CN100525628C - 防治杂草的方法 - Google Patents
防治杂草的方法 Download PDFInfo
- Publication number
- CN100525628C CN100525628C CNB200480017005XA CN200480017005A CN100525628C CN 100525628 C CN100525628 C CN 100525628C CN B200480017005X A CNB200480017005X A CN B200480017005XA CN 200480017005 A CN200480017005 A CN 200480017005A CN 100525628 C CN100525628 C CN 100525628C
- Authority
- CN
- China
- Prior art keywords
- methyl
- alkyl
- och
- group
- hydroresorcinol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 32
- 241000196324 Embryophyta Species 0.000 title description 19
- -1 2-(substituted benzoyl)-1,3-cyclohexanedione Chemical class 0.000 claims abstract description 27
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims abstract description 25
- 230000002363 herbicidal effect Effects 0.000 claims abstract description 25
- 239000005562 Glyphosate Substances 0.000 claims abstract description 16
- 229940097068 glyphosate Drugs 0.000 claims abstract description 16
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000013522 chelant Substances 0.000 claims abstract description 9
- 150000003839 salts Chemical class 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 25
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 22
- 239000004009 herbicide Substances 0.000 claims description 21
- HJSLFCCWAKVHIW-UHFFFAOYSA-N cyclohexane-1,3-dione Chemical compound O=C1CCCC(=O)C1 HJSLFCCWAKVHIW-UHFFFAOYSA-N 0.000 claims description 18
- 239000001257 hydrogen Substances 0.000 claims description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 16
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 10
- 125000005843 halogen group Chemical group 0.000 claims description 10
- 150000002431 hydrogen Chemical class 0.000 claims description 10
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- VXIVSQZSERGHQP-UHFFFAOYSA-N chloroacetamide Chemical group NC(=O)CCl VXIVSQZSERGHQP-UHFFFAOYSA-N 0.000 claims description 8
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 8
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 125000004890 (C1-C6) alkylamino group Chemical group 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000005531 Flufenacet Substances 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 125000006598 aminocarbonylamino group Chemical group 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- IANUJLZYFUDJIH-UHFFFAOYSA-N flufenacet Chemical group C=1C=C(F)C=CC=1N(C(C)C)C(=O)COC1=NN=C(C(F)(F)F)S1 IANUJLZYFUDJIH-UHFFFAOYSA-N 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 125000004454 (C1-C6) alkoxycarbonyl group Chemical group 0.000 claims description 3
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 claims description 3
- XCSGPAVHZFQHGE-UHFFFAOYSA-N alachlor Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl XCSGPAVHZFQHGE-UHFFFAOYSA-N 0.000 claims description 3
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 3
- 125000006624 (C1-C6) alkoxycarbonylamino group Chemical group 0.000 claims description 2
- 125000004916 (C1-C6) alkylcarbonyl group Chemical group 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000000304 alkynyl group Chemical group 0.000 claims description 2
- 125000003368 amide group Chemical group 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000005578 Mesotrione Substances 0.000 description 9
- KPUREKXXPHOJQT-UHFFFAOYSA-N mesotrione Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O KPUREKXXPHOJQT-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 240000008042 Zea mays Species 0.000 description 5
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 5
- 235000005822 corn Nutrition 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 229910021645 metal ion Inorganic materials 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 239000003094 microcapsule Substances 0.000 description 4
- PGMYKACGEOXYJE-UHFFFAOYSA-N pentyl acetate Chemical compound CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 3
- JLYFCTQDENRSOL-UHFFFAOYSA-N 2-chloro-N-(2,4-dimethylthiophen-3-yl)-N-(1-methoxypropan-2-yl)acetamide Chemical group COCC(C)N(C(=O)CCl)C=1C(C)=CSC=1C JLYFCTQDENRSOL-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- OILAIQUEIWYQPH-UHFFFAOYSA-N cyclohexane-1,2-dione Chemical class O=C1CCCCC1=O OILAIQUEIWYQPH-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000003337 fertilizer Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000009333 weeding Methods 0.000 description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical class CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical group CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- 108010020183 3-phosphoshikimate 1-carboxyvinyltransferase Proteins 0.000 description 2
- FFWSICBKRCICMR-UHFFFAOYSA-N 5-methyl-2-hexanone Chemical compound CC(C)CCC(C)=O FFWSICBKRCICMR-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- 235000016068 Berberis vulgaris Nutrition 0.000 description 2
- 241000335053 Beta vulgaris Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 101100339555 Zymoseptoria tritici HPPD gene Proteins 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000013066 combination product Substances 0.000 description 2
- 229940127555 combination product Drugs 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical group CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 244000037671 genetically modified crops Species 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical group CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical group CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical group CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical group CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 2
- UQDUPQYQJKYHQI-UHFFFAOYSA-N methyl laurate Chemical compound CCCCCCCCCCCC(=O)OC UQDUPQYQJKYHQI-UHFFFAOYSA-N 0.000 description 2
- JGHZJRVDZXSNKQ-UHFFFAOYSA-N methyl octanoate Chemical compound CCCCCCCC(=O)OC JGHZJRVDZXSNKQ-UHFFFAOYSA-N 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 239000003826 tablet Substances 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 1
- OZXIZRZFGJZWBF-UHFFFAOYSA-N 1,3,5-trimethyl-2-(2,4,6-trimethylphenoxy)benzene Chemical group CC1=CC(C)=CC(C)=C1OC1=C(C)C=C(C)C=C1C OZXIZRZFGJZWBF-UHFFFAOYSA-N 0.000 description 1
- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical group C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 description 1
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- PXVVQEJCUSSVKQ-XWVZOOPGSA-N 2-(2-hydroxyethoxy)ethyl (1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(=O)OCCOCCO PXVVQEJCUSSVKQ-XWVZOOPGSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- VLDBEZDOSUKOBS-UHFFFAOYSA-O 2-(3-hydroxyphenyl)ethyl-trimethylazanium Chemical compound C[N+](C)(C)CCC1=CC=CC(O)=C1 VLDBEZDOSUKOBS-UHFFFAOYSA-O 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- JHUUPUMBZGWODW-UHFFFAOYSA-N 3,6-dihydro-1,2-dioxine Chemical compound C1OOCC=C1 JHUUPUMBZGWODW-UHFFFAOYSA-N 0.000 description 1
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 1
- WWJLCYHYLZZXBE-UHFFFAOYSA-N 5-chloro-1,3-dihydroindol-2-one Chemical group ClC1=CC=C2NC(=O)CC2=C1 WWJLCYHYLZZXBE-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000004484 Briquette Substances 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- LKLJBFBTRIWQPL-UHFFFAOYSA-N CCCCCCCCCCCCS(O)(=O)=O.CCO.CCO.N Chemical compound CCCCCCCCCCCCS(O)(=O)=O.CCO.CCO.N LKLJBFBTRIWQPL-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- UXDDRFCJKNROTO-UHFFFAOYSA-N Glycerol 1,2-diacetate Chemical compound CC(=O)OCC(CO)OC(C)=O UXDDRFCJKNROTO-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KGEKLUUHTZCSIP-UHFFFAOYSA-N Isobornyl acetate Chemical group C1CC2(C)C(OC(=O)C)CC1C2(C)C KGEKLUUHTZCSIP-UHFFFAOYSA-N 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical group CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 235000019764 Soybean Meal Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000001940 [(1R,4S,6R)-1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl] acetate Chemical group 0.000 description 1
- 239000001089 [(2R)-oxolan-2-yl]methanol Substances 0.000 description 1
- VWDOGWMGRQQICP-UHFFFAOYSA-N acetic acid propane-1,2,3-triol Chemical group C(C)(=O)O.C(C)(=O)O.C(C)(=O)O.C(C)(=O)O.OCC(O)CO VWDOGWMGRQQICP-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000012050 conventional carrier Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Chemical group CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical group CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002168 ethanoic acid esters Chemical class 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229940100242 glycol stearate Drugs 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 229940117955 isoamyl acetate Drugs 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical class CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Chemical group 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- SHOJXDKTYKFBRD-UHFFFAOYSA-N mesityl oxide Chemical group CC(C)=CC(C)=O SHOJXDKTYKFBRD-UHFFFAOYSA-N 0.000 description 1
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical group [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 239000011785 micronutrient Substances 0.000 description 1
- 235000013369 micronutrients Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 230000001069 nematicidal effect Effects 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 150000002885 octadecanoids Chemical class 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- 239000003924 oil dispersant Substances 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 210000000998 shell membrane Anatomy 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- ODCWYMIRDDJXKW-UHFFFAOYSA-N simazine Chemical compound CCNC1=NC(Cl)=NC(NCC)=N1 ODCWYMIRDDJXKW-UHFFFAOYSA-N 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000004455 soybean meal Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- PZTAGFCBNDBBFZ-UHFFFAOYSA-N tert-butyl 2-(hydroxymethyl)piperidine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCCCC1CO PZTAGFCBNDBBFZ-UHFFFAOYSA-N 0.000 description 1
- BSYVTEYKTMYBMK-UHFFFAOYSA-N tetrahydrofurfuryl alcohol Chemical compound OCC1CCCO1 BSYVTEYKTMYBMK-UHFFFAOYSA-N 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- NRZWQKGABZFFKE-UHFFFAOYSA-N trimethylsulfonium Chemical class C[S+](C)C NRZWQKGABZFFKE-UHFFFAOYSA-N 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
一种长季节防治不期望植物的方法，所述方法包括一次施用含有2-(取代的苯甲酰基)-1，3-环己二酮或其金属螯合物、草甘膦或其盐和乙酰胺的除草组合物。
Description
本发明涉及一次处理对不期望植物提供长季节防治的方法。
保护作物免受杂草和其它抑制作物生长的植物的侵害是农业中经常面临的问题。为了帮助解决该问题，合成化学领域的研究人员制备出有效控制这类不期望生长的多种的化学品和化学制剂。多种化学除草剂描述于文献中，并且大部分是商购可得的。
已确定农业上的农药制造商们需要广谱、长效作用的农药产品。单个活性成分制剂很少符合这类需求，因此需要开发或许包含高达四种互补生物活性成分的组合产品。目前可以得到多种组合产品(即包含超过一种活性成分的产品)，但是无一是一次施用产品能提供广谱、长季节的防治。
因此，本发明的目的是提供一种一次处理对不期望植物提供长季节防治的方法。
就其对植物生长的影响来说，用于本发明方法中的单个化合物各自是本领域已知的。例如，与大量的其它环己二酮化合物一起描述于U.S.专利号5,049,046的除草的环己二酮化合物2-(2′-硝基-4′-甲基磺酰基苯甲酰基)-1，3-环己二酮(甲基磺草酮)是选择性除草剂。乙酰胺类，尤其是2-氯-N-(2-乙基-6-甲基苯基)-N-(2-甲氧基-1-甲基乙基)乙酰胺(异丙甲草胺)是已知具有除草活性的化合物种类。草甘膦是非选择性除草剂，尤其是以商品名
来获得。尽管当施用于不期望植物时，所有的这些组分本身有除草活性，然而无一是一次施用能单独提供目前农业生产所需要的广谱、长季节的防治。
因此，本发明提供一种长季节防治不期望植物的方法，所述方法包括将包含2-(取代的苯甲酰基)-1，3-环己二酮或其金属螯合物、草甘膦或其盐以及乙酰胺的除草组合物一次施用至所述不期望植物的所在地。术语“长季节防治”指对任何作物每季仅需要施用除草组合物一次，则不期望的植物将在整个季节期间保持被控制。“季节”通常长达120天，例如40至120天，例如50至120天。
本发明第二方面提供将包含2-(取代的苯甲酰基)-1，3-环己二酮或其金属螯合物、草甘膦或其盐以及乙酰胺的除草组合物通过一次施用组合物长季节防治不期望植物的用途。
适宜地，用于本发明中的2-(取代的苯甲酰基)-1，3-环己二酮是式(I)化合物
其中X表示卤原子；含有多达6个碳原子的直链或支链烷基或烷氧基，其是任选经一个或多个基团-OR1或一个或多个卤原子取代的；或选自硝基、氰基、-CO2R2、-S(O)mR1、-O(CH2)rOR1、-COR2、-NR2R3、-SO2NR2R3、-CONR2R3、-CSNR2R3和-OSO2R4的基团；
R1表示含有多达6个碳原子的直链或支链烷基，其是任选经一个或多个卤原子取代的；
R2和R3各自独立地表示氢原子；或含有多达6个碳原子的直链或支链烷基，其是任选经一个或多个卤原子取代的；
R4表示含有多达6个碳原子的直链或支链烷基、烯基或炔基，其是任选经一个或多个卤原子取代的；或含有3至6个碳原子的环烷基；
各个Z独立地表示卤素、硝基、氰基、S(O)mR5、OS(O)mR5、C1-6烷基、C1-6烷氧基、C1-6卤烷基、C1-6卤烷氧基、羧基、C1-6烷基羰基氧基、C1-6烷氧基羰基、C1-6烷基羰基、氨基、C1-6烷基氨基、在各个烷基上分别具有所示碳原子数的C1-6二烷基氨基、C1-6烷基羰基氨基、C1-6烷氧基羰基氨基、C1-6烷基氨基羰基氨基、在各个烷基上分别具有所示碳原子数的C1-6二烷基氨基羰基氨基、C1-6烷氧基羰基氧基、C1-6烷基氨基羰基氧基、C1-6二烷基羰基氧基、苯基羰基、经取代的苯基羰基、苯基羰基氧基、经取代的苯基羰基氧基、苯基羰基氨基、经取代的苯基羰基氨基、苯氧基或经取代的苯氧基；
R5表示含有多达6个碳原子的直链或支链烷基；
各个Q独立地表示C1-4烷基或-CO2R6，其中R6为C1-4烷基；
m为0、1或2；
n为0或1至4的整数；
r为1、2或3；和
p为0或1至6的整数，
及其任何农业上可接受的金属螯合物。
适宜地，X为氯、溴、硝基、氰基、C1-4烷基、-CF3、-S(O)mR1、或-OR1；各个Z独立地为氯、溴、硝基、氰基、C1-4烷基、-CF3、-OR1、-OS(O)mR5或-S(O)mR5；n为1或2；以及p为0、1或2。
优选地，式(I)的2-(取代的苯甲酰基)-1，3-环己二酮选自下组：2-(2’-硝基-4’-甲基磺酰基苯甲酰基)-1，3-环己二酮、2-(2’-硝基-4’-甲基磺酰基氧基苯甲酰基)-1，3-环己二酮、2-(2’-氯-4’-甲基磺酰基苯甲酰基)-1，3-环己二酮、4，4-二甲基-2-(4-甲基磺酰基-2-硝基苯甲酰基)-1，3-环己二酮、2-(2-氯-3-乙氧基-4-甲基磺酰基苯甲酰基)-5-甲基-1，3-环己二酮和2-(2-氯-3-乙氧基-4-乙基磺酰基苯甲酰基)-5-甲基-1，3-环己二酮；最优选2-(2’-硝基-4’-甲基磺酰基苯甲酰基)-1，3-环己二酮。
式(I)的2-(取代的苯甲酰基)-1，3-环己二酮可以以会引起立体异构体的烯醇互变异构体形式存在。此外，某些情形下，各种取代基会引起光学异构和/或立体异构。所有的这类互变异构形式、外消旋混合物和异构体都包含在本发明范围内。
式(I)化合物的农业上可接受的金属螯合物详细描述于EP0800317中。特别地，可以用于形成金属螯合物化合物的金属离子包括二-和三价过渡金属离子如Cu2+、Zn2+、Co2+、Fe2+、Ni2+和Fe3+。选择具体的金属离子形成金属螯合物化合物将取决于待螯合的二酮化合物。本领域技术人员将可以容易地确定具体二酮化合物所使用的适宜金属离子，无需过多的实验。优选的金属离子是二价金属离子，优选Cu2+、Zn2+、Co2+，其中Cu2+是尤其优选的。
适宜地，用于本发明的乙酰胺是氯乙酰胺或氧乙酰胺。
在本发明的实施方式中，乙酰胺是式(II)的氯乙酰胺
其中R7为氢、甲基或乙基；R8为氢、甲基或乙基；R9为氢或甲基；R10为甲基、-OCH3、-CH2OCH3、-OCH2CH3、-CH2OCH2CH2CH3、-OCH(CH3)2、-OCH2CH2CH2CH3或下式基团
以及A为S或CH＝CH。
在一个优选的实施方式中，A为CH＝CH；R7为氢、甲基或乙基；R8为氢、甲基或乙基；R9为氢或甲基；R10为甲基、-OCH3、-CH2OCH3、-OCH2CH3、-CH2OCH2CH2CH3、-OCH(CH3)2或-OCH2CH2CH2CH3。优选地，氯乙酰胺是选自下组：异丙甲草胺、乙草胺和甲草胺，优选异丙甲草胺，以及最优选s-异丙甲草胺。
在另一个优选的实施方式中，A为S；R7、R8和R9均为甲基；并且R10为甲氧基甲基。优选地，氯乙酰胺为二甲吩草胺或p-二甲吩草胺。
在本发明进一步的实施方式中，乙酰胺为式(III)的氧乙酰胺
其中R11为氢、甲基、乙基、丙基或异丙基；R12为氢或卤素；以及R13为下式基团
或
适宜地，R11为甲基或异丙基；R12为氢或氟。
优选地，氧乙酰胺为氟噻草胺或mefanacet；最优选氟噻草胺。
用于本发明中的草甘膦可以以游离酸或以适宜的农业上可接受的盐存在。这类盐包括但不限于钾盐、铵盐、异丙铵盐、钠盐和三甲基锍盐。
在本发明尤其优选的实施方式中，用于本发明方法的除草组合物包含2-(2’-硝基-4’-甲基磺酰基苯甲酰基)-1，3-环己二酮、草甘膦和s-异丙甲草胺。
所施用除草组合物的量将取决于待防治杂草的具体类型，所需防治的程度以及施用时间和方法。通常来说，该组合物可以以基于活性成分总量的介于约400g a.i./公顷(g/ha)和约7750g a.i./ha之间的施用量来施用。施用量介于940g a.i./ha和3750g a.i./ha之间是优选的。适宜地，环已二酮以20-300g a.i./ha、优选40-250ga.i./ha的量来施用；草甘膦化合物以200-1400g a.i./ha、优选400-1000g a.i./ha的量来施用；乙酰胺以200-6000g a.i./ha、优选500-2500g a.i./ha的量来施用。在本发明尤其优选的实施方式中，所述组分以足以提供至少2000g a.i./ha的施用量(其中环己二酮提供至少100g/ha)的相对量来施用。
本发明另一方面提供了一种如上所述的长季节防治不期望植物的方法，其中所述除草组合物进一步包含一种或多种其它活性成分。其它活性成分是适宜的农药，例如除草剂、杀真菌剂、杀虫剂、杀线虫剂等；优选地，其它活性成分是除草剂。适宜的除草剂实例包括三嗪类，例如莠去津、特丁津、西玛津等。可以用于本发明的除草剂的其它实例是本领域技术人员已知的。
用于本发明方法中的组分可以以多种本领域技术人员已知的方法于不同浓度下施用。本发明的组合物通过苗前或苗后施用至所需控制地点用于控制不期望植物的生长。当苗后施用，尤其是早期苗后施用本发明的组合物是尤其有效的。
本发明的组合物可以用于广泛的作物，例如谷物(玉米)、小麦、稻、马铃薯或甜菜。适宜的作物包括对组合物中的一种或多种组分耐受的作物。耐受性可以是由选择育种产生的天然耐受性或可以通过基因改良作物人工诱导产生的。耐受性是指相比常规的作物品种而言，降低了对特定除草剂所导致损害的敏感性。可以改良或培育作物使其对例如HPPD抑制剂如甲基磺草酮，或EPSPS抑制剂如草甘膦具有耐受性。谷物(玉米)本身对甲基磺草酮具有耐受性。
用于本发明方法中的组分可以同时或先后施用。若先后施用，则组分可以以任何适宜的时间表顺序施用，例如在施用第一组分和施用最后组分之间的时间不超过24小时。适宜地，所有的组分都在数小时如1小时内施用。
若同时施用组分，则可以分开或以桶混物或以所有组分的预配制混合物或部分组分的预配制混合物与剩余组分进行桶混合的形式施用。
因此，本发明的再一个方面是提供包含2-(取代的苯甲酰基)-1，3-环己二酮或其金属螯合物，草甘膦或其盐以及乙酰胺的除草组合物，条件是(i)当2-(取代的苯甲酰基)-1，3-环己二酮为甲基磺草酮，则所述乙酰胺不为异丙甲草胺、乙草胺、甲草胺或二甲吩草胺，以及(ii)当所述乙酰胺为二甲吩草胺，则2-(取代的苯甲酰基)-1，3-环己二酮不为2-(2-氯-4-甲基磺酰基苯甲酰基)-1，3-环己二酮或2-(4-甲基磺酰基氧基-2-硝基苯甲酰基)-4，4，6，6-四甲基-1，3-环己二酮。
本发明的组合物用作已证实能广谱、长季节地防治不期望的植物的除草剂。该组合物可以用于广泛的作物，例如谷物(玉米)、小麦、水稻、马铃薯或甜菜。适宜的作物包括对组合物中的一种或多种组分耐受的作物。耐受性可以是由选择育种产生的天然耐受性或可以通过基因改良作物人工诱导产生的。耐受性是指相比常规的作物品种而言，降低了对特定除草剂所导致损害的敏感性。可以改良或培育作物使其对例如HPPD抑制剂如甲基磺草酮，或EPSPS抑制剂如草甘膦具有耐受性。谷物(玉米)本身对甲基磺草酮具有耐受性。
本发明的除草组合物还优选包含农业上可接受的载体。在实践中，该组合物是以含有多种已知或用于工业中促进分散的助剂和载体的制剂形式施用的。对于任何所述化合物的制剂和施用方式的选择会影响其活性，因此相应地进行该选择。例如，本发明的除草组合物可以为喷粉剂、凝胶、可湿性粉剂、水分散性粒剂、水分散性或水发泡片剂、坯状(briquette)、乳油、微乳剂、水包油乳液、油包水乳液、水分散剂、油分散剂、悬乳剂、可溶性液体(用水或有机溶剂作为载体)、浸渍聚合物膜，或本领域已知的其它形式。这类制剂适用于直接施用或可以在施用前进行适当稀释，所述稀释可以用水、液体肥料、微量营养素、生物有机体、油或溶剂进行。该组合物的制备是通过将活性组分与助剂(包括稀释剂、增量剂、载体和调节剂)相混合以提供细分散的微粒固体、颗粒剂、片剂、溶液、分散液或乳液形式的组合物。因此，确信活性成分可以与助剂例如细分散的固体、矿物油、有机来源的液体、水、各种表面活性剂或它们任何适宜的组合相混合使用。
该活性成分也可包含在非常细的聚合物微胶囊中。微胶囊典型地包含包封在惰性多孔外壳中的活性物质，该外壳以所控制的速度让包封物质释放到周围环境中。包裹的液滴的直径典型地为约0.1至500微米。包封材料典型地组成约25至95重量％的胶囊。活性成分可以在固体或液体中以整体固体、细分散固体颗粒存在，或其可以以适宜溶剂的溶液存在。壳膜材料包括天然和合成橡胶、纤维素材料、苯乙烯-丁二烯共聚物、聚丙烯腈、聚丙烯酸酯、聚酯、聚酰胺、聚脲、聚氨酯类、其它本领域技术人员已知的聚合物类，化学改良聚合物和淀粉黄原酸酯。另外，可以形成非常细的微胶囊，其中活性成分以细分散颗粒分散在固体材料基质中，但无外壳壁包裹微胶囊。
用于制备本发明组合物的适宜农业助剂和载体是本领域技术人员熟知的。
可使用的液体载体包括水、甲苯、二甲苯、石脑油、作物油、丙酮、甲基乙基酮、环己酮、乙酸酐、乙腈、苯乙酮、乙酸戊酯、2-丁酮、氯苯、环己烷、环己醇、烷基乙酸酯、二丙酮醇、1，2-二氯丙烷、二乙醇胺、对-二乙苯、二乙二醇、二乙二醇枞酸酯、二乙二醇丁醚、二乙二醇乙醚、二乙二醇甲醚、N，N-二甲基甲酰胺、二甲亚砜、1，4-二氧六环、二丙二醇、二丙二醇甲醚、二丙二醇二苯甲酸酯、diproxitol、烷基吡咯烷酮、乙酸乙酯、2-乙基己醇、碳酸乙二酯、1，1，1-三氯乙烷、2-庚酮、α-蒎烯、d-苎烯、乙二醇、乙二醇丁醚、乙二醇甲醚、γ-丁内酯、丙三醇、丙三醇双乙酸酯、丙三醇单乙酸酯、丙三醇三乙酸酯、丙三醇四乙酸酯、十六烷、己二醇、乙酸异戊酯、乙酸异冰片酯、异辛烷、异佛尔酮、异丙基苯、异丙基肉豆蔻酸酯、乳酸、月桂胺、异亚丙基丙酮、甲氧基-丙醇、甲基异戊基酮、甲基异丁基酮、十二烷酸甲酯、辛酸甲酯、油酸甲酯、二氯甲烷、间二甲苯、正己烷、正辛胺、十八烷酸、辛胺乙酸酯、油酸、油烯基胺、邻二甲苯、苯酚、聚乙二醇(PEG400)、丙酸、丙二醇、丙二醇单甲醚、丙二醇单甲基醚、对二甲苯、甲苯、磷酸三乙酯、三甘醇、二甲苯磺酸、石蜡、矿物油、三氯乙烯、全氯乙烯、乙酸乙酯、乙酸戊酯、乙酸丁酯、丙二醇单甲醚和二乙二醇单甲醚、甲醇、乙醇、异丙醇，以及更高分子量的醇类如戊醇、四氢糠醇、己醇等，乙二醇、丙二醇、丙三醇、N-甲基-2-吡咯烷酮等。水是稀释浓缩物所选择的常规载体。
适宜的固体载体包括滑石、二氧化钛、叶蜡石粘土、硅石、硅镁土、硅藻石(kieselguhr)、白垩、硅藻土、石灰、碳酸钙、膨润土、富乐土、棉籽壳、面粉、大豆粉、浮石、木粉、核桃壳粉、木质素等。
大量表面活性剂有利地用于固体和液体组合物中，尤其是计划在施用前用载体稀释的组合物。表面活性剂可以为性质上是阴离子、阳离子、非离子或聚合物的，并且可以用作乳化剂、湿润剂、悬浮剂或其它目的。典型的表面活性剂包括烷基硫酸盐，例如月桂基磺酸二乙醇铵；烷基芳基磺酸盐如十二烷基苯磺酸钙；烷基酚-烯烃氧化加成产物，例如壬基酚-C低于18的乙氧基化物；醇-烯烃氧化加成产物如十三醇-C低于16的乙氧基化物；皂类例如硬脂酸钠；烷基萘磺酸盐例如二丁基萘磺酸钠；磺基丁二酸盐的二烷基酯例如磺基丁二酸二(2-乙基己基)酯钠；山梨糖醇酯如山梨糖醇油酸酯；季铵类如月桂基三甲基铵盐氯化物；脂肪酸的聚乙二醇酯类如聚乙二醇硬脂酸酯；环氧乙烷和环氧丙烷的嵌段共聚物；以及单和二烷基磷酸酯的盐。
其它通常用于农业组合物中的助剂包括结晶抑制剂、粘度调节剂、悬浮剂、喷雾滴调节剂、色素、抗氧化剂、起泡剂、光阻断剂、相容剂、消泡剂、多价螯合剂、中和剂和缓冲剂、防腐剂、染料、气味剂、扩散剂、渗透助剂、微粒营养物、软化剂、润滑剂、粘着剂、分散剂、增稠剂、防冻剂、抗微生物剂等。该组合物还可以包含其它的相容组分，例如其它的除草剂、除草安全剂、植物生长调节剂、杀真菌剂、杀虫剂等，并且可以用液体肥料或固体、微粒肥料载体如硝酸铵、尿素等进行配制。
本发明将根据下面的实施例更详细地描述。
利用如下组合物对玉米作物中的多种杂草进行了大量试验：
1.甲基磺草酮/草甘膦
2.甲基磺草酮/草甘膦/S-异丙甲草胺
3.甲基磺草酮/草甘膦/S-异丙甲草胺/莠去津
草甘膦以两种不同水平施用。作物的苗后早期进行处理。在施用后的不同时间评价杂草防治水平(DAA)。可以看出用三或四种化合物组合比两种化合物组合改善了对杂草的防治作用。结果如表1所示。
Claims (16)
1.一种长季节防治不期望植物的方法，所述方法包括一次苗后施用含有2-(取代的苯甲酰基)-1，3-环己二酮或其金属螯合物、草甘膦或其盐和乙酰胺类除草剂的除草组合物。
2.根据权利要求1的方法，其中所述2-(取代的苯甲酰基)-1，3-环己二酮是式(I)化合物
其中X表示卤原子；含有多达6个碳原子的直链或支链烷基或烷氧基，其是任选经一个或多个基团-OR1或一个或多个卤原子取代的；或选自硝基、氰基、-CO2R2、-S(O)mR1、-O(CH2)rOR1、-COR2、-NR2R3、-SO2NR2R3、-CONR2R3、-CSNR2R3和-OSO2R4的基团；
R1表示含有多达6个碳原子的直链或支链烷基，其是任选经一个或多个卤原子取代的；
R2和R3各自独立地表示氢原子；或含有多达6个碳原子的直链或支链烷基，其是任选经一个或多个卤原子取代的；
R4表示含有多达6个碳原子的直链或支链烷基、烯基或炔基，其是任选经一个或多个卤原子取代的；或含有3至6个碳原子的环烷基；
各个Z独立地表示卤素、硝基、氰基、S(O)mR5、OS(O)mR5、C1-6烷基、G1-6烷氧基、C1-6卤烷基、C1-6卤烷氧基、羧基、C1-6烷基羰基氧基、G1-6烷氧基羰基、C1-6烷基羰基、氨基、C1-6烷基氨基、在各个烷基上分别具有所示碳原子数的G1-6二烷基氨基、C1-6烷基羰基氨基、C1-6烷氧基羰基氨基、C1-6烷基氨基羰基氨基、在各个烷基上分别具有所示碳原子数的C1-6二烷基氨基羰基氨基、C1-6烷氧基羰基氧基、C1-6烷基氨基羰基氧基、C1-6二烷基羰基氧基、苯基羰基、苯基羰基氧基、苯基羰基氨基或苯氧基；
R5表示含有多达6个碳原子的直链或支链烷基；
各个Q独立地表示C1-4烷基或-CO2R6，其中R6为C1-4烷基；
m为0、1或2；
n为0或1至4的整数；
r为1、2或3；和
p为0或1至6的整数，
及其任何农业上可接受的金属螯合物。
3.根据权利要求2的方法，其中X为氯、溴、硝基、氰基、C1-4烷基、-CF3、-S(O)mR1、或-OR1；各个Z独立地为氯、溴、硝基、氰基、C1-4烷基、-CF3、-OR1、-OS(O)mR5或-S(O)mR5；n为1或2；以及p为0、1或2。
4.根据权利要求3的方法，其中式(I)的2-(取代的苯甲酰基)-1，3-环己二酮选自下组：2-(2’-硝基-4’-甲基磺酰基苯甲酰基)-1，3-环己二酮、2-(2’-硝基-4’-甲基磺酰基氧基苯甲酰基)-1，3-环己二酮、2-(2’-氯-4’-甲基磺酰基苯甲酰基)-1，3-环己二酮、4，4-二甲基-2-(4-甲基磺酰基-2-硝基苯甲酰基)-1，3-环己二酮、2-(2-氯-3-乙氧基-4-甲基磺酰基苯甲酰基)-5-甲基-1，3-环己二酮和2-(2-氯-3-乙氧基-4-乙基磺酰基苯甲酰基)-5-甲基-1，3-环己二酮。
5.根据权利要求1至4任一项所述的方法，其中所述乙酰胺类除草剂为氯乙酰胺和氧乙酰胺。
6.根据权利要求5的方法，其中所述氯乙酰胺是式(II)化合物
其中R7为氢、甲基或乙基；R8为氢、甲基或乙基；R9为氢或甲基；R10为甲基、-OCH3、-CH2OCH3、-OCH2CH3、-CH2OCH2CH2CH3、-OCH(CH3)2、-OCH2CH2CH2CH3或下式基团
以及A为S或CH＝CH。
7.根据权利要求6的方法，其中A为CH＝CH；R7为氢、甲基或乙基；R8为氢、甲基或乙基；R9为氢或甲基；R10为甲基、-OCH3、-CH2OCH3、-OCH2CH3、-CH2OCH2CH2CH3、-OCH(CH3)2或-OCH2CH2CH2CH3。
8.根据权利要求7的方法，其中所述氯乙酰胺选自异丙甲草胺、乙草胺和甲草胺。
9.根据权利要求8的方法，其中氯乙酰胺为s-异丙甲草胺。
10.根据权利要求6的方法，其中A为S；R7、R8和R9均为甲基；并且R10为甲氧基甲基。
11.根据权利要求5的方法，其中所述氧乙酰胺为式(III)化合物
其中R11为氢、甲基、乙基、丙基或异丙基；R12为氢或卤素；以及R13为下式基团
12.根据权利要求11的方法，其中R11为甲基或异丙基；R12为氢或氟。
13.根据权利要求12的方法，其中所述氧乙酰胺为氟噻草胺或mefanacet。
14.根据权利要求13的方法，其中所述氧乙酰胺为氟噻草胺。
15.根据权利要求1至14任一项所述的方法，其中组合物还包含一种或多种其它的活性成分。
16.包含2-(取代的苯甲酰基)-1，3-环己二酮或其金属螯合物、草甘膦或其盐以及乙酰胺的除草组合物通过一次苗后施用组合物而长季节防治不期望植物的用途。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0314190.0 | 2003-06-18 | ||
| GBGB0314190.0A GB0314190D0 (en) | 2003-06-18 | 2003-06-18 | Method of controlling weeds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1809276A CN1809276A (zh) | 2006-07-26 |
| CN100525628C true CN100525628C (zh) | 2009-08-12 |
Family
ID=27636833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB200480017005XA Expired - Lifetime CN100525628C (zh) | 2003-06-18 | 2004-06-07 | 防治杂草的方法 |
Country Status (27)
| Country | Link |
|---|---|
| US (1) | US20060211578A1 (zh) |
| EP (1) | EP1672982B1 (zh) |
| JP (1) | JP4865546B2 (zh) |
| KR (1) | KR101130985B1 (zh) |
| CN (1) | CN100525628C (zh) |
| AR (1) | AR044664A1 (zh) |
| AT (1) | ATE406098T1 (zh) |
| AU (1) | AU2004248952B2 (zh) |
| BR (1) | BRPI0411571A (zh) |
| CA (1) | CA2527087C (zh) |
| CY (1) | CY1108458T1 (zh) |
| DE (1) | DE602004016193D1 (zh) |
| DK (1) | DK1672982T3 (zh) |
| EA (1) | EA009846B1 (zh) |
| EC (1) | ECSP066289A (zh) |
| ES (1) | ES2309523T3 (zh) |
| GB (1) | GB0314190D0 (zh) |
| HR (1) | HRP20051004B1 (zh) |
| MX (1) | MXPA05013275A (zh) |
| NZ (1) | NZ544590A (zh) |
| PL (1) | PL1672982T3 (zh) |
| PT (1) | PT1672982E (zh) |
| RS (1) | RS51570B (zh) |
| SI (1) | SI1672982T1 (zh) |
| UA (1) | UA83836C2 (zh) |
| WO (1) | WO2004112481A1 (zh) |
| ZA (1) | ZA200509375B (zh) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE525905T1 (de) * | 2007-08-27 | 2011-10-15 | Syngenta Participations Ag | Herbizide zusammensetzung und verfahren zu ihrer verwendung |
| UA102840C2 (ru) * | 2008-02-20 | 2013-08-27 | Сингента Партисипейшнс Аг | Гербицидный состав, способ его получения и способ борьбы с нежелательной растительностью |
| GB2532218B (en) * | 2014-11-11 | 2019-11-20 | Rotam Agrochem Int Co Ltd | Herbicidal composition and method for controlling plant growth |
| US11129384B2 (en) * | 2017-06-19 | 2021-09-28 | Upl Ltd | Polymorphs of mesotrione metal chelate and preparation process |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19834627A1 (de) * | 1998-07-31 | 1998-12-03 | Novartis Ag | Herbizides Mittel |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE510454T1 (de) * | 1993-02-18 | 2011-06-15 | Basf Se | Herbizide zusammensetzungen |
| US5716901A (en) * | 1993-02-18 | 1998-02-10 | Sandoz Ltd. | Synergistic herbicidal compositions of dimethenamid, sulcotrione, and atrazine |
| UA63884C2 (en) * | 1995-04-12 | 2004-02-16 | Singenta Participations Ag | Herbicidal composition and a method of controlling the emergence of undesirable plants |
| ES2405266T3 (es) * | 1998-08-13 | 2013-05-30 | Bayer Cropscience Ag | Agentes herbicidas para cultivos de maíz tolerantes o resistentes |
| AR024781A1 (es) * | 1999-07-27 | 2002-10-23 | Bayer Ag | Agentes herbicidas basados en flufenacet. |
| AU2842501A (en) * | 1999-12-17 | 2001-06-25 | Aventis Cropscience S.A. | Method of controlling weeds |
| US6455469B1 (en) * | 2000-12-05 | 2002-09-24 | Ishihara Sangyo Kaisha, Ltd. | Herbicidal composition |
-
2003
- 2003-06-18 GB GBGB0314190.0A patent/GB0314190D0/en not_active Ceased
-
2004
- 2004-06-07 DK DK04736224T patent/DK1672982T3/da active
- 2004-06-07 WO PCT/GB2004/002409 patent/WO2004112481A1/en active IP Right Grant
- 2004-06-07 CA CA2527087A patent/CA2527087C/en not_active Expired - Lifetime
- 2004-06-07 ES ES04736224T patent/ES2309523T3/es not_active Expired - Lifetime
- 2004-06-07 KR KR1020057024137A patent/KR101130985B1/ko not_active IP Right Cessation
- 2004-06-07 AT AT04736224T patent/ATE406098T1/de active
- 2004-06-07 EA EA200600008A patent/EA009846B1/ru not_active IP Right Cessation
- 2004-06-07 RS YU20050928A patent/RS51570B/sr unknown
- 2004-06-07 DE DE602004016193T patent/DE602004016193D1/de not_active Expired - Lifetime
- 2004-06-07 AU AU2004248952A patent/AU2004248952B2/en not_active Expired
- 2004-06-07 CN CNB200480017005XA patent/CN100525628C/zh not_active Expired - Lifetime
- 2004-06-07 JP JP2006516379A patent/JP4865546B2/ja not_active Expired - Fee Related
- 2004-06-07 PL PL04736224T patent/PL1672982T3/pl unknown
- 2004-06-07 PT PT04736224T patent/PT1672982E/pt unknown
- 2004-06-07 BR BRPI0411571-6A patent/BRPI0411571A/pt not_active Application Discontinuation
- 2004-06-07 NZ NZ544590A patent/NZ544590A/en not_active IP Right Cessation
- 2004-06-07 SI SI200430931T patent/SI1672982T1/sl unknown
- 2004-06-07 MX MXPA05013275A patent/MXPA05013275A/es active IP Right Grant
- 2004-06-07 US US10/560,097 patent/US20060211578A1/en not_active Abandoned
- 2004-06-07 UA UAA200600359A patent/UA83836C2/ru unknown
- 2004-06-07 EP EP04736224A patent/EP1672982B1/en not_active Expired - Lifetime
- 2004-06-10 AR ARP040102015A patent/AR044664A1/es not_active Application Discontinuation
-
2005
- 2005-11-18 ZA ZA200509375A patent/ZA200509375B/en unknown
- 2005-12-16 HR HRP20051004AA patent/HRP20051004B1/hr not_active IP Right Cessation
-
2006
- 2006-01-16 EC EC2006006289A patent/ECSP066289A/es unknown
-
2008
- 2008-10-27 CY CY20081101216T patent/CY1108458T1/el unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19834627A1 (de) * | 1998-07-31 | 1998-12-03 | Novartis Ag | Herbizides Mittel |
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101938907B (zh) | 除草组合物 | |
| CN101511194B (zh) | 除草组合物及其使用方法 | |
| CN101801184B (zh) | 除草组合物 | |
| CN1326455C (zh) | 杂草控制方法 | |
| CN103281897A (zh) | 用4-氨基-3-氯-6-(4-氯-2-氟-3-甲氧基苯基)吡啶-2-羧酸及其盐或酯对抗苯氧基链烷酸除草剂的杂草的防治 | |
| CN101150952B (zh) | 杂草防治 | |
| CN104135862A (zh) | 植物生长调节 | |
| PL206161B1 (pl) | Środek chwastobójczy i sposób zwalczania szkodliwych roślin w uprawach roślin użytkowych | |
| CN106962381A (zh) | 具有增效作用的植物生长调节剂组合物 | |
| CN101511195A (zh) | 除草组合物及其使用方法 | |
| RU2302113C2 (ru) | Гербицидное средство, содержащее бензоилпиразолы и защитные средства, способ борьбы с сорняками в культурных растениях | |
| CN101511173A (zh) | 除草组合物及其使用方法 | |
| CN101083909B (zh) | 除草组合物 | |
| EA011675B1 (ru) | Синергические гербицидные средства, которые хорошо переносятся культурными растениями и содержат гербициды из группы бензоилпиразолов | |
| CA2719026A1 (en) | Surfactant compositions | |
| CN102342286B (zh) | 除草组合物 | |
| CN100525628C (zh) | 防治杂草的方法 | |
| CN101511178B (zh) | 除草组合物及其使用方法 | |
| CS231997B2 (en) | Herbaceous agent against weeds growing on fields where rice is grown | |
| CN101742912B (zh) | 脱叶剂 | |
| TWI563917B (zh) | 除草性組成物 | |
| CN115363031B (zh) | 一种含有Lancotrione-钠盐和敌稗的除草剂组合物 | |
| JPS6045503A (ja) | 除草剤 | |
| CN104904725A (zh) | 一种含硝磺草酮与环戊噁草酮的除草组合物 | |
| JP2002212012A (ja) | 水田用除草剤 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20090812 |