CN100482344C - 亲核取代用催化剂、它的合成、包含它的组合物以及它的用途 - Google Patents

亲核取代用催化剂、它的合成、包含它的组合物以及它的用途 Download PDF

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CN100482344C
CN100482344C CNB028089480A CN02808948A CN100482344C CN 100482344 C CN100482344 C CN 100482344C CN B028089480 A CNB028089480 A CN B028089480A CN 02808948 A CN02808948 A CN 02808948A CN 100482344 C CN100482344 C CN 100482344C
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formula
compound
catalyst
use according
reaction
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Chinese (zh)
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CN1505547A (zh
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V·沙南
H-J·克里斯陶
M·泰勒费尔
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Rhodia Chimie SAS
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Rhone Poulenc Chimie SA
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Priority claimed from FR0105034A external-priority patent/FR2823451B1/fr
Priority claimed from FR0204522A external-priority patent/FR2838441B1/fr
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235Nitrogen containing compounds
    • B01J31/0239Quaternary ammonium compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255Phosphorus containing compounds
    • B01J31/0267Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
    • B01J31/0268Phosphonium compounds, i.e. phosphine with an additional hydrogen or carbon atom bonded to phosphorous so as to result in a formal positive charge on phosphorous
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B39/00Halogenation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/093Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/202Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
    • C07C17/208Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being MX
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06Preparation of nitro compounds
    • C07C201/12Preparation of nitro compounds by reactions not involving the formation of nitro groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/06Phosphorus compounds without P—C bonds
    • C07F9/062Organo-phosphoranes without P-C bonds
    • C07F9/065Phosphoranes containing the structure P=N-
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/535Organo-phosphoranes
    • C07F9/5355Phosphoranes containing the structure P=N-
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB028089480A 2001-04-12 2002-04-12 亲核取代用催化剂、它的合成、包含它的组合物以及它的用途 Expired - Fee Related CN100482344C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR01/05034 2001-04-12
FR0105034A FR2823451B1 (fr) 2001-04-12 2001-04-12 Catalyseurs de substitution aromatique nucleophile, composition en contenant et utilisation pour une substitution sn ar
FR02/04522 2002-04-10
FR0204522A FR2838441B1 (fr) 2002-04-11 2002-04-11 Composes presentant un role catalytique dans les echanges de substitutions nucleophiles et procede de synthese de ces composes

Publications (2)

Publication Number Publication Date
CN1505547A CN1505547A (zh) 2004-06-16
CN100482344C true CN100482344C (zh) 2009-04-29

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CNB028089480A Expired - Fee Related CN100482344C (zh) 2001-04-12 2002-04-12 亲核取代用催化剂、它的合成、包含它的组合物以及它的用途

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US (3) US7217842B2 (enExample)
EP (1) EP1377376A1 (enExample)
JP (1) JP2004524969A (enExample)
CN (1) CN100482344C (enExample)
CA (1) CA2442782A1 (enExample)
HU (1) HUP0303945A2 (enExample)
MX (1) MXPA03009212A (enExample)
WO (1) WO2002092226A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108586257A (zh) * 2018-05-03 2018-09-28 浙江解氏新材料股份有限公司 一种对氟硝基苯的新型制备方法

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004033525A1 (de) * 2004-07-08 2006-02-02 Lanxess Deutschland Gmbh Verbessertes Verfahren zur Herstellung kernfluorierter Aromaten
US7304172B2 (en) * 2004-10-08 2007-12-04 Cornell Research Foundation, Inc. Polycarbonates made using highly selective catalysts
US9162953B2 (en) * 2006-07-05 2015-10-20 Centre Nationale De Recherche Scientifique Iron-copper co-catalyzed process for carbon-carbon or carbon-heteroatom bonding
CA2673190C (en) * 2006-12-22 2015-02-17 Shell Internationale Research Maatschappij B.V. Ligands and catalyst systems for the oligomerization of olefinic monomers
FR2915200B1 (fr) 2007-04-20 2009-07-03 Centre Nat Rech Scient Procede de preparation de ligands de type phosphines butadieniques,leurs complexes avec le cuivre,et leurs applications en catalyse
US9272274B2 (en) 2007-12-06 2016-03-01 Centre National De La Recherche Scientifique (C.N.R.S.) Catalytic system for cross-coupling reactions
FR2928925B1 (fr) 2008-03-19 2011-01-07 Centre Nat Rech Scient Complexes de bore ou d'aluminium, et leurs utilisations.
JP5300123B2 (ja) * 2008-03-24 2013-09-25 広栄化学工業株式会社 アンモニウム塩及びそれを用いた帯電防止剤
JP5481628B2 (ja) * 2008-07-28 2014-04-23 国立大学法人東北大学 高熱安定性を有する機能性フォスファジド
US20110015401A1 (en) * 2009-07-13 2011-01-20 Massachusetts Institute Of Technology Metal-Catalyzed Carbon-Fluorine Bond Formation
CN103553974A (zh) * 2013-10-31 2014-02-05 上海华谊(集团)公司 一种n-烷基共轭离子型季铵盐的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5401814A (en) * 1993-10-13 1995-03-28 The Dow Chemical Company Process for the preparation of thermoplastic poly(hydroxy ethers)
US5463148A (en) * 1991-07-17 1995-10-31 Hoechst Aktiengesellschaft Process for the preparation of chlorofluoronitrobenzenes
CN1244139A (zh) * 1997-01-23 2000-02-09 阿温提斯研究技术两合公司 用于卤氟交换反应的含有氨基鏻盐的催化剂

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4069262A (en) * 1977-03-07 1978-01-17 E. I. Du Pont De Nemours And Company Preparation of 2-fluoronitrobenzene
US4140719A (en) * 1977-10-31 1979-02-20 Merck & Co., Inc. Solid-liquid phase transfer catalysis improved method of preparing 2,4-difluoroaniline
US5045632A (en) * 1989-05-25 1991-09-03 The Dow Chemical Company Novel bis(phosphoranylidene) ammonium salts

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5463148A (en) * 1991-07-17 1995-10-31 Hoechst Aktiengesellschaft Process for the preparation of chlorofluoronitrobenzenes
US5401814A (en) * 1993-10-13 1995-03-28 The Dow Chemical Company Process for the preparation of thermoplastic poly(hydroxy ethers)
CN1244139A (zh) * 1997-01-23 2000-02-09 阿温提斯研究技术两合公司 用于卤氟交换反应的含有氨基鏻盐的催化剂

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108586257A (zh) * 2018-05-03 2018-09-28 浙江解氏新材料股份有限公司 一种对氟硝基苯的新型制备方法

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Publication number Publication date
JP2004524969A (ja) 2004-08-19
US20070225524A1 (en) 2007-09-27
US20040147390A1 (en) 2004-07-29
HUP0303945A2 (hu) 2004-03-29
US20080194886A1 (en) 2008-08-14
CA2442782A1 (fr) 2002-11-21
EP1377376A1 (fr) 2004-01-07
WO2002092226A1 (fr) 2002-11-21
US7217842B2 (en) 2007-05-15
CN1505547A (zh) 2004-06-16
MXPA03009212A (es) 2004-01-29

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