose of salubrious usability (sensation) is set out, and, from it as in order to make compositions before the compression forming relevant become the fine solvent of paste, the preferably following low viscosity silicone of 30cs with the makeup cosmetic manufacturing process.Low viscosity silicone for example can list: the straight chain dimethyl polysiloxane (simethicone) of oligomerization skin, tolyl polysiloxanes, dimethyl polysiloxane tolyl silicone copolymers and cyclic prestox ring tetramethyl silica alkane, decamethyl Pentamethylene. siloxanes, also can enumerate concrete example, material (シ リ コ Application KF-96 (6CS), シ リ コ Application KF-96 (10CS), シ リ コ Application KF-96 (20CS): chemical industrial company of SHIN-ETSU HANTOTAI system) as INCI simethicone by name, according to purpose, one or more are used in combination.In addition, about the cooperation form of silicone oil, can enumerate and match, the form of using with the gel-like silicones of KSG-16 etc. as partially crosslinked organopolysiloxane polymer composition (B), except composition (A), and the form of using separately, preferred these forms of also using.In addition, silicone oil as solvent, preferred example is as the straight chain dimethyl polysiloxane of the low polymerization degree of low viscosity silicone, preferred in order more specifically シ リ コ Application KF-96 (6CS), シ リ コ Application KF-96 (10CS), シ リ コ Application KF-96 (20CS).
The content of composition (C) silicone oil in cosmetics is 30-70%, and preferred 40-60% cooperates.As long as cooperate more than 30%, the especially clearly sense in can guaranteeing to use, in addition as long as cooperate below 70%, can make especially make up lasting, even compression forming in ware shape container also can reduce the impaired probability of article shaped resistance to impact.Illustrated that in the preparation process of makeup cosmetic, can be absorbed when the compression forming though add in the compositions before compression forming as the silicone oil of the simethicone of solvent etc., the part of the composition of Tian Jiaing (C) silicone oil also will be absorbed sometimes.
The unthickened fuel that is selected from hydrocarbon ils and/or ester oil as composition (D), no matter be from animal oil, vegetable oil, synthetic wet goods, aqueous material under preferred 25 ℃, can enumerate for example liquid paraffin, the heavy liquid isoparaffin, squalane, polybutene, polyisobutylene etc. are as hydrocarbon ils, in addition, can enumerate for example three 2 ethyl hexanoic acid glyceride, p-methoxycinnamate 2-Octyl Nitrite, the isooctyl acid cetyl ester, isopropyl myristate, isopropyl palmitate, tetradecanoic acid octyl group lauryl, tricaprylin, two isostearic acid polyglycerin ester, isostearic acid two glyceride, malic acid two different stearyl esters, two sad DOPCP, the Jojoba wet goods also can use these one or more as ester oil.
By gradation composition (D), can in use give skin affinity and driving fit sense etc.Though the content of composition (D) is not particularly limited, used silicone oil equal solvent aspect when absorb loading more preferably contains 0.5-10% in cosmetics, more preferably contain 1-8%.In addition, the cooperation form of composition (D) for example can be enumerated as KSG-4 3, contains form that the partially crosslinked organopolysiloxane polymer of chain alkyl is used or the form of using separately with composition (A).
As the powder body of composition (E), so long as the powder body of using always in the cosmetics has no particular limits, but preferably contains 30-70% in cosmetics.In addition, composition (E) powder body preferably contains the material of tabular powder body, and, be more preferably and contain glossy tabular powder body such as pearly luster is arranged.Further, more preferably contain spherical powder body.Change the tabular powder body that can cooperate 10-50% in the shape product, preferred 20-40%, more preferably 30% degree.And, cooperate the glossiness tabular powder body of 30-98% ratio in the preferred powder body, if in this scope, will occur less coarse deposit, and have preferably when spreading upon on the skin and feel.In addition, can cooperate the spherical powder body of 1-10% in the cosmetics, preferred 1-5%, the preferred spherical powder body that cooperates 0.01%-30%, more preferably 0.5%-10% in the powder body.Spherical powder body has the powdery sense, and stretching, extension and extensibility are good, can obtain the salubrious usability that better is not clamminess.In addition, owing to have the effect that cosmetic applying is difficult to take off after making system's homogenization on daubers such as finger, small pieces, sponge, hairbrush, preferably by with the system of the adverse effect not powder body and the usefulness of homogenize, disintegrate well, adjust the difficulty or ease of taking off cosmetics on the finger.Powder body by spherical powder body and disintegrate well is 0.001: 99.99-90: appropriate combination cooperates in 10 the scope, easily adjusts the taking-up of cosmetics from finger.The mean diameter of spherical powder body (laser diffractometry) is 0.1-80 μ m preferably, is more preferably 0.5-50 μ m.
In addition, the material of composition (E), can enumerate is with inorganic particle classes such as titanium oxide, black oxidation titanium, dark blue, ultramarine, melanterite, iron oxide yellow, iron oxide black, zinc oxide, aluminium oxide, silicon dioxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, chromium oxide, chromic oxide gel, white carbon black, aluminium silicate, magnesium silicate, Magnesiumaluminumsilicate, Muscovitum, synthetic mica, sericite, Pulvis Talci, Kaolin, carborundum, barium sulfate, silicon nitrides; Organic powder classes such as nylon, polymethyl methacrylate salt, polyalkyl acrylate, organopolysiloxane elastomer, poly methyl silsesquioxane, the netted polysiloxane block copolymers of cross-linking type polysiloxanes, polystyrene, acrylonitrile-methacrylic acid copolymer, vinylidene chloride-metering system copolymer, polyethylene, carbamate, Pilus Caprae seu Ovis, silk, crystalline cellulose, N-acyl-lysine; And the pigment powder body classes such as mordant pigment of organic tar class pigment, organic pigment etc.; And the mica titanium of the mica titanium of the mica titanium of micropartical titanium oxide lining, the lining of micropartical zinc oxide, barium sulfate lining, contain titanium oxide silicon dioxide, contain the composite granule classes such as silicon dioxide of zinc oxide; And with these powder body one or more carry out the surface-coated powder body class of surface-treated etc. with fluoride compound, polysiloxanes compounds, metallic soaps, lecithin, hydrolecithin, collagen, hydrocarbon, higher fatty acids, higher alcohol, ester, wax (wax), wax (ロ ウ), surfactant etc., can also use one or more of these powder body.
For example, glossiness tabular powder body can list: the aluminium powder that the mica titanium of the hydroxyl bismuth of the synthetic phlogopite that the glass dust of titanium oxide lining, titanium oxide are handled, mica titanium, titanium oxide lining, ferrum oxide mica titanium, ultramarine lining, the mica titanium of calcium hydrogen phosphate (カ Le ミ Application) lining, hydroxyl bismuth chloride, guanin, the Muscovitum of ferrum oxide lining, the mica titanium of organic pigment lining, aluminium powder, Polyethylene Terephthalates's aluminum epoxy resin laminate powder, Polyethylene Terephthalates's polymethyl methacrylate stack membrane end, silicon dioxide melanterite are handled etc.In addition, spherical powder body can be enumerated: polymethyl methacrylate, nylon, polystyrene, silicon dioxide, polyorganosiloxane resin etc.Powder body with well disintegrate opposite with spherical powder body effect, not spherical and tabular, for example can enumerate: erose powder body such as American football shape, Rhizoma Solani tuber osi shape, gold rice confection shape, material can be enumerated: nylon, polymethyl methacrylate, methyl methacrylate cross linked polymer.
In makeup cosmetic of the present invention; except above-mentioned necessary composition; do not damage the composition that also can in cooperating common cosmetics, cooperate in the scope of effect of the present invention, for example: various medicines such as enzymes such as water compositions such as oiliness composition, surfactant, water and polyhydric alcohol, lower alcohol, water soluble polymer, wetting agent, saccharide, UV absorbent, antioxidant, antiseptic, lipase and protease, resorcinol and sulfur, freshener, pigment, spice etc.
Above-mentioned oiliness composition, except necessary composition, can enumerate normally used with cosmetic field is oils, lanolin derivative class, oil-base gel agent class etc. from the irrelevant hydro carbons of the character of animal oil, vegetable oil, the solid oil of synthesizing wet goods, lard, liquid oil, volatility wet goods, oils, wax class, sclerosis oils, ester oil class, fatty acid, higher alcohols, silicone oil, fluorine.More specifically can enumerate: vaseline, Tissuemat E, ethylene propylene copolymer, paraffin, montan wax, Fischer-Tropsch synthetic wax, ceresine, non-aqueous hydro carbons such as mineral ceresine, haze tallow, olive oil, Oleum Ricini, mink oil, macadamia (マ カ デ ミ ア Application Na Star Star) wet goods oils, Cera Flava, ゲ イ ロ ウ, Brazil wax, wax classes such as candelilla wax, the rosin acid pentaerythritol ester, cholesterol aliphatic ester, non-aqueous esters such as phytosterol fatty acid ester, stearic acid, lauric acid, myristic acid behenic acid, isostearic acid, fatty acids such as oleic acid, stearyl alcohol, spermol, lauryl alcohol, oleyl alcohol, isooctadecanol; senior alcohols such as behenyl alcohol, trimethicone silicic acid, high polymeric tolyl polysiloxanes, polyoxy alkylidene modification organopolysiloxane, crosslinked polyethers modified methyl polysiloxanes, the methacrylic acid modified polyorganosiloxane, stearic (acyl) basic modified methyl polysiloxanes, oil base modified methyl polysiloxanes, docosyl modified methyl polysiloxanes, polyvinyl pyrrolidone modified methyl polysiloxanes, high polymeric dimethyl polysiloxane, polyoxy alkylidene alkyl methyl polysiloxanes methyl polysiloxane copolymer, alkoxy-modified polysiloxanes, fluorine modified polyorganosiloxanes etc. are non-aqueous polysiloxane-based, perfluoro decane, PFO, fluorine such as PFPE are the oil preparation class, lanoline, the acetic acid lanoline, the lanolin fatty acid isopropyl ester, lanolin derivatives such as lanolin alcohol, sucrose fatty acid ester, isostearic acid aluminum, calcium stearate, oil-base gel agent classes such as 12-hydroxy stearic acid etc. also can be share above-mentioned one or more.
Above-mentioned surfactant so long as the general surfactant that uses in the cosmetics can use any one, can be enumerated: non-ionic surface active agent, anion surfactant, cationic surfactant, amphoteric surfactant etc.For example fatty acid glyceride and aklylene glycol addition product thereof, polyglyceryl fatty acid ester and aklylene glycol addition product thereof, sorbitan fatty acid ester and aklylene glycol addition product thereof, sucrose fatty acid ester, polyoxyethylene hardened castor oil, the alkyl co-modified organopolysiloxane of polyoxy alkylidene, polyether-modified organopolysiloxane, lecithin etc. also can use above-mentioned one or more.
Above-mentioned water soluble polymer can be enumerated: the natural class water soluble polymers such as skin ulcer glue, sodium chondroitin sulfate, hyaluronate sodium, arabic gum, sodium alginate, carrageenin of healing; Semi-synthetic class water soluble polymers such as methylcellulose, hydroxyethyl-cellulose, hydroxy methocel; Synthetic class water soluble polymers such as carboxy vinyl polymer, alkyl addition carboxy vinyl polymer, polyvinyl alcohol, polyvinyl pyrrolidone, sodium polyacrylate.Also can enumerate protein, mucopolysaccharide, collagen, elastoidin, keratin etc., also above-mentioned one or more can be share.
Above-mentioned antioxidant can be enumerated for example alpha-tocopherol, ascorbic acid etc.; The beauty treatment composition can be enumerated for example vitamins, antibiotic medicine, crude drug etc.; Antiseptic can be enumerated for example p-Hydroxybenzoate, phenoxyethanol etc., also above-mentioned one or more can be share.
Above-mentioned UV absorbent can be enumerated for example benzophenone, PABA class, cinnamic acid, salicylic acid, 4-tert-butyl-4 '-methoxy dibenzoyl methane, hydroxyl phenol (オ キ シ ベ Application ゾ Application) etc., also above-mentioned one or more can be share.
Contact pin load value after the makeup cosmetic compression forming of the present invention is 20-120gf (gram force) preferably, is more preferably 20-70gf, salubrious sense of touch that will obtain not to be clamminess fully when using in this numerical range and good resistance to impact.For example, though the salubrious sense of touch that can obtain not being clamminess fully to the words of 20gf not may have relatively poor resistance to impact, if surpass 120gf, though have good resistance to impact, the sensation of powder is too strong, may lack elastic sensation during use.In addition, to be meant according to contact pin load value of the present invention makeup cosmetic will be packed in the mould of thick 4mm as sample, with " the RHEO TECH FUDOH RHEO METER " of the レ オ テ of Co., Ltd. Star Network corporate system as determining instrument, with the hardness measurement condition enactment for using adapter (adapter) 3mm φ, entering apart from 1.5mm, rate of climb 2cm/min and measure the numerical value that obtains.
In addition, elasticity number (L2/L1) during the TPA (testureprofile analysis) that makeup cosmetic of the present invention is undertaken by texture analyser measures is 0.48-0.99 preferably, be more preferably 0.50-0.99, in this numerical range, can obtain whippy cosmetics.And, elasticity number (L2/L1) during the TPA that is undertaken by texture analyser among the present invention measures is meant makeup cosmetic is packed into the mould of thick 4mm as sample, machine is measured in " texture analyser " conduct with the great smart machine strain formula meeting corporate system of English, the TPA condition determination is the cylindrical needle of 2mm φ, probe speed 0.5mm/sec, (non-destroyed area) adjustment deflection is 25% under the situation of not exclusively destroying sample, with above-mentioned probe sample is added dynamics 2 times, the first time and secondary time difference keep 3sec, the height change that distortion for the first time causes is counted L1, the height change that distortion for the second time causes is counted L2, come evaluation institute value with L2/L1, its distortion ratio of returning when removing external force of representing to cause because of external force is (referring to kind of a Gu Zhenyi, Lin Hongtong, river end matted crystal is " physical properties of food term dictionary " (supporting virtuous hall) of work altogether).
The preparation method of makeup cosmetic of the present invention will be so long as will contain the compositions of mentioned component (A), composition (B), composition (C), composition (D) and composition (E) and be dispersed in the solvent, after being packed into container, compression forming gets final product in lyosoption, there is not other restriction, but the addition of solvent is preferably the 30-100 weight portion with respect to cosmetics 100 weight portions, 40-90 weight portion more preferably, 45-60 weight portion more preferably makes and is easy to fill and obtains uniform cosmetics because can reduce viscosity under described proportioning.As solvent, as long as the compositions that contains composition (A)-(E) can be scattered in wherein, be packed in the container then, solvent can be absorbed and get final product, it can select silicone oil for use, in hydrocarbon ils, the ester oil any one, but preferred silicone oil are more preferably the straight chain dimethyl polysiloxane (simethicone) of low polymerization degree.Described preparation method more specifically, the powder body of composition (E) is dispersed in the Henschel blender (Mitsui three pond corporate systems), in addition composition (A) is contained the partially crosslinked organopolysiloxane polymer of chain alkyl and composition (B) the partially crosslinked organopolysiloxane polymer except composition (A) with dispersion machine pre-dispersed after, in this dispersion thing, add composition (C) silicone oil, composition (D) is selected from the unthickened fuel of hydrocarbon ils and ester oil, mix homogeneously, dispersive mentioned component (E) stirs with Henschel blender (Mitsui three pond corporate systems), simultaneously to wherein adding mentioned component (A)-(D), add the silicone oil as solvent such as simethicone again, make it the uniform mixing pulp.The compositions of pulpous state is packed in the metallic ware shape container, and when absorbing the solvent that adds, compression forming in metallic ware shape container can obtain makeup cosmetic.In addition, the metallic ware shape container after this filling can be packed in the small containers.
Followingly be described more specifically the present invention, but protection scope of the present invention is not subjected to the restriction of the embodiment shown in these according to embodiment.
[partially crosslinked organopolysiloxane polymer synthetic that contains chain alkyl]
After in the methyl dialkylene polysiloxanes 499.8g that the hydrogenated methyl diene polysiloxanes 160.8g and the following formula (2) of following formula (1) expression are represented, adding 2% chloroplatinic acid alcoholic solution 0.1g, keep temperature to carry out polymerization in 2 hours for 70-80 ℃, obtain as the siloxane polymer (I) that contains the cross-lined organic polyorganosiloxane polymer of chain alkyl.
[synthesizing of partially crosslinked organopolysiloxane polymer]
Trimethyl hydrogenated methyl diene polysiloxanes (molecular weight 2300, CH in three silicyl end-capped
3HSiO: (CH
3)
2SiO is 1: 4 (mol ratio)) in an amount of adds potassium hydroxide solution (ethanol: water=2: 1), heating reflux and carries out polyreaction, obtains reaction product.Then, wash reaction product with water, remove alkaline agent after, natural drying obtains as the siloxane polymer of partially crosslinked organopolysiloxane polymer (II).
[embodiment 1-10 and comparative example 1-3]
Preparation has the eye shadow of constituent as shown in table 1, aspect " finger taking-up property ", " elasticity during use ", " not being clamminess and salubrious usability ", " skin adaptation ", " the cosmetic persistency of resistance to water, anti-sebum etc. ", " resistance to impact ", judge that according to following evaluation methodology that illustrates and judgment standard combined statement is shown in table 1 as a result.
[table 1]
(％)
| Composition | Embodiment | Comparative example | |||||||||||
| ?1 | ?2 | ?3 | ?4 | ?5 | ?6 | ?7 | ?8 | ?9 | ?10 | ?1 | ?2 | ?3 | |
| 1 Muscovitum | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus |
| 2 mica titanium | ?30.0 | ?30.0 | ?30.0 | ?30.0 | ?30.0 | ?30.0 | ?30.0 | ?30.0 | ?30.0 | ?30.0 | ?30.0 | ?30.0 | ?30.0 |
| 3 silicon dioxide *1 | ?3.0 | ?9.0 | ?0.5 | ?3.0 | ?3.0 | ?3.0 | ?3.0 | ?3.0 | ?3.0 | ?3.0 | ?3.0 | ?3.0 | ?3.0 |
| 4 nylon *2 | ?1.0 | ?1.0 | ?0.5 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 |
| 5 titanium oxides | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 |
| 6 melanterite | ?0.1 | ?0.1 | ?0.1 | ?0.1 | ?0.1 | ?0.1 | ?0.1 | ?0.1 | ?0.1 | ?0.1 | ?0.1 | ?0.1 | ?0.1 |
| 7 antiseptic | ?0.2 | ?0.2 | ?0.2 | ?0.2 | ?0.2 | ?0.2 | ?0.2 | ?0.2 | ?0.2 | ?0.2 | ?0.2 | ?0.2 | ?0.2 |
| 8 polysiloxane polymers (I) *3 | ?0.5 | ?0.5 | ?0.5 | ?0.001 | ?15.0 | ?0.5 | ?0.5 | ?0.5 | ?0.5 | ?0.5 | ?- | ?0.5 | ?0.5 |
| 9 polysiloxane polymers (II) *4 | ?10.0 | ?10.0 | ?10.0 | ?10.0 | ?10.0 | ?1.0 | ?20.0 | ?10.0 | ?10.0 | ?5.0 | ?10.0 | ?- | ?10.0 |
| 10 simethicone *5 | ?45.0 | ?43.0 | ?50.0 | ?45.0 | ?34.0 | ?50.0 | ?39.0 | ?44.0 | ?50.0 | ?45.0 | ?45 | ?45 | ?45 |
| 11 liquid paraffin *6 | ?3.0 | ?3.0 | ?3.0 | ?3.0 | ?3.0 | ?3.0 | ?3.0 | ?5.0 | ?0.25 | ?3.0 | ?3 | ?3 | ?- |
| 12 32 ethyl hexanoic acid glyceride *7 | ?2.0 | ?2.0 | ?2.0 | ?2.0 | ?2.0 | ?2.0 | ?2.0 | ?5.0 | ?0.25 | ?2.0 | ?2 | ?2 | ?- |
| Assessment item and result of determination | |||||||||||||
| Finger taking-up property | ?◎ | ?○ | ?○ | ?◎ | ?◎ | ?◎ | ?◎ | ?○ | ?◎ | ?◎ | ?◎ | ?○ | ?△ |
| Elasticity during use | ?◎ | ?◎ | ?◎ | ?○ | ?◎ | ?○ | ?◎ | ?◎ | ?◎ | ?○ | ?○ | ?× | ?◎ |
| The skin adaptation | ?◎ | ?◎ | ?◎ | ?◎ | ?◎ | ?◎ | ?◎ | ?◎ | ?○ | ?◎ | ?× | ?◎ | ?× |
| The usability that water is tender | ?◎ | ?◎ | ?◎ | ?◎ | ?○ | ?◎ | ?○ | ?◎ | ?◎ | ?◎ | ?◎ | ?◎ | ?○ |
| The cosmetic persistency of resistance to water, anti-sebum etc. | ?◎ | ?◎ | ?◎ | ?◎ | ?◎ | ?◎ | ?◎ | ?◎ | ?◎ | ?◎ | ?△ | ?× | ?◎ |
| Resistance to impact | ?○ | ?○ | ?○ | ?○ | ?○ | ?○ | ?○ | ?○ | ?○ | ?○ | ?△ | ?ND | ?○ |
| The contact pin load value | ?40 | ?50 | ?40 | ?40 | ?60 | ?110 | ?60 | ?30 | ?50 | ?100 | ?40 | ?190 | ?40 |
ND: can't observe (content comes off, and can't observe the wrinkle on surface) from the metallic vessel
* 1: go Star ト ボ one Le D11-796C (the spherical powder body of particle diameter 2-5 μ m: Suzuki oil prodution industry corporate system)
* 2: the リ Le サ Application パ ウ ダ one S (powder body of particle diameter 10-14 μ m: ATOFZNA Japanese firm system)
* 3: the polysiloxane polymer of above-mentioned synthesis example (I)
* 4: the polysiloxane polymer of above-mentioned synthesis example (II)
* 5:KF-96 (20CS) (chemical industrial company of SHIN-ETSU HANTOTAI system)
* 6: Ha イ コ one Le K-500 (カ ネ ダ corporate system)
* 7:TIO (N) (Nisshin Oillio Group Co., Ltd.'s system)
(preparation method)
A, composition 1-7 is dispersed in the Henschel blender (Mitsui three pond corporate systems).
B, composition 8, composition 9 disperseed in advance after, add composition 10-12, uniform mixing.
C, A stirred in the Henschel blender in, add B, homodisperse.
D, in 100 parts of C, add as 50 parts of the simethicone (KF-96 (10CS)) (chemical industrial company of SHIN-ETSU HANTOTAI system) of solvent, uniform mixing.
E, D is packed in the metallic vessel, compression forming when drawing solvent with paper obtains eye shadow.
(evaluation methodology 1): " finger taking-up property ", " elasticity during use ", " not being clamminess and salubrious usability ", " skin adaptation ", " the cosmetic persistency of resistance to water, anti-sebum etc. "
Allow cosmetic evaluation specialize in 20 eye shadows that use the foregoing description and comparative example of group member, aspect " finger taking-up property ", " elasticity during use ", " not being clamminess and salubrious usability ", " skin adaptation ", " the cosmetic persistency of resistance to water, anti-sebum etc. ", carry out the evaluation of 7 grades respectively separately according to following metewand, every kind of sample is given a mark, and the meansigma methods of full-fledged research group member's scoring is judged according to following determinating reference.
Metewand
(evaluation) (content)
6: very good
5: good
4: good slightly
3: common
2: poor slightly
1: poor
0: non-constant
Determinating reference
(meansigma methods of scoring) (judgement)
5.0 more than: ◎ (very good)
3.5 below not to 5.0: zero (good)
2.0 below not to 3.5: △ (common)
Not to 2.0: * (bad)
(evaluation methodology 2): " resistance to impact "
Freely fall to the acrylic panel vertical direction from the height of 50cm being packed into the foregoing description of state of metallic vessel and the eye shadow of comparative example, observe the apparent condition after falling, each eye shadow is judged by following 3 grades evaluation determinating reference.
(evaluation determinating reference)
(evaluation) (judgement)
Complete no change: zero
There are wrinkle on the surface: △
Wrinkle are arranged on the big surface: *
(mensuration of contact pin load value)
It is that the mould of 4mm is as sample that makeup cosmetic is packed into thickness, measure machine with the レ オ テ of Co., Ltd. Star Network corporate system " RHEO TECH FUDOH RHEO METER " conduct, set the hardness measurement condition for using adapter 3mm φ, entering, carry out the contact pin load value and measure apart from 1.5mm, rate of climb 2cm/min.
As can be seen from Table 1, be the equal exhibits excellent of whole projects as the eye shadow of the embodiment 1-9 of product of the present invention in " finger takes out property ", " elasticity during use ", " the salubrious usability that is not clamminess ", " skin adaptation ", " the cosmetic persistency of resistance to water, anti-sebum etc. ", " resistance to impact ".Especially aspect " elasticity during use ", " usability that is not clamminess ", as Fig. 1 explanation of back, initial elastic sensation is very good, but disappears along with extending elastic sensation, and the quality of people's sense of touch pulverize sense is given in expansion lentamente.In contrast, do not have the comparative example 1 of the polysiloxane polymer (I) of gradation composition (A) to have relatively poor " skin adaptation " and reach " cosmetic persistency such as resistance to water, anti-sebum " etc.; In addition, there is not the comparative example 2 of polysiloxane polymer (II) of gradation composition (B) relatively poor in " elasticity during use ", " cosmetic persistency such as resistance to water, anti-sebum ", " resistance to impact " each side; And the comparative example 3 that does not have gradation composition (D) is " skin adaptation " relatively poor products.
(mensuration of dynamic viscoelastic)
Makeup cosmetic of the present invention is different with in the past oiliness eye shadow, powder solid eye shadow, and it has the feature of resilient unique sense of touch.Therefore, with Off Le one De spectrometer (レ オ ト リ Star Network corporate system, RES-II) dynamic viscoelastic of the eye shadow of mensuration the foregoing description 1 record.With parallel-plate or the Network ェ Star ト of 25-50mm, mainly use the mode determination of deformation amplitude dependencies (dynamic frequency scanning, dynamic frequency sweep) to measure geometric features.Distortion herein will count 100% with the situation that the deformation amplitude that equates with the interval of parallel-plate moves parallel-plate, and fixed-frequency makes the deformation amplitude 10 at 1Hz
-8To 10
3Between change.Under this condition, measure, obtain energy storage elastic modelling quantity (G '), loss elastic modulus (G ").Like this, Fig. 1 show the G ' that uses cosmetics of the present invention (eye shadow of embodiment 1) to measure to obtain (the energy storage elastic modelling quantity: the elasticity item), G " (loss elastic modulus: curve viscosity term).G ' the expression energy storage elastic modelling quantity (elasticity item) of the longitudinal axis, G " expression loss elastic modulus (viscosity term), transverse axis (%) expression distortion.In Fig. 1, because the elasticity item significantly reduces after having increased share, but viscosity term does not rise, that reduces than the elasticity item is less slightly, is that initial elastic sensation is very good corresponding to sense of touch therefore, disappear along with extending elastic sensation, expansion becomes the quality that the powder sense is arranged for people's thoughts and feelings lentamente.
(mensuration of TPA)
Texture analyser with great smart machine (strain) corporate system of English carries out TPA (texture profile analysis) mensuration to powder eye shadow, the Emulsion eye shadow (oiliness eye shadow) that product of the present invention (embodiment 1,6,10), reference substance (comparative example 2) reach product in the past.Condition determination be 2mm φ cylindrical needle, probe speed 0.5mm/sec,, under the situation of not exclusively destroying sample (non-destroyed area) to adjust deflection be 25%.TPA is determined as with certain probe sample is added dynamics 2 times, the first time and secondary time difference keep 3sec, the height change that distortion is for the first time caused is designated as L1, and the height change that distortion is for the second time caused is designated as L2, with the index of L2/L1 as elasticity (springness).For example, the situation of spring, because it is a perfectly elastic body, L1=L2 causes elasticity L2/L1=1 thus.Table 2 shows the result of elasticity (L2/L1).Can have elasticity by clear and definite product of the present invention by table 2.In addition, Fig. 2 shows with texture analyser product of the present invention (embodiment 1) is carried out result that TPA measures as a reference.
[table 2]
| L2/L1 | |
| Product of the present invention (embodiment 1) | 0.923 |
| Product of the present invention (embodiment 6) | 0.487 |
| Product of the present invention (embodiment 10) | 0.489 |
| Reference substance (comparative example 2) | 0.470 |
| Product in the past (powder eye shadow) | 0.467 |
| Product in the past (Emulsion eye shadow) | 0.245 |
In addition, below show product (powder eye shadow) and the prescription and the preparation method of product (Emulsion eye shadow) in the past in the past.
[prescription of powder eye shadow and preparation method]
(composition) (%)
1, the Muscovitum * 8 20.0 of polysiloxanes processing
2, Pulvis Talci * 8 surpluses of polysiloxanes processing
3, the Muscovitum 30.0 of titanium oxide lining
4, boron nitride 5.0
5, ultramarine 2.0
6, yellow No. 401 0.5
7, synthetic chloroflo 2.5
8, the netted polysiloxane block copolymers * 9 2.0 of cross-linking type polysiloxanes
9, antiseptic 0.2
10, liquid paraffin 2.0
11, vaseline 1.0
12, dimethyl polysiloxane 3.0
13, spice 0.01
* the dimethyl polysiloxane of 8:3% is handled
* 9:KSP-100 (the spherical powder body of particle diameter 5 μ m: chemical industrial company of SHIN-ETSU HANTOTAI system)
(preparation method)
A, composition 1-9 is dispersed in the Henschel blender (Mitsui three pond corporate systems).
B, heating composition 10-13 make it homodisperse.
In the time of C, usefulness Henschel blender stirring A, add B, make it homodisperse.
D, in pulverizer, pulverize C.
E, fill D in metalware, compression forming obtains the powder eye shadow.
[prescription of Emulsion eye shadow and preparation method]
(composition) (%)
1, paraffin 3.5
2, distearyl acid ethylene glycol 2.0
3, Brazil wax 1.5
4, methyl polysiloxane 15.0
5, squalane 7.0
6, three 2 ethyl hexanoic acid glyceride 20.0
7, the netted polysiloxane block copolymers * 9 5.0 of cross-linking type polysiloxanes
8, the mica titanium * 8 35.0 of polysiloxanes processing
9, alloy Muscovitum * 8 surpluses of polysiloxanes processing
10, ferrum oxide 0.4
11, ultramarine 0.1
12, paraffin 0.5
13, squalane 2.5
14, spice 0.01
(preparation method)
A, the 12-14 heating for dissolving is even.
B, in A, add 9-11, in cylinder, disperse.
C, the 1-6 heating for dissolving is even.
D, B is added among the C, heating for dissolving is even.
E, add among the D 7,8, heating for dissolving is even.
F, E is heated to 80 ℃, is packed into metalware, after the cooling, obtain the Emulsion eye shadow.
[embodiment 11: eye shadow]
(composition) (%)
1, Muscovitum surplus
2, the Muscovitum (glossy powder body) 5.0 of titanium oxide lining
3, silicon dioxide * 10 3.0
4, nylon * 11 1.0
5, mica titanium (glossy powder body) 20.0
6, iron oxide yellow 0.1
7, iron oxide black 0.1
8, melanterite 0.1
9, ultramarine 0.1
10, the titanium oxide 1.0 of polysiloxanes processing
11, the P-hydroxybenzoic acid methyl 0.1
12, simethicone * 12 20.0
13, the mixture * 1 34.0 that contains the partially crosslinked organopolysiloxane polymer of chain alkyl
14, the mixture * 14 35.0 of partially crosslinked organopolysiloxane polymer
15, heavy liquid isoparaffin * 15 5.0
16, three 2 ethyl hexanoic acid glyceride 1.0
17, spice is an amount of
(prescription is outer)
18, solvent: 12 40 parts of simethicone *
* 10: go Star ト ボ one Le E2-824C (particle diameter: the spherical powder body of 0.9-1.4 μ m: Suzuki oil prodution industry corporate system)
* 11: リ Le サ Application パ ウ ダ one L (particle diameter: the special-shaped powder of 18-25 μ m: ATOFINA Japanese firm system)
* 12:KF-96 (10CS) (chemical industrial company of SHIN-ETSU HANTOTAI system)
* 13:KSG-43 (chemical industrial company of SHIN-ETSU HANTOTAI system)
* 14:KSG-16 (chemical industrial company of SHIN-ETSU HANTOTAI system)
* 15: パ one Le リ, one system 18 (Nof Corp.'s system)
(preparation method)
A, composition 1-11 is dispersed in the Henschel blender (Mitsui three pond corporate systems).
B, with composition 12-17 uniform mixing.
C, in the Henschel blender, stir in the A, add B, make it homodisperse.
D, in 100 parts of C, add composition 18, make it uniform mixing.
E, D is packed in the metallic vessel, compression forming in the time of with the paper lyosoption obtains eye shadow.
Eye shadow of the present invention all shows excellence aspect " finger taking-up property ", " elasticity during use ", " the salubrious usability that is not clamminess ", " skin adaptation ", " the cosmetic persistency of resistance to water, anti-sebum etc. ", " resistance to impact " etc. are whole.
[embodiment 12: eye shadow]
(composition) (%)
1, Muscovitum surplus
2, Pulvis Talci 7.0
3, the netted polysiloxane block copolymers * 9 3.0 of cross-linking type polysiloxanes
4, nylon * 2 2.0
5, mica titanium (glossy powder body) 20.0
6, the iron oxide yellow 0.1 of polysiloxanes processing
7, the iron oxide black 0.1 of polysiloxanes processing
8, the titanium oxide 0.1 of polysiloxanes processing
9, the P-hydroxybenzoic acid methyl 0.1
10, tolyl polysiloxanes * 16 20.0
11, the mixture * 13 4.0 that contains the partially crosslinked organopolysiloxane polymer of chain alkyl
12, the mixture * 14 35.0 of partially crosslinked organopolysiloxane polymer
13, polybutene 5.0
14, three 2 ethyl hexanoic acid glyceride 1.5
15, spice is an amount of
(prescription is outer)
16, solvent: 12 60 parts of simethicone *
* 16:KF-56 (chemical industrial company of SHIN-ETSU HANTOTAI system)
(preparation method)
A, composition 1-9 is dispersed in the Henschel blender (Mitsui three pond corporate systems).
B, with composition 10-15 uniform mixing.
C, in the Henschel blender, stir in the A, add B, make it homodisperse.
D, composition 16 is added among 100 parts of C, make it uniform mixing.
E, D is packed in the metallic vessel, compression forming in the time of with the paper lyosoption obtains eye shadow.
All performance is excellent whole 1 of " finger (small pieces) taking-up property ", " elasticity during use ", " the salubrious usability that is not clamminess ", " skin adaptation ", " the cosmetic persistency of resistance to water, anti-sebum etc. ", " resistance to impact " etc. for eye shadow of the present invention.
[embodiment 13: foundation cream]
(composition) (%)
1, Muscovitum surplus
2, Pulvis Talci 5.0
3, the netted polysiloxane block copolymers * 9 3.0 of cross-linking type polysiloxanes
4, polystyrene * 17 2.0
5, mica titanium (glossy powder body) 20.0
6, the iron oxide yellow 0.1 of fluorine compounds processing
7, the iron oxide black 0.1 of fluorine compounds processing
8, the melanterite 0.1 of fluorine compounds processing
9, the particulate titanium dioxide 2.0 of fluorine compounds processing
10, simethicone * 5 25.0
11, the mixture * 13 5.0 that contains the partially crosslinked organopolysiloxane polymer of chain alkyl
12, the mixture * 14 30.0 of partial cross-linked organopolysiloxane polymer
13, p-methoxycinnamic acid 2-Octyl Nitrite 4.0
14, three 2 ethyl hexanoic acid glyceride 1.5
15, spice is an amount of
(prescription is outer)
16, solvent: 18 45 parts of simethicone *
* 17: Off ア イ Application パ one Le 3000SP-Q (the spherical powder body of particle diameter 5-20 μ m: loose Pu corporate system)
* 18:KF-96 (6CS) (chemical industrial company of SHIN-ETSU HANTOTAI system)
(preparation method)
A, composition 1-9 is dispersed in the Henschel blender (Mitsui three pond corporate systems).
B, with composition 10-15 uniform mixing.
C, in the Henschel blender, stir in the A, add B, make it homodisperse.
D, composition 16 is added among 100 parts of C, make it uniform mixing.
E, D is packed in the metallic vessel, compression forming in the time of with the paper lyosoption obtains foundation cream.
Foundation cream of the present invention all shows excellence aspect " finger (sponge) taking-up property ", " elasticity during use ", " the salubrious usability that is not clamminess ", " skin adaptation ", " the cosmetic persistency of resistance to water, anti-sebum etc. ", " resistance to impact " etc. are whole.
[embodiment 14: rouge (face color)]
(composition) (%)
1, Muscovitum surplus
2, Pulvis Talci 5.0
3, nylon * 19 1.0
4, methacrylic acid methyl cross linked polymer * 20 10.0
5, mica titanium (glossy powder body) 10.0
6, the redness 226 0.1 of fluorine compounds processing
7, the iron oxide black 0.1 of fluorine compounds processing
8, the particulate titanium dioxide 2.0 of fluorine compounds processing
9, simethicone * 5 30.0
10, the mixture * 13 2.0 that contains the partially crosslinked organopolysiloxane polymer of chain alkyl
11, the mixture * 14 30.0 of partially crosslinked organopolysiloxane polymer
12, liquid paraffin 2.0
13, polybutene 2.0
14, three 2 ethyl hexanoic acid glyceride 1.5
15, spice is an amount of
(prescription is outer)
16, solvent: 18 55 parts of simethicone *
* 19: eastern beautiful system nylon powder SP-500 (the spherical powder body of particle diameter 1-23 μ m: eastern beautiful corporate system)
* 20: ガ Application Star パ one Le GMI-0804 (special-shaped powder of particle diameter 4-15 μ m: ガ Application Star changes into corporate system)
(preparation method)
A, composition 1-8 is dispersed in the Henschel blender (Mitsui three pond corporate systems).
B, make composition 9-15 uniform mixing.
C, in the Henschel blender, stir in the A, add B, make it homodisperse.
D, composition 16 is added among 100 parts of C, make it uniform mixing.
E, D is packed in the metallic vessel, compression forming in the time of with the paper lyosoption obtains rouge.
Rouge of the present invention all shows excellence aspect " finger taking-up property ", " elasticity during use ", " the salubrious usability that is not clamminess ", " skin adaptation ", " the cosmetic persistency of resistance to water, anti-sebum etc. ", " resistance to impact " etc. are whole.
[embodiment 15: lip honey]
(composition) (%)
1, the glass dust (glossy powder body) 20.0 of titanium oxide lining
2, silicon dioxide * 10 2.0
3, polystyrene * 17 2.0
4, simethicone (20cs) 15.0
5, the mixture * 13 10.0 that contains the partially crosslinked organopolysiloxane polymer of chain alkyl
6, the mixture * 14 35.0 of partially crosslinked organopolysiloxane polymer
7, heavy liquid isoparaffin * 15 4.0
8, malic acid two iso stearyl ester surpluses
9, three 2 ethyl hexanoic acid glyceride 1.5
10,1,3 butylene glycol 1.0
11, beauty treatment composition (Flos Matricariae chamomillae extract) 0.1
12, Purified Water 3.0
13, spice is an amount of
(prescription is outer)
14, solvent: 35 parts of simethicone (6cs)
(preparation method)
A, composition 1-3 is dispersed in the Henschel blender (Mitsui three pond corporate systems).
B, make composition 4-13 uniform mixing.
C, in the Henschel blender, stir in the A, add B, make it homodisperse.
D, composition 14 is added among 100 parts of C, make it uniform mixing.
E, D is packed in the metallic vessel, compression forming in the time of with the paper lyosoption obtains lip honey.
Lip honey of the present invention all shows excellence aspect " finger (brush) taking-up property ", " elasticity during use ", " the salubrious usability that is not clamminess ", " skin adaptation ", " the cosmetic persistency of resistance to water, anti-sebum etc. ", " resistance to impact " etc. are whole.
Industrial applicability
Makeup cosmetic of the present invention has salubrious use sense and soft sense of touch and the flexible while of not being clamminess, also have good resistance to water, anti-sebum, resistance to impact, in addition, can compression forming in metal-made vessel or synthetic resin vessel processed, then the small containers of packing into is complete, multiple color is merged use, have simplicity and convenience.
Claims (14)
1. makeup cosmetic, it is characterized in that, contain: the composition of forming by the partially crosslinked organopolysiloxane polymer that contains chain alkyl (A), the composition of forming by the partially crosslinked organopolysiloxane polymer except composition (A) (B), the composition of forming by silicone oil (C), the composition of forming by one or more the unthickened fuel that is selected from hydrocarbon ils and/or ester oil (D) and the composition of forming by powder body (E).
2. makeup cosmetic as claimed in claim 1 is characterized in that makeup cosmetic is butyrous.
3. makeup cosmetic as claimed in claim 1 or 2 is characterized in that, composition (A) is (vinyl-dimethyl silicone oil/dodecyl simethicone) cross linked polymer.
4. as each described makeup cosmetic of claim 1-3, it is characterized in that composition (B) is (simethicone/vinyl-dimethyl silicone oil) cross linked polymer.
5. as each described makeup cosmetic of claim 1-4, it is characterized in that composition (C) is a simethicone.
6. as each described makeup cosmetic of claim 1-5, it is characterized in that, contain the composition (C) of 30-70 quality %.
7. as each described makeup cosmetic of claim 1-6, it is characterized in that, contain the composition (D) of 0.5-10 quality %.
8. as each described makeup cosmetic of claim 1-7, it is characterized in that composition (E) contains the tabular powder body with glossiness.
9. as each described makeup cosmetic of claim 1-8, it is characterized in that composition (E) contains spherical powder body.
10. as each described makeup cosmetic of claim 1-9, it is characterized in that be packed in the ware shape container and compression forming, at least one of this ware shape container is contained in the compact container.
11., it is characterized in that the contact pin load value of the makeup cosmetic of compression forming is 20-120gf as each described makeup cosmetic of claim 1-10.
12., it is characterized in that the elasticity number (L2/L1) that the makeup cosmetic of the compression forming TPA (texture profile analysis) by texture analyser is measured is 0.48-0.99 as each described makeup cosmetic of claim 1-11.
13., it is characterized in that described cosmetics are eye shadows as each described makeup cosmetic of claim 1-12.
14. the preparation method of makeup cosmetic, it is characterized in that, the compositions of the composition (B) that will contain the composition (A) be made up of the partially crosslinked organopolysiloxane polymer that contains chain alkyl, be made up of the partially crosslinked organopolysiloxane polymer except composition (A), the composition of being made up of silicone oil (C), the composition of being made up of one or more the unthickened fuel that is selected from hydrocarbon ils and/or ester oil (D) and the composition (E) be made up of powder body is dispersed in the solvent, be packed in the ware shape container compression forming when absorbing above-mentioned solvent after the dispersion.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP134511/2005 | 2005-05-02 | ||
| JP2005134511 | 2005-05-02 | ||
| PCT/JP2006/308518 WO2006120876A1 (en) | 2005-05-02 | 2006-04-24 | Makeup cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101208073A true CN101208073A (en) | 2008-06-25 |
| CN101208073B CN101208073B (en) | 2012-09-05 |
Family
ID=37396386
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006800150248A Active CN101208073B (en) | 2005-05-02 | 2006-04-24 | Makeup cosmetic |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP5085323B2 (en) |
| KR (1) | KR101320677B1 (en) |
| CN (1) | CN101208073B (en) |
| HK (1) | HK1118705A1 (en) |
| TW (1) | TW200722108A (en) |
| WO (1) | WO2006120876A1 (en) |
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| JP2796856B2 (en) * | 1989-09-28 | 1998-09-10 | 株式会社コーセー | Oily cosmetics |
| JPH03197413A (en) * | 1989-12-26 | 1991-08-28 | Kobayashi Kose Co Ltd | Solid powdery make-up cosmetic |
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| JP2001278730A (en) * | 2000-03-29 | 2001-10-10 | Kose Corp | Powder cosmetic |
| JP2002322030A (en) * | 2001-04-26 | 2002-11-08 | Kose Corp | Unevenness-correcting cosmetic |
| WO2003041664A1 (en) * | 2001-11-15 | 2003-05-22 | Shin-Etsu Chemical Co., Ltd. | Cosmetics containing clay mineral |
| JP2003292415A (en) * | 2002-04-01 | 2003-10-15 | Shin Etsu Chem Co Ltd | Cosmetic |
| JP3979922B2 (en) | 2002-11-08 | 2007-09-19 | 信越化学工業株式会社 | Hydrophilized powder and composition containing the same |
| GB0226089D0 (en) * | 2002-11-08 | 2002-12-18 | Weintroub Jeremy N | House carton |
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| JP2004346046A (en) * | 2003-05-26 | 2004-12-09 | Shin Etsu Chem Co Ltd | Cosmetic |
| CN100594878C (en) * | 2004-03-31 | 2010-03-24 | 信越化学工业株式会社 | Cosmetic containing siloxane polymer |
-
2006
- 2006-04-24 JP JP2007528203A patent/JP5085323B2/en active Active
- 2006-04-24 WO PCT/JP2006/308518 patent/WO2006120876A1/en active Application Filing
- 2006-04-24 CN CN2006800150248A patent/CN101208073B/en active Active
- 2006-04-24 KR KR1020077026824A patent/KR101320677B1/en active IP Right Grant
- 2006-04-28 TW TW095115417A patent/TW200722108A/en unknown
-
2008
- 2008-09-11 HK HK08110102.6A patent/HK1118705A1/en unknown
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Also Published As
| Publication number | Publication date |
|---|---|
| JP5085323B2 (en) | 2012-11-28 |
| KR101320677B1 (en) | 2013-10-18 |
| JPWO2006120876A1 (en) | 2008-12-18 |
| HK1118705A1 (en) | 2009-02-20 |
| TWI367108B (en) | 2012-07-01 |
| KR20070122564A (en) | 2007-12-31 |
| WO2006120876A1 (en) | 2006-11-16 |
| CN101208073B (en) | 2012-09-05 |
| TW200722108A (en) | 2007-06-16 |
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