CN100500893C - 铜钴铁合金中分离铜钴的方法 - Google Patents
铜钴铁合金中分离铜钴的方法 Download PDFInfo
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- CN100500893C CN100500893C CNB2007100425783A CN200710042578A CN100500893C CN 100500893 C CN100500893 C CN 100500893C CN B2007100425783 A CNB2007100425783 A CN B2007100425783A CN 200710042578 A CN200710042578 A CN 200710042578A CN 100500893 C CN100500893 C CN 100500893C
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- Prior art keywords
- copper
- cobalt
- alloy
- leaching
- pipe
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- 238000000034 method Methods 0.000 title claims abstract description 31
- RYTYSMSQNNBZDP-UHFFFAOYSA-N cobalt copper Chemical compound [Co].[Cu] RYTYSMSQNNBZDP-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 238000011084 recovery Methods 0.000 title abstract description 10
- 229910000531 Co alloy Inorganic materials 0.000 title abstract description 9
- 238000000926 separation method Methods 0.000 title description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 26
- 239000000956 alloy Substances 0.000 claims abstract description 26
- 239000010949 copper Substances 0.000 claims abstract description 26
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052802 copper Inorganic materials 0.000 claims abstract description 24
- 238000002386 leaching Methods 0.000 claims abstract description 22
- 239000010941 cobalt Substances 0.000 claims abstract description 20
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 20
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052742 iron Inorganic materials 0.000 claims abstract description 16
- 229910052751 metal Inorganic materials 0.000 claims abstract description 16
- 239000002184 metal Substances 0.000 claims abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 11
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims description 20
- RIVZIMVWRDTIOQ-UHFFFAOYSA-N cobalt iron Chemical compound [Fe].[Co].[Co].[Co] RIVZIMVWRDTIOQ-UHFFFAOYSA-N 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000741 silica gel Substances 0.000 claims description 10
- 229910002027 silica gel Inorganic materials 0.000 claims description 10
- 239000006228 supernatant Substances 0.000 claims description 10
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 6
- 210000005056 cell body Anatomy 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
- 239000006061 abrasive grain Substances 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000000706 filtrate Substances 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 239000013049 sediment Substances 0.000 claims description 3
- 238000004062 sedimentation Methods 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 239000003082 abrasive agent Substances 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 238000012216 screening Methods 0.000 claims description 2
- -1 with vitriol Inorganic materials 0.000 claims description 2
- 238000005265 energy consumption Methods 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 238000009835 boiling Methods 0.000 abstract description 2
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 238000003801 milling Methods 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 238000007873 sieving Methods 0.000 abstract 1
- 238000001914 filtration Methods 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910002588 FeOOH Inorganic materials 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB2007100425783A CN100500893C (zh) | 2007-06-22 | 2007-06-22 | 铜钴铁合金中分离铜钴的方法 |
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CNB2007100425783A CN100500893C (zh) | 2007-06-22 | 2007-06-22 | 铜钴铁合金中分离铜钴的方法 |
Publications (2)
Publication Number | Publication Date |
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CN101086039A CN101086039A (zh) | 2007-12-12 |
CN100500893C true CN100500893C (zh) | 2009-06-17 |
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CNB2007100425783A Active CN100500893C (zh) | 2007-06-22 | 2007-06-22 | 铜钴铁合金中分离铜钴的方法 |
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CN (1) | CN100500893C (zh) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101608258B (zh) * | 2008-11-20 | 2011-02-16 | 厦门钨业股份有限公司 | 采用钴铜合金作原料工业提取钴、铜、铁的方法 |
CN102021326B (zh) * | 2009-09-09 | 2013-04-17 | 彭国伟 | 铜钴合金浸出方法 |
CN101717862B (zh) * | 2009-11-20 | 2011-06-08 | 湖南铠通金属有限公司 | 一种铜钴铁合金综合回收有价金属的生产工艺 |
CN101705371B (zh) * | 2009-11-20 | 2011-04-06 | 北京矿冶研究总院 | 一种硫化铜钴矿中提取钴的方法 |
CN101768669B (zh) * | 2010-01-28 | 2012-07-25 | 浙江华友钴业股份有限公司 | 一种常温下处理钴铜合金的方法 |
CN101906537B (zh) * | 2010-07-08 | 2012-08-08 | 英德佳纳金属科技有限公司 | 一种分解钴合金的工艺 |
CN101921914B (zh) * | 2010-09-17 | 2012-07-25 | 浙江华友钴业股份有限公司 | 一种铜钴矿浸出液的除铁工艺 |
CN103114209A (zh) * | 2013-02-01 | 2013-05-22 | 英德佳纳金属科技有限公司 | 一种用氧化亚铁硫杆菌协同浸出钴铜合金中钴和铜的方法 |
CN103409773B (zh) * | 2013-07-24 | 2015-09-30 | 浙江华友钴业股份有限公司 | 一种从铜钴合金中提取铜、钴的方法 |
CN104017989A (zh) * | 2014-06-16 | 2014-09-03 | 天津市茂联科技有限公司 | 一种高铁合金处理工艺 |
CN104611565A (zh) * | 2014-12-24 | 2015-05-13 | 金川集团股份有限公司 | 一种从钴铜锌锰生产废液中选择性回收钴铜的方法 |
CN104988311B (zh) * | 2015-04-23 | 2018-01-12 | 兰州金川新材料科技股份有限公司 | 一种提高高硅钴原料溶解液过滤速度的方法 |
CN108866330A (zh) * | 2017-05-08 | 2018-11-23 | 江苏凯力克钴业股份有限公司 | 一种钴铜白合金的浸出工艺及装置 |
CN110835692A (zh) * | 2019-10-16 | 2020-02-25 | 厦门钨业股份有限公司 | 提高硫酸钴浸出液的方法 |
CN112410538A (zh) * | 2020-11-17 | 2021-02-26 | 湖南仁发材料科技有限公司 | 一种铜钴铁合金综合回收有价金属的生产工艺 |
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2007
- 2007-06-22 CN CNB2007100425783A patent/CN100500893C/zh active Active
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CN101086039A (zh) | 2007-12-12 |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Copper cobalt alloy separation and recovery method Effective date of registration: 20151010 Granted publication date: 20090617 Pledgee: China Co truction Bank Corp Changsha Tianxin Branch Pledgor: Nantong Reshine New Material Co. Ltd. Registration number: 2015980000225 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Separation of copper and cobalt from copper cobalt ferroalloy Effective date of registration: 20200820 Granted publication date: 20090617 Pledgee: China Co. truction Bank Corp Changsha Tianxin Branch Pledgor: NANTONG RESHINE NEW MATERIAL Co.,Ltd. Registration number: Y2020980005164 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20200817 Granted publication date: 20090617 Pledgee: China Co. truction Bank Corp Changsha Tianxin Branch Pledgor: NANTONG RESHINE NEW MATERIAL Co.,Ltd. Registration number: 2015980000225 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220112 Granted publication date: 20090617 Pledgee: China Co. truction Bank Corp Changsha Tianxin Branch Pledgor: NANTONG RESHINE NEW MATERIAL Co.,Ltd. Registration number: Y2020980005164 |