KR101978370B1 - Cosmetic composition with excellent durability and manufacturing method thereof - Google Patents

Abstract

The present invention relates to a method for producing a cosmetic composition, comprising the steps of: preparing a powder part containing a silicone powder; preparing a slurry phase by mixing the powder part and a solvent; and drying the slurry phase . The cosmetic composition of the present invention exhibits a natural cosmetic effect with a smooth spreadability and enhances the persistence of makeup, so that a lucid skin tone can be maintained even after a long time has elapsed.

Description

TECHNICAL FIELD The present invention relates to a cosmetic composition having excellent cosmetic durability and manufacturing method,

The present invention relates to a cosmetic composition having excellent makeup persistence and a method for producing the same. More particularly, the present invention relates to a cosmetic composition having excellent long-lasting properties and excellent cosmetic effects, and a method for producing the same.

In general, the color cosmetic composition is made up of three components of powder, oil and water as main components. The color cosmetics may be classified into base makeups such as face powder, compact, powder foundation, two-way cake, makeup base, liquid foundation and cream foundation, eye shadow, powder blush, , Eyeliner and mascara point makeup (Point Makeup) can be divided into.

These products are applied to the skin and attached for about 8 to 12 hours, and the cosmetic film is changed by the skin secretions such as sweat and sebum secreted from the skin while attached.

Changes in cosmetics are one of the biggest complaints of women using color cosmetics, and they appear in many physical forms, such as creasing, clumping, tone tone, or shine. Especially, in the case of base makeup products, it is considered that cosmetic persistence is largely lowered due to the unevenness of makeup caused by sebum or sweat secreted after the makeup.

Japanese Unexamined Patent Application, First Publication No. 10-212211 proposes a method for reducing shine by scattering light by using a titanium oxide porous body as a flaky titanium oxide aggregate, which is a nanometer unit, in order to solve makeup persistence, but titanium oxide itself has a white band Therefore, cosmetics are unnatural when added to cosmetics for color cosmetics, and the formability is deteriorated. Japanese Unexamined Patent Publication No. Hei 7-119168 proposes a method of using a powder coated with silicone or a fluorine surface treating agent to prevent the powder from being wetted with perspiration or sebum so as to reduce the coagulation phenomenon caused by excessive sweating and sebum, Powder coated with a surface treatment agent is wetted by sebum, and persistence of makeup is not maintained. Powder coated with a fluorine-based surface treatment agent has a poor adhesion between powder-powder or powder-skin, There is a problem in that feeling and formability are deteriorated.

In addition, a method has been proposed in which a powder having excellent absorbency is compounded to absorb excess sebum secreted. However, since such a powder absorbs water or oil added during the production of cosmetics, In particular, when the compounding amount is large in the case of a powdered product, it is difficult to increase the compounding amount because it is difficult to form because the oil used as the binder is excessively absorbed.

Another method is to use the metal oxide to make the metal ions of the metal oxide and the sebaceous constituents, and the fatty acid, which is the main cause of the shine, reacts to solidify into the metal salt to enhance the makeup persistence.

However, the above-mentioned methods do not provide a fundamental solution for reducing the change of the cosmetic film and thereby increasing the makeup sustainability.

SUMMARY OF THE INVENTION Accordingly, the present invention provides a cosmetic composition and a process for producing the same that solve the above problems and have excellent cosmetic persistence.

Further, the present invention can exhibit a natural cosmetic effect with smooth spreadability and can enhance the persistence of the natural cosmetic effect expressed.

In order to achieve the above object, the present invention also provides a color cosmetic composition which is excellent in spreadability and durability even when the silicone powder having a low refractive index is used in a large amount while maintaining an oil absorption amount to absorb sebum, .

In order to solve the above problems, the present invention provides a cosmetic composition comprising a powder portion containing a silicone powder, a powder portion and a solvent to prepare a slurry phase, and a step of drying the slurry phase And a manufacturing method thereof.

The inventors of the present invention have found that the silicone powder has a low refractive index and is excellent in the ability to absorb sebum, and when used in a cosmetic composition such as powder, it effectively absorbs sweat and sebum secreted naturally from the skin after makeup, And the present invention has been completed.

The types of the silicone powder include silicone resin and silicon rubber. The silicone rubber has a higher elasticity than silicone resin, and thus causes a lot of problems when the cosmetic composition is dry-produced.

In the case of a cosmetic composition containing a large amount of the silicone rubber, the compressed powder is restored and air pockets are formed on the surface of the product, which is unstable, has a large amount of powder dust, and is easily damaged when the product is dropped. I was using only a small amount to produce a dry product.

Accordingly, the present invention provides a cosmetic composition comprising a large amount of silicone powder to improve sebum absorption ability while solving these problems.

The silicone powder may be selected from the group consisting of dimethicone / vinyl dimethicone crosspolymer, polymethylsilsesquioxane, polymethylvinylsilsesquioxane, vinyl dimethicone / methicone silsesquioxane crosspolymer and diphenyl dimethicone / And a chicone / silsesquioxane crosspolymer. The dimethicone / vinyl dimethicone crosspolymer may be preferably used. The dimethicone / vinyl dimethicone crosspolymer is rubber type as compared with other silicone powders, and unreacted monomers exist on the surface thereof, so that stability can be improved in a compression type powder product by solvent and heat treatment.

As used herein, the term "powder" refers to an aggregate of solid materials having a particle size of usually not more than 1 mm, and the powders usable in the present invention include extender pigments, coloring pigments, and white pigments commonly used in the cosmetics field do. The 'powder part' used in the specification of the present invention refers to a cosmetic material aggregate having a powder form property including the powder and an oil binder capable of providing a bonding force between the powder particles.

According to the present invention, the extender pigment is an inorganic pigment comprising talc, mica, kaolin, alumina, barium silicate, zeolite, muscovite, synthetic mica, silica, magnesium carbonate, barium sulfate, iron titanate and titanium oxide coated mica; Polymethylmethacrylate powder, polyethylene powder, and nylon powder. It is preferable to use at least one selected from the group consisting of polystyrene powder, polystyrene powder, polymethyl methacrylate powder, polyethylene powder and nylon powder. However, the present invention is not limited to the above-listed ones, and extender pigments conventionally known in the art such as extender pigments described in " New Cosmetics, Kwon Kyung-ok et al. Translation, book publishing technology, It can be used as an extender pigment described in the invention.

The extender pigment is preferably subjected to a hydrophobic treatment. Specifically, the surface of the powder pigment may be treated with a high viscosity silicone, an alkyl hydrogen polysiloxane, a cationic surfactant, an anionic surfactant, a nonionic surfactant or a wax.

The white pigment includes, but is not limited to, titanium dioxide, zinc oxide, and the like.

The cosmetic composition according to the present invention may include an oil binder to enhance binding of the powder and at the same time to provide a smooth feeling when the powder is applied to the skin.

The kind of the oil binder is not particularly limited, and a common oil used in the cosmetic composition may be used. Specifically, hydrocarbon oils such as squalane and mineral oil; Caprylic / capric triglyceride, neopentyl glycol dicaprate, 2-octyldodecyl myristate, isopropyl myristate, cetyl 2-ethylhexanoate, octyldodecanol, and glyceryl triethylhexanoate An ester-based oil containing; Vegetable oils including olive oil, jojoba oil and macadamia oil; And a silicone oil containing cyclomethicone and dimethicone, are preferably used. Mineral oils, animal oils, synthetic oils, etc., which are well known in the art, may also be used.

The silicone powder may be contained in an amount of 11 to 30% by weight, preferably 15 to 25% by weight, and more preferably 18 to 22% by weight based on the total weight of the total cosmetic composition.

If the content of the silicone powder is less than 11% by weight, persistence of makeup is deteriorated, and the feeling of use is not smooth. If the content of the silicone powder is more than 30% by weight, the drop stability may be insufficient to easily break the impact. In addition, when the silicone powder is used as a puff and a brush, the amount of pay-off increases.

The cosmetic composition of the present invention comprises a step of mixing a silicone powder and a solvent to prepare a slurry phase.

As used herein, the term 'slurry phase' means a state in which a solid and a liquid are mixed, and a powder portion containing the silicone powder is mixed in the solvent.

The solvent used for preparing the slurry phase may be purified water, ethanol, isopropyl alcohol (IPA), and the like, but is not limited thereto.

The powder portion and the solvent may be mixed in a weight ratio of 50:50 to 70:30. When the powder part is less than 50 parts by weight based on the weight of the solvent, the hardness of the mixed slurry is too low, so that there may be a problem such as a lot of cracks or shrinkage of the surface depending on the volatilization of the solvent during molding, , The hardness of the mixed slurry is too high, so that filling may be difficult. The hardness was measured by FUDHO RHEOMETER (Adapter No. 9 (10 mm)). Therefore, the mixing ratio of the powder part and the solvent can solve the problem related to the hardness of the cosmetic composition, which is a problem in the production of the cosmetic composition of the present invention.

The cosmetic composition of the present invention can be prepared by mixing the powder part and the solvent in a mixer, particularly preferably in a high-viscometer (Mixer) for 10 minutes. The slurry-like mixture is charged into a dish, and the solvent is removed by suction in a vacuum, followed by drying at a high temperature for a long time to remove the solvent.

The drying step is preferably carried out at 40 to 80 ° C.

Unreacted monomers remaining on the surface of the silicone powder when drying is carried out within the temperature range described above form an intervening polymer network by the solvent contained in the cosmetic composition of the present invention and the drying temperature It is found that the air pocket phenomenon does not occur on the surface of the product and the drop stability can be improved.

According to another embodiment of the present invention, there is provided a cosmetic composition containing a silicone powder.

The cosmetic composition may include 10 to 30% by weight of silicone powder based on the total weight of the cosmetic composition.

In addition, the cosmetic composition according to the present invention may further contain fragrance, dye, preservative, fungicide, pearl, etc. in addition to the above-mentioned components within a range not to deteriorate the effect of the composition.

The cosmetic composition may have a form of a makeup base, a powder, a foundation or a concealer, but is not limited thereto.

According to an embodiment of the present invention, there is provided a cosmetic composition capable of effectively absorbing sebum or perspiration by using a large amount of silicone powder having a low refractive index, and a method for producing the same.

In addition, the cosmetic composition of the present invention exhibits a natural cosmetic effect with smooth spreadability and enhances the persistence of make-up, thereby maintaining a lucid skin tone even after a long time has elapsed.

In addition, the cosmetic composition of the present invention exhibits excellent stability due to reduced air pocket phenomenon appearing on the surface of the product, and the drop stability can be improved to reduce the damage of the product.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a diagram comparing sebum secretion areas according to time after applying the cosmetic composition containing the silicone powder of the present invention and the cosmetic composition not containing the silicone powder of the present invention to the skin. FIG.

Hereinafter, embodiments of the present invention will be described in detail to facilitate understanding of the present invention. However, the embodiments according to the present invention can be modified into various other forms, and the scope of the present invention should not be construed as being limited to the following embodiments. Embodiments of the invention are provided to more fully describe the present invention to those skilled in the art.

Comparative Example  One, Comparative Example  2 and Comparative Example  3

Compression type powders were prepared by the conventional dry production method using raw materials 1 to 11 according to the composition shown in Table 1 below.

First, powder (1 to 7) is mixed in a powder mixer, and then binder, preservative and perfume are added and mixed well in an agitator. After mixing, the mixture was pulverized using a hammer mill, and then compressed by a molding machine to produce compressed powder.

Comparative Example  4, Comparative Example  5 and Example  One

Powders were prepared in the same manner as in Comparative Example 1 using raw materials 1 to 11 according to the compositions shown in Table 1 below.

The prepared powder part was mixed with 15% by weight of a solvent (ethanol, IPA, etc.) and 85% by weight of purified water in a high viscosity mixer (Hi-Vis Mixer, TK) Mix. The mixed dough was charged into an aluminum plate, and a part of the aqueous solution was removed by a vacuum apparatus, and then dried in a convection type dryer at 50 ° C for at least 12 hours to remove all of the aqueous solution to prepare a compression type powder.

number Raw material (% by weight) Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Example 1 One Talc to 100 to 100 To 100 To 100 To 100 to 100 2 Mica 30.0 30.0 30.0 30.0 30.0 30.0 3 Polymethyl methacrylate 5.0 5.0 5.0 5.0 5.0 5.0 4 Titanium dioxide 10.0 10.0 10.0 10.0 10.0 10.0 5 Dimethicone / Vinyl Dimethicone Crosspolymer 20.0 - 5.0 40.0 5.0 20.0 6 Magnesium Aluminum Silicate 1.0 1.0 1.0 1.0 1.0 1.0 7 Iron oxide pigment 1.0 1.0 1.0 1.0 1.0 1.0 8 Ester oil 5.0 5.0 5.0 5.0 5.0 5.0 9 Dimethicone 5.0 5.0 5.0 5.0 5.0 5.0 10 antiseptic 1.0 1.0 1.0 1.0 1.0 1.0 11 incense 0.2 0.2 0.2 0.2 0.2 0.2

<Moldability Evaluation>

Moldability was confirmed by using an intrusion hardness machine for the compression type powders prepared in Comparative Examples 1, 2, 3, 4 and 5 and Example 1, and the drop stability was evaluated.

The moldability was measured for ten products using a JAL TYPE (JIS K 6301) penetration hardness tester manufactured by Japan Polymer Meter Co., Ltd., and the average value was shown in Table 2. The drop stability was determined by falling freely from a height of 70 cm on a 3 mm rubber plate The average values are shown in Table 2.

division Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Example 1 Moldability (hardness) 5 ~ 9 25 to 35 5 to 10 5 to 15 19-28 15-25 Drop stability (failure time) 1.0 times 5.7 times 1.0 times 2.0 times 3.0 times 4.5 times

Referring to Table 2 showing the results of stability, it can be seen that Comparative Example 1 produced by dry method has very poor moldability and drop stability. However, in Example 1 produced by wet method, satisfactory moldability and drop stability Respectively.

In the case of Comparative Example 4 in which 40 wt% of the silicon powder was added to produce wet powder, a large amount of silicon powder was used, but the stability was superior to Comparative Example 1, which was made by a general dry manufacturing method. However, the use of a large amount of spherical powder has a disadvantage in that there is a large amount of payoff and powdery spots, the feeling of use is not smooth, and the powder is slackened. In addition, as shown in Comparative Example 3 prepared by adding 5 wt% of the silicon powder, it was found that the dryability was very poor in the moldability and the drop stability compared to the case of producing by wet method.

<Evaluation of Usability>

In order to examine the effect of the cosmetic composition of Comparative Example 2, Comparative Example 5 and Example 1 on the actual skin, transparent and natural cosmetic effect and persistence, 30 women of 20 to 50 years old were subjected to blind test Respectively. The feel and condition of the makeup were evaluated by sensory evaluation based on the following evaluation criteria, and they were statistically processed and shown in Table 2.

Evaluation standard

(5: very good, 4: excellent, 3: normal, 2: bad, 1: very bad)

division Example 1 Comparative Example 2 Comparative Example 5 Transparent 4.3 3.3 3.5 Naturalness 4.1 3.7 3.7 Make-up persistence 4.5 3.6 3.7 Toiletries 4.3 3.5 3.7

As shown in Table 3 and FIG. 1, the wet compacted powder containing a large amount of silicon powder has much better durability than the compact dry powder compact produced by the general dry method, Compared to the compression type powder prepared by the method of the present invention,

Further, as a result of adding 5 wt% of silicone powder to produce a wet product, the product exhibited physical properties similar to those of products containing no silicone powder in terms of make-up durability and naturalness, and thus it was difficult to achieve the object of the present invention. In addition, when it contains not less than the silicone powder content of the present invention, it is difficult to produce a compression-type powder formulation, so that it is difficult to compare physical properties.

FIG. 1 is a photograph of a photograph taken before and after the application of the fact through a janus. The amount of sebum secretion was analyzed using an image pro program, and the amount of sebum was measured with the application of Example 1 and Comparative Example 2 This is a result.

Referring to FIG. 1, it can be seen that the red color number of the portion coated with the Example 1 is much smaller than the red color number of the portion coated with the Comparative Example 2. As a result, it was found that persistence was improved in both the verification through the consumer and the verification through the device.

As a result of evaluating usability and formability, the compression type powder prepared in Example 1 showed excellent spreadability, transparency and naturalness compared with the compression type powder produced by general dry type, Able to know.

Claims (10)

Preparing a powder part containing a silicone powder;
Mixing the powder part and the water-containing solvent at a weight ratio of 50:50 to 70:30 to prepare a slurry phase; And
Drying the slurry phase,
The water-containing solvent comprises i) purified water; And
ii) at least one selected from ethanol and isopropyl alcohol,
Wherein the silicone powder is contained in an amount of 11 to 30% by weight based on the total weight of the total cosmetic composition. delete delete delete 2. The method of claim 1, wherein the step of drying the slurry phase is performed at a temperature of 40 to 80 DEG C for 10 to 20 hours. delete The method of claim 1, wherein the silicone powder is selected from the group consisting of dimethicone / vinyl dimethicone crosspolymer, polymethylsilsesquioxane, polymethylvinylsilsesquioxane, vinyl dimethicone / methicone silsesquioxane crosspolymer, Wherein the cosmetic composition is at least one selected from the group consisting of chicone / vinyl diphenyl dimethicone / silsesquioxane crosspolymer. The method of claim 1, wherein the silicone powder comprises 18 to 22 wt% of the total weight of the cosmetic composition. delete delete

Images