KR101320677B1 - Makeup cosmetic - Google Patents

Abstract

It is non-sticky and has a refreshing feel, elastic touch and softness, and impact resistance, and can be compacted by filling into a metal dish or a resin dish, and the dish-shaped container is mounted in a compact container. The present invention provides a makeup cosmetic material having simplicity and convenience in which various colors can be used in combination.

Partially crosslinked organopolysiloxane polymer containing component (A) long-chain alkyl group, component (B) partially crosslinked organopolysiloxane polymer other than component (A), component (C) silicone oil, component (D) hydrocarbon It is a makeup cosmetic material containing the 1 type (s) or 2 or more types of liquid oil chosen from the group which consists of oil and / or ester oil, and a component (E) powder body, Comprising: The composition which consists of said (A)-(E) is dish-shaped Is filled into a container of a container and compression molded to obtain a makeup cosmetic material.

Cosmetic Ingredients, Eye Shadow

Description

Makeup Cosmetics {MAKEUP COSMETIC}

TECHNICAL FIELD This invention relates to a makeup cosmetic material and its manufacturing method. More specifically, it is the component (A) which consists of a partially crosslinked organopolysiloxane polymer containing a long-chain alkyl group, and components other than a component (A). Component (B) consisting of a partially crosslinked organopolysiloxane polymer, Component (C) consisting of silicone oil, Component (D) consisting of one or two or more liquid oils selected from the group consisting of hydrocarbon oils and / or ester oils; The present invention relates to a make-up cosmetic material containing a component (E) made of a powder and a manufacturing method thereof.

Since cosmetic materials such as makeup cosmetics are applied directly to the face, nails, etc., the use feeling and the effect of use that can be used comfortably, cleanly finished and beautifully dressed are important. Influence the value of. The first step in using a cosmetic material begins with tilting the container first to squeeze out the contents along the palm of the hand, withdrawing fingers from the container, and squeezing the contents out of the metal or plastic tube. In the second step, it is applied to the surface of the skin, spreading thinly, or rubbing. During this process, the fluidity of the cosmetic material varies, and oil is absorbed into the skin or moisture evaporates at the beginning and the end of the use of the cosmetic material, and thus the skin receives a different feeling. For this reason, the physical properties of the cosmetic material are complicated. Therefore, in the evaluation of these cosmetic materials and the like, they are expressed by vocabulary such as hard, soft, fresh and moist, wide open, entangled, sticky, rough, and powdery. These expressions are sensational response vocabularies from the start of the use of the cosmetic material to the end of use.

When the flow characteristics, feelings, and the like according to the use stage of the cosmetic material are classified, first of all, evaluation before use includes appearance, characteristics when contacting the cosmetic material to be used, ease of collecting cosmetic material from the container, and the like. The characteristic at the time of contact with a cosmetic material is crimping | bonding a cosmetic material with a thumb and an index finger, and evaluates the force. In addition, the ease at the time of taking out from a container is evaluated by the flow resistance and deformation | transformation state at the time of taking out a cosmetic material from a container. Subsequently, evaluation during use includes adhesion to the site of use, difficulty in extension of the sample on the skin, and a sense of permeability through the skin. Tensile and penetrability were also evaluated sensibly, and after use, the evaluation was performed after applying the cosmetic material or after applying the coating at regular intervals. Evaluate whether it is easy to wipe off. In order to know and correctly evaluate the flow characteristics, usability, and use effect of such a cosmetic material, it is considered that Rheology's method is necessary (for example, refer nonpatent literature 1).

A liquid whose flow complies with Newton's law is called Newtonian fluid, and so its flow behavior is called Newtonian flow, while a liquid that does not obey Newton's law is called non-Newtonian fluid, and so the flow behavior is called non-Newtonian flow. It is called. Most emulsions, suspensions, polymer solutions, and semisolid materials are non-Newtonian fluids. Flow types that are not proportional to the shear stress applied are called plastic flows, and flow types that are difficult to flow without being proportional to the applied shear stress are called dilatancy (for example, See Non-Patent Document 2).

In recent years, as a material applied to cosmetic ingredients, such as a moisturizing agent and a massage agent, etc., a composition having a dilatancy property, which is one of the above-mentioned fluid forms, has been developed, and the composition comprises the following components (A) and (B) And (C), ie, (A) a polyethylene oxide having a weight average molecular weight of 100,000 or more, (B) a water swellable clay mineral, and (C) water. ), Or a composition having the same properties, comprising the following components (A) and (B), namely: (A) O / W containing an average particle diameter of oil droplets of 0.2 µm or less and containing ceramides or fatty acids Type emulsions and (B) a dilatancy composition containing the water-soluble polymer of 300,000 or more (for example, refer patent document 2) are known.

On the other hand, various improvements have been attempted in the rheology of makeup cosmetic materials. For example, an oil-based solid cosmetic material contains a lot of oil, so that it is greasy and sticky, and spreads and spreads poorly, and an oily feel is strong. Thus, a cosmetic material using silicone oil is used. Due to the excellent properties of silicone oils, various silicone oils have been employed, and are widely used as oil components, particularly useful for cosmetic materials. This is because silicone oil is less sticky, smooth, spreads well, has a fresh feel, is rich in lubricity and water repellency, and has favorable characteristics and conditions of tasteless and odorless. As such silicone oil, cyclic octamethylcyclo tetrasiloxane, and methylphenyl polysiloxane, including dimethyl polysiloxane of chain form from which molecular weight and a viscosity differ, are mentioned.

R ₂ SiO unit, which is not dissolved in benzene but may contain more than the same weight of benzene as self-improved silicone oil, in order to obtain a cosmetic material having a smooth and fresh feel, usability, and stability over time. and RSiO _{1 .5} ratio is 1 to 30 units of: silicone polymer having a first three-dimensional cross-linked structure and a low viscosity of less than 50cs also made silicone oil, the weight ratio of the silicone polymer and a low viscosity silicone oil is also a 5 A silicone oil composition having a 95:30:70 silicone oil composition (see Patent Document 3, for example), and an oily substance having a matte texture with no matting of the makeup film and deterioration of melt filling properties. 0.5-10 weight% of (A) partially crosslinked organopolysiloxane polymer which consists of following components (A)-(D) suitable for solid cosmetic material of (B), and 5-50 weight% of low viscosity silicone oil , (C) in spherical powder 10 to 50 %, (For example, see Patent Document 4) (D) a solid oil and / or semi-solid oil of 1 to oily solid cosmetic material that contains 50% by weight is known.

In addition, the powdery cosmetic material has good adhesion and smooth spreading properties, and is composed of the following components (a) to (e), that is, component (a) partially crosslinked to improve the uniformity and aging stability of the makeup film. Powdered cosmetic material (for example, refer patent document 5) containing kanopolysiloxane, liquid silicone oil of component (b), liquid oil other than component (c) component (b), and powder of component (e), and at least A composition containing one particulate phase and at least one fatty phase, wherein the composition further comprises at least one gelling agent of a silicone elastomer type having interfacial properties, wherein the particulate form is 50 to about the total amount of the composition in the composition. Powder cosmetics (for example, refer to Patent Document 6) present in a content of 98% by weight are known.

Moreover, the composition which consists of a crosslinking organopolysiloxane polymer and oils other than silicone oil, and the cosmetic material containing the said composition (for example, refer patent document 7) are known.

Patent Document 1: Japanese Patent Application Laid-Open No. 10-182403

Patent Document 2: Japanese Patent Application Laid-Open No. 2002-317124

Patent Document 3: Japanese Patent Application Laid-Open No. 8-6035

Patent Document 4: Japanese Patent Application Laid-Open No. 2000-281532

Patent Document 5: Japanese Patent Application Laid-Open No. 2001-278730

Patent Document 6: Japanese Patent Application Laid-Open No. 2003-55150

Patent Document 7: Republished Patent Publication WO2003 / 024413

[Non-Patent Document 1] Japanese Cosmetic Engineers' Guide, Cosmetic Dictionary, published on September 25, 2004, Second Edition, Maruzen Corporation, p.215-216

[Non-Patent Document 2] Japanese Cosmetic Engineers' Association, Cosmetic Dictionary, published on September 25, 2004, Second Printing, Maruzen Corporation. P217

Conventional makeup cosmetic materials, such as oil-based powders and powder solid eyeshadows, are filled in a dish-shaped container, attached to a compact container to provide portability, and a plurality of It was convenient to mount colors in one compact container. However, there was a lack of fresh touch, softness and elasticity. On the other hand, the aqueous gel state has a neat touch and a soft feeling, but since it is difficult to fill a dish-shaped container, it is inconvenient that a plurality of colors cannot be mounted in one compact container. The problem of the present invention is that it is non-sticky and has a refreshing feel, an elastic touch, a soft feeling, and impact resistance, and is filled in a metal or resin dish container, and the dish container is mounted in a compact container. The present invention provides a makeup cosmetic material having simplicity and convenience in which a plurality of colors can be collected and used in one compact container.

MEANS TO SOLVE THE PROBLEM The present inventors paid attention to the characteristic of the various organosiloxane polymers conventionally used as makeup cosmetic materials, such as eye shadow, and earnestly examined the combination of many organosiloxane polymers which differ in physical property, and, as a result, identified two types of specific A composition containing one or two or more liquid oils selected from the group consisting of organosiloxane polymers, hydrocarbon oils and / or ester oils, silicone oils, and powders is used as a solvent (e.g., a low-polymerization straight chain Silicone oil, such as dimethicone, which is a dimethylpolysiloxane, is added to form a slurry, and the result of compression molding while absorbing the solvent is non-sticky, and has a good feeling of use, soft touch, elasticity and impact resistance, and also a container filling. It has been found to be a possible makeup material, and also has simplicity and convenience in use Confirmed and completed the present invention.

That is, this invention is a component (A) which consists of (1) the partial crosslinking organopolysiloxane polymer containing a long-chain alkyl group, the component (B) which consists of partial crosslinking organopolysiloxane polymers other than a component (A), Component (C) consisting of silicone oil, component (D) consisting of one or two or more liquid oils selected from the group consisting of hydrocarbon oil and / or ester oil, and component (E) comprising powder The makeup cosmetic material according to the above (1), wherein the makeup makeup material, (2) makeup makeup material is oily, and (3) component (A) is a (vinyl dimethicone / lauryl dimethicone) crosspolymer The makeup cosmetic material according to the above (1) or (2), and (4) the component (B) are (dimethicone / vinyldimethicone) crosspolymers; 3) any one The makeup cosmetic material according to any one of (1) to (4), and the makeup cosmetic material according to any one of the above (1) to (4), wherein the component (C) is dimethicone. It contains -70 mass%, 0.5-10 mass% of makeup cosmetic materials in any one of said (1)-(5), and (7) component (D) characterized by the above-mentioned (1) The makeup cosmetic material as described in any one of ())-(6), and (8) component (E) contain the plate-shaped powder body which has brightness, The said (1)-(7) characterized by the above-mentioned. (9) The component (E) contains a spherical powder, the makeup cosmetic material according to any one of the above (1) to (8), and ( 10) It is filled in a dish-shaped container by compression molding, and at least one of the dish-shaped containers is mounted on a compact container. The makeup cosmetic material according to any one of the above (1) to (9), and (11) the penetration penetration weight of the makeup cosmetic material that is compression molded is 20 to 120 gf. Elasticity (L2 / L1) in TPA (Texture profile analysis) measurement by the texture analyzer of the makeup cosmetic material in any one of 1)-(10), and the makeup cosmetic material (12) compression-molded is 0.48- It is 0.99, The makeup cosmetic material in any one of said (1)-(11), and (13) It is an eye shadow, The makeup cosmetic material in any one of said (1)-(12) characterized by the above-mentioned. It is about.

 Moreover, this invention is a component (A) which consists of a partial crosslinking organopolysiloxane polymer containing (14) long-chain alkyl group, the component (B) which consists of partial crosslinking organopolysiloxane polymers other than a component (A), The composition containing the component (C) which consists of silicone oil, the component (D) which consists of 1 type, or 2 or more types of liquid oils chosen from the group which consists of hydrocarbon oil and / or ester oil, and the component (E) which consists of a powder body is silicone oil The present invention relates to a method for producing a make-up cosmetic material, characterized in that it is dispersed in a solvent such as a solvent, filled into a dish-like container, and compressed by sucking the solvent.

BRIEF DESCRIPTION OF THE DRAWINGS The figure which shows the result of having measured the dynamic viscoelasticity of this invention (Example 1), The horizontal axis | shaft shows the deformation (%), The vertical axis | shaft G 'shows the storage modulus (elastic term), G " Is the loss modulus (viscosity term).

Fig. 2 is a diagram showing TPA measurement results by the texture analyzer of the present invention (Example 1).

Examples of the makeup cosmetic material of the present invention include a component (A) made of a partially crosslinked organopolysiloxane polymer containing a long chain alkyl group and a partially crosslinked organopolysiloxane polymer other than the component (A), that is, containing no long chain alkyl groups. Component (B) consisting of, Component (C) consisting of silicone oil, Component (D) consisting of one or two or more liquid oils selected from the group consisting of hydrocarbon oil and / or ester oil, and Component (E) consisting of powder Although it will not restrict | limit especially if it contains, The composition containing each said component is more preferable to be oily. Moreover, as for the composition containing each said component, solvent, such as silicone oil, is added, It is preferable to carry out compression molding, absorbing this solvent, and it is more preferable to carry out compression molding and to fill in the dish container. Such a dish-shaped container can be attached to a compact container, and a plurality of dishes can be collected in one compact container and set as a set. Here, the dish-shaped container means a dish-shaped container made of a thin metal or synthetic resin that is thin enough to be accommodated in a compact container. In the present invention, the oily cosmetic material is a powder body dispersed in an oily base, and is different from a powdered solid cosmetic material, an aqueous gel cosmetic material, or an emulsified cosmetic material. Examples of the makeup cosmetic material include eye shadow, foundation, concealer, basic cosmetics, ball touch, lipstick, mascara, eye liner, eyebrow, and the like.

The partially crosslinked organopolysiloxane polymer containing the long-chain alkyl group as the component (A) is not particularly limited as long as it is a compound having a long-chain alkyl group in the silicone-based elastomer that exhibits a three-dimensional structure having a partial crosslinking. 8-30 linear alkyl groups can be illustrated suitably. Such a component (A) is, for example, SiO ₂ units, HSiO _{1 .5} units, RSiO _{1 .5} units, RHSiO units, R ₂ SiO units, R ₃ SiO _0.5 units and R ₂ HSiO _{0 .5} units ( Wherein R is an at least one structural unit selected from the group consisting of substituted or unsubstituted monovalent hydrocarbon groups having 1 to 30 carbon atoms except for aliphatic unsaturated groups, and an average of hydrogen atoms bonded to silicon atoms more than 1.5 organohydrogenpolysiloxane containing in a molecule and, SiO _{2 units, (CH 2 = CH) SiO} 1.5 units, RSiO _{1 .5 units, R (CH 2 = CH)} SiO units, R ₂ SiO unit, R ₃ SiO _{0 .5} unit and a _{R 2 (CH 2 = CH)} SiO 0.5 units, a structural unit selected from the group consisting of (where R 1 is a substituted or unsubstituted 1 to 30 carbon atoms other than an aliphatic unsaturated hydrocarbon group) At the same time, organopolysil containing on average 1.5 or more vinyl groups bound to silicon atoms in the molecule It can be obtained by addition polymerization with Roxane.

Examples of the partially crosslinked organopolysiloxane polymer containing such a long chain alkyl group include (vinyldimethicone / lauryldimethicone) crosspolymers as INCI (International Nomenclature Cosmetic Ingredient labeling names) names. As a commercial item, the silicone gel which mix | blended hydrocarbon oil or ester oil with the partially crosslinked organopolysiloxane polymer containing a long-chain alkyl group is mentioned. For example, KSG-41 contains 65-75 mass% of mineral oils (it abbreviates as "%" hereafter.), KSG-42 contains 70-80% of isododecane, and KSG-43 Silver contains 65-75% of trioctanoin (glyceryl tri-2-ethylhexanoate), and KSG-44 contains 65-75% of squalene (all manufactured by Shin-Etsu Chemical Co., Ltd.) Etc. can be mentioned specifically.

According to the purpose, the component (A) of the present invention may be used alone or in combination of two or more thereof, and the content thereof is not particularly limited, but is preferably 0.001 to 15%, particularly preferably 0.1 to 10% in the cosmetic material. . By mix | blending component (A), the compatibility of the whole oil system can be improved and an oil system and a powder system can be mixed uniformly. Moreover, it becomes possible to mix | blend the oil agent with high adhesiveness with skin to the silicone oil with poor adhesiveness with skin.

The partially crosslinked organopolysiloxane polymer other than the component (A), which is the component (B), is not particularly limited as long as it is a silicone-based elastomer that exhibits a three-dimensional structure partially having crosslinking, and is a polymer obtained by crosslinking the organopolysiloxane. and, having a three-dimensional crosslinking structure in a part, R ₂ consists of SiO units and RSiO _{1 .5} units, R ₃ SiO _0.5 units and / or SiO ₂ units may also include a good compound (where, in the structural units R May include an alkyl group such as a hydrogen atom, a methyl group, an ethyl group, a propyl group, an aryl group such as a phenyl group, a tolyl group, and an aliphatic unsaturated group such as a vinyl group, a fluoro group or an ethylene oxide group, and the like. Other types may be used.), Specifically, the polymers described in Japanese Patent Application Laid-Open No. 8-6035, Japanese Patent Laid-Open No. 2001-342255, and the like. The can.

Such a component (B) includes (dimethicone / vinyl dimethicone) crosspolymer as an INCI (International Nomenclature Cosmetic Ingredient labeling names) name, for example. The component (B) may be a polymerized product alone, but in general, it is often used in combination with a low viscosity silicone oil. As such a mixture, for example, KSG-15 (5 parts of partially crosslinked methyl polysiloxane and 95 parts of decamethylcyclopentasiloxane), KSG-16 (20 to 30 parts of partially crosslinked methyl polysiloxane and 70 to 80 parts of methyl polysiloxane). ), KSG-17 (5 parts of partially crosslinked methyl polysiloxane and 95 parts of octamethylcyclotetrasiloxane), KSG-18 (10 to 20 parts of partially crosslinked methyl polysiloxane and 80 to 90 parts of methylphenylpolysiloxane) [both Shin-Etsukagakuko Teacher products].

According to the purpose, component (B) can use 1 type (s) or 2 or more types, The content is not specifically limited, Although 1-20% is preferable in cosmetic materials, 5-15% is especially preferable. By blending the component (B), the cosmetic material can be made elastic, and a structure capable of compression molding to a dish-shaped container can be maintained.

The silicone oil as the component (C) may be linear or cyclic, but for example, a viscosity having a viscosity of 50 cs or less and 30 cs or less, in particular, has a non-sticky, fresh feeling (feel). Moreover, it is preferable at the point which has an effect as an excellent solvent in making the composition before compression molding into a slurry state in the manufacturing process of a makeup cosmetic material. As low-viscosity silicone oil, low-polymerization linear dimethylpolysiloxane (dimethicone), methylphenyl polysiloxane, dimethylsiloxane methylphenylsiloxane copolymer, cyclic octamethylcyclo tetrasiloxane, and decamethyl cyclopentasiloxane are mentioned, for example. Although the number of dimethicones (silicone KF-96 (6CS), silicon KF-96 (10CS), and silicon KF-96 (20CS): Shin-Etsukagaku Co., Ltd.) can be exemplified by the INCI name, Therefore, the 1 type, or 2 or more types can be used. Moreover, as a compounding form of silicone oil, it is mix | blended with the partially crosslinked organopolysiloxane polymer other than the component (A) which is a component (B), and the form used as gel silicone, such as KSG-16, and the form used independently. Although these are mentioned, It is preferable to use these forms together. Moreover, as silicone oil as a solvent, low-polymerization linear dimethyl polysiloxane of low viscosity which is a low viscosity silicone oil can be illustrated preferably, Specifically, silicone KF-96 (6CS), silicone KF-96 (10CS), silicone KF Preferred is -96 (20CS).

The content of component (C) silicone oil is preferably 30 to 70%, preferably 40 to 60%, in the cosmetic material. When 30% or more of the compound is blended, it has a feeling of freshness in use, and when it is blended at 70% or less, the makeup lasts particularly well, and the impact resistance of the molded product may be lowered even when compression molded into a dish-shaped container. Lowers. In addition, although silicone oil as a solvent, such as dimethicone, into the composition before compression molding in the manufacturing process of a make-up cosmetic material is absorbed at the time of compression molding, some of the added component (C) silicone oil may also be absorbed.

The liquid oil selected from the group consisting of hydrocarbon oil and / or ester oil as the component (D) is preferably liquid at 25 ° C regardless of the origin of animal oil, vegetable oil, synthetic oil and the like. Examples thereof include liquid paraffin, heavy flow isoparaffin, squalene, polybutene, polyisobutylene, and the like, and tri-ethylhexanoic acid glyceryl and paramethoxy are mentioned as ester oils. 2-ethylhexyl cinnamic acid, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octylate acid octylate acid, glyceryl trioctanoate, polyglyceryl diisostearic acid, diglyceryl isostearic acid, diisostearate Aryl, neopentyl glycol dioctanoate, jojoba oil, etc. are mentioned, These can use 1 type (s) or 2 or more types.

By mix | blending a component (D), the affinity and adhesiveness with respect to the skin in use are provided. Although content of a component (D) is not specifically limited, It is preferable to mix | blend 0.5-10%, especially 1-8% in a cosmetics material from the point which improves the adsorption of solvent, such as silicone oil at the time of filling. Moreover, as a compounding form of the component (D), like the KSG-43, the form used by mixing with the partially crosslinked organopolysiloxane polymer containing a long-chain alkyl group of the component (A), and the form used alone, for example. Can be mentioned.

Although it will not specifically limit, if it is the powder used for a normal cosmetics material as a powder which is a component (E), It is preferable to contain 30 to 70% among cosmetics materials. Moreover, it is preferable that the powder of component (E) contains a plate-like powder, and it is preferable to contain the plate-like powder which has brightness, such as pearl gloss. Moreover, it is more preferable to contain a spherical powder. The plate-like powder can be blended in a cosmetic material in 10 to 50%, preferably 20 to 40%, more preferably about 30%. In addition, it is preferable to mix | blend a plate-shaped powder body with a brightness | luminance in the ratio of 30 to 98% among powders, and if it exists in this range, it will be less scuffiness and the texture when it is apply | coated to skin becomes more comfortable. . In addition, the spherical powder can be blended 1 to 10%, preferably 1 to 5%, in the cosmetic material. In the powder, 0.01% to 30% is preferable, and more preferably 0.5% to 10%. to be. Since the spherical powder has a powdery feeling and the spread becomes good, it can be more sticky and has a fresh feeling. In addition, by uniformizing the system, it is difficult to extract the cosmetic material with an application tool such as a finger, a chip, a sponge, or a brush. By using together with a sieve, since picking up cosmetics materials can be adjusted with a finger, it is preferable. By suitably blending the spherical powder and the powder that improves the unwinding within the range of 0.001: 99.99 to 90:10, adjustment for collecting the cosmetic material with a finger is facilitated. 0.1-80 micrometers is preferable and, as for the average particle diameter (laser diffraction method) of a spherical powder, 0.5-50 micrometers is more preferable.

As the material of the component (E), methane oxide, black titanium oxide, blue wire, ultramarine blue, bengala, iron sulfate, black iron oxide, zinc oxide, aluminum oxide, silicic anhydride, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, Inorganic powders such as chromium oxide, chromium hydroxide, carbon black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, sericite, talc, kaolin, silicon carbide, barium sulfate, silicon nitride, nylon, polymethylmeth Acrylates, alkyl polyacrylates, organopolysiloxane elastomers, polymethyl sesquioxanes, cross-linked silicone-mesh silicone block copolymers, polystyrenes, acrylonitrile-methacrylic acid copolymers, vinylidene chloride-methacrylic acid copolymers And organic powders such as polyethylene, urethane, wool, silk, crystalline cellulose and N-acyldine, and lake pigments such as organic tar pigments and organic pigments. Composite powders such as pigment powders, fine particle titanium oxide coated mica titanium, fine particle zinc oxide coated mica titanium, barium sulfate coated mica titanium, titanium oxide containing silicic anhydride and zinc oxide containing silicic anhydride, and these powders include fluorine compounds, Surface coating powders which have been surface-treated using one or two or more kinds of silicone compounds, metal soaps, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, lead, surfactants, etc. These powders can use these 1 type, or 2 or more types.

For example, as a plate-like powder having brightness, titanium oxide coated glass powder, titanium oxide treated synthetic mica, mica titanium, titanium oxide coated oxybismuth, iron oxide mica titanium, wire coated mica titanium, carmine coated mica titanium, Bismuth oxychloride, scale foil, iron oxide coated mica, organic pigment coated mica titanium, aluminum powder, polyethylene terephthalate, aluminum epoxy powder, polyethylene terephthalate polymethyl methacrylate laminated film powder, silicic acid anhydride Processed aluminum powder etc. are mentioned. Moreover, as spherical powder body, methyl polymethacrylate, nylon, polystyrene, a silica (silic anhydride), silicone resin, etc. are mentioned. The loose powder having the opposite action as the spherical powder is not spherical or plate-shaped, and examples thereof include a rugby ball shape, a potato shape, and a star candy-shaped release material. Silver nylon, polymethyl methacrylate, and methyl methacrylate crosspolymer.

The makeup cosmetic material of the present invention is, in addition to the above essential components, a component that is usually blended in a cosmetic material, such as an oily component, a surfactant, water, a polyhydric alcohol, a lower alcohol, a water-soluble polymer, and a moisturizing agent. , Sugars, ultraviolet absorbers, antioxidants, preservatives, enzymes such as lipases and proteases, various drugs such as resorcin and sulfur, refreshing agents, pigments, flavorings and the like can be blended in a range that does not interfere with the effects of the present invention.

As the oily component, hydrocarbons, fats and oils, regardless of the properties of solid oils, semi-solid oils, liquid oils, volatile oils and the like originating from animal oils, vegetable oils, synthetic oils, etc., which are generally used for cosmetic materials, in addition to essential components (Iii), cured oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine oils, lanolin derivatives, oily gelling agents and the like. Specifically, non-liquid hydrocarbons such as petrolatum, polyethylene wax, ethylene / propylene copolymer, paraffin wax, montan wax, Fischer-Tropsch wax, ceresin wax, ozokerite wax, wax, olive oil Fats and oils such as castor oil, mink oil, macadamian nut oil, beeswax, spermatozoon, carnauba wax, candelilla wax, lead rosin, pentaerythrite ester, cholesterol fatty acid ester, phytosterol fatty acid ester, etc. Non-liquid esters, stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, fatty acids such as oleic acid, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, Higher alcohols such as behenyl alcohol, trimethylsiloxy silicic acid, high degree of polymerization methylphenylpolysiloxane, polyoxyalkylene-modified organopolysiloxane, and crosslinked poly Le modified methyl polysiloxane, methacryl modified polysiloxane, stearyl modified methyl polysiloxane, oleyl modified methyl polysiloxane, behenyl modified methyl polysiloxane, polyvinylpyrrolidone modified methyl polysiloxane, high polymerization degree dimethyl polysiloxane, polyoxyalkylene alkyl Non-liquid silicones such as methyl polysiloxane, methyl polysiloxane copolymer, alkoxy-modified polysiloxane, and fluorine-modified polysiloxane, fluorine-based emulsions such as perfluorodecane, perfluorooctane, perfluoropolyether, lanolin, lanolin acetate, lanolin fatty acid Lanolin derivatives such as isopropyl and lanolin alcohol, sucrose fatty acid esters, oily gelling agents such as aluminum isostearic acid, calcium stearate, 12-hydroxystearic acid, and the like, and these may be used alone or in combination of two or more.

As said surfactant, any surfactant generally used for a cosmetics material can be used, and a nonionic surfactant, anionic surfactant, cationic surfactant, an amphoteric surfactant, etc. are mentioned. For example, glycerin fatty acid esters and alkylene glycol adducts thereof, polyglycerol fatty acid esters and alkylene glycol adducts thereof, sorbitan fatty acid esters and alkylene glycol adducts thereof, sucrose fatty acid esters, polyoxyethylene hydrogenated castor oil, Polyoxyalkylene alkyl co-modified organopolysiloxane, polyether-modified organopolysiloxane, lecithin, and the like, and the like, and these may be used alone or in combination of two or more thereof.

Examples of the water-soluble polymer include natural substances such as guar gum, sodium condoitin sulfate, sodium hyaluronate, gum arabic, sodium arginate and carrageenan, and semisynthetic systems such as methyl cellulose, hydroxyethyl cellulose, and carboxymethyl cellulose. And synthetic compounds such as carboxyvinyl polymer, alkyl addition carboxyvinyl polymer, polyvinyl alcohol, polyvinylpyrrolidone and sodium polyacrylate. Protein, mucopolysaccharide, collagen, elastin, keratin, etc. can be mentioned, These can be used 1 type or 2 types or more.

Examples of the antioxidants include α-tocopherol, ascorbic acid, and the like, and beauty ingredients include, for example, vitamins, anti-inflammatory agents, herbal medicines, and the like. Oxybenzoic acid ester, phenoxyethanol, etc. can be mentioned, These can be used 1 type or 2 types or more.

Examples of the ultraviolet absorbents include benzophenone series, PABA series, cinnamic acid series, sarytylic acid series, 4-tert-butyl-4'-methoxydibenzoylmethane, oxybenzone, and the like. Two or more kinds can be used.

As the make-up cosmetic material of the present invention, the penetration weight after compression molding is preferably 20 to 120 gf (gram force), more preferably 20 to 70 gf, and it is in such a numerical range that there is no stickiness in use. It is possible to obtain a fresh touch and excellent impact resistance. For example, if it is less than 20 gf, it is a non-sticky and neat touch, but impact resistance may fall, and if it exceeds 120 gf, impact resistance may be excellent, but a powdery feeling is strong, and the elasticity at the time of use may fall. In addition, with the penetration-in weight in this invention, what made the sample which filled the makeup cosmetic material into the metal mold | die of thickness 4mm as a sample, uses "RHEO TECH FUDOH RHEO METER" made from Leotech Co., Ltd. as a measuring instrument, As hardness measurement conditions, it uses the adapter 3 mm (phi), and sets the entrance distance 1.5 mm and the climbing speed 2 cm / min., And measures the value.

In addition, as the makeup cosmetic material of the present invention, the elasticity (L2 / L1) in the texture profile analysis (TPA) measurement by the texture analyzer is preferably 0.48 to 0.99, more preferably 0.50 to 0.99, and By setting it as the same numerical range, it can be set as the cosmetic material rich in elasticity. In addition, the elasticity (L2 / L1) in the TPA measurement by the texture analyzer in this invention is a sample filled with the makeup cosmetic material in the metal mold | die of thickness 4mm, and is manufactured by Eiko Seiki Co., Ltd. Texture analyzer ”is used as a measuring instrument, and 2% Φ cylinder probe and probe speed is set to 0.5mm / sec as a measurement condition of TPA, and 25% of deformation is given so as not to completely destroy the sample (in the non-destructive region). The pressure is applied twice to the sample by the probe, the time difference between the first and second is maintained at 3 sec, and the height change due to the first deformation is changed by L1 and the second deformation. Is L2, and it is the value calculated by L2 / L1, and it means the rate of return when the deformation by external force is removed (Taneya Shinichi, Hiroshi Hayashi, Akiko Kawabata) Food Property Terms Dictionary ”(Yokendo).

As a manufacturing method of the makeup cosmetic material of this invention, the composition containing said component (A), component (B), component (C), component (D), and component (E) is disperse | distributed to a solvent, Although it does not specifically limit if it is the manufacturing method of extrusion molding, after filling a container and sucking a solvent, The addition amount of a solvent becomes like this. Preferably it is 30-100 weight part with respect to 100 weight part of cosmetic materials, More preferably, 40 By using ˜90 parts by weight, and in particular, 45 to 60 parts by weight, the viscosity is lowered, making it easier to fill, and is preferable in that a uniform cosmetic material is obtained. As a solvent, the composition containing components (A)-(E) can be disperse | distributed, As long as it can fill a container and a solvent can be absorbed, any of silicone oil, hydrocarbon oil, ester oil, etc. can be used, Silicone oil is preferable, and low-polymerization linear dimethylpolysiloxane (dimethicone) is preferable. More specifically, the component (E) powder is uniformly dispersed with a Henshel Mixer (manufactured by Mitsui-Mike Co., Ltd.), and separately, a partially crosslinked organopolysiloxane polymer containing a component (A) long-chain alkyl group, Partially crosslinked organopolysiloxane polymers other than component (B) and component (A) are predispersed with a disper and then selected from component (C) silicone oil, component (D) hydrocarbon oil and ester oil in this dispersion. The above-mentioned components (E) were added and mixed uniformly, and the above-mentioned components (E) which were uniformly dispersed were stirred with a Henschel mixer (manufactured by Mitsui-Mike Co., Ltd.). Silicone oil as a solvent such as chicon is added and uniformly mixed to obtain a slurry state. The composition made into a slurry state can be filled into a metal dish container, and it can be compression-molded to a metal dish container while sucking the added solvent, and a makeup cosmetics material can be obtained. Moreover, the said filled metal dish type container can be attached to a compact container and can be used.

Hereinafter, the present invention will be described in more detail with reference to Examples, but the technical scope of the present invention is not limited to these examples.

[Synthesis of partially crosslinked organopolysiloxane polymer containing long chain alkyl group]

After adding 0.1 g of 2% platinum chloride ethanol solution to 160.8 g of methylhydrogen polysiloxane represented by the following formula (1) and 499.8 g of methyl vinyl polysiloxane represented by the following formula (2), the internal temperature was 70-80 ° C. The mixture was polymerized for 2 hours to obtain a silicone polymer (I) which is a crosslinked organopolysiloxane polymer containing a long chain alkyl group.

[Synthesis of partially crosslinked organopolysiloxane polymer]

To an appropriate amount of 1% potassium hydroxide solution (ethanol: water = 2: 1) is added to trimethylsilyl terminal blockade dimethylmethylhydrogen polysiloxane (molecular weight 2300, CH ₃ HSiO: (CH ₃ ) ₂ SiO = 1: 4 (molar ratio)) The mixture was heated and refluxed to carry out a polymerization reaction to obtain a reaction product. Subsequently, the reaction product was washed with water to remove the alkali agent, followed by air drying to obtain a silicone polymer (II) which is a partially crosslinked organopolysiloxane polymer.

[Examples 1-10 and Comparative Examples 1-3]

Eye shadow of the composition shown in Table 1 is prepared, "fingerprintability", "elasticity at the time of use", "sticky and refreshing feeling", "adhesiveness to skin", "water-resistance, sebum resistance, etc." About "shock resistance", it determines by the evaluation method and judgment criteria shown below, and summarizes the result and is shown in Table 1.

ND: Unobservable (The content came out of the metal dish and the surface "tangle" was not able to be observed.

* 1: Goto Ball (a type of micron capsule) D11-796C (Spherical powder with a particle diameter of 2 to 5 µm: manufactured by Suzuki Yushiko)

* 2: Lysyl Powder S (Powder having a particle diameter of 10 to 14 µm: manufactured by Atopina Japan)

* 3: silicone polymer (I) according to the above synthesis example

* 4: silicone polymer (II) according to the above synthesis example

* 5: KF-96 (20CS) (manufactured by Shin-Etsu Chemical Co., Ltd.)

* 6: Hi-Col K-500 (Kaneda Co., Ltd.)

* 7: TIO (N) (made by Nissei Irio Group)

(Manufacturing method)

A. The components 1-7 are uniformly dispersed with a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.).

B. After component 8 and component 9 are pre-dispersed, components 10-12 are added and uniformly mixed.

C. While stirring A with a Henschel mixer, B is added and uniformly dispersed.

D. To 100 parts of C, 50 parts of dimethicone (KF-96 (10CS) (manufactured by Shin-Etsu Chemical Co., Ltd.)) is added as a solvent and mixed uniformly.

E. D was filled into a metal dish, and the mixture was compression molded while absorbing the solvent with paper to obtain an eye shadow.

(Evaluation method 1): "fingerprintability", "elasticity in use", "sticky and fresh feeling", "adhesion to skin", "water-resistance, sebum resistance, etc."

20 panel specialists for evaluating cosmetic materials were used to use the eyeshadows of the above examples and comparative examples, such as "finger extractability", "elasticity in use", "sticky and fresh feeling", "adhesion to skin", "water resistance" , Cosmetic persistence, such as sebum resistance, "was evaluated in seven levels according to the following evaluation criteria, and each sample was rated, and the average score of all panels was determined according to the following criteria.

Evaluation standard

  (Evaluation) (contents)

     6: very good

     5: good

     4: slightly good

     3: normal

     2: a little bad

     1: bad

     0: very bad

Criteria

  (Average score of the rating) (judgment)

     5.0 or more: ◎ (very good)

     3.5 or more and less than 5.0: ○ (good)

     2.0 or more and less than 3.5: △ (normal)

     Less than 2.0: × (bad)

  (Evaluation method 2): "shock resistance"

The eyeshadows of the examples and comparative examples were freely dropped from the height of 50 cm onto the acrylic plate in a state filled with a metal dish, and the surface state after the drop was observed, and the following three steps were applied to each eyeshadow. It judged by evaluation criteria.

Evaluation criteria

  (Evaluation) (judgment)

  Almost no change: ○

  In the tangle of the surface: △

  In the large tangle of the surface: ×

(Measurement of infiltration weight)

For the measurement of the penetration weight, a sample filled with a make-up cosmetic material in a mold having a thickness of 4 mm is used as a sample, and the measuring device uses "RHEO TECH FUDOH RHEO METER" manufactured by Leo Tech Co., Ltd. as a measuring device. As hardness measurement conditions, it measured by setting the entry distance 1.5 mm and the ascent speed 2cm / min. Using adapter 3mm (phi).

As is apparent from Table 1, the eyeshadows of Examples 1 to 9, which are the present invention, are "finger collection", "elasticity in use", "sticky and fresh feeling", "adhesion to skin", "water resistance" It was an excellent eyeshadow in all items such as "permanent makeup such as sebum resistance" and "impact resistance". In particular, the feeling of "elasticity at the time of use", "a feeling of non-stickiness and a refreshing feeling", as described above of FIG. 1, feel a lot of elasticity at first, but when it is applied, the elasticity is smooth and spreads smoothly so that it changes to a powdery feeling. It is thought to correspond to a texture to become a texture. In contrast, Comparative Example 1 in which the silicone polymer (I) of the component (A) is not blended shows that "adhesion to skin" and "cosmetic persistence such as water resistance and sebum resistance" are inferior. The comparative example 2 which does not mix | blend silicone polymer (II) falls under each item of "a feeling of elasticity at the time of use", "cosmetic persistence, such as water resistance and sebum resistance", and "shock resistance", and mix | blended component (D) further In Comparative Example 3, which was not performed, "adhesion to skin" was inferior.

(Measurement of Dynamic Viscoelasticity)

The makeup cosmetic material of the present invention is characterized by having a unique texture with elasticity in the system, unlike conventional oily eyeshadows or powdered solid eyeshadows. Therefore, the dynamic viscoelasticity of the eyeshadow described in the said Example 1 was measured using the flood spectrometer (RES-II by the product Lleotrix). As the measurement geometry, parael plates or cuettes of 25 to 50 mm were used, and the measurement mode mainly used a dynamic frequency sweep. In this case, the deformation is 100% when the plate is moved with the displacement amplitude equivalent to the distance between the pararell plates, the frequency is fixed at 1 Hz, and the displacement amplitude is changed from 10 ⁻⁸ to 10 ³ . The measurement was carried out under these conditions, and the storage modulus (G ') and the loss modulus (G'') were determined. Thus, when applied to the makeup material (eye shadow of Example 1) of the present invention, as shown in Fig. 1, the curves of G '(storage modulus: elastic term) and G''(loss modulus: viscosity term) are shown. It was. G 'on the vertical axis represents the storage modulus (elastic term), G''represents the loss modulus (viscosity term), and the horizontal axis (%) represents deformation. From Fig. 1, when the shear is applied, the elastic terms are remarkably lowered, but since the viscous terms do not rise and slowly decrease as compared with the elastic terms, the elastic terms are initially reduced. It spreads quickly and thinks that it becomes texture changing by powdery texture.

(Measurement of TPA)

TPA by Texture Analyzer, manufactured by Eiko Seiki Co., Ltd. for the present invention (Examples 1, 6, 10), the comparative product (Comparative Example 2), and the conventional powder eye shadow and cream eye shadow (oily eye shadow) texture profile analysis was performed. The measurement conditions were adjusted so that the 2 mm diameter cylinder probe and the probe speed were 0.5 mm / sec, and 25% of deformation was performed so as not to completely destroy the sample (in the non-destructive region). In the TPA measurement, a constant probe is applied twice to the sample, the time difference between the first and second is maintained for 3 sec, and the change in height due to the first deformation is determined by the L1 and the second deformation. Change is L2, and L2 / L1 is an index of springness. For example, in the case of a spring, since L1 = L2 since it is a completely elastic body, elasticity L2 / L1 = 1. Table 2 shows the results of the elasticity (L2 / L1). From Table 2, it was confirmed that the present invention had elasticity. In addition, the TPA measurement result by the texture analyzer of this invention (Example 1) is shown in FIG.

L2 / L1 Invention (Example 1) 0.923 Invention (Example 6) 0.487 Invention (Example 10) 0.489 Comparative product (Comparative Example 2) 0.470 Conventional (Powder Eyeshadow) 0.467 Conventional (Cream Eyeshadow) 0.245

In addition, the prescription and manufacturing method of a conventional cosmetics (powder eye shadow) and a conventional cosmetics (cream eye shadow) are shown below.

[Prescription and Manufacturing Method of Powder Eyeshadow]

(ingredient) (%)

1.Silicone treated mica * 8 20.0

2. Siliconized Talc * 8 residues

3. Titanium oxide coated mica 30.0

4. Boron Nitride 5.0

5. County Offices 2.0

6. Yellow 401 0.5

7. Synthetic Hydrocarbon Wax 2.5

8. Crosslinked Silicone / Silicon Block Copolymer * 9 2.0

9. Preservative 0.2

10. Floating Paraffin 2.0

11.Vaseline 1.0

12.Dimethylpolysiloxane 3.0

13. Fragrance 0.01

* 8: 3% dimethylpolysiloxane treatment

* 9: KSP-100 (Spherical powder with a particle diameter of 5 μm: manufactured by Shin-Etsu Chemical Co., Ltd.)

(Manufacturing method)

A. The components 1-9 are uniformly dispersed with a Henschel mixer (manufactured by Mitsui Miike).

B. The components 10-13 are heated and distributed uniformly.

C. While stirring A with a Henschel mixer, B is added and it disperse | distributes uniformly.

D. C is ground with a parberizer.

E. D was filled into a metal dish and compression molded to obtain a powder eyeshadow.

[Prescription and Manufacturing Method of Cream Eyeshadow]

(ingredient) (%)

Paraffin Wax 3.5

2. Distearic acid ethylene glycol 2.0

3. Carnauba Nap 1.5

4. Methylpolysiloxane 15.0

5. Squalene 7.0

6. Glyceryl tri2-ethylhexanoate 20.0

7. Crosslinked Silicone / Silicon Block Copolymer * 9 5.0

8. Silicon Treatment Mica Titanium * 8 35.0

9. Silicon treated synthetic mica * 8 residues

10. Iron Oxide 0.4

11.County 0.1

12. Paraffin Wax 0.5

13. Squalene 2.5

14. Spices 0.01

(Manufacturing method)

A. Dissolve 12 ~ 14 evenly.

B. Add 9-11 to A and disperse | distribute with a roller.

C. Dissolve 1 ~ 6 evenly.

D. Add B to C and heat mix uniformly.

E. 7, 8 is added to D and uniformly heat mixed.

F. E was heated to 80 degreeC, it filled into the metal dish, and cooled, and obtained the cream eyeshadow.

[Example 11; Eye shadow]

(ingredient) (%)

1. Mica balance

2. Titanium oxide coated mica (bright powder) 5.0

3. Silic anhydride * 10 3.0

4.nylon * 11 1.0

5. Mica titanium (bright powder) 20.0

6. Iron Sulfate 0.1

7. Iron Oxide 0.1

8. Bengala 0.1

9. County Office 0.1

10. Siliconized Titanium Oxide 1.0

11.Methyl paraoxybenzoate 0.1

12.Dimethicone * 12 20.0

13. Mixture of partially crosslinked organopolysiloxane polymers containing long-chain alkyl groups * 13 4.0

14. Mixture of partially crosslinked organopolysiloxane polymers * 14 35.0

15. Heavy Flow Isoparaffins * 15 5.0

16. Glyceryl tri2-ethylhexanoate 1.0

17. Appropriate amount of spices

(Outside the prescription)

18.Solvent: Dimethicone * 12 40 parts

* 10: Goto Ball E2-824C (Spherical powder with particle diameter 0.9 ~ 1.4㎛: manufactured by Suzuki Yushiko)

* 11: Lysane powder L (release powder with particle diameter 18 ~ 25㎛: manufactured by Atopina Japan)

* 12: KF-96 (10CS) (manufactured by Shin-Etsu Chemical Co., Ltd.)

* 13: KSG-43 (manufactured by Shin-Etsu Chemical Co., Ltd.)

* 14: KSG-16 (manufactured by Shin-Etsukagaku Co., Ltd.)

* 15: parleam18 (made by Nihon Yushi Corporation)

(Manufacturing method)

A. Disperse ingredients 1 to 11 uniformly with a Henschel mixer (manufactured by Mitsui Miike).

B. Mix components 12 to 17 uniformly.

C. While stirring A with a Henschel mixer, B is added and it disperse | distributes uniformly.

D. Add component 18 to 100 parts of C and mix uniformly.

E. D was filled into a metal dish, and the mixture was compression molded while absorbing the solvent with paper to obtain an eye shadow.

The eye shadow of the present invention has the characteristics of "fingerprintability", "elasticity at the time of use", "sticky and refreshing feeling", "adhesiveness to skin", "water resistance, sebum resistance, etc.", "impact resistance" It was an excellent eyeshadow for all items.

[Example 12; Eye shadow]

(ingredient) (%)

1. Mica balance

2. Talc 7.0

3. Crosslinked Silicone / Silicone Silicone Block Copolymer * 9 3.0

4.nylon * 2 2.0

5. Mica titanium (bright powder) 20.0

6. Siliconized Iron Sulfate 0.1

7. Silicon-treated black iron oxide 0.1

8. Siliconized Titanium Oxide 0.1

9. Paraoxymethyl Benzoate 0.1

10.Methylphenylpolysiloxane * 16 20.0

11. Mixture of partially crosslinked organopolysiloxane polymers containing long-chain alkyl groups * 13 4.0

12. Mixtures of partially crosslinked organopolysiloxane polymers * 14 35.0

13. Polybutene 5.0

14. Glyceryl tri2-ethylhexanoate 1.5

15. Spices

(Outside the prescription)

16. Solvent: Dimethicone * 12 60 parts

* 16: KF-56 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Manufacturing method)

A. The components 1-9 are uniformly dispersed with a Henschel mixer (manufactured by Mitsui Miike).

B. Mix ingredients 10-15 uniformly.

C. While stirring A with a Henschel mixer, B is added and it disperse | distributes uniformly.

D. Add component 16 to 100 parts of C and mix uniformly.

E. D was filled into a metal dish, and the mixture was compression molded while absorbing the solvent with paper to obtain an eye shadow.

The eye shadow of the present invention is "finger (chip) extractability", "elasticity at the time of use", "sticky and refreshing feeling", "adhesion to skin", "water resistance, sebum resistance and other cosmetic persistence", "resistant It was excellent eye shadow in all items of "impact property".

[Example 13; foundation]

(ingredient) (%)

1. Mica balance

2. Talc 5.0

3. Crosslinked Silicone / Silicone Silicone Block Copolymer * 9 3.0

4.polystyrene * 17 2.0

5. Mica titanium (bright powder) 20.0

6. Fluoride Compound Treatment Iron Sulfate 0.1

7. Fluoride Compound Black Iron Oxide 0.1

8. Fluorine Treatment Bengala 0.1

9. Fluoride compound treated fine particle titanium oxide 2.0

10.Dimethicone * 5 25.0

11. Mixture of partially crosslinked organopolysiloxane polymers containing long-chain alkyl groups * 13 5.0

12. Mixtures of partially crosslinked organopolysiloxane polymers * 14 30.0

13. Paramethoxy Cinnamic Acid 2-ethylhexyl 4.0

14. Glyceryl tri2-ethylhexanoate 1.5

15. Spices

(Outside the prescription)

16.Solvent: Dimethicone * 18 45 parts

* 17: Fine Pearl 3000SP-Q (Spherical powder with a particle diameter of 5 to 20 μm: manufactured by Matsuura)

* 18: KF-96 (6CS) (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Manufacturing method)

A. The components 1-9 are uniformly dispersed with a Henschel mixer (manufactured by Mitsui Miike).

B. Mix ingredients 10-15 uniformly.

C. While stirring A with a Henschel mixer, B is added and it disperse | distributes uniformly.

D. Add component 16 to 100 parts of C and mix uniformly.

E. D was filled into a metal dish, compression molded while sucking the solvent with paper to obtain a foundation.

The foundation of the present invention is "fingerprint (sponge)", "elasticity at the time of use", "sticky and refreshing feeling", "adhesion to skin", "water-resistance, such as water resistance, sebum resistance", "impact resistance" It was excellent foundation in all items of 」.

[Example 14; Face color]

(ingredient) (%)

1. Mica balance

2. Talc 5.0

3.nylon * 19 1.0

4. Methyl methacrylate crosspolymer * 20 10.0

5. Mica titanium (bright powder) 10.0

6. Fluorine Compound Red 226 0.1

7. Fluoride Compound Black Iron Oxide 0.1

8. Fluoride Compound Treated Particle Titanium Oxide 2.0

9. Demethicone * 5 30.0

10. Mixture of partially crosslinked organopolysiloxane polymers containing long chain alkyl groups * 13 2.0

11. Mixture of partially crosslinked organopolysiloxane polymers * 14 30.0

12. Floating Paraffin 2.0

13. Polybutene 2.0

14. Glyceryl tri2-ethylhexanoate 1.5

15. Spices

(Outside the prescription)

16.Solvent: Dimethicone * 18 55 parts

* 19: Torre nylon powder SP-500 (spherical powder with a particle diameter of 1 to 23 μm: manufactured by Toray Corporation)

* 20: Gantz Pearl GMI-0804 (release powder having a particle diameter of 4 to 15 µm: manufactured by Gansukasei Co., Ltd.)

(Manufacturing method)

A. The components 1-8 are uniformly dispersed with a Henschel mixer (manufactured by Mitsui Miike).

B. Mix components 9-15 uniformly.

C. While stirring A with a Henschel mixer, B is added and it disperse | distributes uniformly.

D. Add component 16 to 100 parts of C and mix uniformly.

E. D was filled into a metal dish, compression molded while sucking the solvent with paper to obtain a face color.

Face color of the present invention, "fingerprintability", "elasticity in use", "sticky and fresh feeling", "adhesion to skin", "water-resistance, sebum resistance, such as makeup persistence", "impact resistance" It was excellent face color in all items.

[Example 15; Lip gloss]

(ingredient) (%)

1.Titanium oxide coated glass powder (bright powder) 20.0

2. Silic anhydride * 10 2.0

3.polystyrene * 17 2.0

4. Dimethicone (20cs) 15.0

5. Mixtures of partially crosslinked organopolysiloxane polymers containing long chain alkyl groups * 13 10.0

6. Mixture of partially crosslinked organopolysiloxane polymers * 14 35.0

7. Heavy Flow Isoparaffins * 15 4.0

8. Residual amount of diisostearyl malic acid

9. Glyceryl tri2-ethylhexanoate 1.5

10. 1,3-butylene glycol 1.0

11. Beauty Ingredients (Chamomile Extract) 0.1

12. Purified Water 3.0

13. appropriate amount of spices

(Outside the prescription)

14. Solvent: 35 parts dimethicone (6cs)

(Manufacturing method)

A. The components 1-3 are uniformly dispersed with a Henschel mixer (manufactured by Mitsui Miike).

B. Mix components 4 to 13 uniformly.

C. While stirring A with a Henschel mixer, B is added and it disperse | distributes uniformly.

D. Add component 14 to 100 parts of C and mix uniformly.

E. D was filled into a metal dish, compression molded while sucking the solvent with paper to obtain lip gloss.

Lip gloss of the present invention, "finger (brush) extractability", "elasticity at the time of use", "sticky and refreshing feeling", "adhesion to skin", "water-resistance, such as water resistance, sebum resistance", "impact resistance" It was excellent lip gloss in all items of "."

The makeup cosmetic material of the present invention is not sticky and has a neat feeling, soft touch and elasticity, and has excellent water resistance and sebum resistance, and excellent impact resistance, and can also be compression molded to a metal dish or a synthetic resin dish. Therefore, it can be attached to a compact container, and also has the simplicity and convenience which can use various colors simultaneously.

Claims (17)

Group consisting of component (A) consisting of a partially crosslinked organopolysiloxane polymer containing a C8-C30 linear alkyl group, R ₂ SiO units and RSiO _1.5 units, consisting of R ₃ SiO _0.5 units and SiO ₂ units It may include one or two selected from (wherein R in each structural unit may be the same or different, and represents a hydrogen atom, an alkyl group, an aryl group, an aliphatic unsaturated group or a fluoro group), component (A Component (D) consisting of component (B) consisting of partially crosslinked organopolysiloxane polymer other than), component (C) consisting of silicone oil, and one or two or more liquid oils selected from the group consisting of hydrocarbon oil and ester oil. And a component (E) made of a powder. The method of claim 1, Makeup cosmetics, characterized in that the makeup makeup material is oily. The method according to claim 1 or 2, Component (A) is a (vinyl dimethicone / lauryl dimethicone) crosspolymer, the makeup cosmetic material characterized by the above-mentioned. The method according to claim 1 or 2, Component (B) is a (dimethicone / vinyl dimethicone) crosspolymer, the makeup cosmetic material characterized by the above-mentioned. The method according to claim 1 or 2, Component (C) is dimethicone, The makeup cosmetic material characterized by the above-mentioned. The method according to claim 1 or 2, Makeup cosmetics characterized by containing 30-70 mass% of component (C). The method according to claim 1 or 2, The makeup cosmetic material containing 0.5-10 mass% of component (D). The method according to claim 1 or 2, Component (E) contains the plate-shaped powder which has brightness, The makeup cosmetic material characterized by the above-mentioned. The method according to claim 1 or 2, Component (E) contains a spherical powder, the makeup cosmetic material characterized by the above-mentioned. The method according to claim 1 or 2, A make-up cosmetic material, wherein the dish-shaped container is compressed and filled, and at least one of the dish-shaped containers is mounted on a compact container. The method according to claim 1 or 2, Makeup cosmetic material characterized in that the penetration weight of the compression-molded makeup cosmetic material is 20 ~ 120gf. The method according to claim 1 or 2, A makeup cosmetic material characterized in that the elasticity (L2 / L1) in the texture profile analysis (TPA) measurement by the texture analyzer of the compression-molded makeup cosmetic material is 0.48 to 0.99. The method according to claim 1 or 2, Makeup cosmetics, characterized in that the eye shadow. The method according to claim 1 or 2, The component (A) is a (vinyl dimethicone / lauryl dimethicone) crosspolymer, and the component (B) is a (dimethicone / vinyl dimethicone) crosspolymer. The method according to claim 1 or 2, Component (A) is a (vinyl dimethicone / lauryl dimethicone) crosspolymer, and component (C) is dimethicone, The makeup cosmetics material characterized by the above-mentioned. The method according to claim 1 or 2, The component (B) is a (dimethicone / vinyl dimethicone) crosspolymer, and the component (C) is a dimethicone. Group consisting of component (A) consisting of a partially crosslinked organopolysiloxane polymer containing a C8-C30 linear alkyl group, R ₂ SiO units and RSiO _1.5 units, consisting of R ₃ SiO _0.5 units and SiO ₂ units It may include one or two selected from (wherein R in each structural unit may be the same or different, and represents a hydrogen atom, an alkyl group, an aryl group, an aliphatic unsaturated group or a fluoro group), component (A Component (D) consisting of component (B) consisting of partially crosslinked organopolysiloxane polymer other than), component (C) consisting of silicone oil, and one or two or more liquid oils selected from the group consisting of hydrocarbon oil and ester oil. And the composition containing the component (E) consisting of a powder is dispersed in a solvent, and after dispersing, filled into a dish-like container, under compression molding while sucking the solvent Method for manufacturing a make-up cosmetic material characterized.

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