CN101029257A - 生物柴油安定性添加剂及其制备、使用方法 - Google Patents
生物柴油安定性添加剂及其制备、使用方法 Download PDFInfo
- Publication number
- CN101029257A CN101029257A CN 200710027292 CN200710027292A CN101029257A CN 101029257 A CN101029257 A CN 101029257A CN 200710027292 CN200710027292 CN 200710027292 CN 200710027292 A CN200710027292 A CN 200710027292A CN 101029257 A CN101029257 A CN 101029257A
- Authority
- CN
- China
- Prior art keywords
- oil
- mixture
- biofuel
- biological diesel
- oxidant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002283 diesel fuel Substances 0.000 title claims abstract description 17
- 239000000654 additive Substances 0.000 title claims description 19
- 230000000996 additive effect Effects 0.000 title claims description 19
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 239000000126 substance Substances 0.000 claims abstract description 16
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 15
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 15
- 235000006708 antioxidants Nutrition 0.000 claims abstract description 15
- 239000002904 solvent Substances 0.000 claims abstract description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 12
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims abstract description 9
- -1 citrate ester Chemical class 0.000 claims abstract description 8
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 6
- 229930003427 Vitamin E Natural products 0.000 claims abstract description 6
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000019165 vitamin E Nutrition 0.000 claims abstract description 6
- 229940046009 vitamin E Drugs 0.000 claims abstract description 6
- 239000011709 vitamin E Substances 0.000 claims abstract description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 235000021466 carotenoid Nutrition 0.000 claims abstract description 4
- 150000001747 carotenoids Chemical class 0.000 claims abstract description 4
- 239000002551 biofuel Substances 0.000 claims description 40
- 239000003921 oil Substances 0.000 claims description 25
- 235000019198 oils Nutrition 0.000 claims description 25
- 229940123973 Oxygen scavenger Drugs 0.000 claims description 12
- 239000012747 synergistic agent Substances 0.000 claims description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 7
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical group OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 claims description 6
- 235000012424 soybean oil Nutrition 0.000 claims description 6
- 239000003549 soybean oil Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 4
- IMOYOUMVYICGCA-UHFFFAOYSA-N 2-tert-butyl-4-hydroxyanisole Chemical compound COC1=CC=C(O)C=C1C(C)(C)C IMOYOUMVYICGCA-UHFFFAOYSA-N 0.000 claims description 3
- MRBKEAMVRSLQPH-UHFFFAOYSA-N 3-tert-butyl-4-hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1 MRBKEAMVRSLQPH-UHFFFAOYSA-N 0.000 claims description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 3
- 125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 claims description 3
- 239000012263 liquid product Substances 0.000 claims description 3
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 3
- 229940079877 pyrogallol Drugs 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 150000003712 vitamin E derivatives Chemical group 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- 235000010323 ascorbic acid Nutrition 0.000 abstract 2
- 239000011668 ascorbic acid Substances 0.000 abstract 2
- FRTNIYVUDIHXPG-UHFFFAOYSA-N acetic acid;ethane-1,2-diamine Chemical compound CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.NCCN FRTNIYVUDIHXPG-UHFFFAOYSA-N 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 229940072107 ascorbate Drugs 0.000 abstract 1
- 229960005070 ascorbic acid Drugs 0.000 abstract 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000446 fuel Substances 0.000 description 7
- 230000001939 inductive effect Effects 0.000 description 6
- 230000001590 oxidative effect Effects 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 1
- 239000003747 fuel oil additive Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Fats And Perfumes (AREA)
Abstract
Description
生物柴油样品 | 添加剂加入量(g/kg) | 诱导期(h) |
由潲水油合成的生物柴油 | 0 | 3.3 |
由潲水油合成的生物柴油 | 1 | 8.9 |
由潲水油合成的生物柴油 | 2 | 9.2 |
由潲水油合成的生物柴油 | 3 | 9.4 |
生物柴油样品 | 添加剂加入量(g/kg) | 诱导期(h) |
由棕榈油合成的生物柴油 | 0 | 3.3 |
由棕榈油合成的生物柴油 | 1 | 8.8 |
由棕榈油合成的生物柴油 | 2 | 9.2 |
由棕榈油合成的生物柴油 | 3 | 9.4 |
生物柴油样品 | 添加剂加入量(g/kg) | 诱导期(h) |
由大豆油合成的生物柴油 | 0 | 3.0 |
由大豆油合成的生物柴油 | 1 | 8.6 |
由大豆油合成的生物柴油 | 2 | 8.9 |
由大豆油合成的生物柴油 | 3 | 9.1 |
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007100272928A CN101029257B (zh) | 2007-03-26 | 2007-03-26 | 生物柴油安定性添加剂及其制备、使用方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007100272928A CN101029257B (zh) | 2007-03-26 | 2007-03-26 | 生物柴油安定性添加剂及其制备、使用方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101029257A true CN101029257A (zh) | 2007-09-05 |
CN101029257B CN101029257B (zh) | 2010-11-17 |
Family
ID=38714811
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2007100272928A Expired - Fee Related CN101029257B (zh) | 2007-03-26 | 2007-03-26 | 生物柴油安定性添加剂及其制备、使用方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101029257B (zh) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009108747A1 (en) * | 2008-02-27 | 2009-09-03 | Wayne State University | The effect of natural and synthetic antioxidants on the oxidative stability of biodiesel |
CN102378809A (zh) * | 2009-03-28 | 2012-03-14 | 埃科巴希斯股份公司 | 作为源于生物的再生燃料和加热材料的柠檬酸酯 |
CN102634399A (zh) * | 2012-04-28 | 2012-08-15 | 云南大学 | 一种延长小桐子生物柴油储藏期的方法 |
WO2013075296A1 (zh) * | 2011-11-23 | 2013-05-30 | Xiong Liang | 碳氢燃料抗氧化剂及其使用方法 |
EP2459687A4 (en) * | 2009-07-31 | 2013-10-30 | Exxonmobil Res & Eng Co | BIODIESEL AND FUELS MIXED WITH BIODIESEL |
CN109092357A (zh) * | 2017-06-21 | 2018-12-28 | 中国石油化工股份有限公司 | 环己烷直接氧化合成己二酸的催化剂 |
CN109777530A (zh) * | 2019-01-31 | 2019-05-21 | 中实投石化科技有限公司 | 一种柴油发动机尾气净化液 |
CN109957426A (zh) * | 2017-12-22 | 2019-07-02 | 广州市浪奇实业股份有限公司 | 调合型生物柴油 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100383220C (zh) * | 2006-01-23 | 2008-04-23 | 生作仁 | 生物柴油及其制备工艺 |
-
2007
- 2007-03-26 CN CN2007100272928A patent/CN101029257B/zh not_active Expired - Fee Related
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009108747A1 (en) * | 2008-02-27 | 2009-09-03 | Wayne State University | The effect of natural and synthetic antioxidants on the oxidative stability of biodiesel |
US8657890B2 (en) | 2008-02-27 | 2014-02-25 | Wayne State University | Effect of natural and synthetic antioxidants on the oxidative stability of biodiesel |
CN102378809A (zh) * | 2009-03-28 | 2012-03-14 | 埃科巴希斯股份公司 | 作为源于生物的再生燃料和加热材料的柠檬酸酯 |
EP2459687A4 (en) * | 2009-07-31 | 2013-10-30 | Exxonmobil Res & Eng Co | BIODIESEL AND FUELS MIXED WITH BIODIESEL |
WO2013075296A1 (zh) * | 2011-11-23 | 2013-05-30 | Xiong Liang | 碳氢燃料抗氧化剂及其使用方法 |
CN104039936A (zh) * | 2011-11-23 | 2014-09-10 | 熊靓 | 碳氢燃料抗氧化剂及其使用方法 |
CN102634399A (zh) * | 2012-04-28 | 2012-08-15 | 云南大学 | 一种延长小桐子生物柴油储藏期的方法 |
CN109092357A (zh) * | 2017-06-21 | 2018-12-28 | 中国石油化工股份有限公司 | 环己烷直接氧化合成己二酸的催化剂 |
CN109957426A (zh) * | 2017-12-22 | 2019-07-02 | 广州市浪奇实业股份有限公司 | 调合型生物柴油 |
CN109777530A (zh) * | 2019-01-31 | 2019-05-21 | 中实投石化科技有限公司 | 一种柴油发动机尾气净化液 |
Also Published As
Publication number | Publication date |
---|---|
CN101029257B (zh) | 2010-11-17 |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
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ASS | Succession or assignment of patent right |
Owner name: SANSHUI ZHENGHE PRECISE CHEMICAL ENGINEERING CO., Free format text: FORMER OWNER: ZHAO ZHIMING; APPLICANT Effective date: 20080411 |
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C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20080411 Address after: Guangdong, Foshan, Sanshui District, South West Street, village committee, resource post (former Coating Factory), zip code: 528100 Applicant after: Foshan Sanshui Zhenghe Fine Chemical Co., Ltd. Address before: Zip code 95, South Fenjiang Road, Chancheng District, Foshan, Guangdong, China: 528000 Applicant before: Zhao Zhi Ming Co-applicant before: Huang Jiangchuan |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20101117 Termination date: 20150326 |
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EXPY | Termination of patent right or utility model |