CN101096599A - 无卤素液态阻燃剂、粉状阻燃剂及其制造方法和阻燃性发泡体的制造方法 - Google Patents
无卤素液态阻燃剂、粉状阻燃剂及其制造方法和阻燃性发泡体的制造方法 Download PDFInfo
- Publication number
- CN101096599A CN101096599A CNA2006100282145A CN200610028214A CN101096599A CN 101096599 A CN101096599 A CN 101096599A CN A2006100282145 A CNA2006100282145 A CN A2006100282145A CN 200610028214 A CN200610028214 A CN 200610028214A CN 101096599 A CN101096599 A CN 101096599A
- Authority
- CN
- China
- Prior art keywords
- ammonium
- tetramethylolmethane
- dipropylene glycol
- water
- boric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 61
- 238000000034 method Methods 0.000 title claims abstract description 37
- 238000005187 foaming Methods 0.000 title claims abstract description 33
- 239000007788 liquid Substances 0.000 title claims abstract description 27
- 238000002485 combustion reaction Methods 0.000 title claims description 21
- 239000003112 inhibitor Substances 0.000 title claims description 20
- 238000004519 manufacturing process Methods 0.000 title claims description 19
- 229910052736 halogen Inorganic materials 0.000 title description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000011734 sodium Substances 0.000 claims abstract description 28
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 26
- 239000002253 acid Substances 0.000 claims abstract description 26
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims abstract description 26
- 235000011130 ammonium sulphate Nutrition 0.000 claims abstract description 26
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000004327 boric acid Substances 0.000 claims abstract description 26
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 26
- 239000000843 powder Substances 0.000 claims abstract description 12
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims abstract description 10
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 26
- 229940059574 pentaerithrityl Drugs 0.000 claims description 25
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 25
- 239000007864 aqueous solution Substances 0.000 claims description 15
- BNWPUUZJGBXAFM-UHFFFAOYSA-N azane oxalonitrile Chemical compound N.N#CC#N BNWPUUZJGBXAFM-UHFFFAOYSA-N 0.000 claims description 15
- 239000006261 foam material Substances 0.000 claims description 13
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 11
- 239000012467 final product Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 8
- 239000004254 Ammonium phosphate Substances 0.000 claims description 6
- 235000019270 ammonium chloride Nutrition 0.000 claims description 6
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 6
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 6
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 3
- 239000006260 foam Substances 0.000 abstract description 22
- 239000000463 material Substances 0.000 abstract description 15
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 abstract 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 18
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 15
- -1 stir Substances 0.000 description 8
- 239000002585 base Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 229920001169 thermoplastic Polymers 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000003351 stiffener Substances 0.000 description 4
- 238000006424 Flood reaction Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 239000002984 plastic foam Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 208000034189 Sclerosis Diseases 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 231100000956 nontoxicity Toxicity 0.000 description 2
- 229920000921 polyethylene adipate Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 239000002341 toxic gas Substances 0.000 description 2
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- DUFKCOQISQKSAV-UHFFFAOYSA-N Polypropylene glycol (m w 1,200-3,000) Chemical class CC(O)COC(C)CO DUFKCOQISQKSAV-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 150000001913 cyanates Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006100282145A CN100526424C (zh) | 2006-06-27 | 2006-06-27 | 无卤素液态阻燃剂、粉状阻燃剂及其制造方法和阻燃性发泡体的制造方法 |
Applications Claiming Priority (1)
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CNB2006100282145A CN100526424C (zh) | 2006-06-27 | 2006-06-27 | 无卤素液态阻燃剂、粉状阻燃剂及其制造方法和阻燃性发泡体的制造方法 |
Publications (2)
Publication Number | Publication Date |
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CN101096599A true CN101096599A (zh) | 2008-01-02 |
CN100526424C CN100526424C (zh) | 2009-08-12 |
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CNB2006100282145A Expired - Fee Related CN100526424C (zh) | 2006-06-27 | 2006-06-27 | 无卤素液态阻燃剂、粉状阻燃剂及其制造方法和阻燃性发泡体的制造方法 |
Country Status (1)
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CN (1) | CN100526424C (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011085531A1 (zh) * | 2010-01-12 | 2011-07-21 | Sheng Yajun | 一种阻燃聚合物泡沫材料及其制备方法 |
CN103174226A (zh) * | 2013-03-18 | 2013-06-26 | 上海一金节能科技有限公司 | 机械锚固网格加强筋无机改性泡沫保温板的外保温墙体 |
CN106565888A (zh) * | 2016-10-14 | 2017-04-19 | 浙江中科恒泰新材料科技有限公司 | 一种阻燃型聚甲基丙烯酰亚胺泡沫及其制件的制备方法 |
CN106566050A (zh) * | 2016-10-31 | 2017-04-19 | 江苏昊晟塑业科技有限公司 | 用于汽车内饰的发泡材料 |
-
2006
- 2006-06-27 CN CNB2006100282145A patent/CN100526424C/zh not_active Expired - Fee Related
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011085531A1 (zh) * | 2010-01-12 | 2011-07-21 | Sheng Yajun | 一种阻燃聚合物泡沫材料及其制备方法 |
CN102127269B (zh) * | 2010-01-12 | 2014-01-29 | 盛亚军 | 一种阻燃聚合物泡沫材料及其制备方法 |
CN103174226A (zh) * | 2013-03-18 | 2013-06-26 | 上海一金节能科技有限公司 | 机械锚固网格加强筋无机改性泡沫保温板的外保温墙体 |
WO2014146531A1 (zh) * | 2013-03-18 | 2014-09-25 | 上海一金节能科技有限公司 | 机械锚固网格加强筋无机改性泡沫保温板的外保温墙体 |
CN103174226B (zh) * | 2013-03-18 | 2017-10-03 | 上海一金节能科技有限公司 | 全部用机械锚固加强筋无机改性不燃泡沫板的外保温墙体 |
CN106565888A (zh) * | 2016-10-14 | 2017-04-19 | 浙江中科恒泰新材料科技有限公司 | 一种阻燃型聚甲基丙烯酰亚胺泡沫及其制件的制备方法 |
CN106566050A (zh) * | 2016-10-31 | 2017-04-19 | 江苏昊晟塑业科技有限公司 | 用于汽车内饰的发泡材料 |
Also Published As
Publication number | Publication date |
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CN100526424C (zh) | 2009-08-12 |
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Effective date of registration: 20130809 Address after: 200031, room 1, building 446, Lane 1208, Zhao Jia Bang Road, Shanghai, Xuhui District Patentee after: Zhang Linlin Address before: 200011, room 2, No. 161, Lane 605, South Road, Shanghai, Zhongshan Patentee before: Xu Shuang |
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Address after: 200031 room 1, building 446, Lane 1207, Zhao Jia Bang Road, Shanghai, Xuhui District Patentee after: Zhang Linlin Address before: 200031 room 1, building 446, Lane 1208, Zhao Jia Bang Road, Shanghai, Xuhui District Patentee before: Zhang Linlin |
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Granted publication date: 20090812 Termination date: 20170627 |