CN100580147C - 有色金属电积用节能惰性阳极材料的制备方法 - Google Patents
有色金属电积用节能惰性阳极材料的制备方法 Download PDFInfo
- Publication number
- CN100580147C CN100580147C CN200810058194A CN200810058194A CN100580147C CN 100580147 C CN100580147 C CN 100580147C CN 200810058194 A CN200810058194 A CN 200810058194A CN 200810058194 A CN200810058194 A CN 200810058194A CN 100580147 C CN100580147 C CN 100580147C
- Authority
- CN
- China
- Prior art keywords
- anode material
- energy
- inert anode
- lead
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000010405 anode material Substances 0.000 title claims abstract description 31
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 28
- 239000002184 metal Substances 0.000 title claims abstract description 28
- 238000004070 electrodeposition Methods 0.000 title claims description 24
- 150000002739 metals Chemical class 0.000 title claims description 13
- 238000000034 method Methods 0.000 title abstract description 14
- 238000004519 manufacturing process Methods 0.000 title abstract description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 22
- 239000004411 aluminium Substances 0.000 claims abstract description 19
- 239000004033 plastic Substances 0.000 claims abstract description 14
- 229920003023 plastic Polymers 0.000 claims abstract description 14
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 6
- 239000007921 spray Substances 0.000 claims abstract description 4
- YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims description 13
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical group CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 10
- 239000011159 matrix material Substances 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 8
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 7
- 229910006529 α-PbO Inorganic materials 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 6
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 4
- 239000011231 conductive filler Substances 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 229920000768 polyamine Polymers 0.000 claims description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 2
- 238000005488 sandblasting Methods 0.000 claims description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 7
- 239000011701 zinc Substances 0.000 abstract description 7
- 229910052725 zinc Inorganic materials 0.000 abstract description 7
- 238000007747 plating Methods 0.000 abstract description 6
- 229910052802 copper Inorganic materials 0.000 abstract description 4
- 239000010949 copper Substances 0.000 abstract description 4
- 238000005363 electrowinning Methods 0.000 abstract description 4
- 239000000956 alloy Substances 0.000 abstract description 3
- 229910045601 alloy Inorganic materials 0.000 abstract description 3
- YADSGOSSYOOKMP-UHFFFAOYSA-N lead dioxide Inorganic materials O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- 238000002791 soaking Methods 0.000 abstract description 2
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 abstract 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 238000004090 dissolution Methods 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 239000010936 titanium Substances 0.000 description 13
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 8
- 229910052719 titanium Inorganic materials 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
- 230000003245 working effect Effects 0.000 description 3
- 229910014474 Ca-Sn Inorganic materials 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 229910000978 Pb alloy Inorganic materials 0.000 description 1
- 229910020159 Pb—Cd Inorganic materials 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- LWUVWAREOOAHDW-UHFFFAOYSA-N lead silver Chemical compound [Ag].[Pb] LWUVWAREOOAHDW-UHFFFAOYSA-N 0.000 description 1
- VJPLIHZPOJDHLB-UHFFFAOYSA-N lead titanium Chemical compound [Ti].[Pb] VJPLIHZPOJDHLB-UHFFFAOYSA-N 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Electrolytic Production Of Metals (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200810058194A CN100580147C (zh) | 2008-03-19 | 2008-03-19 | 有色金属电积用节能惰性阳极材料的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200810058194A CN100580147C (zh) | 2008-03-19 | 2008-03-19 | 有色金属电积用节能惰性阳极材料的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101245478A CN101245478A (zh) | 2008-08-20 |
CN100580147C true CN100580147C (zh) | 2010-01-13 |
Family
ID=39946153
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200810058194A Active CN100580147C (zh) | 2008-03-19 | 2008-03-19 | 有色金属电积用节能惰性阳极材料的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN100580147C (zh) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101736369B (zh) * | 2009-12-29 | 2011-08-17 | 昆明理工大学 | 锌电积用新型铝基复合二氧化铅-二氧化锰阳极的制备方法 |
CN102465314A (zh) * | 2010-11-17 | 2012-05-23 | 北京有色金属研究总院 | 一种电积锌用铅或铅合金惰性阳极的预处理方法 |
CN102864469B (zh) * | 2011-07-08 | 2015-11-25 | 浙江盈联科技有限公司 | 一种新型复合阳极板的制作方法 |
CN103205780B (zh) * | 2013-04-15 | 2017-04-26 | 昆明理工恒达科技有限公司 | 有色金属电积用栅栏型钛基PbO2电极及其制备方法 |
CN107245729B (zh) * | 2017-06-21 | 2018-12-25 | 昆明理工大学 | 锰电积用碳纤维基梯度复合阳极材料及其制备方法 |
CN108149280A (zh) * | 2017-12-20 | 2018-06-12 | 西安泰金工业电化学技术有限公司 | 一种旋流电解装置用钛基管网复合铅阳极及其制备方法 |
CN108774737B (zh) * | 2018-06-13 | 2020-02-14 | 昆明理工恒达科技股份有限公司 | 一种泡沫金属基铅合金复合阳极材料的制备方法 |
CN109537000B (zh) * | 2018-11-27 | 2020-12-08 | 昆明理工大学 | 一种不锈钢基β-PbO2-MnO2-CeO2-ZrO2惰性复合阳极材料的制备方法 |
CN109628957A (zh) * | 2018-12-27 | 2019-04-16 | 西安泰金工业电化学技术有限公司 | 一种锌电积用钛基纳米复合阳极的制备方法 |
CN111926349B (zh) * | 2020-09-09 | 2021-10-15 | 中南大学 | 一种湿法冶金用复合阳极及其制备方法和应用 |
CN113604841A (zh) * | 2021-07-22 | 2021-11-05 | 田成 | 非惰性阳极板在废液中提取回收有价金属的方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101058889A (zh) * | 2006-04-17 | 2007-10-24 | 中国科学院生态环境研究中心 | 一种提高PbO2电极降解效能的电极改性方法 |
-
2008
- 2008-03-19 CN CN200810058194A patent/CN100580147C/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101058889A (zh) * | 2006-04-17 | 2007-10-24 | 中国科学院生态环境研究中心 | 一种提高PbO2电极降解效能的电极改性方法 |
Non-Patent Citations (6)
Title |
---|
钛基金属氧化物涂层电极的研究进展. 汪文兵等.电镀与涂饰,第25卷第7期. 2006 |
钛基金属氧化物涂层电极的研究进展. 汪文兵等.电镀与涂饰,第25卷第7期. 2006 * |
锌电积用惰性阳极材料的研究现状. 徐瑞东等.电镀与环保,第25卷第1期. 2005 |
锌电积用惰性阳极材料的研究现状. 潘君益等.云南冶金,第33卷第6期. 2004 |
锌电积用惰性阳极材料的研究现状. 徐瑞东等.电镀与环保,第25卷第1期. 2005 * |
锌电积用惰性阳极材料的研究现状. 潘君益等.云南冶金,第33卷第6期. 2004 * |
Also Published As
Publication number | Publication date |
---|---|
CN101245478A (zh) | 2008-08-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN100580147C (zh) | 有色金属电积用节能惰性阳极材料的制备方法 | |
CN101343758B (zh) | 锌电积用惰性阳极材料的制备方法 | |
CN103205780B (zh) | 有色金属电积用栅栏型钛基PbO2电极及其制备方法 | |
CN101736369B (zh) | 锌电积用新型铝基复合二氧化铅-二氧化锰阳极的制备方法 | |
CN102212849B (zh) | 一种有色金属电积用新型阳极板制备方法 | |
CN101538724B (zh) | 有色金属电积用节能型金属基陶瓷惰性阳极材料的制备方法 | |
CN101736390B (zh) | 一种二氧化铅电极板及其制备方法 | |
CN101922024B (zh) | 一种有色金属电沉积用轻质复合电催化节能阳极及其制备方法 | |
CN104313652B (zh) | 一种铝基多相惰性复合阳极材料的制备方法 | |
CN107604388A (zh) | 复合阳极材料及其制备方法、阳极板及其制备方法 | |
CN103060874A (zh) | 一种不锈钢基β-PbO2-SnO2-CeO2-ZrO2惰性复合阳极材料的制备方法 | |
CN201220972Y (zh) | 有色金属电积用节能惰性阳极板 | |
CN108149280A (zh) | 一种旋流电解装置用钛基管网复合铅阳极及其制备方法 | |
CN1184357C (zh) | 梯度功能复合阳极材料的制备方法 | |
CN102433581B (zh) | 一种有色金属电积用新型阳极材料的制备方法 | |
CN110714219A (zh) | 镁合金微弧氧化表面电镀镍的方法 | |
CN103572331B (zh) | 有色金属电积用栅栏型钛基PbO2阳极的制作方法 | |
CN105132980B (zh) | 一种铅银合金阳极表面复合陶瓷膜层成膜方法 | |
CN102443822B (zh) | 一种锌电积用梯度功能惰性阳极材料及其制备方法 | |
CN103981541A (zh) | 一种非贵金属氧化物涂层电极的制备方法 | |
CN108754546B (zh) | 锌电积用多孔铝棒铅合金表面镀膜复合阳极及其制备方法 | |
CN102296330B (zh) | 钛基铅-碳化钨-氧化铈-聚苯胺复合阳极板的制备方法 | |
CN102586821A (zh) | 一种锡-锌合金电镀液 | |
CN102534717A (zh) | 一种在工程塑料基底上制备二氧化铅电极板的方法 | |
CN103060875A (zh) | 一种铜基SnO2-Sb2O5-CeO2-TiO2惰性复合阳极材料的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: LIGONG HENGDA SCI. + TECH. CO., LTD., KUNMING Free format text: FORMER OWNER: GUO ZHONGCHENG Effective date: 20110803 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20110803 Address after: 650106, No. 1299 Chang Yuan North Road, hi tech Development Zone, Yunnan, Kunming Patentee after: Ligong Hengda Sci. & Tech. Co., Ltd., Kunming Address before: 650106, No. 1299 Chang Yuan North Road, Kunming hi tech Development Zone, Yunnan, China Patentee before: Guo Zhongcheng |
|
C56 | Change in the name or address of the patentee |
Owner name: KUNMING HENDERA SCIENCE AND TECHNOLOGY CO., LTD. Free format text: FORMER NAME: LIGONG HENGDA SCI. + TECH. CO., LTD., KUNMING |
|
CP03 | Change of name, title or address |
Address after: 650101, No. 1299 Chang Yuan North Road, Kunming hi tech Development Zone, Yunnan Patentee after: KUNMING HENDERA SCIENCE AND TECHNOLOGY CO., LTD. Address before: 650106, No. 1299 Chang Yuan North Road, hi tech Development Zone, Yunnan, Kunming Patentee before: Ligong Hengda Sci. & Tech. Co., Ltd., Kunming |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Method for manufacturing energy-saving inert anode material for non-ferro metals electrodeposition Effective date of registration: 20140414 Granted publication date: 20100113 Pledgee: China Merchants Bank, Limited by Share Ltd, Kunming Yuantong branch Pledgor: KUNMING HENDERA SCIENCE AND TECHNOLOGY CO., LTD. Registration number: 2014990000265 |
|
PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20150728 Granted publication date: 20100113 Pledgee: China Merchants Bank, Limited by Share Ltd, Kunming Yuantong branch Pledgor: KUNMING HENDERA SCIENCE AND TECHNOLOGY CO., LTD. Registration number: 2014990000265 |
|
PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20151223 Address after: 650000 two street base, Jinning Industrial Park, Kunming, Yunnan Patentee after: Jinning science and technology Hengda Technology Co., Ltd. Address before: 650101, No. 1299 Chang Yuan North Road, Kunming hi tech Development Zone, Yunnan Patentee before: KUNMING HENDERA SCIENCE AND TECHNOLOGY CO., LTD. |