CN100567338C - 制备可分级的1-丁烯聚合物的方法 - Google Patents

制备可分级的1-丁烯聚合物的方法 Download PDF

Info

Publication number
CN100567338C
CN100567338C CNB2005800244626A CN200580024462A CN100567338C CN 100567338 C CN100567338 C CN 100567338C CN B2005800244626 A CNB2005800244626 A CN B2005800244626A CN 200580024462 A CN200580024462 A CN 200580024462A CN 100567338 C CN100567338 C CN 100567338C
Authority
CN
China
Prior art keywords
formula
alkyl
butylene
compound
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB2005800244626A
Other languages
English (en)
Chinese (zh)
Other versions
CN1989159A (zh
Inventor
M·S·唐蒂
L·雷斯科尼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Publication of CN1989159A publication Critical patent/CN1989159A/zh
Application granted granted Critical
Publication of CN100567338C publication Critical patent/CN100567338C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CNB2005800244626A 2004-07-22 2005-06-10 制备可分级的1-丁烯聚合物的方法 Expired - Fee Related CN100567338C (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP04103525.4 2004-07-22
EP04103525 2004-07-22
US60/592,346 2004-07-28
EP05100415.8 2005-01-24
US60/652,184 2005-02-10

Publications (2)

Publication Number Publication Date
CN1989159A CN1989159A (zh) 2007-06-27
CN100567338C true CN100567338C (zh) 2009-12-09

Family

ID=38185425

Family Applications (2)

Application Number Title Priority Date Filing Date
CNB2005800244626A Expired - Fee Related CN100567338C (zh) 2004-07-22 2005-06-10 制备可分级的1-丁烯聚合物的方法
CNB2005800245277A Expired - Fee Related CN100567387C (zh) 2004-07-22 2005-06-10 1-丁烯聚合物组合物

Family Applications After (1)

Application Number Title Priority Date Filing Date
CNB2005800245277A Expired - Fee Related CN100567387C (zh) 2004-07-22 2005-06-10 1-丁烯聚合物组合物

Country Status (15)

Country Link
US (1) US7799871B2 (enExample)
EP (1) EP1769030B1 (enExample)
JP (1) JP2008506824A (enExample)
KR (1) KR20070043800A (enExample)
CN (2) CN100567338C (enExample)
AT (1) ATE388994T1 (enExample)
AU (1) AU2005263670A1 (enExample)
BR (1) BRPI0513109A (enExample)
CA (1) CA2573975A1 (enExample)
DE (1) DE602005005334T2 (enExample)
ES (1) ES2303260T3 (enExample)
PL (1) PL1769030T3 (enExample)
RU (2) RU2371459C2 (enExample)
TW (1) TW200613418A (enExample)
WO (1) WO2006008211A1 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE445650T1 (de) 2004-05-04 2009-10-15 Basell Polyolefine Gmbh Verfahren zur herstellung von ataktischen 1- butenpolymeren
CA2573984A1 (en) 2004-07-22 2006-01-26 Basell Polyolefine Gmbh Process for producing fractionable 1-butene polymers
WO2007122098A1 (en) 2006-04-21 2007-11-01 Basell Polyolefine Gmbh Process for the preparation of ethylene copolymers
US8785575B2 (en) * 2006-04-21 2014-07-22 Basell Polyolefine Gmbh Process for the preparation of ethylene propylene copolymers
US8097681B2 (en) 2006-08-30 2012-01-17 Basell Polyolefine Gmbh 1-butene propylene copolymer compositions
EP2057226B1 (en) 2006-08-30 2009-12-09 Basell Polyolefine GmbH 1-butene propylene copolymer compositions
DE102008005947A1 (de) * 2008-01-24 2009-07-30 Evonik Degussa Gmbh Polyolefine mit Ataktischen Strukturelementen, Verfahren zu deren Herstellung und deren Verwendung
ATE527289T1 (de) * 2008-04-22 2011-10-15 Basell Poliolefine Srl 1-butenterpolymere
CN101337997B (zh) * 2008-08-13 2012-09-05 中国科学院化学研究所 一种载体型双金属复合催化剂及其制备方法
CN101891856B (zh) * 2010-07-09 2011-10-19 锦州康泰润滑油添加剂有限公司 一种利用工业废碳四中烯烃制备正丁烯聚合物的方法
KR101749433B1 (ko) * 2012-09-14 2017-06-20 미쯔이가가꾸가부시끼가이샤 1-부텐·α-올레핀 공중합체 조성물
PL3266824T3 (pl) * 2016-07-07 2022-05-09 Basell Poliolefine Italia S.R.L. Kompozycja polimerowa butenu-1 o wysokim wskaźniku szybkości płynięcia
EP3266825B1 (en) * 2016-07-07 2022-03-09 Basell Poliolefine Italia S.r.l. Butene-1 polymer composition having a high melt flow rate
WO2019025583A1 (en) * 2017-08-04 2019-02-07 Basell Poliolefine Italia S.R.L. Butene-1 polymer composition having high melt flow rate
US11267911B2 (en) * 2017-08-04 2022-03-08 Basell Poliolefine Italia S.R.L. Butene-1 polymer composition having high melt flow rate
CN115991804A (zh) * 2021-10-20 2023-04-21 中国石油化工股份有限公司 聚1-丁烯及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5852143A (en) * 1995-05-16 1998-12-22 Union Carbide Chemicals & Plastics Technology Corporation Production of polyethylene using stereoisomeric metallocenes
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
CN1444594A (zh) * 2000-06-30 2003-09-24 埃克森美孚化学专利公司 桥接双(茚基)金属茂化合物

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1915061B2 (de) * 1969-03-25 1972-03-23 Chemische Werke Hüls AG, 4370 Mari Leitfaehige kunststoffmasse fuer den kabelsektor
DE2254128C3 (de) * 1972-11-04 1975-08-14 Chemische Werke Huels Ag, 4370 Marl Thermoplastische Formmasse aus Polybuten-I
US4298722A (en) 1980-03-11 1981-11-03 E. I. Du Pont De Nemours And Company Fractionable, elastomeric poly (1-butene)
ATE38044T1 (de) 1984-08-30 1988-11-15 Mitsui Petrochemical Ind Buten-1-polymer und seine verwendung.
WO1991002012A1 (en) 1989-08-03 1991-02-21 Exxon Chemical Patents Inc. Very high molecular weight polyethylene
WO1992000333A2 (en) 1990-06-22 1992-01-09 Exxon Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
IT1243430B (it) * 1990-09-28 1994-06-10 Himont Inc Composizioni di polimeri cristallini del propilene aventi bassa temperatura
EP0584609B1 (de) * 1992-08-15 1999-03-10 TARGOR GmbH Verfahren zur Herstellung von Polyolefinen
IT1256259B (it) 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Composti mettallocenici aventi leganti di tipo fluorenilico
EP0930320A1 (en) * 1997-07-22 1999-07-21 Mitsui Chemicals, Inc. Ethylene/alpha-olefin copolymers, compositions, and processes for the preparation of the copolymers and the compositions
IT1295052B1 (it) * 1997-09-24 1999-04-27 Montell North America Inc Miscele poliolefiniche elastomeriche parzialmente reticolate
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
KR19990067851A (ko) * 1998-01-14 1999-08-25 고오사이 아끼오 올레핀 중합체, 올레핀 중합 촉매 및 올레핀 중합체의 제조 방법
DE69910511T2 (de) 1998-03-05 2004-06-17 Basell Poliolefine Italia S.P.A. Polybutene-1 (co)polymere und verfahren zu ihrer herstellung
US6900343B1 (en) 1998-11-25 2005-05-31 Basell Polyolefine Gmbh Method for the purification of metallocenes
EP1214364B1 (en) 1999-09-22 2003-07-16 Basell Polyolefine GmbH Catalyst system and process for the polymerization of olefins
DE19962910A1 (de) 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
DE19962814A1 (de) 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
EP1173445B1 (en) 2000-02-24 2004-06-09 Basell Polyolefine GmbH Organometallic compound useful as cocatalyst for polymerizing olefins
US20020123538A1 (en) * 2000-12-29 2002-09-05 Peiguang Zhou Hot-melt adhesive based on blend of amorphous and crystalline polymers for multilayer bonding
JP2002348343A (ja) * 2001-05-28 2002-12-04 Idemitsu Petrochem Co Ltd オレフィン系重合体、その製造方法及び該重合体を含む熱可塑性樹脂組成物
JP4571798B2 (ja) 2001-06-12 2010-10-27 バーゼル・ポリオレフィン・ゲーエムベーハー １−ブテンの重合方法
DE60233961D1 (de) 2001-06-12 2009-11-19 Basell Polyolefine Gmbh Verfahren zur Polymerisation von Buten-1
EP1412347B1 (en) 2001-08-01 2006-01-11 Basell Polyolefine GmbH Process for the preparation of heterocyclic pentalene derivatives
JP2003096135A (ja) * 2001-09-21 2003-04-03 Idemitsu Petrochem Co Ltd ポリ（ブテン−１）とその製造方法および成形体
ES2268126T3 (es) 2001-11-30 2007-03-16 Basell Polyolefine Gmbh Compuestos de metaloceno y procedimiento para la preparacion de polimeros de propileno.
WO2003099883A1 (en) 2002-05-29 2003-12-04 Basell Poliolefine Italia S.P.A. Butene-1 (co)polymers and process for their preparation
AU2003296585A1 (en) * 2002-12-04 2004-06-23 Basell Polyolefine Gmbh 1-buten copolymers and process for preparing them
US7534848B2 (en) * 2002-12-04 2009-05-19 Basell Polyolefine Gmbh 1-butene copolymers and process for preparing them
KR101060985B1 (ko) 2003-05-12 2011-08-31 바젤 폴리올레핀 게엠베하 1-부텐의 중합 방법
DE10324541A1 (de) 2003-05-28 2004-12-16 Basell Polyolefine Gmbh Organoübergangsmetallverbindung mit einem speziellen Substitutionsmuster, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
JP2007505947A (ja) 2003-05-28 2007-03-15 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 特定の置換パターンを有する有機遷移金属化合物、ビスシクロペンタジエニル配位子組成物、触媒組成物、及ポリオレフィンの製造法
CN101001892A (zh) 2004-03-12 2007-07-18 巴塞尔聚烯烃股份有限公司 用于烯烃聚合的催化剂体系
ATE445650T1 (de) 2004-05-04 2009-10-15 Basell Polyolefine Gmbh Verfahren zur herstellung von ataktischen 1- butenpolymeren
CA2573984A1 (en) 2004-07-22 2006-01-26 Basell Polyolefine Gmbh Process for producing fractionable 1-butene polymers

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5852143A (en) * 1995-05-16 1998-12-22 Union Carbide Chemicals & Plastics Technology Corporation Production of polyethylene using stereoisomeric metallocenes
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
CN1444594A (zh) * 2000-06-30 2003-09-24 埃克森美孚化学专利公司 桥接双(茚基)金属茂化合物

Also Published As

Publication number Publication date
CN100567387C (zh) 2009-12-09
DE602005005334T2 (de) 2009-03-26
ATE388994T1 (de) 2008-03-15
WO2006008211A1 (en) 2006-01-26
RU2007106716A (ru) 2008-08-27
CN1989199A (zh) 2007-06-27
RU2007106715A (ru) 2008-08-27
CN1989159A (zh) 2007-06-27
DE602005005334D1 (de) 2008-04-24
EP1769030A1 (en) 2007-04-04
US7799871B2 (en) 2010-09-21
KR20070043800A (ko) 2007-04-25
CA2573975A1 (en) 2006-01-26
US20080319135A1 (en) 2008-12-25
EP1769030B1 (en) 2008-03-12
ES2303260T3 (es) 2008-08-01
TW200613418A (en) 2006-05-01
PL1769030T3 (pl) 2008-08-29
AU2005263670A1 (en) 2006-01-26
RU2371459C2 (ru) 2009-10-27
BRPI0513109A (pt) 2008-04-29
JP2008506824A (ja) 2008-03-06

Similar Documents

Publication Publication Date Title
CN100567338C (zh) 制备可分级的1-丁烯聚合物的方法
EP1622948B1 (en) Process for polymerizing 1-butene
CN101163723B (zh) 烯烃聚合方法
US20080281060A1 (en) Process For Polymerizaing 1-Hexene or Higher Alpha-Olefins
KR20100024433A (ko) 1-부텐 에틸렌 공중합체
KR20060133960A (ko) 헤테로페이스 프로필렌 공중합체의 제조를 위한 다단계공정
US7538174B2 (en) Isotactic 1-butene copolymers
US20070276076A1 (en) 1-Butene Polymer and Process for the Preparation Thereof
US7776978B2 (en) Process for producing fractionable 1-butene polymers
US20070004814A1 (en) Process for preparing porous polymers and polymers thereof
JP2006509064A (ja) １−ブテンコポリマー類およびそれらの製造方法
JP2011515518A (ja) １−ブテン系ポリマー類の組成物類
CN101023105A (zh) 金属茂化合物、它们制备中使用的配体，1－丁烯聚合物的制备和由此得到的1－丁烯聚合物
JP5027665B2 (ja) １−ブテンポリマー及びこの調製方法
KR20060135606A (ko) 헤테로페이스 프로필렌 공중합체의 제조를 위한 다단계공정
US7531609B2 (en) Process for the preparation of 1-butene/propylene copolymers
CN101511931B (zh) 1-丁烯丙烯共聚物组合物
CN101528841B (zh) 1-丁烯丙烯共聚物组合物
US20070293641A1 (en) Propylene Based Terpolymers

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20091209

Termination date: 20130610