CN109316382B - Elastic color cosmetic product and preparation method thereof - Google Patents
Elastic color cosmetic product and preparation method thereof Download PDFInfo
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- CN109316382B CN109316382B CN201811293764.9A CN201811293764A CN109316382B CN 109316382 B CN109316382 B CN 109316382B CN 201811293764 A CN201811293764 A CN 201811293764A CN 109316382 B CN109316382 B CN 109316382B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/88—Polyamides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/893—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by an alkoxy or aryloxy group, e.g. behenoxy dimethicone or stearoxy dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
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Abstract
The invention discloses an elastic color cosmetic product and a preparation method thereof, wherein the elastic color cosmetic product comprises the following components in parts by weight: component A) 20-70 parts of siloxane; component B) oil component 10-20 parts; component C) 10-25 parts of water; component D) 5-10 parts of composite pigment; component E) powder 1-5 parts; component F) 5-10 parts of other auxiliary agents. According to the invention, the silicone composite component with specific compound type and specific compound proportion is compounded with oil, moisture, composite pigment, powder and the like with specific content, so that the prepared elastic color cosmetic product has good elasticity and strong water-moistening feeling and is not easy to dry, thereby providing special use feeling for consumers.
Description
Technical Field
The invention relates to the field of cosmetics, in particular to an elastic color cosmetic product and a preparation method thereof.
Background
The color cosmetic product is a product for decorating beauty and showing beauty and confidence. The color cosmetic products can be divided into powder, ointment, emulsion, aqua and the like in form, and different using effects are reflected in use. In recent years, with the rapid development of the color cosmetics industry at home and abroad, new breakthrough directions are continuously sought for products to meet basic use. Wherein it is a good direction to improve the sensory experience of the consumer. In this regard, the present invention is developed with the aim of bringing a different feeling of use to the consumer.
Disclosure of Invention
The invention aims to provide a color cosmetic product with elastic texture.
The invention also aims to provide a preparation method of the color cosmetic product with elastic texture.
The invention adopts the following specific technical scheme:
the elastic color cosmetic product comprises the following components in parts by weight:
component A) 20-70 parts of siloxane;
component B) oil component 10-20 parts;
component C) 10-25 parts of water;
component D) 5-10 parts of composite pigment;
component E) powder 1-5 parts;
component F) 5-10 parts of other auxiliary agents.
Wherein, the siloxane of the component A) is one or two selected from PEG/PPG-19/19 polydimethylsiloxane, PEG-10 polydimethylsiloxane, lauryl PEG-9 polydimethylsiloxane, cetyl PEG/PPG-10/1 polydimethylsiloxane, cyclopentadimethylsiloxane, 5CS polydimethylsiloxane, 6CS polydimethylsiloxane, phenyl polydimethylsiloxane, diphenyl siloxy phenyl polydimethylsiloxane and octyl methicone.
Preferably, the siloxane of the component A) is selected from PEG/PPG-19/19 dimethyl silicone polymer, and the compounding of PEG-10 dimethyl silicone polymer and cyclopenta dimethyl silicone polymer, and the compounding weight ratio of the three is (10-18): (1-2): (40-50).
Wherein, the component B) oil component is selected from one or more of isononyl isononanoate, dioctyl carbonate, cetyl ethyl hexanoate, glycerol tri (ethyl hexanoate), isododecane, neopentyl glycol diheptanoate, ethylhexyl methoxycinnamate and microcrystalline wax.
Wherein the component D) composite pigment is one or more selected from titanium dioxide, iron oxide red, iron oxide yellow, iron oxide black, ultramarine blue, ultramarine violet, chromium oxide green, pearlescent pigment, ultramarine and organic pigment.
Wherein the powder of the component E) is one or more selected from nylon-12, boron nitride, polymethylsilsesquioxane, polymethyl methacrylate, bismuth oxychloride, silica, mica, synthetic fluorophlogopite, sericite, vinyl polydimethylsiloxane/polymethylsiloxane silsesquioxane cross-linked polymer and talcum powder.
Wherein, the other auxiliary agents of the component F) are selected from one or more of film forming agent, humectant, stabilizing agent, pH regulator, preservative, antioxidant and dispersant; wherein the film forming agent is selected from one or more of trimethylsiloxysilicate, acrylic acid (ester)/ethylhexyl acrylate/polydimethylsiloxane methacrylate copolymer, acrylic acid (ester)/polydimethylsiloxane copolymer; the humectant is one or more selected from glycerol, 1, 3-butanediol, DPG, propylene glycol, pentanediol, hexanediol, sodium hyaluronate, allantoin and trehalose; the stabilizing agent is selected from sodium chloride; the pH regulator is one or more selected from citric acid and sodium citrate; the preservative is selected from phenoxyethanol; the antioxidant is selected from vitamin E; the dispersant is selected from isostearic acid.
The preparation method of the elastic color cosmetic product comprises the following steps:
(1) weighing the component A according to the proportion, and uniformly stirring;
(2) weighing the component B material according to the proportion, mixing with the component A material, heating and stirring uniformly
(3) Weighing the film forming agent or the dispersing agent in the component F according to the proportion, and uniformly stirring the film forming agent or the dispersing agent and the A, B mixed material;
(4) weighing the materials of the components D and E according to the proportion, adding the materials into the mixed phase of the first 3, uniformly stirring and wetting, homogenizing for 3min at the speed of 5000rpm until the material body is fine and uniform, and marking as an oil phase;
(5) weighing the component C material in proportion, weighing the component F material in proportion, mixing and stirring uniformly, and recording as a water phase;
(6) and under the condition of stirring, the stirring speed is 200rpm, and the water-phase material is added into the oil-phase material until the water-phase material is completely added, so that the elastic color cosmetic product is obtained.
Compared with the prior art, the invention has the following beneficial effects:
according to the invention, the elastic color cosmetic product prepared by compounding the specific compound type and the siloxane with the specific compound proportion with the specific content of oil, moisture, composite pigment, powder and the like has good elasticity, strong water-moistening feeling and is not easy to dry, so that the special use feeling of consumers is provided.
Detailed Description
In order that the invention may be more fully understood, reference will now be made to the following description. The present invention may be embodied in many different forms and is not limited to the embodiments described herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
In the following detailed description, unless otherwise specified, all conventional methods are used; the raw materials, reagents, and the like used in the following embodiments are all commercially available products unless otherwise specified.
The test methods or standards for each performance index are as follows:
observing the state of the material body, standing the material body on a desktop after the experiment is finished to observe the state of the material body, and preferably evaluating the state of the material body (fine, smooth and flat); the material body state is better (smoother, smoother and more exquisite) and B is evaluated; the material body state is qualified (generally smooth and flat, generally fine and smooth) and C is evaluated; the material body state was poor (not smooth, not fine) and rated D.
The specific test method of the elasticity is that the materials which are finished in the experiment are arranged in the same container, and the quality is the same; after standing for 24 hours, respectively pressing the samples with the same force, calculating the time required for restoring the samples to the original flat state after pressing, and recording the time; the recovery time is short, and the elasticity is poor; the recovery time is long (can not be recovered), the elasticity is poor, the recovery time is preferably 15-40 minutes, and the recovery time is preferably 30-36 minutes.
Examples 1 to 5 and comparative examples 1 to 6: preparation of elastic color cosmetic product
Weighing the component A according to the proportion in the table 1, and uniformly stirring; weighing the component B material according to the proportion in the table 1, mixing with the component A material, heating and stirring uniformly; weighing the film forming agent or the dispersing agent in the component F according to the proportion in the table 1, and uniformly stirring the film forming agent or the dispersing agent and the A, B mixed material; weighing the materials of the components D and E according to the proportion in the table 1, adding the materials into the mixed phase of the first 3, uniformly stirring and wetting, homogenizing for 3min at the speed of 5000rpm until the material body is fine and uniform, and marking as an oil phase; weighing the component C material according to the proportion in the table 1, weighing the component F material according to the proportion in the table 1, mixing and stirring uniformly, and marking as a water phase; and under the condition of stirring, the stirring speed is 200rpm, and the water-phase material is added into the oil-phase material until the water-phase material is completely added, so that the elastic color cosmetic product is obtained. The data of various performance indexes of the prepared elastic color cosmetic product are shown in table 1.
TABLE 1 ingredient ratio (parts by weight) and experimental results
Claims (8)
1. The elastic color cosmetic product is characterized by comprising the following components in parts by weight:
component A) 20-70 parts of siloxane;
component B) oil component 10-20 parts;
component C) 10-25 parts of water;
component D) 5-10 parts of composite pigment;
component E) powder 1-5 parts;
component F) 5-10 parts of other auxiliary agents;
the siloxane of the component A) is selected from the compound of PEG/PPG-19/19 dimethyl silicone polymer, PEG-10 dimethyl silicone polymer and cyclopenta dimethyl silicone polymer, and the compound weight ratio of the three is (10-18): (1-2): (40-50).
2. The elastic color cosmetic product according to claim 1, wherein the component B) oil component is selected from one or more of isononyl isononanoate, dioctyl carbonate, cetyl ethylhexanoate, glycerol tri (ethylhexanoate), isododecane, neopentyl glycol diheptanoate, ethylhexyl methoxycinnamate, microcrystalline wax.
3. The elastic color cosmetic product according to claim 1, wherein the component D) composite pigment is one or more selected from titanium dioxide, iron oxide red, iron oxide yellow, iron oxide black, chromium oxide green, pearlescent pigments, ultramarine blue pigments and organic pigments.
4. The elastic color cosmetic product of claim 3, wherein the ultramarine group is selected from ultramarine blue or ultramarine violet.
5. The elastic color cosmetic product according to claim 1, wherein the component E) powder is one or more selected from nylon-12, boron nitride, polymethylsilsesquioxane, polymethyl methacrylate, bismuth oxychloride, silica, mica, vinyl polydimethylsiloxane/polymethylsilsesquioxane crosspolymer, and talc.
6. The elastic color cosmetic product according to claim 5, wherein the mica is selected from synthetic fluorophlogopite or sericite.
7. The elastic color cosmetic product according to claim 1, wherein the component F) other auxiliary agents are selected from one or more of film forming agents, humectants, stabilizers, pH regulators, preservatives, antioxidants and dispersing agents; wherein the film forming agent is selected from one or more of trimethylsiloxysilicate, acrylic acid (ester)/ethylhexyl acrylate/polydimethylsiloxane methacrylate copolymer, acrylic acid (ester)/polydimethylsiloxane copolymer; the humectant is one or more selected from glycerol, 1, 3-butanediol, DPG, propylene glycol, pentanediol, hexanediol, sodium hyaluronate, allantoin and trehalose; the stabilizing agent is selected from sodium chloride; the pH regulator is one or more selected from citric acid and sodium citrate; the preservative is selected from phenoxyethanol; the antioxidant is selected from vitamin E; the dispersant is selected from isostearic acid.
8. A method of preparing the elastic color cosmetic product of any one of claims 1 to 7, comprising the steps of:
(1) weighing the component A according to the proportion, and uniformly stirring;
(2) weighing the component B material according to the proportion, mixing with the component A material, heating and stirring uniformly
(3) Weighing the film forming agent or the dispersing agent in the component F according to the proportion, and uniformly stirring the film forming agent or the dispersing agent and the A, B mixed material;
(4) weighing the materials of the components D and E according to the proportion, adding the materials into the mixed phase of the first 3, uniformly stirring and wetting, homogenizing for 3min at the speed of 5000rpm until the material body is fine and uniform, and marking as an oil phase;
(5) weighing the component C material in proportion, weighing the component F material in proportion, mixing and stirring uniformly, and recording as a water phase;
(6) and under the condition of stirring, the stirring speed is 200rpm, and the water-phase material is added into the oil-phase material until the water-phase material is completely added, so that the elastic color cosmetic product is obtained.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811293764.9A CN109316382B (en) | 2018-11-01 | 2018-11-01 | Elastic color cosmetic product and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811293764.9A CN109316382B (en) | 2018-11-01 | 2018-11-01 | Elastic color cosmetic product and preparation method thereof |
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| CN109316382B true CN109316382B (en) | 2021-07-27 |
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| CN115707446A (en) * | 2021-08-20 | 2023-02-21 | 苏州安特化妆品股份有限公司 | Metal luster eye shadow and preparation process thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107440919B (en) * | 2017-08-08 | 2019-11-19 | 广州市科能化妆品科研有限公司 | A kind of stable dropper foundation emulsion and preparation method thereof |
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| CN101208073A (en) * | 2005-05-02 | 2008-06-25 | 株式会社高丝 | Makeup cosmetic |
| CN102719101A (en) * | 2011-03-28 | 2012-10-10 | 信越化学工业株式会社 | Organopolysiloxane elastomer composition and cosmetic containing the same |
| CN102973436A (en) * | 2012-12-19 | 2013-03-20 | 珀莱雅化妆品股份有限公司 | Making-up cosmetics composition with elastic touch |
| CN105636576A (en) * | 2013-10-31 | 2016-06-01 | 道康宁公司 | Cosmetic composition comprising a carboxy-functional elastomers |
| JP2016222599A (en) * | 2015-05-29 | 2016-12-28 | 花王株式会社 | Water-in-oil type emulsion cosmetic |
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| CN108066175A (en) * | 2017-12-29 | 2018-05-25 | 广州慈康生物科技有限公司 | A kind of preparation method for the flexible muffin that can assign the smooth sense of skin |
| CN108324595A (en) * | 2018-04-18 | 2018-07-27 | 上海中翊日化有限公司 | A kind of water-in-oil foundation liquid combining form having toning function and its use and preparation method |
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