CN108619005A - Cosmetics for skin, body detergent composition and oil-based cosmetic preparation - Google Patents

Cosmetics for skin, body detergent composition and oil-based cosmetic preparation Download PDF

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CN108619005A
CN108619005A CN201810216512.XA CN201810216512A CN108619005A CN 108619005 A CN108619005 A CN 108619005A CN 201810216512 A CN201810216512 A CN 201810216512A CN 108619005 A CN108619005 A CN 108619005A
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ingredient
molal quantity
average addition
mass
carbon atom
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CN108619005B (en
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胁田和晃
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NOF Corp
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NOF Corp
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Priority claimed from JP2017052109A external-priority patent/JP6847396B2/en
Priority claimed from JP2017138726A external-priority patent/JP6965611B2/en
Priority claimed from JP2017179745A external-priority patent/JP6921384B2/en
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14—Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/592—Mixtures of compounds complementing their respective functions
    • A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

The present invention provides a kind of cosmetics for skin, it contains 0.1~25 mass % ingredients (a), 0.01~5 mass % ingredients (b) and 0.01~5 mass % ingredients (c), ingredient (b) is 1/200~1/6 relative to mass ratio (b)/(a) of ingredient (a), ingredient (a) is polyalkylene oxide derivative shown in formula (1), Z [O (A1O)m(EO)n‑R1] p (1) Z is the residue that all hydroxyls are eliminated from the alcohol of carbon atom number 1~6, p is 1 or more, 6 hereinafter, R1For the alkyl of carbon atom number 1~4, A1O is the oxyalkylene group of carbon atom number 3~4, and EO is oxyethylene group, meets 1≤p × m≤70,1≤p × n≤70, and n/ (m+n) is 0.15~0.75, and ingredient (b) is alkylene oxide derivative shown in formula (2), R2O‑[(A2O)x(EO)y]‑H···(2)R2For the alkyl of carbon atom number 1~4, A2O is the oxyalkylene group of carbon atom number 3, and EO is oxyethylene group, meets 1≤x≤40,3≤y≤60, and x/ (x+y) is 0.35~0.85, A2O and EO carries out addition with random shape, and ingredient (c) is tackifier, and ingredient (d) is water.

Description

Cosmetics for skin, body detergent composition and oil-based cosmetic preparation
Technical field
The present invention relates to a kind of skin preparations for extenal use, in particular to a kind of use feeling can get water profit when smearing, Improve aqueous cosmetic to the adhesion of skin and the persistent cosmetics for skin of makeup.
In addition, the present invention relates to a kind of body detergents, even if in particular to a kind of secret suitable for women Also there is mild use feeling Deng sensitive position, the duration of foam when cleaning is excellent, while can get refreshing after cleaning The body detergent composition of pleasant sensation.
In addition, the present invention relates to a kind of oil-based cosmetic preparation, aqueous cosmetic removing material can be utilized to be easy in particular to one kind Ground remove, have smooth ductility, and not through when dry sensation oil-based cosmetic preparation.
Background technology
In the past, cosmetics were to create U.S. flesh, and the impressive eye circumference with color or shade, the corners of the mouth are mesh And used.In order to play its dressing effect to the maximum extent, it is important that in forming uniform and beautiful change on skin Adornment film.It is dispersed with the Water-borne modifications such as oil type emulsification cosmetic in the distributed aqueous cosmetic of powder, the water containing powder in water Cosmetic, since water moistens smooth use feeling, as to the bearing the State of cosmetics for feeling few of skin and centered on by young man Crowd in have high popularity.
However, although to moisten smooth use feeling excellent for the water of aqueous cosmetic, but then, with oil-based cosmetic preparation or oil Mid-water type cosmetics are compared, for the adherence to skin it is poor, be difficult to improve the adhesion of makeup film or the persistent dosage form of makeup.
In view of the actual conditions, it is thus proposed that a kind of to improve the adherence to skin, the adhesion for film of making up, makeup Aqueous cosmetic for the purpose of persistence.For example, proposing a kind of aqueous cosmetic in patent document 1, which is characterized in that addition There are glycosyl trehalose, polyacrylate, powder.
Scalp, eyebrow, eyelashes, armpit, private parts etc. adipose gland are intensive, these positions are easy to accumulate by sebum or protein etc. Dirt caused by secretion.Other than bringing the senses of discomfort such as sticky, also easily become is caused by bacterial multiplication etc. these dirts Various skin problems the reason of.Especially at the secret of women, the reason of accumulation of sebum becomes stench, further cause The problems such as sense of discomfort caused by leukorrhea or menses or even fash, eczema.
In general, in order to remove the sebum or other dirts of body, the bodies cleaning agents such as soap, bath foam can be used, but logical Normal body detergent is insufficient to the cleaning force of the compound dirt of sebum-protein, the frank sense after cannot cleaning.
Therefore, it is proposed in patent document 2 a kind of at a specific ratio containing cationic surfactant, non-ionic surface The composition of skin cleanser of activating agent, water-soluble inorganic salt and alcohol.In addition, proposing one kind in patent document 3 contains silicone oil And wiping agent composition of the lower alcohol as cleaning-wiping ingredient.
In recent years, with the variation of life style, seek the simplicity of makeup behavior and swiftness, be impregnated in cotton pads etc. And the market share that can be readily removable the aqueous cosmetic removing materials such as the makeup remover of cosmetics, makeup removing paper handkerchief is gradually expanded.
On the other hand, for cosmetics, from aspect easy to carry, easy to use, solid-like or gelatinous oiliness Cosmetics receive an acclaim on the market.Since oil-based cosmetic preparation is using finish as main component, water resistance is high, dressing effect Duration is excellent, in addition, by containing a large amount of powder, can effectively show the distinctive smooth ductility of powder.
However, since oil-based cosmetic preparation contains a large amount of powder, exists and easy to produce by caused by seizing sebum Dry tendency.Further, since oil-based cosmetic preparation using finish as main component, therefore, it is difficult to be shed with aqueous cosmetic removing material, is It is fully removed from skin, is needed using the high oiliness cosmetic removing material of cleaning force as makeup remover.
Therefore, a kind of composite used for lipstick is proposed in patent document 4, contains and is useful for preventing the specific of time dependent drying Alkylene oxide derivative (alkylene oxide derivative), improve moisture retention.In addition, being proposed in patent document 5 The filming emulsion polymer of specific structure is combined by a kind of cosmetics with water-soluble film forming polymer, even if utilizing Aqueous cosmetic removing material also can simply be shed.
Existing technical literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 2008-273943 bulletins
Patent document 2：Japanese Unexamined Patent Publication 2001-187726 bulletins
Patent document 3：Japanese Unexamined Patent Publication 5-58408 bulletins
Patent document 4：Japanese Unexamined Patent Publication 2004-168759 bulletins
Patent document 5：Japanese Unexamined Patent Publication 2015-196646 bulletins
Invention content
The technical problem to be solved in the present invention
Although the aqueous cosmetic described in patent document 1 improves makeup persistence to a certain extent, makeup film Adhesion is insufficient.Although also having done other various motions, but still hardly possible achieves over oil-based cosmetic preparation by aqueous cosmetic To the adherence of skin, the adhesion for film of making up, makeup persistence.
The technical problem of the present invention is, provides a kind of use feeling can get water profit when smearing, improves aqueous makeup Adhesion and makeup persistent cosmetics for skin of the product to skin.
The detergent of patent document 2 contains cationic surfactant, not although the frankness sense after cleaning is excellent It can say that it is fully mild in terms of the cleaning at the secret of women.
In addition, the wiping agent composition of patent document 3, although obtaining certain frank sense and mildness, cleaning private Foam duration when close place is insufficient.
As described above, actual conditions be not yet received while meeting at secret mildness, cleaning when foam hold The body detergent of frank sense after continuous property and cleaning.
The technical problem of the present invention is, provides a kind of body detergent composition, even if the secret suitable for women The sensitive position such as place also has a mild use feeling, and the duration of foam when cleaning is excellent, while after can get cleaning Frankness sense.
The cosmetics of patent document 4 are difficult to be utilized aqueous cosmetic removing material and fully remove.
Further, since the composite used for lipstick of patent document 5 cannot contain finish and powder higher, therefore when smearing Smooth ductility is insufficient.
As described above, actual conditions are to be not yet received while meeting easily clean, smear using aqueous cosmetic removing material When ductility it is smooth and not through when dry sensation oil-based cosmetic preparation.
The technical problem of the present invention is, provides and a kind of is readily removable, with smooth using aqueous cosmetic removing material Ductility and not through when dry sensation oil-based cosmetic preparation.
Solve the technological means of technical problem
In order to solve the above-mentioned technical problem, present inventor is not conceived to aqueous cosmetic itself, but has in mind In makeup substrate, consider whether that aqueous cosmetic can be improved to flesh by making makeup substrate play a role as binder The adhesion and makeup persistence of skin.Present inventor, which passes through, conscientiously to be studied, as a result, it has been found that, with special ratios by two kinds The cosmetics for skin that alkylene oxide derivative, tackifier and water are composed solves above-mentioned all technical problems, from And complete the present invention.
That is, the first invention is related to a kind of cosmetics for skin, which is characterized in that the following compositions containing 0.1~25 mass % (a), the following compositions (b) of 0.01~5 mass % and the following compositions (c) of 0.01~5 mass %, ingredient (b) is relative to ingredient (a) mass ratio ((b)/(a)) is 1/200~1/6,
(a) it is the polyalkylene oxide derivative (polyalkylene oxide derivati ve) represented by following formula (1),
Z-[O(A1O)m(EO)n-R1]p···(1)
In formula (1), Z be 1~6 from carbon atom number alcohol in eliminate residue made of all hydroxyls, p is the alcohol Valence mumber is 1 or more, 6 hereinafter, R1The alkyl for being 1~4 for carbon atom number, A1O is the oxyalkylene group that carbon atom number is 3~4, and EO is Oxyethylene group, the oxyalkylene group A in the derivative1Average addition molal quantity p × m of O meets 1≤p × m≤70, institute The average addition molal quantity p × n for stating the oxyethylene group EO in derivative meets 1≤p × n≤70, the oxyethylene group EO Average addition molal quantity relative to the oxyalkylene group A1The average addition molal quantity of O adds with the average of the oxyethylene group EO Total ratio n/ (m+n) at molal quantity is 0.15~0.75,
(b) it is the alkylene oxide derivative represented by following formula (2),
R2O-[(A2O)x(EO)y]-H···(2)
In formula (2), R2The alkyl for being 1~4 for carbon atom number, A2O is the oxyalkylene group that carbon atom number is 3, and EO is ethylene oxide Base, x are the oxyalkylene group A2The average addition molal quantity of O meets 1≤x≤40, and y is that the average of the oxyethylene group EO adds At molal quantity, meet 3≤y≤60, the average addition molal quantity of the oxyethylene group EO is relative to the oxyalkylene group A2O's is flat Total ratio x/ (x+y) of the average addition molal quantity of equal addition molal quantity and the oxyethylene group EO is 0.35~0.85, The oxyalkylene group A2The O and oxyethylene group EO carries out addition with random shape,
(c) it is tackifier,
(d) it is water.
Cosmetics for skin according to the present invention can get the use feeling of water profit when smearing, and improve aqueous cosmetic to flesh The adhesion and makeup persistence of skin.
In addition, in order to solve the above-mentioned technical problem, present inventor, which passes through, conscientiously to be studied, as a result, it has been found that, with spy The body detergent that two kinds of alkylene oxide derivatives, amino acids anion surfactant and water are composed by certainty ratio combines Object solves above-mentioned all technical problems, so as to complete the present invention.
That is, the second invention is as described below.
A kind of body detergent composition, which is characterized in that following compositions (a) containing 0.1~25 mass %, 0.01~ The following compositions (e) and following compositions (f) of the following compositions (b) of 5 mass %, 0.1~10 mass %, the ingredient (b) are opposite In the mass ratio ((b)/(a)) of the ingredient (a) be 1/200~1/6, pH it is 3~7,
(a) it is the polyalkylene oxide derivative represented by following formula (1),
Z-[O(A1O)m(EO)n-R1]p···(1)
In formula (1), Z be 1~6 from carbon atom number alcohol in eliminate residue made of all hydroxyls, p is the alcohol Valence mumber is 1 or more, 6 hereinafter, R1The alkyl for being 1~4 for carbon atom number, A1O is the oxyalkylene group that carbon atom number is 3~4, and EO is Oxyethylene group, the oxyalkylene group A in the derivative1Average addition molal quantity p × m of O meets 1≤p × m≤70, institute The average addition molal quantity p × n for stating the oxyethylene group EO in derivative meets 1≤p × n≤70, the oxyethylene group EO Average addition molal quantity relative to the oxyalkylene group A1The average addition molal quantity of O adds with the average of the oxyethylene group EO Total ratio n/ (m+n) at molal quantity is 0.15~0.75,
(b) it is the alkylene oxide derivative represented by following formula (2),
R2O-[(A2O)x(EO)y]-H···(2)
In formula (2), R2The alkyl for being 1~4 for carbon atom number, A2O is the oxyalkylene group that carbon atom number is 3, and EO is ethylene oxide Base, x are the oxyalkylene group A2The average addition molal quantity of O meets 1≤x≤40, and y is that the average of the oxyethylene group EO adds At molal quantity, meet 3≤y≤60, the average addition molal quantity of the oxyethylene group EO is relative to the oxyalkylene group A2O's is flat Total ratio x/ (x+y) of the average addition molal quantity of equal addition molal quantity and the oxyethylene group EO is 0.35~0.85, The oxyalkylene group A2The O and oxyethylene group EO carries out addition with random shape,
(e) it is amino acids anion surfactant,
(f) it is water.
The body detergent composition of the present invention has mildly at the secret suitable for women etc. sensitive position Use feeling, the duration of foam when cleaning is excellent, while can get the frank sense after cleaning.
In addition, in order to solve the above-mentioned technical problem, present inventor, which passes through, conscientiously to be studied, as a result, it has been found that, with spy The oil-based cosmetic preparation that two kinds of alkylene oxide derivatives, powder and finish are composed is solved above-mentioned all technologies and asked by certainty ratio Topic, so as to complete the present invention.
That is, third invention is as described below.
A kind of oil-based cosmetic preparation, which is characterized in that following compositions (a), 0.01~5 matter containing 0.1~25 mass % Measure % following compositions (b), the following compositions (h) of the following compositions (g) of 25~50 mass % and 30~70 mass %, it is described at Point (b) is 1/200~1/6 relative to the mass ratio ((b)/(a)) of the ingredient (a),
(a) it is the polyalkylene oxide derivative represented by following formula (1),
Z-[O(A1O)m(EO)n-R1]p···(1)
In formula (1), Z be 1~6 from carbon atom number alcohol in eliminate residue made of all hydroxyls, p is the alcohol Valence mumber is 1 or more, 6 hereinafter, R1The alkyl for being 1~4 for carbon atom number, A1O is the oxyalkylene group that carbon atom number is 3~4, and EO is Oxyethylene group, the oxyalkylene group A in the polyalkylene oxide derivative1Average addition molal quantity p × m of O meets 1≤p × m Average addition molal quantity p × n of≤70, the oxyethylene group EO in the polyalkylene oxide derivative meet 1≤p × n≤70, The average addition molal quantity of the oxyethylene group EO is relative to the oxyalkylene group A1The average addition molal quantity of O and the oxygen second Total ratio n/ (m+n) of the average addition molal quantity of alkenyl EO is 0.15~0.75,
(b) it is the alkylene oxide derivative represented by following formula (2),
R2O-[(A2O)x(EO)y]-H···(2)
In formula (2), R2The alkyl for being 1~4 for carbon atom number, A2O is the oxyalkylene group that carbon atom number is 3, and EO is ethylene oxide Base, x are the oxyalkylene group A2The average addition molal quantity of O meets 1≤x≤40, and y is that the average of the oxyethylene group EO adds At molal quantity, meet 3≤y≤60, the average addition molal quantity of the oxyethylene group EO is relative to the oxyalkylene group A2O's is flat Total ratio x/ (x+y) of the average addition molal quantity of equal addition molal quantity and the oxyethylene group EO is 0.35~0.85, The oxyalkylene group A2The O and oxyethylene group EO carries out addition with random shape,
(g) it is powder,
(h) it is finish.
The oil-based cosmetic preparation of the present invention, is readily removable using aqueous cosmetic removing material, prolongs with smooth when smearing Malleability, and can get not through when dry sensation use feeling.
Specific implementation mode
(cosmetics for skin)
The cosmetics for skin of the present invention contains following ingredient (a)~(d).
[ingredient (a)]
The present invention general formula (1) represented by polyalkylene oxide derivative in, Z be 1~6 from carbon atom number alcohol (Z (OH) p) in eliminate residue made of hydroxyl, p indicates the valence mumber of alcohol, is 1~6.
When the carbon atom number of the alcohol (Z (OH) p) is more than 6, moistening when smearing is damaged, thus be set as 6 with Under, but further preferably 3 or less.In addition, when the carbon atom number of the alcohol (Z (OH) p) is zero, as hydrogen atom when, water Property cosmetics adhesion and makeup persistence decline, therefore be set as 1 or more.In addition, the valence mumber p when the alcohol (Z (OH) p) is super When 6, the adhesion and makeup persistence of aqueous cosmetic decline, therefore are set as 6 hereinafter, but further preferably 3 or less.
The alcohol (Z (OH) p) specifically indicates methanol, ethyl alcohol, normal propyl alcohol, isopropanol, n-butanol, sec-butyl alcohol, tertiary fourth Alcohol, amylalcohol, hexanol, ethylene glycol, propylene glycol, butanediol, pentanediol, hexylene glycol, glycerine, erythrite, pentaerythrite, xylose The alcohol such as alcohol, trimethylolpropane, D-sorbite.The alcohol (Z (OH) p) is preferably methanol, ethyl alcohol, ethylene glycol, propylene glycol, the third three The residue of alcohol, more preferably methanol, ethylene glycol, propylene glycol.
A1O is the oxyalkylene group that carbon atom number is 3~4, specifically, oxypropylene group, oxygen cyclobutenyl, oxidation can be enumerated Trimethylene (oxytrimethylene), oxytetramethylene (oxytetramethy lene) etc..Preferably oxypropylene group, Oxygen cyclobutenyl, more preferably oxypropylene group.
M is the A of each hydroxyl of the alcohol1The average addition molal quantity of O.The A of ingredient (a) entirety1The average addition of O rubs Your number " p × m " is 1~70, preferably 3~50, more preferably 5~40.When " p × m " is more than 70, moistening when smearing by To damage, when less than 1, the adhesion or makeup persistence of aqueous cosmetic decline.
N is the average addition molal quantity of the EO of each hydroxyl of the alcohol.The average addition mole of the EO of ingredient (a) entirety Number " p × n " is 1~70, preferably 5~60, more preferably 10~50.When " p × n " is more than 70, the attachment of aqueous cosmetic Property and makeup persistence decline, when less than 1, moistening when smearing is damaged.
The average addition molal quantity of the oxyethylene group EO is relative to the oxyalkylene group A1The average addition molal quantity of O with Total ratio " n/ (m+n) " of the average addition molal quantity of the oxyethylene group EO be 0.15~0.75, preferably 0.30~ 0.72, more preferably 0.45~0.70.When the ratio is more than 0.75, under the adhesion and makeup persistence of aqueous cosmetic Drop, moistening when being smeared if less than 0.15 are damaged.
A1O and EO can carry out addition with block-wise, addition can also be carried out with random shape, but more preferably with random shape Carry out addition.
R1The alkyl for being 1~4 for carbon atom number.If R1Carbon atom number be 5 or more, then hydrophily declines, water when smearing Lubricant nature is damaged.As the alkyl, methyl, ethyl, n-propyl, isopropyl, normal-butyl, sec-butyl, tertiary butyl can be enumerated Deng preferably methyl, ethyl.
The ingredient (a) of the present invention can utilize well known method to manufacture.For example, can by make to have the compound of hydroxyl with After the alkylene oxide addition polymerization that ethylene oxide and carbon atom number are 3~4, make in the presence of alkali metal halogenated alkyl carry out ether reaction and It obtains.
When ingredient (a), (b), (c) and gross mass (d) are set as 100 mass %, the content of ingredient (a) is 0.1~ 25 mass %, preferably 0.5~20 mass %, more preferably 1~15 mass %.When the content of ingredient (a) is less than 0.1 mass % When, moistening when smearing is damaged, and the adhesion of aqueous cosmetic is insufficient.In addition, the content when ingredient (a) is more than 25 When quality %, the adhesion of aqueous cosmetic is also deteriorated.
[ingredient (b)]
In alkylene oxide derivative represented by the general formula (2) of the present invention, A2O is the oxyalkylene group that carbon atom number is 3, tool For body, oxypropylene group, oxidation trimethylene, preferably oxypropylene group can be enumerated.
X is oxyalkylene group A2The average addition molal quantity of O, and 1≤x≤40, preferably 3≤x≤30, more preferably 5≤x ≤20.When x is more than 40, moistening when smearing is damaged, and when x is less than 1, the adhesion of aqueous cosmetic and makeup are held Long property is deteriorated.
Y is the average addition molal quantity of oxyethylene group EO, and 3≤y≤60, preferably 5≤y≤50, more preferably 10≤y ≤30.When y is more than 60, the adhesion of aqueous cosmetic and makeup persistence are deteriorated, when y is less than 3, moistening when smearing It is damaged.
In ingredient (b), the average addition molal quantity of the oxyethylene group EO is relative to the oxyalkylene group A2The average of O adds Total ratio x/ (x+y) at the average addition molal quantity of molal quantity and the oxyethylene group EO is 0.35~0.85, preferably It is 0.45~0.80, more preferably 0.50~0.70.When the ratio is less than 0.35, moistening when smearing is damaged, when When more than 0.85, the adhesion and makeup persistence of aqueous cosmetic decline.
Never sticky angle is set out, and oxyethylene group EO and oxyalkylene group A are made2O carries out addition with random shape.
R2The alkyl for being 1~4 for carbon atom number.Work as R2Carbon atom number when being 5 or more, hydrophily declines, water when smearing Lubricant nature declines.As alkyl, methyl, ethyl, n-propyl, isopropyl, normal-butyl, sec-butyl, tertiary butyl etc. can be enumerated.It is preferred that For methyl, normal-butyl.
The ingredient (b) of the present invention can utilize well known method to manufacture.For example, can by make to have the compound of hydroxyl with Ethylene oxide and carbon atom number obtain for 3~4 alkylene oxide addition polymerization.
When ingredient (a), (b), (c) and gross mass (d) are set as 100 mass %, the content of ingredient (b) is 0.01~ 5 mass %, preferably 0.03~4 mass %, more preferably 0.05~3 mass %.When the content of ingredient (b) is less than 0.01 matter When measuring %, the adhesion and makeup persistence of aqueous cosmetic decline, and when more than 5 mass %, makeup persistence is deteriorated.
[ingredient (c)]
The ingredient (c) of the present invention is tackifier, such as can enumerate carragheen, xanthans, dextrin, Methyl cellulose The natural polysaecharides such as element, hyaluronic acid, chitosan；Ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose etc. are semi-synthetic more Carbohydrate；Polyvinyl alcohol, polyacrylic acid, polymethylacrylic acid, carbopol (carboxyvinyl polymer), (acrylic acid/the third The synthesis macromolecules such as olefin(e) acid Arrcostab (carbon atom number is 10~30) copolymer.Wherein, from makeup persistence or not sticky angle Degree sets out, preferably xanthans, hydroxypropyl methyl cellulose, carbopol, ((carbon atom number is acrylic acid/alkyl acrylate 10~30) copolymer.
When ingredient (a), (b), (c) and gross mass (d) are set as 100 mass %, the content of ingredient (c) is 0.01~ 5 mass %, preferably 0.05~4 mass %, more preferably 0.1~3 mass %.When the content of ingredient (c) is less than 0.01 matter When measuring %, the adhesion of aqueous cosmetic declines, and when more than 5 mass %, makeup persistence is deteriorated.
[ingredient (d)]
The ingredient (d) of the present invention is water, and the water being typically used in cosmetics or pharmaceuticals etc. can be used.For example, can make With ion exchange water or purified water etc..
The content of ingredient (d) is remaining obtained from ingredient (a), (b) and total content (c) from being subtracted in 100 mass % Part.
[ratio of each ingredient]
In the present invention, it is 1/200 to account for the ingredient (b) of total composition relative to the mass ratio ((b)/(a)) of ingredient (a) ~1/6, preferably 1/150~1/10, more preferably 1/100~1/20.When (b)/(a) is less than 1/200, aqueous cosmetic Adhesion is insufficient, and when (b)/(a) is more than 1/6, the makeup persistence of aqueous cosmetic is deteriorated.
In the range of not damaging The effect of invention, other compositions can be added into the cosmetics for skin of the present invention.Make For other any ingredients, it can suitably add alcohols, polyalcohol, carbohydrate, polysaccharide, amino acid, various surfactants, have Machine salt, inorganic salts, pH adjusting agent, chelating agent, antioxidant, fungicide, blood flow ameliorant, antiphlogistic, ultra-violet absorber, purple Outside line scattering diluent, vitamins, pigment, fragrance etc..
(body detergent composition)
The body detergent composition of the present invention contains the ingredient (a), (b) and following compositions (e), (f).
[ingredient (a)]
Ingredient (a) be and the identical ingredient of ingredient (a).
Wherein, as the alcohol (Z (OH)p) carbon atom number when being more than 6, the frankness sense after cleaning is insufficient, therefore is set as 6 Hereinafter, but further preferably 3 or less.In addition, when the carbon atom number of the alcohol (Z (OH) p) is zero, as hydrogen atom when, The stability of foam when cleaning becomes inadequate, therefore is set as 1 or more.In addition, the valence mumber p when the alcohol (Z (OH) p) is more than When 6, the frank sense after cleaning declines, therefore is set as 6 hereinafter, but further preferably 3 or less.
When " p × m " is more than 70, foam duration when cleaning becomes inadequate, when less than 1, the frankness after cleaning Sense becomes inadequate.
" p × n " is 1~70, preferably 5~60, more preferably 10~50.It is refreshing after cleaning when " p × n " is more than 70 Pleasant sensation is insufficient, and when less than 1, foam duration when cleaning is insufficient.
" n/ (m+n) " is 0.15~0.75, preferably 0.30~0.72, more preferably 0.45~0.70.When the ratio is super When 0.75, the frankness sense after cleaning is insufficient, and foam duration when being cleaned if less than 0.15 is insufficient.
R1The alkyl for being 1~4 for carbon atom number.If R1Carbon atom number be 5 or more, then show surface-active, just clean For mildness this point when at secret and it is not suitable for.
When ingredient (a), (b), (e) and gross mass (f) are set as 100 mass %, the content of ingredient (a) is 0.1~ 25 mass %, preferably 0.5~20 mass %, more preferably 1~15 mass %.When the content of ingredient (a) is less than 0.1 mass % When, the frankness sense after cleaning is insufficient, and when the content of ingredient (a) is more than 25 mass %, the duration of foam when cleaning becomes It obtains insufficient.
[ingredient (b)]
Ingredient (b) be and the identical ingredient of ingredient (b).
X is oxyalkylene group A2The average addition molal quantity of O is 1~40, preferably 3~30, more preferably 5~20.Work as x When more than 40, foam duration when cleaning is insufficient, and when x is less than 1, the frankness sense after cleaning is insufficient.
Y is the average addition molal quantity of oxyethylene group EO, is 3~60, preferably 5~50, more preferably 10~30.Work as y When more than 60, the frank sense after cannot cleaning, when y is less than 3, foam when mildness when cleaning at secret, cleaning Duration is insufficient.
X/ (x+y) is 0.35~0.85, preferably 0.45~0.80, more preferably 0.50~0.70.When the ratio is less than When 0.35, foam duration when cleaning is insufficient, when more than 0.85, the frank sense after cannot cleaning.
The angle of mildness when at cleaning secret, oxyethylene group EO and oxyalkylene group A2O is carried out with random shape Addition.
Work as R2Carbon atom number be 5 or more when, show surface-active, just clean secret at when mildness this point and It says and is not suitable for.As the alkyl, methyl, ethyl, n-propyl, isopropyl, normal-butyl, sec-butyl, tertiary butyl etc. can be enumerated. Preferably methyl, normal-butyl.
When ingredient (a), (b), (e) and gross mass (f) are set as 100 mass %, the content of ingredient (b) is 0.01~ 5 mass %, preferably 0.05~4 mass %, more preferably 0.1~3 mass %.When the content of ingredient (b) is less than 0.01 matter When measuring %, the frankness sense after cleaning is insufficient, and when more than 5 mass %, foam duration when cleaning is insufficient.
[ingredient (e)]
The ingredient (e) of the present invention is amino acids anion surfactant.Amino acids anion table in the present invention Face activating agent refers to containing primary amino group, secondary amino group or tertiary amino and the compound of carboxylic acid or sulfonic acid and fat in same intramolecular The acylate of acid mainly reacts (Schotten-Baumann by the way that fat acyl chloride to be used as to the Xiao Deng-Bao Man of acylating agent ) etc. reaction manufactured.
As the compound for containing primary amino group, secondary amino group or tertiary amino and carboxylic acid or sulfonic acid in same intramolecular, can enumerate Go out natural acidity obtained from extraction method or fermentation method or neutral amino acid, is closed obtained from synthetic method or enzyme process At acidity or neutral amino acid.As the concrete example of amino acid, glutamic acid, aspartic acid, glycine, the third ammonia can be enumerated Acid, taurine, N-methyltaurine, sarcosine (sarcosine), Beta-alanine etc., may be present the respective L of these amino acid Body, D bodies, racemic modification, but can also use any one in them.
The type of the amino acids anion surfactant of acylate as above-mentioned amino acid, can be appropriate according to purpose Selection, such as acyl methyl taurine salt, acyl taurine salt, sulfonylmethyl-Beta-alanine or its salt, acyl group-can be enumerated Beta-alanine or its salt, acyl glutamic acid or its salt, acylglycine or its salt, acylaspartic acid or its salt, acyl group flesh ammonia Acid or its salt etc..Wherein, as can get abundant foam volume, at cleaning secret when the excellent amino acids the moon of mildness from Sub- surfactant, preferably acyl methyl taurine salt, sulfonylmethyl-Beta-alanine or its salt.
It as the salt, is not particularly limited, alkali metal salt, alkanol amine salt etc. can be enumerated.As the alkali metal Salt, such as sodium salt, sylvite can be enumerated etc., as the alkanol amine salt, such as monoethanolamine salt, triethanolamine can be enumerated Salt etc..In order to further increase the duration of foam, preferably alkali metal salt, most preferably sodium salt.
Though the carbon atom number of the acyl group of ingredient (e) is not particularly limited, it is achieved with abundant foam volume, cleaning secret For the excellent this point of mildness when place, preferably 8~18, more preferably 10~16, further preferably 12~14.
The content of ingredient (e) is 0.1~10 mass %, preferably 0.5~8 mass %, more preferably 1~5 mass %.When When the content of ingredient (e) is less than 0.1 mass %, the foam duration when frankness after cleaning is felt, cleans is insufficient, when more than 10 When quality %, with regard to not preferred for the mildness this point at secret.
[ingredient (f)]
The ingredient (f) of the present invention is water, and the water being typically used in cosmetics or pharmaceuticals etc. can be used.For example, can make With ion exchange water or purified water etc..
The content of ingredient (f) is remaining obtained from ingredient (a), (b) and total content (e) from being subtracted in 100 mass % Part.
[ratio of each ingredient]
In the present invention, account for the ingredient (b) of clean body agent total composition relative to ingredient (a) mass ratio ((b)/ (a)) it is 1/200~1/6, preferably 1/150~1/10, more preferably 1/100~1/20.When (b)/(a) is less than 1/200, For foam duration this point when cleaning and insufficient, when (b)/(a) is more than 1/6, the frank sense after cleaning is not filled Point.
[pH of body detergent composition]
The pH of cleaning agent in the present invention is 3~7, preferably 3.5~6.5, more preferably 4~6.If pH is in the model of invention Other than enclosing, then the mildness at secret is become inadequate.
In the range of not damaging The effect of invention, can to the present invention body detergent composition in add other at Point, as other any ingredients, it can suitably add alcohols, polyalcohol, carbohydrate, polysaccharide, amino acid, various surface-actives Agent, organic salt, inorganic salts, pH adjusting agent, chelating agent, antioxidant, fungicide, blood flow ameliorant, antiphlogistic, ultraviolet radiation absorption Agent, ultraviolet light scattering diluent, vitamins, pigment, fragrance etc..
(cosmetics)
The cosmetics of the present invention contain the ingredient (a), (b) and following compositions (g), (h).
[ingredient (a)]
This ingredient (a) is identical ingredient with the ingredient (a).
As the alcohol (Z (OH)p) carbon atom number when being more than 6, occur through when dry sensation, therefore be set as 6 hereinafter, but into One step is preferably 3 or less.In addition, when the carbon atom number of the alcohol (Z (OH) p) is zero, as hydrogen atom when, when losing smearing Smooth ductility, therefore be set as 1 or more.It is smooth when smearing in addition, when the valence mumber p of the alcohol (Z (OH) p) is more than 6 Ductility decline, therefore be set as 6 hereinafter, but further preferably 3 or less.
" p × m " is 1~70, preferably 3~50, more preferably 5~40.When " p × m " is more than 70, aqueous makeup removing is used Cleaning when material becomes inadequate, and when less than 1, smooth ductility when smearing becomes inadequate.
" p × n " is 1~70, preferably 5~60, more preferably 10~50.It is flat when smearing when " p × n " is more than 70 Sliding ductility is insufficient, when less than 1, generate through when dry sensation, it is thus not preferred.
" n/ (m+n) " is 0.15~0.75, preferably 0.30~0.72, more preferably 0.45~0.70.When the ratio is super When 0.75, smooth ductility when smearing is insufficient, if being less than 0.15, cleaning when using aqueous cosmetic removing material is not Fully, generate through when dry sensation, it is thus not preferred.
If R1Carbon atom number be 5 or more, then show surface-active, generate through when dry sensation, thus be not suitable for.As The alkyl can enumerate methyl, ethyl, n-propyl, isopropyl, normal-butyl, sec-butyl, tertiary butyl etc..Preferably methyl, second Base.
When ingredient (a), (b), (g) and gross mass (h) are set as 100 mass %, the content of ingredient (a) is 0.1~ 25 mass %, preferably 0.5~20 mass %, more preferably 1~15 mass %.When the content of ingredient (a) is less than 0.1 mass % When, smooth ductility when smearing is insufficient, generate through when dry sensation.On the other hand, when the content of ingredient (a) is more than 25 When quality %, it is difficult to ensure the stability of preparation.
[ingredient (b)]
This ingredient (b) be and the identical ingredient of ingredient (b).
X is oxyalkylene group A2The average addition molal quantity of O is 1~40, preferably 3~30, more preferably 5~20.Work as x When more than 40, cleaning when using aqueous cosmetic removing material is insufficient, and when x is less than 1, smooth ductility when smearing is not filled Point.
Y is the average addition molal quantity of oxyethylene group EO, is 3~60, preferably 5~50, more preferably 10~30.Work as y When more than 60, smooth ductility when smearing is insufficient, and when y is less than 3, cleaning when using aqueous cosmetic removing material does not fill Point, can experience through when dry sensation.
X/ (x+y) is 0.35~0.85, preferably 0.45~0.80, more preferably 0.50~0.70.When the ratio is less than When 0.35, cleaning when using aqueous cosmetic removing material is insufficient, generate through when dry sensation, it is thus not preferred.When more than When 0.85, smooth ductility when smearing is insufficient.
Never generate through when the angle of dry sensation set out, oxyethylene group EO and oxyalkylene group A2O is added with random shape At.
Work as R2Carbon atom number be 5 or more when, show surface-active, just generation through when dry sensation this point for simultaneously It is not suitable for.As the alkyl, methyl, ethyl, n-propyl, isopropyl, normal-butyl, sec-butyl, tertiary butyl etc. can be enumerated.It is preferred that For methyl, normal-butyl.
When ingredient (a), (b), (g) and gross mass (h) are set as 100 mass %, the content of ingredient (b) is 0.01~ 5 mass %, preferably 0.05~4 mass %, more preferably 0.1~3 mass %.When the content of ingredient (b) is less than 0.01 matter When measuring %, cleaning when using aqueous cosmetic removing material is insufficient, and when more than 5 mass %, the storage stability of preparation becomes It is insufficient.
[ingredient (g)]
Ingredient (g) is powder, and powder is typically used in cosmetics, there is a shapes such as spherical, plate, needle-shaped, smoke-like, micro- The grain sizes such as grain, pigment-level, porous, non-porous equal grain structures etc., are not particularly limited, can enumerate inorganic particle class, light Brightness powder (luster powder) class, organic powder class, pigment powder class, metal-powder class, composite granule class etc..
About ingredient (g), specifically, the white inorganics face such as titanium oxide, zinc oxide, cerium oxide, barium sulfate can be enumerated Material, the colored inorganics pigment such as iron oxide, carbon black, titanium-titanium oxide sinter, chromium oxide, chromium hydroxide, Prussian blue, ultramarine, two Silica, talcum, muscovite, phlogopite, rubellan, biotite, synthetic mica, sericite (sericite), synthesis sericite, Kaolin, silicon carbide, bentonite, smectite, aluminium oxide, magnesia, zirconium oxide, antimony oxide, diatomite, alumina silicate, positive silicic acid The white constitution powder such as magnalium, calcium silicates, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, oxidation The mica of titanium coating, the bismuth oxychloride of titanium oxide coating, iron oxide mica titanium, Prussian blue processing mica titanium, fuchsin handle cloud Female titanium, bismuth oxychloride, guanin, polyethylene terephthalate-aluminium-epoxy stacked film powder, poly terephthalic acid second two Alcohol ester-polyolefin stacked film powder, polyethylene terephthalate-polymethyl methacrylate layers fold the photoluminescents such as film powder Powder, polyamide-based resin, polythylene resin, polyacrylics, polyester resin, fluorine resin, cellulose family tree The copolymer resins such as fat, polystyrene resins, Styrene And Chloroalkyl Acrylates copolymer resins, polypropylene-based resin, carbamate tree The organic polymer resins powder such as fat, the organic low moleculars powders such as zinc stearate, N- acyl-lysines, Silk Powder (silk Powder), the natural organic powder such as cellulose powder, dextrin powder, it is No. 201 red, No. 202 red, No. 205 red, red No. 226, No. 228 red, No. 203 orange, No. 204 orange, blue 404, yellow 401 etc. or it is No. 3 red, No. 104 red, Red No. 106, No. 205 orange, yellow 4, Sunset Yellow FCF, green 3, zirconium, barium or the aluminum lake of blue 1 etc. etc. it is organic Powder pigment, or can further enumerate the metal-powders such as aluminium powder, bronze, silver powder, it is the mica titanium of particulate titanium dioxide coating, micro- The mica titanium of grain zinc oxide coated, the mica titanium of barium sulfate coating, the silica containing titanium oxide, the silica containing zinc oxide Equal composite granules, fibers such as nylon, polyester, staple fibre, cellulose etc..These substances can also utilize fluorine compounds, silicone oil, Powder, finish, gelating agent, emulsion polymer, surfactant etc. are surface-treated.These powders can use it is a kind of or It is two or more, it can also use and further carry out the powder of Composite.
When ingredient (a), (b), (g) and gross mass (h) are set as 100 mass %, the content of ingredient (g) is 25~50 Quality %, preferably 30~45 mass %, more preferably 35~45 mass %.When the content of ingredient (g) is less than 25 mass %, Smooth ductility is insufficient, when more than 50 mass %, generate through when dry sensation.
[ingredient (h)]
Ingredient (h) is as long as that finish is not particularly limited, can make to be typically used in the finish in cosmetics With one or more kinds of finishes.Specifically, dimethyl polysiloxane, methyl phenyl silicone, hexichol can be enumerated The chains polysiloxanes such as based polysiloxane, methylhydrogenpolysi,oxane (methyl hydrogen polysiloxane)；Prestox The cyclic annular poly- silicon such as cyclotetrasiloxane, decamethylcyclopentaandoxane, ten diformazan basic rings, six siloxanes, tetramethyl tetrahydrochysene cyclotetrasiloxane Oxygen alkane；Amino modified polysiloxane, Siloxane-Oxyalkylene Copolymers, alkyl-modified polysiloxanes, fluorine richness polysiloxanes etc. are various Modified polyorganosiloxane；The hydrocarbon ils such as atoleine, Parleam, saualane, olefin oligomer；Ethylhexyl palmitate, meat Isopropyl myristate, thylhexoic acid hexadecyl ester, three (caprylic/capric) glyceride etc. synthesize ester oil；Avocado oil, camellia oil, Australia The vegetable fat such as macadamia nut oil, the solid oils such as cocoa butter, house oil, solidification coconut oil, palm oil, haze tallow, beeswax, solidification castor oil Fat；Beeswax, candelila wax, cotton wax, Brazil wax, lanolin, polyethylene wax, microwax, paraffin, ceresine, (ethylene/propene) The solid fats such as copolymer.
Wherein, if unthickened fuel, then it is preferable to use dimethyl polysiloxane, macadimia nut oil, saualane, the poly- isobutyls of hydrogenation Alkene etc., if solid fat, then it is preferable to use haze tallow, Brazil wax, beeswax, candelila wax, microwax, candelila wax, beeswaxs Deng.
When ingredient (a), (b), (g) and gross mass (h) are set as 100 mass %, the content of ingredient (h) is 30~70 Quality %, preferably 35~65 mass %, more preferably 40~60 mass %.When the content of ingredient (h) is less than 30 mass %, It is difficult to stably keep the shape of preparation, when more than 70 mass %, cleaning when using aqueous cosmetic removing material, when smearing Smooth ductility is insufficient.
[ratio of each ingredient]
In the present invention, the ingredient (b) for accounting for oil-based cosmetic preparation total amount is relative to the mass ratio ((b)/(a)) of ingredient (a) 1/200~1/6, preferably 1/150~1/10, more preferably 1/100~1/20.When (b)/(a) is less than 1/200, water is used Cleaning when property cosmetic removing material is insufficient, and when (b)/(a) is more than 1/6, smooth ductility when smearing is insufficient, can feel By through when dry sensation.
In the range of not damaging The effect of invention, other compositions can be added into the oil-based cosmetic preparation of the present invention.Make For other any ingredients, it can suitably add alcohols, polyalcohol, carbohydrate, polysaccharide, amino acid, various surfactants, have Machine salt, inorganic salts, pH adjusting agent, chelating agent, antioxidant, fungicide, blood flow ameliorant, antiphlogistic, ultra-violet absorber, dimension Raw element class, pigment, fragrance etc..
Embodiment
The embodiment of the preparation example of (b) and cosmetics for skin (ingredient (a))
Hereinafter, the present invention is specifically described by embodiment.
First, each compound shown in table 1 has been synthesized.
1~a2 of ＜ compound as, compound a ' 1, a ' 3, a ' 4 synthesis ＞
Alcohol shown in table 1 by 1 mole and relative to alkylene oxide derivative final weight be 0.1 mass % conduct urge The potassium hydroxide of agent is added in autoclave, after the air in autoclave is replaced with drying nitrogen, at 140 DEG C while stirring Catalyst is set to be completely dissolved.Then Dropping feeder is utilized, p × n moles of ethylene oxide and p × m moles of propylene oxide is added dropwise Mixture so that it has been reacted at 140 DEG C 2 hours after completion of dropwise addition.Then, the potassium hydroxide of p × 2 mole is added, with After drying nitrogen replaces autoclave, it is pressed into the chloromethanes of p × 3 mole at a temperature of 80~130 DEG C, it is made to react 5 hours.Then, response composite is taken out from autoclave, with hydrochloric acid neutralize makes pH for 6~7, contained in order to remove Moisture has carried out dehydration in 1 hour under conditions of decompression -0.095MPa (50m mHg), 100 DEG C.Further, in order to remove The salt that is generated due to dehydration and be filtered, obtained compound a 1, a2, a ' 1, a ' 3, a ' 4.
The hydroxyl value for having confirmed these compounds is respectively less than 0.1, and hydrogen atom almost all becomes methyl.
The synthesis ＞ of ＜ compound as 3
It is catalyzed by 1 mole of propylene glycol (PG) and relative to the conduct that alkylene oxide derivative final weight is 0.1 mass % The potassium hydroxide of agent is added in autoclave, after the air in autoclave is replaced with drying nitrogen, is made while stirring at 140 DEG C Catalyst is completely dissolved.Then Dropping feeder is utilized, 41 moles of propylene oxide has been added dropwise.Then 36 moles of epoxy second is added dropwise Alkane makes it react 2 hours after completion of dropwise addition at 140 DEG C.Then, 4 moles of potassium hydroxide is added, with drying nitrogen After replacing autoclave, the chloromethanes of 6 moles of indentation, makes it react 5 hours at a temperature of 80~130 DEG C.Then, Response composite is taken out from autoclave, with hydrochloric acid neutralize makes pH for 6~7, in order to remove contained moisture, is subtracting Pressure -0.095MPa (50mmHg), the dehydration that 1 hour has been carried out under conditions of 100 DEG C.Further, it is given birth to because of dehydration to remove At salt and be filtered, obtained compound a 3.
The hydroxyl value for having confirmed compound a 3 is less than 0.1, and hydrogen atom almost all becomes methyl.
The synthesis ＞ of ＜ compound as 4, a5, a6
It is used as catalyst by 1 mole of pentaerythrite and relative to alkylene oxide derivative final weight for 0.1 mass % Potassium hydroxide be added in autoclave, with drying nitrogen replace autoclave in air after, make to urge while stirring at 140 DEG C Agent is completely dissolved.Then Dropping feeder is utilized, 15 moles of propylene oxide and 40,50 or 42 moles of ethylene oxide has been added dropwise Mixture, so that it has been reacted at 140 DEG C 2 hours.Then, 8 moles of potassium hydroxide is added, high pressure is replaced with drying nitrogen After inside kettle, it is pressed into 10 moles of chloromethanes at a temperature of 80~130 DEG C, it is made to have reacted 5 hours.Then, from autoclave Middle taking-up response composite, with hydrochloric acid neutralize makes pH for 6~7, in order to remove contained moisture, in decompression- 0.095MPa (50mmHg), the dehydration that 1 hour has been carried out under conditions of 100 DEG C.Further, it is generated because of dehydration to remove Salt and be filtered, obtained compound a 4, a5, a6.
The hydroxyl value of compound a 4, a5, a6 are confirmed less than 0.1, hydrogen atom almost all becomes methyl.
The synthesis ＞ of ＜ compound as ' 2
By the work of the ethyl alcohol of 1 mole (46g) and 1.07g (being 0.1 mass % relative to alkylene oxide derivative final weight) It is added in autoclave for the potassium hydroxide of catalyst, after the air in autoclave is replaced with drying nitrogen, is stirred below at 140 DEG C Mixing side makes catalyst be completely dissolved.Then Dropping feeder is utilized, the ethylene oxide and 7 moles (406g) of 14 moles (616g) is added dropwise Propylene oxide mixture, after completion of dropwise addition, it is made to have reacted at 140 DEG C 2 hours.Then, 2 moles are added The 1- bromo-octadecanes of the potassium hydroxide of (56.1g) and 5 moles (1667g) make after replacing autoclave with drying nitrogen It has been reacted 5 hours.Then, response composite is taken out from autoclave, with hydrochloric acid neutralize makes pH for 6~7, in order to remove Contained moisture has carried out dehydration in 1 hour under conditions of decompression -0.095MPa (50mmH g), 100 DEG C.Further, It is filtered to remove the salt generated due to dehydration, ' 2 that obtained compound a.
The hydroxyl value for ' 2 that confirmed compound a is 0.08, and hydrogen atom almost all becomes methyl.
' 1 ＜ compounds b1, b2, b, b ' 2 synthesis ＞
By alcohol shown in 1 mole of following table 2 and relative to the work that alkylene oxide derivative final weight is 0.1 mass % It is added in autoclave for the potassium hydroxide of catalyst, after the air in autoclave is replaced with drying nitrogen, is stirred below at 140 DEG C Mixing side makes catalyst be completely dissolved.Then Dropping feeder, the ethylene oxide of x moles of dropwise addition and y moles of propylene oxide are utilized Mixture (compound b ' 1 is only ethylene oxide, and compound b ' 2 is only propylene oxide), after completion of dropwise addition, makes it at 140 DEG C It has reacted 2 hours.Then, response composite is taken out from autoclave, with hydrochloric acid neutralize makes pH for 6~7, in order to remove The moisture contained has carried out dehydration in 1 hour under conditions of decompression -0.095MPa (50mmHg), 100 DEG C.Further, in order to It removes the salt that is generated due to dehydration and is filtered, obtained compound b1, b2, b ' 1, b ' 2.
The preparation method ＞ of ＜ All-in-One beautifying liquids
(1) when using arginine, previously prepared 10% aqueous solution.
(2) dispersing mixer blending constituent (d) (ion exchange water), while a small amount of addition and solvent components by several times are used (c)。
(3) and then adding ingredient (a), ingredient (b) and other compositions it, is stirred until homogeneous.
＜ evaluation methods ＞
The use feeling test of 20 special subjects is carried out.The prepared All-in-One beautifying liquid of 0.2g is taken at hand In, wrist inside portion before being applied to makes every subject pass through following absolute evaluations, with 0 point~3 points of four grades, is applied to (1) The adhesion of moistening, (2) aqueous cosmetic, the duration of (3) aqueous cosmetic when smearing are evaluated.Then, according to Adding up to for scoring, is divided into five grades of AA~D, AA, A and B is chosen as qualification.
Total final evaluation ＞s of the ＜ based on absolute score
AA：Scoring adds up to 50~60 points
A：Scoring adds up to 40~49 points
B：Scoring adds up to 30~39 points
C：Scoring adds up to 20~29 points
D：The total of scoring is less than 20 points
(1) moistening when smearing
(absolute evaluation standard)
(scoring)：(evaluation)
3：Moistening when smearing is extremely good
2：Moistening when smearing is good
1：Almost it is not felt by moistening when smearing
0：It is not felt by moistening when smearing completely
(2) adhesion of aqueous cosmetic
Prepared All-in-One beautifying liquid is set after percutaneous absorption, to be coated with the commercially available aqueous cosmetic of 0.1g, with following Standard has rated the adhesion to skin.
(absolute evaluation standard)
(scoring)：(evaluation)
3：The adhesion of aqueous cosmetic is extremely good
2：The adhesion of aqueous cosmetic is good
1：The adhesion of aqueous cosmetic is not very good
0：Aqueous cosmetic is completely non-cohesive
(3) duration of aqueous cosmetic
With following standards, the duration after 6 hours of the aqueous cosmetic smeared in the manner is carried out Evaluation.
(absolute evaluation standard)
(scoring)：(evaluation)
3：The duration of aqueous cosmetic is extremely good, and makeup film is not affected by destruction
2：The duration of aqueous cosmetic is good, and makeup film is almost not affected by destruction
1：The duration of aqueous cosmetic is not very good, and part makeup film is destroyed
0：The duration of aqueous cosmetic is poor, and makeup film almost all is destroyed
1~12 ＞ of ＜ Examples 1 to 6 and comparative example
All-in-One beautifying liquid is prepared by above-mentioned method, and is evaluated.Formula and result are shown in 3~table of table 5 In.In addition, in all formulas, prepared with the scale (scale) of 100g.
About Examples 1 to 6, each formula has obtained the use feeling of water profit when smearing, and aqueous cosmetic is to skin Adhesion and makeup persistence are good.
On the other hand, about comparative example 1~12, sufficient effect is not obtained.
That is, in comparative example 1~4, compare ingredient (a ') due to containing, there is the model of the not ingredient (a) in the present invention Interior structure is enclosed, therefore fails the effect for meeting the present invention simultaneously.In comparative example 5,6, compare ingredient due to containing to have (b ') has the structure not in the range of the ingredient (b) of the present invention, therefore fails the effect for meeting the present invention simultaneously.
In comparative example 7, due to being free of ingredient (b), the adhesion of aqueous cosmetic is insufficient.In comparative example 8, Since b/a is more than 1/6, the duration of aqueous cosmetic is insufficient.In comparative example 9, due to ingredient (a) and ingredient (b) Content be more than 25 mass %, 5 mass % respectively, therefore all effects are all insufficient.
In comparative example 10, due to being free of ingredient (a), the duration of moistening and aqueous cosmetic when smearing is not Fully.In comparative example 11, since the content of ingredient (c) is 6.0 mass %, it is higher than the scope of the present invention, in comparative example 12, Since the content of ingredient (c) is 0 mass %, fail the effect for meeting the present invention simultaneously.
(embodiment of body detergent composition)
The preparation method ＞ of ＜ body detergents
By following step, it is prepared for body detergent.
At room temperature, hydroxypropyl methyl cellulose is scattered in ion exchange water, is warming up to 45 DEG C.
After confirming dissolving, the remaining raw material in addition to citric acid is all added.
Utilize lemon acid for adjusting pH.
＜ evaluation methods ＞
The use feeling test of 20 women (20~40 years old) is carried out.The prepared body detergent of 1g is taken at hand In, after fully getting foam with palm, every subject is made to pass through following absolute evaluations, with 0 point~3 points of four grades, The frank sense after foam duration, (3) cleaning when being cleaned to the mildness at secret, (2) to (1) is evaluated.Then, According to the total of scoring, it is divided into five grades of AA~D, AA, A and B is chosen as qualification.
Total final evaluation ＞s of the ＜ based on absolute score
AA：Scoring adds up to 50~60 points
A：Scoring adds up to 40~49 points
B：Scoring adds up to 30~39 points
C：Scoring adds up to 20~29 points
D：The total of scoring is less than 20 points
(1) to the mildness at secret
(absolute evaluation standard)
(scoring)：(evaluation)
3：Mild cleaning has fully been experienced in cleaning and after cleaning
2：Mild cleaning has been experienced in cleaning and after cleaning
1：Mild cleaning is not almost experienced in cleaning and after cleaning
0：Mild cleaning is not experienced completely in cleaning and after cleaning
(2) foam duration when cleaning
(absolute evaluation standard)
(scoring)：(evaluation)
3：When cleaning at secret, the decline of foam volume is not almost experienced
2：When cleaning at secret, the decline of foam volume is slightly experienced
1：When cleaning at secret, it will be apparent that experience the decline of foam volume
0：When cleaning at secret, foam disappears at once.
(3) the frank sense after cleaning
(absolute evaluation standard)
(scoring)：(evaluation)
3：Salubrious frank sense is fully obtained after cleaning
2：Frank sense is obtained after cleaning
1：Frank sense is not almost obtained after cleaning
0：Frank sense after not cleaned
1~13 ＞ of ＜ Examples 1 to 6 and comparative example
Body detergent is prepared by above-mentioned method, and is evaluated.Formula and result are shown in table 6, table 7 and table In 8.In addition, in all formulas, prepared with the scale of 100g.
About Examples 1 to 6, have to the mildness at secret, foam duration when cleaning at secret is excellent, cleaning Frank sense afterwards is also good.
In contrast, about comparative example 1~13, fail to obtain three effects simultaneously.
That is, in comparative example 1, although having used the carbon atom number for the alcohol for constituting Z and big compound a ' 1 of alcohol valence number, Frank sense after foam duration, cleaning when cleaning is poor.
In comparative example 2, although having used R1Big compound a ' 2 of carbon atom number, but each characteristic inequality.
In comparative example 3, although compound a ' 3 for having used n/ (m+n) big, at secret mildness and cleaning after Frank sense it is poor.
It is foam duration when cleaning, clear although the compound a for having used p × m, p × n big ' 4 in comparative example 4 Frank sense after washing is poor.
In comparative example 5, although having used R2Big, the non-addition propylene oxide of carbon atom number compound b ' 1, but to private The mildness of Mi Chu and the frankness after cleaning feel poor.
In comparative example 6, although having used the compound b ' 2 of non-addition of ethylene oxide, each characteristic inequality.
In comparative example 7, although compound (b), each characteristic inequality is not used.
In comparative example 8, although component ratio (b)/(a) is high, each characteristic inequality.
In comparative example 9, although the adding proportion of compound a 2, b2 are high, component ratio (b)/(a) is high, and each characteristic is equal Difference.
In comparative example 10, although being not added with compound (a), each characteristic inequality.
In comparative example 11, although being not added with ingredient (e), each characteristic inequality.
In comparative example 12, although the additive amount of ingredient (e) is big, to the mildness at secret and the frank sense after cleaning Difference.
In comparative example 13, although reducing the pH of body detergent composition, each characteristic inequality.
(embodiment of oil-based cosmetic preparation)
The preparation method ＞ of ＜ powder foundations (powdery foundation)
By following step, it is prepared for powder foundation.
(1) ingredient (h) is dissolved by heating at 100 DEG C, is mixed.
(2) ingredient (a), (b), (g) are added into ingredient (h), is cooled down using roll mill, while making it uniformly Ground disperses.
(3) it is filled at 90 DEG C in resin ware.
＜ evaluation methods ＞
The use feeling test of 20 women (20~40 years old) is carried out.Each subject is set to pass through following absolute evaluations, with 0 point ~3 points of four grades, the presence or absence of ductility, (2) dry sensation when to using (1) when prepared powder foundation to smear, And (3) using aqueous cosmetic removing material when cleaning evaluated.Then, according to the total of scoring, it is divided into the five of AA~D AA, A and B are chosen as qualification by a grade.
Total final evaluation ＞s of the ＜ based on absolute score
AA：Scoring adds up to 50~60 points
A：Scoring adds up to 40~49 points
B：Scoring adds up to 30~39 points
C：Scoring adds up to 20~29 points
D：The total of scoring is less than 20 points
(1) ductility when smearing
(absolute evaluation standard)
(scoring)：(evaluation)
3：Ductility when smearing is extremely good
2：Ductility when smearing is good
1：Ductility when smearing is slightly worse
0：Poor ductility when smearing
(2) the presence or absence of dry sensation
With following standards, the dry sensation of the skin after smearing 8 hours is evaluated.
(absolute evaluation standard)
(scoring)：(evaluation)
3：It is not felt by dry sensation completely
2：Dry sensation is experienced slightly
1：Experience dry sensation
0：Consumingly experience dry sensation
(3) using aqueous cosmetic removing material cleaning when
Commercially available makeup remover is impregnated in cotton pads, with following standards, takes cleaning when foundation cream to carry out wiping Evaluation.
(absolute evaluation standard)
(scoring)：(evaluation)
3：Foundation cream can almost entirely be removed
2：The residual of a little foundation cream is confirmed
1：The residual of foundation cream is clearly confirmed
0：Almost fail to remove foundation cream.
1~10 ＞ of ＜ Examples 1 to 6 and comparative example
Powder foundation is prepared by above-mentioned method, and is evaluated.Formula and result are shown in table 9, table 10 and table In 11.In addition, in all formulas, prepared with the scale of 100g.In addition, the "-" table described in the value column of table 11 Show and the undesirable conditions such as do not cure or do not assemble due to having confirmed separation immediately after preparation or having confirmed preparation, not It is evaluated.
[table 9]
[table 10]
[table 11]
About Examples 1 to 6, can be readily removable using aqueous cosmetic removing material, have smooth ductility, through when The presence or absence of dry sensation aspect it is also good.
On the other hand, about comparative example 1~10, sufficient effect is not obtained.In comparative example 1~4, due to the use of at this Ingredient (a ') other than the range of invention replaces ingredient (a), therefore each characteristic is deteriorated.
In comparative example 5,6, ingredient (b) is replaced due to the use of ingredient (b ') other than the scope of the present invention, therefore Each characteristic is deteriorated.
In comparative example 7, due to not containing ingredient (b), cleaning when using aqueous cosmetic removing material is insufficient.
In comparative example 8,9,10, since the content of ingredient (a), ingredient (g), ingredient (h) has been more than the model of invention respectively It encloses, therefore fails to obtain stable preparation.

Claims (3)

1. a kind of cosmetics for skin, which is characterized in that the following compositions (a) containing 0.1~25 mass %, 0.01~5 mass % Following compositions (b), the following compositions (c) and following compositions (d) of 0.01~5 mass %, ingredient (b) is relative to ingredient (a) Mass ratio (b)/(a) is 1/200~1/6,
Ingredient (a) is the polyalkylene oxide derivative represented by following formula (1),
Z-[O(A1O)m(EO)n-R1]p···(1)
In formula (1), Z be 1~6 from carbon atom number alcohol in eliminate residue made of all hydroxyls, p is the valence of the alcohol Number is 1 or more, 6 hereinafter, R1The alkyl for being 1~4 for carbon atom number, A1O is the oxyalkylene group that carbon atom number is 3~4, and EO is oxygen Vinyl, the oxyalkylene group A in the derivative1Average addition molal quantity p × m of O meets 1≤p × m≤70, described Average addition molal quantity p × n of the oxyethylene group EO in derivative meets 1≤p × n≤70, the oxyethylene group EO's Average addition molal quantity is relative to the oxyalkylene group A1The average addition of the average addition molal quantity and the oxyethylene group EO of O Total ratio n/ (m+n) of molal quantity is 0.15~0.75,
Ingredient (b) is the alkylene oxide derivative represented by following formula (2),
R2O-[(A2O)x(EO)y]-H···(2)
In formula (2), R2The alkyl for being 1~4 for carbon atom number, A2O is the oxyalkylene group that carbon atom number is 3, and EO is oxyethylene group, x For the oxyalkylene group A2The average addition molal quantity of O meets 1≤x≤40, and y is that the average addition of the oxyethylene group EO rubs That number meets 3≤y≤60, and the average addition molal quantity of the oxyethylene group EO is relative to the oxyalkylene group A2The average of O adds Total ratio x/ (x+y) at the average addition molal quantity of molal quantity and the oxyethylene group EO is 0.35~0.85, described Oxyalkylene group A2The O and oxyethylene group EO carries out addition with random shape,
Ingredient (c) is tackifier,
Ingredient (d) is water.
2. a kind of body detergent composition, which is characterized in that the following compositions (a) containing 0.1~25 mass %, 0.01~5 The following compositions (e) and following compositions (f) of the following compositions (b) of quality %, 0.1~10 mass %, the ingredient (b) relative to Mass ratio (b)/(a) of the ingredient (a) is that 1/200~1/6, pH is 3~7,
Ingredient (a) is the polyalkylene oxide derivative represented by following formula (1),
Z-[O(A1O)m(EO)n-R1]p···(1)
In formula (1), Z be 1~6 from carbon atom number alcohol in eliminate residue made of all hydroxyls, p is the valence of the alcohol Number is 1 or more, 6 hereinafter, R1The alkyl for being 1~4 for carbon atom number, A1O is the oxyalkylene group that carbon atom number is 3~4, and EO is oxygen Vinyl, the oxyalkylene group A in the polyalkylene oxide derivative1Average addition molal quantity p × m satisfactions 1≤p × m of O≤ Average addition molal quantity p × n of 70, the oxyethylene group EO in the polyalkylene oxide derivative meet 1≤p × n≤70, institute The average addition molal quantity of oxyethylene group EO is stated relative to the oxyalkylene group A1The average addition molal quantity of O and the ethylene oxide Total ratio n/ (m+n) of the average addition molal quantity of base EO is 0.15~0.75,
Ingredient (b) is the alkylene oxide derivative represented by following formula (2),
R2O-[(A2O)x(EO)y]-H···(2)
In formula (2), R2The alkyl for being 1~4 for carbon atom number, A2O is the oxyalkylene group that carbon atom number is 3, and EO is oxyethylene group, x For the oxyalkylene group A2The average addition molal quantity of O meets 1≤x≤40, and y is that the average addition of the oxyethylene group EO rubs That number meets 3≤y≤60, and the average addition molal quantity of the oxyethylene group EO is relative to the oxyalkylene group A2The average of O adds Total ratio x/ (x+y) at the average addition molal quantity of molal quantity and the oxyethylene group EO is 0.35~0.85, described Oxyalkylene group A2The O and oxyethylene group EO carries out addition with random shape,
Ingredient (e) is amino acids anion surfactant,
Ingredient (f) is water.
3. a kind of oil-based cosmetic preparation, which is characterized in that the following compositions (a) containing 0.1~25 mass %, 0.01~5 mass % Following compositions (b), the following compositions (h) of the following compositions (g) of 25~50 mass % and 30~70 mass %, the ingredient (b) it is 1/200~1/6 relative to mass ratio (b)/(a) of the ingredient (a),
Ingredient (a) is the polyalkylene oxide derivative represented by following formula (1),
Z-[O(A1O)m(EO)n-R1]p···(1)
In formula (1), Z be 1~6 from carbon atom number alcohol in eliminate residue made of all hydroxyls, p is the valence of the alcohol Number is 1 or more, 6 hereinafter, R1The alkyl for being 1~4 for carbon atom number, A1O is the oxyalkylene group that carbon atom number is 3~4, and EO is oxygen Vinyl, the oxyalkylene group A in the polyalkylene oxide derivative1Average addition molal quantity p × m satisfactions 1≤p × m of O≤ Average addition molal quantity p × n of 70, the oxyethylene group EO in the polyalkylene oxide derivative meet 1≤p × n≤70, institute The average addition molal quantity of oxyethylene group EO is stated relative to the oxyalkylene group A1The average addition molal quantity of O and the ethylene oxide Total ratio n/ (m+n) of the average addition molal quantity of base EO is 0.15~0.75,
Ingredient (b) is the alkylene oxide derivative represented by following formula (2),
R2O-[(A2O)x(EO)y]-H···(2)
In formula (2), R2The alkyl for being 1~4 for carbon atom number, A2O is the oxyalkylene group that carbon atom number is 3, and EO is oxyethylene group, x For the oxyalkylene group A2The average addition molal quantity of O meets 1≤x≤40, and y is that the average addition of the oxyethylene group EO rubs That number meets 3≤y≤60, and the average addition molal quantity of the oxyethylene group EO is relative to the oxyalkylene group A2The average of O adds Total ratio x/ (x+y) at the average addition molal quantity of molal quantity and the oxyethylene group EO is 0.35~0.85, described Oxyalkylene group A2The O and oxyethylene group EO carries out addition with random shape,
Ingredient (g) is powder,
Ingredient (h) is finish.
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