CN101115699B - 控制苯乙烯类单体与磺酸的放热反应的手段 - Google Patents
控制苯乙烯类单体与磺酸的放热反应的手段 Download PDFInfo
- Publication number
- CN101115699B CN101115699B CN2006800040290A CN200680004029A CN101115699B CN 101115699 B CN101115699 B CN 101115699B CN 2006800040290 A CN2006800040290 A CN 2006800040290A CN 200680004029 A CN200680004029 A CN 200680004029A CN 101115699 B CN101115699 B CN 101115699B
- Authority
- CN
- China
- Prior art keywords
- group
- alkyl
- aryl
- compound
- inhibitor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 0 Cc1c(*)c(*)c(*)c(N(*)O)c1* Chemical compound Cc1c(*)c(*)c(*)c(N(*)O)c1* 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B63/00—Purification; Separation; Stabilisation; Use of additives
- C07B63/04—Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
- C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
- C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
- C07C15/46—Styrene; Ring-alkylated styrenes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64956305P | 2005-02-04 | 2005-02-04 | |
| US60/649,563 | 2005-02-04 | ||
| PCT/US2006/003487 WO2006083923A1 (en) | 2005-02-04 | 2006-01-31 | Means for controlling the exothermic reaction of styrenic monomers with sulfonic acids |
| US11/345,194 US8013083B2 (en) | 2005-02-04 | 2006-01-31 | Means for controlling the exothermic reaction of styrenic monomers with sulfonic acids |
| US11/345,194 | 2006-01-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101115699A CN101115699A (zh) | 2008-01-30 |
| CN101115699B true CN101115699B (zh) | 2011-09-14 |
Family
ID=36592989
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006800040290A Expired - Fee Related CN101115699B (zh) | 2005-02-04 | 2006-01-31 | 控制苯乙烯类单体与磺酸的放热反应的手段 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8013083B2 (https=) |
| EP (1) | EP1843995B1 (https=) |
| JP (1) | JP4686550B2 (https=) |
| KR (1) | KR101276975B1 (https=) |
| CN (1) | CN101115699B (https=) |
| BR (1) | BRPI0606801A2 (https=) |
| CA (1) | CA2593400C (https=) |
| ES (1) | ES2441429T3 (https=) |
| MX (1) | MX2007009236A (https=) |
| RU (1) | RU2393143C2 (https=) |
| WO (1) | WO2006083923A1 (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2006051941A1 (ja) * | 2004-11-15 | 2008-05-29 | 伯東株式会社 | ジビニルベンゼンと芳香族ビニル化合物を含む共重合体の重合抑制方法 |
| KR101625049B1 (ko) * | 2011-11-29 | 2016-05-27 | 도르프 케탈 케미칼즈 (인디아) 프라이비트 리미티드 | 스티렌의 중합의 조절 및 억제를 위한 아민 기반 첨가제 조성물 및 그 이용 방법 |
| WO2013102930A1 (en) * | 2011-12-26 | 2013-07-11 | Dorf Ketal Chemicals (India) Private Limited | Improved amine based additive composition for control and inhibition of polymerization of aromatic vinyl monomers, and method of use thereof |
| CN108341736A (zh) * | 2017-01-23 | 2018-07-31 | 中国石油化工股份有限公司 | 一种复配阻聚剂及其应用 |
| CN112512470B (zh) | 2018-04-02 | 2023-05-05 | 聚合物绿色有限责任公司 | 用于处理非织造网的液体聚合物溶液 |
| US12128144B2 (en) | 2018-04-02 | 2024-10-29 | Polygreen Ltd | Process for the production of biodegradable superabsorbent polymer with high absorbency under load based on styrene maleic acid copolymers and biopolymer |
| TW202005938A (zh) * | 2018-07-13 | 2020-02-01 | 美商藝康美國公司 | 具有胺穩定劑之聚合抑制劑及阻滯劑組合物 |
| WO2020102227A1 (en) | 2018-11-13 | 2020-05-22 | Green Polymers Ltd. | Polymeric composition for use as soil conditioner with improved water absorbency during watering of the agricultural crops |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5824829A (en) * | 1993-12-16 | 1998-10-20 | Baker Hughes Incorporated | Hydrocarbon viscosity inhibitor and inhibiting method |
| CN1505599A (zh) * | 2001-04-25 | 2004-06-16 | ������������ʽ���� | 抑制芳香族乙烯基化合物聚合的方法 |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US665344A (en) * | 1900-04-02 | 1901-01-01 | Anders Andersen Pindstofte | Apparatus for automatically washing bottles. |
| US2046356A (en) | 1933-12-27 | 1936-07-07 | Ici Ltd | Manufacture of diarylamine derivatives |
| US2522680A (en) * | 1949-07-20 | 1950-09-19 | American Cyanamid Co | Polymerizable dioxolane compound, products prepared therefrom, and methods of preparation |
| US2867672A (en) | 1955-08-29 | 1959-01-06 | Shell Dev | Method of minimizing styrene polymerization during storage |
| NL137479C (https=) | 1962-08-14 | |||
| JPS52153817A (en) | 1976-06-18 | 1977-12-21 | Masatoshi Tsuda | Flux for modification of proeutectic silicon in the high silicon aluminium alloy |
| US4086147A (en) | 1976-12-10 | 1978-04-25 | Cosden Technology, Inc. | Polymerization inhibitor for vinyl aromatic compounds |
| US4468343A (en) | 1983-04-11 | 1984-08-28 | Cosden Technology, Inc. | Polymerization co-inhibitors for vinyl aromatic compounds |
| US4670131A (en) * | 1986-01-13 | 1987-06-02 | Exxon Chemical Patents Inc. | Method for controlling fouling of hydrocarbon compositions containing olefinic compounds |
| US4654450A (en) | 1986-02-24 | 1987-03-31 | Atlantic Richfield Company | Inhibiting polymerization of vinyl aromatic monomers |
| US5023372A (en) | 1989-05-16 | 1991-06-11 | Betz Laboratories, Inc. | Methods and compositions for inhibiting (meth)acrylic acid polymerization |
| US5290888A (en) | 1990-07-20 | 1994-03-01 | Ciba-Geigy Corporation | Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions |
| US5212272A (en) * | 1990-10-31 | 1993-05-18 | Peach State Labs, Inc. | Polyacrylic acid compositions for textile processing |
| US5254760A (en) | 1992-07-29 | 1993-10-19 | Ciba-Geigy Corporation | Inhibiting polymerization of vinyl aromatic monomers |
| JP3545440B2 (ja) * | 1993-12-16 | 2004-07-21 | 伯東株式会社 | 芳香族不飽和化合物の粘度上昇抑制剤およびその方法 |
| US5728872A (en) | 1994-06-27 | 1998-03-17 | Lutz Riemenschneider | Stabilized acrylic acid compositions |
| US5446220A (en) * | 1994-08-24 | 1995-08-29 | Betz Laboratories, Inc. | Methods for inhibiting vinyl aromatic monomer polymerization |
| JP3673292B2 (ja) | 1994-07-27 | 2005-07-20 | 伯東株式会社 | ビニル化合物を扱う工程でのファウリング防止方法 |
| US5545786C1 (en) | 1994-11-28 | 2001-10-16 | Ciba Geigy Corp | Method for inhibiting premature polymerization of vinyl aromatic monomers |
| RU2127243C1 (ru) * | 1995-02-03 | 1999-03-10 | Циба Спешиалти Чемикалс Холдинг Инк. | Композиция, предупреждающая преждевременную полимеризацию, и способ ингибирования преждевременной полимеризации |
| US5590232A (en) | 1995-02-16 | 1996-12-31 | Motorola, Inc. | Optical package and method of making |
| DE19510184A1 (de) | 1995-03-21 | 1996-09-26 | Basf Ag | 4-Acylaminopiperidin-N-oxyle |
| US5648573A (en) | 1995-06-12 | 1997-07-15 | Betzdearborn Inc. | Compositions and methods for inhibiting vinyl aromatic monomer polymerization |
| WO1997046504A1 (de) | 1996-06-05 | 1997-12-11 | Basf Aktiengesellschaft | Mischungen, enthaltend monomere und stabilisatoren |
| DE19651307A1 (de) | 1996-12-10 | 1998-06-18 | Basf Ag | Stoffmischungen, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
| US5932735A (en) | 1997-06-13 | 1999-08-03 | Ciba Specialty Chemicals Corporation | Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers |
| US6156858A (en) * | 1997-06-25 | 2000-12-05 | Xerox Corporation | Stable free radical polymerization processes |
| US6136951A (en) | 1999-08-16 | 2000-10-24 | Uniroyal Chemical Company, Inc. | Test method for evaluating insoluble polymer growth |
| AR029410A1 (es) | 1999-12-02 | 2003-06-25 | Crompton Corp | Metodo para inhibir la polimerizacion prematura de monomeros etilenicamente insaturados y composiciones de los mismos |
| ATE307789T1 (de) | 1999-12-02 | 2005-11-15 | Crompton Corp | Polymerisationsinhibierung von ungesättigten monomeren |
| US6685823B2 (en) * | 2000-10-16 | 2004-02-03 | Uniroyal Chemical Company, Inc. | C-nitrosoaniline compounds and their blends as polymerization inhibitors |
| KR100812038B1 (ko) | 2000-10-16 | 2008-03-10 | 유니로얄 캐미칼 캄파니, 인크. | 중합 억제제로서 퀴논 알키드와 니트록실 화합물의 블렌드물 |
| JP4223222B2 (ja) * | 2002-03-19 | 2009-02-12 | 伯東株式会社 | 芳香族ビニル化合物の重合抑制方法 |
| JP4165816B2 (ja) * | 2003-03-31 | 2008-10-15 | 伯東株式会社 | 芳香族ビニル化合物の重合抑制剤組成物 |
| JP2004300385A (ja) * | 2003-04-01 | 2004-10-28 | Hakuto Co Ltd | 芳香族ビニル化合物の重合抑制方法 |
| US20060069219A1 (en) | 2004-09-28 | 2006-03-30 | Vilan Kosover | Sulfonated phenols with nitrophenols as polymerization inhibitors |
| JPWO2006051941A1 (ja) * | 2004-11-15 | 2008-05-29 | 伯東株式会社 | ジビニルベンゼンと芳香族ビニル化合物を含む共重合体の重合抑制方法 |
-
2006
- 2006-01-31 CA CA2593400A patent/CA2593400C/en not_active Expired - Fee Related
- 2006-01-31 WO PCT/US2006/003487 patent/WO2006083923A1/en not_active Ceased
- 2006-01-31 JP JP2007554176A patent/JP4686550B2/ja not_active Expired - Fee Related
- 2006-01-31 KR KR1020077017634A patent/KR101276975B1/ko not_active Expired - Fee Related
- 2006-01-31 EP EP06734143.8A patent/EP1843995B1/en not_active Expired - Lifetime
- 2006-01-31 MX MX2007009236A patent/MX2007009236A/es active IP Right Grant
- 2006-01-31 CN CN2006800040290A patent/CN101115699B/zh not_active Expired - Fee Related
- 2006-01-31 BR BRPI0606801-4A patent/BRPI0606801A2/pt not_active Application Discontinuation
- 2006-01-31 ES ES06734143.8T patent/ES2441429T3/es not_active Expired - Lifetime
- 2006-01-31 US US11/345,194 patent/US8013083B2/en not_active Expired - Fee Related
- 2006-01-31 RU RU2007133105/04A patent/RU2393143C2/ru not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5824829A (en) * | 1993-12-16 | 1998-10-20 | Baker Hughes Incorporated | Hydrocarbon viscosity inhibitor and inhibiting method |
| CN1505599A (zh) * | 2001-04-25 | 2004-06-16 | ������������ʽ���� | 抑制芳香族乙烯基化合物聚合的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2593400A1 (en) | 2006-08-10 |
| MX2007009236A (es) | 2007-09-19 |
| ES2441429T3 (es) | 2014-02-04 |
| KR101276975B1 (ko) | 2013-06-19 |
| CN101115699A (zh) | 2008-01-30 |
| RU2007133105A (ru) | 2009-03-10 |
| US20060178489A1 (en) | 2006-08-10 |
| US8013083B2 (en) | 2011-09-06 |
| WO2006083923A1 (en) | 2006-08-10 |
| BRPI0606801A2 (pt) | 2015-06-16 |
| EP1843995A1 (en) | 2007-10-17 |
| JP2008530269A (ja) | 2008-08-07 |
| EP1843995B1 (en) | 2013-06-05 |
| JP4686550B2 (ja) | 2011-05-25 |
| CA2593400C (en) | 2013-03-12 |
| RU2393143C2 (ru) | 2010-06-27 |
| KR20070103015A (ko) | 2007-10-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US7728083B1 (en) | Aromatic sulfonic acids, amines and nitrophenols in combination with nitroxyl radical-containing compounds or C-nitrosoanilines as polymerization inhibitors | |
| CN101115699B (zh) | 控制苯乙烯类单体与磺酸的放热反应的手段 | |
| CN101102984A (zh) | 作为聚合抑制剂的与含氮氧自由基的化合物或c-亚硝基苯胺结合的芳族磺酸、胺和硝基酚 | |
| EP1794106B1 (en) | Sulfonated phenols with nitrophenols as polymerization inhibitors | |
| RU2378242C2 (ru) | Сульфированные нитрофенолы в качестве ингибиторов полимеризации | |
| US7691952B2 (en) | Sulfonated nitrophenols as polymerization inhibitors |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110914 Termination date: 20150131 |
|
| EXPY | Termination of patent right or utility model |