CN101102741B - 具有释放钙和磷的玻璃的牙科组合物 - Google Patents

具有释放钙和磷的玻璃的牙科组合物 Download PDF

Info

Publication number
CN101102741B
CN101102741B CN200580046578XA CN200580046578A CN101102741B CN 101102741 B CN101102741 B CN 101102741B CN 200580046578X A CN200580046578X A CN 200580046578XA CN 200580046578 A CN200580046578 A CN 200580046578A CN 101102741 B CN101102741 B CN 101102741B
Authority
CN
China
Prior art keywords
composition
dental
calcium
dental composition
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN200580046578XA
Other languages
English (en)
Chinese (zh)
Other versions
CN101102741A (zh
Inventor
理查德·P·鲁辛
凯文·M·卡明斯
苏米塔·B·米特拉
保罗·A·布尔焦
邹采蓉
戴维·S·阿尼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN101102741A publication Critical patent/CN101102741A/zh
Application granted granted Critical
Publication of CN101102741B publication Critical patent/CN101102741B/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/831—Preparations for artificial teeth, for filling teeth or for capping teeth comprising non-metallic elements or compounds thereof, e.g. carbon
    • A61K6/836—Glass
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C13/00—Dental prostheses; Making same
    • A61C13/0003—Making bridge-work, inlays, implants or the like
    • A61C13/0022—Blanks or green, unfinished dental restoration parts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C5/00—Filling or capping teeth
    • A61C5/70—Tooth crowns; Making thereof
    • A61C5/77—Methods or devices for making crowns
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C7/00—Orthodontics, i.e. obtaining or maintaining the desired position of teeth, e.g. by straightening, evening, regulating, separating, or by correcting malocclusions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/30—Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/831—Preparations for artificial teeth, for filling teeth or for capping teeth comprising non-metallic elements or compounds thereof, e.g. carbon
    • A61K6/838—Phosphorus compounds, e.g. apatite
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • A61K6/889—Polycarboxylate cements; Glass ionomer cements
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/062—Glass compositions containing silica with less than 40% silica by weight
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/12—Silica-free oxide glass compositions
    • C03C3/16—Silica-free oxide glass compositions containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/12—Silica-free oxide glass compositions
    • C03C3/16—Silica-free oxide glass compositions containing phosphorus
    • C03C3/19—Silica-free oxide glass compositions containing phosphorus containing boron
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/12—Silica-free oxide glass compositions
    • C03C3/16—Silica-free oxide glass compositions containing phosphorus
    • C03C3/21—Silica-free oxide glass compositions containing phosphorus containing titanium, zirconium, vanadium, tungsten or molybdenum
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/12—Silica-free oxide glass compositions
    • C03C3/23—Silica-free oxide glass compositions containing halogen and at least one oxide, e.g. oxide of boron
    • C03C3/247—Silica-free oxide glass compositions containing halogen and at least one oxide, e.g. oxide of boron containing fluorine and phosphorus
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00—Compositions for glass with special properties
    • C03C4/0007—Compositions for glass with special properties for biologically-compatible glass
    • C03C4/0021—Compositions for glass with special properties for biologically-compatible glass for dental use
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2204/00—Glasses, glazes or enamels with special properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
    • Y10T428/2995—Silane, siloxane or silicone coating

Landscapes

  • Health & Medical Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Plastic & Reconstructive Surgery (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Molecular Biology (AREA)
  • Dental Preparations (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dental Prosthetics (AREA)
  • Cosmetics (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
CN200580046578XA 2004-11-16 2005-11-07 具有释放钙和磷的玻璃的牙科组合物 Expired - Fee Related CN101102741B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US62833604P 2004-11-16 2004-11-16
US60/628,336 2004-11-16
PCT/US2005/040286 WO2006055317A1 (en) 2004-11-16 2005-11-07 Dental compositions with calcium phosphorus releasing glass

Publications (2)

Publication Number Publication Date
CN101102741A CN101102741A (zh) 2008-01-09
CN101102741B true CN101102741B (zh) 2012-05-02

Family

ID=35985275

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200580046578XA Expired - Fee Related CN101102741B (zh) 2004-11-16 2005-11-07 具有释放钙和磷的玻璃的牙科组合物

Country Status (9)

Country Link
US (2) US8957126B2 (enExample)
EP (3) EP1811942B1 (enExample)
JP (1) JP2008520565A (enExample)
KR (1) KR20070086324A (enExample)
CN (1) CN101102741B (enExample)
AT (1) ATE526935T1 (enExample)
AU (1) AU2005306857A1 (enExample)
CA (1) CA2588103A1 (enExample)
WO (1) WO2006055317A1 (enExample)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE602005025682D1 (de) 2004-11-16 2011-02-10 3M Innovative Properties Co Dentalfüllstoffe und zusammensetzungen mit phosphatsalzen
DE602005023509D1 (de) 2004-11-16 2010-10-21 3M Innovative Properties Co Dentalfüllstoffe, verfahren, zusammensetzungen mit einem caseinat
KR101366911B1 (ko) 2004-11-16 2014-02-24 쓰리엠 이노베이티브 프로퍼티즈 컴파니 인-함유 표면 처리제를 포함하는 치과용 충전제, 및 그의조성물 및 방법
EP1811942B1 (en) 2004-11-16 2011-10-05 3M Innovative Properties Company Dental compositions with calcium phosphorus releasing glass
US8047843B2 (en) 2006-09-13 2011-11-01 Clark David J Matrix stabilizer devices and a seamless, single load cavity preparation and filling technique
US9539065B2 (en) * 2006-10-23 2017-01-10 3M Innovative Properties Company Assemblies, methods, and kits including a compressible material
EP2229130A2 (en) * 2007-12-13 2010-09-22 3M Innovative Properties Company Remineralizing compositions and methods
US20090197221A1 (en) * 2008-02-04 2009-08-06 Marshall Jr Grayson W Dental bonding compositions and methods useful in inhibition of microleakage in resin-bonded dentin
MX2010014243A (es) * 2008-06-27 2011-03-25 Novamin Tech Inc Star Composicion y metodo para aumentar la captacion de fluoruro utilizando vidrio bioactivo.
US20100086497A1 (en) * 2008-10-08 2010-04-08 Biofilm Limited Tooth remineralisation
AR076178A1 (es) 2009-04-01 2011-05-26 Colgate Palmolive Co Composiciones dentifricas de accion doble para prevenir la hipersensibilidad y promover la remineralizacion
TWI395595B (zh) * 2009-04-01 2013-05-11 美國棕欖公司 用於治療牙齒敏感之口腔用組成物及其使用方法與製造
AR076179A1 (es) 2009-04-01 2011-05-26 Colgate Palmolive Co Composicion dentifrica no acuosa con vidrio bioaceptable y bioactivo y metodos de uso y fabricacion de la misma
EP2467119B1 (en) * 2009-08-19 2017-05-17 ETH Zurich Radio-opaque bioactiveglass materials
EP2588060A4 (en) * 2010-07-01 2016-09-07 Joseph F Bringley BIOACTIVE COMPOSITIONS
WO2012151464A2 (en) * 2011-05-05 2012-11-08 Creighton University Use of radiographic contrast agents for detecting dental caries
EP2938316A1 (en) * 2012-12-31 2015-11-04 The University Of Sheffield A novel glass-ionomer cement
WO2014203279A2 (en) * 2013-06-21 2014-12-24 Indian Institute Of Technology Madras Dental composite formulations
US9168114B2 (en) 2013-10-17 2015-10-27 B & D Dental Corp. Method of making a dental prosthesis
US10219986B2 (en) 2015-03-04 2019-03-05 Modern Ideas LLC Stabilized calcium phosphate and methods of forming same
US9956314B2 (en) 2016-01-26 2018-05-01 Modern Ideas LLC Adhesive for use with bone and bone-like structures
RU2719414C1 (ru) 2016-05-26 2020-04-17 3М Инновейтив Пропертиз Компани Лечебные стоматологические пасты и связанные с ними способы и наборы
BR112019000329B1 (pt) 2016-07-15 2022-08-02 Gc Corporation Vidro odontológico e composição odontológica
CN106885881A (zh) * 2017-02-24 2017-06-23 四川大学 一种模拟口腔环境的实验方法用于该环境的材料及应用
JP6793241B2 (ja) * 2017-02-27 2020-12-02 株式会社ジーシー 歯科用硬化性組成物
JP7140765B2 (ja) * 2017-08-17 2022-09-21 クラレノリタケデンタル株式会社 歯科用清掃材
KR101964686B1 (ko) * 2017-08-18 2019-04-02 경북대학교 산학협력단 치과용 라이너 및 그 제조방법
US10624994B2 (en) 2017-08-30 2020-04-21 King Abdulaziz University Borate bioactive glass and methods of use for dentin and enamel restoration
CN108455843A (zh) * 2018-03-01 2018-08-28 中南大学湘雅医院 一种溶解速率可控的氧化锆改性生物玻璃及其制备方法
US11446214B2 (en) 2018-08-08 2022-09-20 Gc Corporation Curable dental composite
US11642199B2 (en) * 2018-09-24 2023-05-09 3M Innovative Properties Company Dental appliance with cosmetic therapeutic aqueous solution
JP7546615B2 (ja) 2019-07-04 2024-09-06 ファートン ホールディング エス．アー． 歯の再石灰化のための組成物
CN114522107A (zh) * 2020-11-23 2022-05-24 松山湖材料实验室 一种牙科粘合剂及制备牙科制品的方法
JP7608689B2 (ja) * 2021-03-31 2025-01-07 株式会社ジーシー 歯科用重合性組成物
KR102651809B1 (ko) * 2021-04-27 2024-03-27 (주)메디클러스 다공성 유리 나노 입자 및 이를 포함하는 상아질 접착제 조성물
DE102021113969A1 (de) 2021-05-31 2022-12-01 Mühlbauer Technology Gmbh Monomermischung zur Herstellung eines Dentalmaterials
US11337897B1 (en) 2021-07-07 2022-05-24 King Abdulaziz University Bioactive adhesive system compositions and methods of use
KR102747516B1 (ko) * 2021-11-05 2024-12-31 연세대학교 산학협력단 치아 재광화 효과가 우수한 Zn-PBG 유리 파우더, 이를 이용한 치과 교정용 브라켓 접착제 조성물 및 이의 제조방법
US11602491B1 (en) 2022-02-21 2023-03-14 King Abdulaziz University Bioactive dental temporary filling material
CN114732739B (zh) * 2022-03-24 2023-04-11 成都爱睿康乐医疗器械有限公司 一种窝沟封闭剂及其制备方法
DE102022116577A1 (de) 2022-07-04 2024-01-04 Mühlbauer Technology Gmbh Monomermischung zur Herstellung eines Dentalmaterials
DE102023111186A1 (de) 2023-05-02 2024-11-07 Mühlbauer Technology Gmbh Radikalisch polymerisierbare Verbindung und Zusammensetzung
DE102023135732A1 (de) 2023-12-19 2025-06-26 Mühlbauer Technology Gmbh Radikalisch polymerisierbare Verbindung und Zusammensetzung

Family Cites Families (188)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2323550A (en) 1940-08-03 1943-07-06 Alan R Lukens Filler material for paint, rubber, paper, etc.
US3018262A (en) 1957-05-01 1962-01-23 Shell Oil Co Curing polyepoxides with certain metal salts of inorganic acids
NL128404C (enExample) 1959-12-24
DE2101939C3 (de) 1971-01-15 1980-01-31 Espe Fabrik Pharmazeutischer Praeparate Gmbh, 8031 Seefeld Durch Zusatz von Zinkoxid härtende Massen
US3842059A (en) 1971-02-22 1974-10-15 M Chiang Acrylate and methacrylate terminated polystyrene macromolecular monomers having a substantially uniform molecular weight distribution
US3786116A (en) 1972-08-21 1974-01-15 Cpc International Inc Chemically joined,phase separated thermoplastic graft copolymers
GB1434081A (en) 1973-04-02 1976-04-28 Koh I Nor Rapidograph Inc Tooth whitening cosmetic composition
US3926870A (en) 1973-10-15 1975-12-16 Warner Lambert Co Denture adhesive preparation containing an anionic protein material
US4141864A (en) 1974-03-15 1979-02-27 University Of Virginia Alumni Patents Foundation Osseous cement composition
DE2501683C3 (de) * 1975-01-17 1979-11-29 Ernst Leitz Wetzlar Gmbh, 6300 Wetzlar Polymeres Verbundmaterial für prothetische Zwecke und Verfahren zu seiner Herstellung
GB1569021A (en) 1976-03-17 1980-06-11 Kuraray Co Adhesive cementing agents containing partial phosphonic orphosphonic acid esters
GB1560992A (en) 1976-07-06 1980-02-13 Univ Virginia Osseous cement
DE2830927A1 (de) 1978-07-14 1980-01-31 Basf Ag Acylphosphinoxidverbindungen und ihre verwendung
DE2909994A1 (de) 1979-03-14 1980-10-02 Basf Ag Acylphosphinoxidverbindungen, ihre herstellung und verwendung
DE2909992A1 (de) 1979-03-14 1980-10-02 Basf Ag Photopolymerisierbare aufzeichnungsmassen, insbesondere zur herstellung von druckplatten und reliefformen
US4695251A (en) 1980-04-07 1987-09-22 Minnesota Mining And Manufacturing Company Orthodontic bracket adhesive and abrasive for removal thereof
US4356296A (en) 1981-02-25 1982-10-26 The United States Of America As Represented By The Secretary Of The Navy Fluorinated diacrylic esters and polymers therefrom
US4539382A (en) 1981-07-29 1985-09-03 Kuraray Co., Ltd. Adhesive composition
US4518430A (en) 1982-04-29 1985-05-21 American Dental Association Health Foundation Dental resptorative cement pastes
JPS59135272A (ja) 1983-01-21 1984-08-03 Kuraray Co Ltd 接着剤
US4418057A (en) 1983-02-09 1983-11-29 Scherer Laboratories, Inc. Method of forming stable dental gel of stannous fluoride
US4612053A (en) 1983-10-06 1986-09-16 American Dental Association Health Foundation Combinations of sparingly soluble calcium phosphates in slurries and pastes as mineralizers and cements
DD247888A1 (de) 1984-01-24 1987-07-22 Univ Schiller Jena Phosphatglaskeramik
JPS6117409A (ja) 1984-07-02 1986-01-25 Meishin Toryo Kk 非晶質リン酸カルシウムの製法およびこれを主成分とする生体適応性組成物
US4533544A (en) 1984-03-26 1985-08-06 Scherer Laboratories, Inc. Method of forming stable dental gel of stannous fluoride
US4503169A (en) 1984-04-19 1985-03-05 Minnesota Mining And Manufacturing Company Radiopaque, low visual opacity dental composites containing non-vitreous microparticles
GR852068B (enExample) 1984-08-30 1985-12-24 Johnson & Johnson Dental Prod
DE3443221A1 (de) 1984-11-27 1986-06-05 ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld Bisacylphosphinoxide, ihre herstellung und verwendung
US4642126A (en) 1985-02-11 1987-02-10 Norton Company Coated abrasives with rapidly curable adhesives and controllable curvature
JPS61220658A (ja) * 1985-03-27 1986-09-30 日本電気硝子株式会社 生体用材料
DE3516257A1 (de) 1985-05-07 1986-11-13 Bayer Ag, 5090 Leverkusen (meth)-acrylsaeureester und ihre verwendung
DE3516256A1 (de) 1985-05-07 1986-11-13 Bayer Ag, 5090 Leverkusen (meth)-acrylsaeureester und ihre verwendung
US4648843A (en) 1985-07-19 1987-03-10 Minnesota Mining And Manufacturing Company Method of dental treatment using poly(ethylenically unsaturated) carbamoyl isocyanurates and dental materials made therewith
US4652274A (en) 1985-08-07 1987-03-24 Minnesota Mining And Manufacturing Company Coated abrasive product having radiation curable binder
DE3536076A1 (de) 1985-10-09 1987-04-09 Muehlbauer Ernst Kg Polymerisierbare zementmischungen
CA1315480C (en) 1986-06-12 1993-03-30 Eric Charles Reynolds Phosphopeptides
US5015628A (en) 1986-06-12 1991-05-14 The University Of Melbourne Anticariogenic phosphopeptides
CA1323949C (en) 1987-04-02 1993-11-02 Michael C. Palazzotto Ternary photoinitiator system for addition polymerization
US5135396A (en) 1987-06-30 1992-08-04 Kabushiki Kaisha Sangi Fine filling method and fine filler for dental purposes
US4880660A (en) 1987-08-28 1989-11-14 Minnesota Mining And Manufacturing Company Method for priming hard tissue
AU618772B2 (en) 1987-12-30 1992-01-09 Minnesota Mining And Manufacturing Company Photocurable ionomer cement systems
DE68904665T2 (de) 1988-03-17 1993-09-02 Kuraray Co Haertbare harzzusammensetzung.
GB8811829D0 (en) 1988-05-19 1988-06-22 Unilever Plc Oral compositions
US4871786A (en) 1988-10-03 1989-10-03 Minnesota Mining And Manufacturing Company Organic fluoride sources
JPH0667816B2 (ja) 1988-11-11 1994-08-31 株式会社クラレ 歯科用修復材
US5296026A (en) 1988-12-02 1994-03-22 Monroe Eugene A Phosphate glass cement
US5076844A (en) 1988-12-10 1991-12-31 Goldschmidt AG & GDF Gesellschaft fur Dentale Forschung u. Innovationen GmbH Perfluoroalkyl group-containing (meth-)acrylate esters, their synthesis and use in dental technology
DE3841617C1 (enExample) 1988-12-10 1990-05-10 Th. Goldschmidt Ag, 4300 Essen, De
US5037639A (en) 1989-05-24 1991-08-06 American Dental Association Health Foundation Methods and compositions for mineralizing calcified tissues
US6056930A (en) 1989-05-24 2000-05-02 American Dental Association Health Foundation Methods and compositions for mineralizing and fluoridating calcified tissues
US5071637A (en) 1989-10-06 1991-12-10 Pellico Michael A Foamable fluoride compositions and method
US5074916A (en) 1990-05-18 1991-12-24 Geltech, Inc. Alkali-free bioactive sol-gel compositions
GB2245559A (en) * 1990-06-25 1992-01-08 Farmos Oy Bioceramic system for delivery of a bioactive compound.
JP3334050B2 (ja) 1990-11-29 2002-10-15 藤倉化成株式会社 軟質樹脂組成物
US5340776A (en) 1991-01-11 1994-08-23 Schott Glaswerke Preparation of very fine glass powder of high purity
JPH04329960A (ja) 1991-05-01 1992-11-18 Onoda Cement Co Ltd 医科用または歯科用硬化性組成物
US5332429A (en) 1991-05-31 1994-07-26 Minnesota Mining And Manufacturing Company Method for treating fluoroaluminosilicate glass
US5154762A (en) 1991-05-31 1992-10-13 Minnesota Mining And Manufacturing Company Universal water-based medical and dental cement
US5162267A (en) 1991-09-27 1992-11-10 Smyth Milagros B Radio-opaque calcium phosphate glass
US5525648A (en) 1991-12-31 1996-06-11 Minnesota Mining And Manufacturing Company Method for adhering to hard tissue
PL172401B1 (en) * 1991-12-31 1997-09-30 Minnesota Mining & Mfg Composition for bonding or coating hard tissue
US5468477A (en) 1992-05-12 1995-11-21 Minnesota Mining And Manufacturing Company Vinyl-silicone polymers in cosmetics and personal care products
ES2144458T3 (es) 1992-06-29 2000-06-16 Univ Melbourne Tratamiento para dientes sensibles.
EP0599187B1 (de) 1992-11-25 1998-09-30 Vita Zahnfabrik H. Rauter GmbH & Co KG Verfahren zur Herstellung von Zahnersatz auf Keramikbasis
US5883153A (en) * 1993-04-15 1999-03-16 Shofu Inc. Fluoride ion sustained release preformed glass ionomer filler and dental compositions containing the same
JPH06321515A (ja) 1993-05-18 1994-11-22 Osaka Cement Co Ltd 高強度硬化性材料
DE4323143C1 (de) 1993-07-10 1994-12-01 Schott Glaswerke Verwendung eines Glases als bariumfreies Dentalglas mit guter Röntgenabsorption
US5530038A (en) 1993-08-02 1996-06-25 Sun Medical Co., Ltd. Primer composition and curable composition
US5888491A (en) 1993-12-06 1999-03-30 Minnesota Mining And Manufacturing Company Optionally crosslinkable coatings, compositions and methods of use
US6312668B2 (en) 1993-12-06 2001-11-06 3M Innovative Properties Company Optionally crosslinkable coatings, compositions and methods of use
US5508342A (en) 1994-02-01 1996-04-16 The United States Of America As Represented By The Secretary Of Commerce Polymeric amorphous calcium phosphate compositions
JPH09509392A (ja) 1994-02-28 1997-09-22 ミネソタ マイニング アンド マニュファクチャリング カンパニー ペースト：ペーストガラスイオノマーセメント系および方法
US5501727A (en) 1994-02-28 1996-03-26 Minnesota Mining And Manufacturing Company Color stability of dental compositions containing metal complexed ascorbic acid
FI104881B (fi) 1994-10-06 2000-04-28 Bioxid Oy Uusien bioaktiivista piipitoista lasia sisältävien koostumusten valmistusmenetelmä
EP0712622B1 (en) 1994-11-21 1999-09-01 Tokuyama Corporation Dental composition and kit
US5662887A (en) 1994-12-01 1997-09-02 Minnesota Mining And Manufacturing Company Fluorocarbon containing coatings, compositions and methods of use
US5607663A (en) 1994-12-01 1997-03-04 Minnesota Mining And Manufacturing Company Hydrocarbyl containing coatings, compositions and methods of use
DE4443173C2 (de) 1994-12-05 1997-04-10 Schott Glaswerke Bariumfreies Dentalglas mit guter Röntgenabsorption
JP3534910B2 (ja) 1994-12-13 2004-06-07 三菱鉛筆株式会社 歯の塗布液
JPH10511956A (ja) 1995-01-06 1998-11-17 アメリカン デンタル アソシエイション ヘルス ファウンデーション 嗽剤、歯磨き及びゲルにおける弗化カルシウム形成の制御
US8333996B2 (en) 1995-05-19 2012-12-18 Etex Corporation Calcium phosphate delivery vehicle and adjuvant
US5605675A (en) 1995-06-06 1997-02-25 Enamelon Inc. Processes and compositions for remineralization and prevention of demineralization of dental enamel
US5571502A (en) 1995-08-08 1996-11-05 Enamelon Research Stable single-part compositions and the use thereof for remineralization of lesions in teeth
US5603922A (en) 1995-08-08 1997-02-18 Enamelon Inc. Processes and compositions for the remineralization of teeth
US6036944A (en) 1995-08-08 2000-03-14 Enamelon, Inc. Processes for the remineralization and mineralization of teeth
CN1090038C (zh) 1995-09-18 2002-09-04 美国3M公司 包括冷凝机构的组分分离系统
AR004014A1 (es) 1995-10-13 1998-09-30 Meiji Seika Kaisha Una composicion antibacteriana de cefditoren pivoxilo para administracion oral y metodo para obtener dicha composicion
US6391286B1 (en) 1995-11-17 2002-05-21 3M Innovative Properties Company Use of metallofluorocomplexes for dental compositions
WO1997027148A1 (en) * 1996-01-29 1997-07-31 Usbiomaterials Corporation Bioactive glass compositions and methods of treatment using bioactive glass
DE69731184T2 (de) 1996-01-29 2005-10-13 University Of Maryland, Baltimore Bioaktive glaszusammensetzungen zur verwendung zur behandlung von zahnstrukturen
US5735942A (en) 1996-02-07 1998-04-07 Usbiomaterials Corporation Compositions containing bioactive glass and their use in treating tooth hypersensitivity
US5824289A (en) 1996-03-05 1998-10-20 Sultan Dental Products Dental fluoride foam
EP0891421A4 (en) 1996-03-18 2001-07-25 Univ Pennsylvania BIOACTIVE SUBSTRATE MATERIAL FOR IMPROVED CELLULAR FIXATION AND FUNCTION
JP3542683B2 (ja) * 1996-03-25 2004-07-14 デンツプライ三金株式会社 歯科用セメント組成物
AUPN898296A0 (en) 1996-03-28 1996-04-26 Nulite Systems International Pty Ltd Elastomeric state glass ionomer cement
US6136885A (en) 1996-06-14 2000-10-24 3M Innovative Proprerties Company Glass ionomer cement
US5817296A (en) 1996-09-27 1998-10-06 Enamelon, Inc. Processes and compositions for the remineralization of teeth
AU4083597A (en) 1996-09-27 1998-04-17 Enamelon, Inc. Improved products and methods for the remineralization and prevention of demineralization of teeth
JP3816999B2 (ja) * 1996-12-04 2006-08-30 サンスター株式会社 生体活性ガラス含有口腔用塗布剤
WO1998017236A1 (en) * 1996-10-23 1998-04-30 Sunstar Inc. Oral preparations containing biologically active crystallized glass
AUPO566297A0 (en) 1997-03-13 1997-04-10 University Of Melbourne, The Calcium phosphopeptide complexes
US6159449A (en) 1997-04-03 2000-12-12 Enamelon, Inc. Dentifrice products and methods for remineralizing and/or mineralizing teeth
US5922786A (en) 1997-04-11 1999-07-13 Minnesota Mining And Manufacturing Company Dental primer composition
US5998495A (en) 1997-04-11 1999-12-07 3M Innovative Properties Company Ternary photoinitiator system for curing of epoxy/polyol resin compositions
WO1999007326A2 (en) 1997-08-11 1999-02-18 The University Of Toronto Innovations Foundation Antimicrobial cement compositions
DE19736665A1 (de) 1997-08-22 1999-02-25 Espe Dental Ag Härtbare Masse mit Silan-Dendrimeren
US6353039B1 (en) 1997-12-15 2002-03-05 Ivoclar Ag Polymerizable composite material
US6180688B1 (en) 1997-12-15 2001-01-30 Ivoclar Ag Ion-releasing composite material
JPH11180815A (ja) 1997-12-17 1999-07-06 Gc:Kk 歯科用グラスアイオノマーセメント用ガラス粉末
AU1527099A (en) 1998-01-09 1999-07-26 Enamelon, Inc. Solid products and methods for the remineralization and prevention of demineralization of teeth
FR2776282B1 (fr) 1998-03-20 2000-05-19 Toulouse Inst Nat Polytech Procede de preparation d'un biomateriau a base d'hydroxyapatite, biomateriau obtenu et application chirurgicale ou dentaire
US6036494A (en) 1998-04-03 2000-03-14 Cohen; Morton Method for cosmetically improving and altering the appearance of teeth
US6036762A (en) 1998-04-30 2000-03-14 Sambasivan; Sankar Alcohol-based precursor solutions for producing metal phosphate materials and coating
US6270562B1 (en) 1998-06-11 2001-08-07 Jeneric/Pentron, Inc. Filler material for dental composites
US6030606A (en) 1998-06-22 2000-02-29 3M Innovative Properties Company Dental restoratives comprising Bis-EMA6
AUPP494798A0 (en) 1998-07-29 1998-08-20 Pacific Biolink Pty Limited Protective protein formulation
US5858333A (en) 1998-08-07 1999-01-12 Enamelon, Inc. Two-part oral products and methods of using same to remineralize teeth
AU763355B2 (en) 1998-08-20 2003-07-17 Kuraray Co., Ltd. Bonding compositions for dental use
WO2000011089A1 (de) 1998-08-21 2000-03-02 Sachtleben Chemie Gmbh Anorganische korrosionsschutz-pigmente und verfahren zu deren herstellung
US6306926B1 (en) 1998-10-07 2001-10-23 3M Innovative Properties Company Radiopaque cationically polymerizable compositions comprising a radiopacifying filler, and method for polymerizing same
DK1123081T3 (da) 1998-10-19 2003-03-24 Synthes Ag Hærdelig keramisk hydraulisk cement
DE19849388C2 (de) 1998-10-27 2001-05-17 Schott Glas Bariumfreies röntgenopakes Dentalglas sowie dessen Verwendung
SE9904080D0 (sv) 1998-12-03 1999-11-11 Ciba Sc Holding Ag Fotoinitiatorberedning
US6398859B1 (en) * 1998-12-24 2002-06-04 American Dental Association Health Foundation Resin-based pulp capping and basing cements
DE19860361A1 (de) 1998-12-24 2000-06-29 Espe Dental Ag Vernetzbare Monomere auf Cyclosiloxanbasis, deren Herstellung und deren Verwendung in polymerisierbaren Massen
DE19860364C2 (de) 1998-12-24 2001-12-13 3M Espe Ag Polymerisierbare Dentalmassen auf der Basis von zur Aushärtung befähigten Siloxanverbindungen, deren Verwendung und Herstellung
CA2357000A1 (en) 1999-01-08 2000-07-13 3M Innovative Properties Company Dental mill blanks
US6303104B1 (en) 1999-02-12 2001-10-16 Enamelon, Inc. Remineralizing/mineralizing oral products having improved whitening and stain removal properties
US6846500B1 (en) 1999-03-25 2005-01-25 Cadbury Adams Usa Llc Oral care chewing gums and method of use
BR0006009A (pt) 1999-03-31 2001-03-06 Kuraray Co Compostos organofosforosos para composições dentais polimerizáveis
TWI284540B (en) 1999-05-13 2007-08-01 Kuraray Co Bonding composition suitable to tooth tissue
US6365134B1 (en) 1999-07-07 2002-04-02 Scientific Pharmaceuticals, Inc. Process and composition for high efficacy teeth whitening
DE19934407A1 (de) 1999-07-22 2001-01-25 Espe Dental Ag Hydrolysierbare und polymerisierbare Silane mit geringer Viskosität und deren Verwendung
US6730156B1 (en) 1999-10-28 2004-05-04 3M Innovative Properties Company Clustered particle dental fillers
US6387981B1 (en) 1999-10-28 2002-05-14 3M Innovative Properties Company Radiopaque dental materials with nano-sized particles
US6572693B1 (en) 1999-10-28 2003-06-03 3M Innovative Properties Company Aesthetic dental materials
JP4800535B2 (ja) 1999-10-28 2011-10-26 スリーエム イノベイティブ プロパティズ カンパニー ナノサイズシリカ粒子を含有する歯科材料
US6632412B2 (en) 1999-12-01 2003-10-14 Timo Peltola Bioactive sol-gel derived silica fibers and methods for their preparation
WO2001041822A1 (en) 1999-12-09 2001-06-14 Biosyntech Canada Inc. Mineral-polymer hybrid composition
US20030158302A1 (en) 1999-12-09 2003-08-21 Cyric Chaput Mineral-polymer hybrid composition
FR2805748B1 (fr) 2000-03-01 2002-09-13 Ceravic Procede de preparation d'un materiau pateux phosphocalcique injectable en vue de former un biomateriau apatitique et application chirurgicale ou dentaire
US6361761B1 (en) 2000-04-05 2002-03-26 Colgate Palmolive Company Foamable dental fluoride composition
US6426114B1 (en) 2000-05-02 2002-07-30 The University Of British Columbia Sol-gel calcium phosphate ceramic coatings and method of making same
AU2001261960A1 (en) 2000-05-19 2001-11-26 The University Of British Columbia Process for making chemically bonded composite hydroxide ceramics
KR100457993B1 (ko) * 2000-05-22 2004-11-26 가부시키가이샤 구라레 항균성 조성물
DE10026432A1 (de) 2000-05-29 2002-02-14 3M Espe Ag Präpolymere (Meth)acrylate mit polycyclischen oder aromatischen Segmenten
CN1380827A (zh) 2000-05-31 2002-11-20 独立行政法人产业技术综合研究所 牙科用制品的脱臭、污染防止用组合物
US6372198B1 (en) 2000-09-14 2002-04-16 Joseph M. Abbate Dentifrice for the mineralization and remineralization of teeth
JP4580531B2 (ja) * 2000-10-04 2010-11-17 株式会社松風 歯科充填用ガラスおよびそのガラス粒子を含む歯科用組成物
NZ507335A (en) 2000-10-05 2004-10-29 New Zealand Dairy Board Bone health compositions derived from milk comprising an acidic protein fraction but that does not contain CGMP
DE10063945A1 (de) 2000-12-20 2002-07-04 Henkel Kgaa Remineralisierende Dental-Klebefolie
US6613812B2 (en) 2001-01-03 2003-09-02 3M Innovative Properties Company Dental material including fatty acid, dimer thereof, or trimer thereof
US6793725B2 (en) 2001-01-24 2004-09-21 Ada Foundation Premixed calcium phosphate cement pastes
DE10111449A1 (de) * 2001-03-09 2002-09-26 Schott Glas Verwendung von bioaktivem Glas in Zahnfüllmaterial
US6818682B2 (en) 2001-04-20 2004-11-16 3M Innovative Properties Co Multi-part dental compositions and kits
US6653365B2 (en) 2001-05-01 2003-11-25 Pentron Clinical Technologies, Llc Dental composite materials and method of manufacture thereof
AUPR517701A0 (en) 2001-05-21 2001-06-14 University Of Melbourne, The Dental restorative materials
US20040241238A1 (en) 2001-05-25 2004-12-02 Pilar Sepulveda Foamed sol-gel and method of manufacturing the same
US6709744B1 (en) * 2001-08-13 2004-03-23 The Curators Of The University Of Missouri Bioactive materials
JP2003104821A (ja) 2001-09-28 2003-04-09 Gc Corp 歯面処理材
DE10161827A1 (de) 2001-12-15 2003-06-26 Dot Gmbh Verfahren zur Beschichtung eines Substrats mit Calciumphosphat
US6649669B2 (en) 2001-12-28 2003-11-18 American Dental Association Health Foundation Single solution bonding formulation
US7173074B2 (en) 2001-12-29 2007-02-06 3M Innovative Properties Company Composition containing a polymerizable reducing agent, kit, and method
US6765036B2 (en) 2002-01-15 2004-07-20 3M Innovative Properties Company Ternary photoinitiator system for cationically polymerizable resins
JP4748938B2 (ja) 2002-01-31 2011-08-17 スリーエム イノベイティブ プロパティズ カンパニー 歯科ペースト、歯科物品、および方法
AU2003208056A1 (en) * 2002-02-20 2003-09-09 Kabushiki Kaisha Ohara Optical glass
US20030167967A1 (en) 2002-03-01 2003-09-11 Timo Narhi Glass ionomers for enhancing mineralization of hard tissue
US6982288B2 (en) 2002-04-12 2006-01-03 3M Innovative Properties Company Medical compositions containing an ionic salt, kits, and methods
US6960079B2 (en) 2002-04-18 2005-11-01 3M Innovative Properties Company Orthodontic adhesives and appliances including an adhesive on the base of the appliance
AUPS303202A0 (en) 2002-06-20 2002-07-11 Pacific Biolink Pty Limited Protein based oral lubricant
US7091259B2 (en) 2002-07-03 2006-08-15 3M Innovative Properties Company Dental fillers, pastes, and compositions prepared therefrom
NZ522071A (en) 2002-10-18 2005-07-29 Patrick Joseph Silcock Hydrolysed casein phosphoprotein preparations for bioactive metal ion delivery and teeth remineralisation
EP1566167B1 (en) 2002-11-07 2011-10-12 Taisho Pharmaceutical Co., Ltd Base for oral composition and oral composition
US20040206932A1 (en) 2002-12-30 2004-10-21 Abuelyaman Ahmed S. Compositions including polymerizable bisphosphonic acids and methods
US20040185013A1 (en) 2003-01-30 2004-09-23 Burgio Paul A. Dental whitening compositions and methods
DE10307646B3 (de) * 2003-02-21 2004-10-21 Ivoclar Vivadent Ag Bioaktive Rhenanit-Glaskeramik, Verfahren zu ihrer Herstellung und ihre Verwendung
US7393493B2 (en) 2003-02-27 2008-07-01 A Enterprises, Inc. Crosslinkable polymeric materials and their applications
US7449499B2 (en) 2003-08-12 2008-11-11 3M Innovative Properties Company Self-etching dental compositions and methods
US7189409B2 (en) 2004-03-09 2007-03-13 Inion Ltd. Bone grafting material, method and implant
US7649029B2 (en) 2004-05-17 2010-01-19 3M Innovative Properties Company Dental compositions containing nanozirconia fillers
US7090721B2 (en) 2004-05-17 2006-08-15 3M Innovative Properties Company Use of nanoparticles to adjust refractive index of dental compositions
US7156911B2 (en) 2004-05-17 2007-01-02 3M Innovative Properties Company Dental compositions containing nanofillers and related methods
DE102004026432A1 (de) * 2004-05-29 2005-12-22 Schott Ag Glaszusammensetzungen als antimikrobieller Zusatz für Dentalmaterialien und deren Verwendung
US8722760B2 (en) 2004-08-11 2014-05-13 3M Innovative Properties Company Self-adhesive compositions including a plurality of acidic compounds
DE602005025682D1 (de) 2004-11-16 2011-02-10 3M Innovative Properties Co Dentalfüllstoffe und zusammensetzungen mit phosphatsalzen
DE602005023509D1 (de) 2004-11-16 2010-10-21 3M Innovative Properties Co Dentalfüllstoffe, verfahren, zusammensetzungen mit einem caseinat
EP1811942B1 (en) 2004-11-16 2011-10-05 3M Innovative Properties Company Dental compositions with calcium phosphorus releasing glass
KR101366911B1 (ko) 2004-11-16 2014-02-24 쓰리엠 이노베이티브 프로퍼티즈 컴파니 인-함유 표면 처리제를 포함하는 치과용 충전제, 및 그의조성물 및 방법

Non-Patent Citations (8)

* Cited by examiner, † Cited by third party
Title
ANA I D ET AL.Effects of added bioactive glass on the setting andmechanical properties of resin-modified glass ionomer cement.BIOMATERIALS24 18.2003,24(18),3062-3063.
ANA I D ET AL.Effects of added bioactive glass on the setting andmechanical properties of resin-modified glass ionomer cement.BIOMATERIALS24 18.2003,24(18),3062-3063. *
FORSBACK ARI-PEKKA
NARHI,TIMO O.
VAKIPARTA, MARJU.Release of silica, calcium, phosphorus, and fluoride from glassionomer cement containing bioactive glass.JOURNAL OF BIOMATERIALS APPLICATIONS19 1.2004,19(1),7.
VALLITTU, PEKKA, K
YLI-URPO,HELENA
YLI-URPO,HELENA;VALLITTU, PEKKA, K;NARHI,TIMO O.;FORSBACK ARI-PEKKA;VAKIPARTA, MARJU.Release of silica, calcium, phosphorus, and fluoride from glassionomer cement containing bioactive glass.JOURNAL OF BIOMATERIALS APPLICATIONS19 1.2004,19(1),7. *

Also Published As

Publication number Publication date
EP1811942A1 (en) 2007-08-01
US8957126B2 (en) 2015-02-17
CA2588103A1 (en) 2006-05-26
US20090317772A1 (en) 2009-12-24
EP2401997A2 (en) 2012-01-04
EP1811942B1 (en) 2011-10-05
CN101102741A (zh) 2008-01-09
WO2006055317A1 (en) 2006-05-26
ATE526935T1 (de) 2011-10-15
KR20070086324A (ko) 2007-08-27
AU2005306857A1 (en) 2006-05-26
US9517186B2 (en) 2016-12-13
EP2401997A3 (en) 2012-03-21
EP2832342A2 (en) 2015-02-04
EP2401997B1 (en) 2016-08-24
US20150125823A1 (en) 2015-05-07
JP2008520565A (ja) 2008-06-19
EP2832342A3 (en) 2015-02-11

Similar Documents

Publication Publication Date Title
US9517186B2 (en) Dental compositions with calcium phosphorus releasing glass
CN101098673B (zh) 包括磷酸盐的牙科填料和组合物
EP1819312B1 (en) Dental fillers including a phosphorus-containing surface treatment
US8450388B2 (en) Dental fillers, methods, compositions including a caseinate
EP1928929A4 (en) POLYMERIZABLE COMPOSITIONS CONTAINING DITHIANE MONOMERS

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120502

Termination date: 20181107

CF01 Termination of patent right due to non-payment of annual fee