CN100486946C - 在包含带有磺酸基的高度氟化的聚合物的颗粒催化剂的存在下分解有机氢过氧化物的方法以及双酚a的制备方法 - Google Patents

在包含带有磺酸基的高度氟化的聚合物的颗粒催化剂的存在下分解有机氢过氧化物的方法以及双酚a的制备方法 Download PDF

Info

Publication number
CN100486946C
CN100486946C CNB028128389A CN02812838A CN100486946C CN 100486946 C CN100486946 C CN 100486946C CN B028128389 A CNB028128389 A CN B028128389A CN 02812838 A CN02812838 A CN 02812838A CN 100486946 C CN100486946 C CN 100486946C
Authority
CN
China
Prior art keywords
catalyst
sulfonic acid
particles
acid groups
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB028128389A
Other languages
English (en)
Chinese (zh)
Other versions
CN1524067A (zh
Inventor
拉尔夫·伯查德·劳埃德
孙群
马克·安德鲁·哈默
爱德华·乔治·霍华德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of CN1524067A publication Critical patent/CN1524067A/zh
Application granted granted Critical
Publication of CN100486946C publication Critical patent/CN100486946C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/08Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/20Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/03Acids of sulfur other than sulfhydric acid or sulfuric acid, e.g. halosulfonic acids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB028128389A 2001-06-26 2002-06-21 在包含带有磺酸基的高度氟化的聚合物的颗粒催化剂的存在下分解有机氢过氧化物的方法以及双酚a的制备方法 Expired - Fee Related CN100486946C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US30084001P 2001-06-26 2001-06-26
US60/300,840 2001-06-26

Publications (2)

Publication Number Publication Date
CN1524067A CN1524067A (zh) 2004-08-25
CN100486946C true CN100486946C (zh) 2009-05-13

Family

ID=23160808

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB028128389A Expired - Fee Related CN100486946C (zh) 2001-06-26 2002-06-21 在包含带有磺酸基的高度氟化的聚合物的颗粒催化剂的存在下分解有机氢过氧化物的方法以及双酚a的制备方法

Country Status (6)

Country Link
US (1) US6586640B2 (enExample)
EP (1) EP1399403B1 (enExample)
JP (1) JP2004536100A (enExample)
CN (1) CN100486946C (enExample)
DE (1) DE60215500T2 (enExample)
WO (1) WO2003002499A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7154010B2 (en) * 2003-06-04 2006-12-26 General Electric Company Integrated process for the production of bisphenol A from cumene hydroperoxide
US7417003B2 (en) * 2006-12-29 2008-08-26 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
US7888537B2 (en) * 2006-12-29 2011-02-15 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
CN102698801B (zh) * 2012-06-01 2014-02-19 凯瑞化工股份有限公司 一种应用于过氧化氢异丙苯分解制备苯酚的树脂催化剂及其制备方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US4322560A (en) 1976-02-23 1982-03-30 Varen Technology Process for controlling highly exothermic hydroperoxide decomposition
US4053522A (en) * 1976-05-21 1977-10-11 Shell Oil Company Preparation of bisphenols
US4339613A (en) * 1980-03-14 1982-07-13 Pcuk Produits Chimiques Ugine Kuhlmann Superacid catalyzed preparation of resorcinol from meta-diisopropylbenzene
US4339614A (en) * 1980-03-14 1982-07-13 Pcuk Produits Chimiques Ugine Kuhlmann Superacid catalyzed preparation of resorcinol from meta-isopropylphenol
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4433082A (en) 1981-05-01 1984-02-21 E. I. Du Pont De Nemours And Company Process for making liquid composition of perfluorinated ion exchange polymer, and product thereof
JPS5814949A (ja) * 1981-07-16 1983-01-28 バ−レン・テクノロジ− 固体重合体酸触媒重合体および製法
US4595704A (en) * 1984-08-13 1986-06-17 The Dow Chemical Company Preparation of ion-exchange catalysts
JPS62221650A (ja) 1986-03-24 1987-09-29 Mitsui Toatsu Chem Inc 2,2−ビス(4−ヒドロキシフエニル)プロパンの製造における未反応アセトンの回収法
US4940525A (en) 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
EP0367408A3 (en) * 1988-10-24 1991-06-12 Texaco Development Corporation Method for production of phenol/acetone from cumene hydroperoxide
US5824622A (en) 1994-01-12 1998-10-20 E. I. Du Pont De Nemours And Company Porous microcomposite of perfluorinated ion-exchange polymer and metal oxide, a network of silica, or a network of metal oxide and silica derived via a sol-gel process
JP3775832B2 (ja) * 1995-10-20 2006-05-17 三菱化学株式会社 ビスフェノールaの製造方法
FR2765871A1 (fr) * 1997-07-08 1999-01-15 Goodyear Tire & Rubber Procede pour la preparation de composes aromatiques dihydroxyles
JP2001511478A (ja) 1997-07-29 2001-08-14 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー ケイ酸塩および高度にフッ素化されたイオン交換樹脂からの触媒微小複合材料の製造法

Also Published As

Publication number Publication date
EP1399403A1 (en) 2004-03-24
WO2003002499A1 (en) 2003-01-09
CN1524067A (zh) 2004-08-25
US20030050513A1 (en) 2003-03-13
DE60215500D1 (de) 2006-11-30
EP1399403B1 (en) 2006-10-18
DE60215500T2 (de) 2007-09-20
JP2004536100A (ja) 2004-12-02
US6586640B2 (en) 2003-07-01

Similar Documents

Publication Publication Date Title
EP1511112B1 (en) Polymer nanocomposite membrane and fuel cell using the same
US5916837A (en) Porous microcomposite of metal cation exchanged perfluorinated ion-exchanged polymer and network of metal oxide, silica or metal oxide and silica
CN100486946C (zh) 在包含带有磺酸基的高度氟化的聚合物的颗粒催化剂的存在下分解有机氢过氧化物的方法以及双酚a的制备方法
JP5755346B2 (ja) 燃料電池用電極触媒層、膜電極接合体及び固体高分子型燃料電池。
US7993797B2 (en) Chemically modified catalyzed support particles for electrochemical cells
JP4469425B2 (ja) ルイス酸で変性されたパーフルオロ化イオン交換性微小組成物触媒
Weaver et al. Supported fluorocarbonsulfonic acid catalysts
US6281400B1 (en) Process for preparation of a catalytic microcomposite from a silicate and a highly fluorinated ion exchange resin
US20210328247A1 (en) Catalyst layer, catalyst layer forming liquid and membrane electrode assembly
US6107233A (en) Process for the preparation of spherically shaped microcomposites
JP5614891B2 (ja) 膜電極複合体、及び固体高分子電解質型燃料電池
JP4001385B2 (ja) 球形微細複合体の製造方法
US6262326B1 (en) Process for the preparation of spherically shaped microcomposites
KR20120007153A (ko) 유무기 복합 이온교환막의 제조
JPH04507215A (ja) 液体組成物および担持過フツ素化イオン交換重合体
WO2025121187A1 (ja) 液状組成物の製造方法
JP6158377B2 (ja) 固体高分子電解質型燃料電池
JP2009289463A (ja) 固体高分子型燃料電池用膜電極接合体の製造方法、及び固体高分子型燃料電池
CN118204117A (zh) 一种双亲催化剂及其制备方法和应用
KR20240098210A (ko) 촉매를 사용하는 수소발생기용 강화복합막 및 이의 제조 방법
WO2008043804A1 (en) Fluoropolymer composition

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20090513

Termination date: 20120621