CN100450615C - 包含双金属氰化物（dmc）催化剂的氢氧化物 - Google Patents

包含双金属氰化物（dmc）催化剂的氢氧化物 Download PDF

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Publication number
CN100450615C
CN100450615C CNB2004100579311A CN200410057931A CN100450615C CN 100450615 C CN100450615 C CN 100450615C CN B2004100579311 A CNB2004100579311 A CN B2004100579311A CN 200410057931 A CN200410057931 A CN 200410057931A CN 100450615 C CN100450615 C CN 100450615C
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China
Prior art keywords
catalyst
organic ligand
butanol
dmc
metals
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Expired - Fee Related
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CNB2004100579311A
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English (en)
Chinese (zh)
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CN1623661A (zh
Inventor
G·G·坎布斯
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Koth A Ltd By Share Ltd
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Bayer Antwerpen NV
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Publication of CN1623661A publication Critical patent/CN1623661A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08—Saturated oxiranes
    • C08G65/10—Saturated oxiranes characterised by the catalysts used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4866—Polyethers having a low unsaturation value
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • General Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyethers (AREA)
  • Polyesters Or Polycarbonates (AREA)
CNB2004100579311A 2003-08-26 2004-08-26 包含双金属氰化物（dmc）催化剂的氢氧化物 Expired - Fee Related CN100450615C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/649520 2003-08-26
US10/649,520 US6855658B1 (en) 2003-08-26 2003-08-26 Hydroxide containing double metal cyanide (DMC) catalysts

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN2008100054735A Division CN101230133B (zh) 2003-08-26 2004-08-26 包含双金属氰化物(dmc)催化剂的氢氧化物

Publications (2)

Publication Number Publication Date
CN1623661A CN1623661A (zh) 2005-06-08
CN100450615C true CN100450615C (zh) 2009-01-14

Family

ID=34104678

Family Applications (2)

Application Number Title Priority Date Filing Date
CNB2004100579311A Expired - Fee Related CN100450615C (zh) 2003-08-26 2004-08-26 包含双金属氰化物（dmc）催化剂的氢氧化物
CN2008100054735A Expired - Fee Related CN101230133B (zh) 2003-08-26 2004-08-26 包含双金属氰化物(dmc)催化剂的氢氧化物

Family Applications After (1)

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CN2008100054735A Expired - Fee Related CN101230133B (zh) 2003-08-26 2004-08-26 包含双金属氰化物(dmc)催化剂的氢氧化物

Country Status (10)

Country Link
US (2) US6855658B1 (enExample)
EP (1) EP1510534B1 (enExample)
JP (1) JP2005068436A (enExample)
KR (1) KR101168425B1 (enExample)
CN (2) CN100450615C (enExample)
BR (1) BRPI0403520B1 (enExample)
CA (1) CA2478778C (enExample)
MX (1) MXPA04008285A (enExample)
RU (1) RU2004125640A (enExample)
SG (2) SG127868A1 (enExample)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
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US20060058182A1 (en) * 2004-09-13 2006-03-16 Combs George G Processes for the preparation of double metal cyanide (DMC) catalysts
CN100349949C (zh) * 2005-07-12 2007-11-21 黎明化工研究院 一种多金属氰化物络合物催化剂及其制备方法
US7834082B2 (en) 2007-01-17 2010-11-16 Bayer Materialscience Llc Polyether-polysiloxane polyols
DE102007005960A1 (de) * 2007-02-07 2008-08-14 Bayer Materialscience Ag Ruß-gefüllte Polyurethane mit hoher Dielektrizitätskonstante und Durchschlagsfestigkeit
KR101404702B1 (ko) 2011-03-08 2014-06-17 에스케이이노베이션 주식회사 에테르 결합 단위체를 함유한 이산화탄소/에폭사이드 공중합체의 제조 방법
CN103508894B (zh) * 2012-06-19 2015-08-05 嘉兴学院 一种合成碳酸二甲酯的方法
US9562134B2 (en) 2013-03-12 2017-02-07 Covestro Llc Catalyst for the production of polyols having lower amounts of high molecular weight tail
GB201515350D0 (en) 2015-08-28 2015-10-14 Econic Technologies Ltd Method for preparing polyols
GB201703324D0 (en) 2017-03-01 2017-04-12 Econic Tech Ltd Method for preparing polyether carbonates
GB201717441D0 (en) 2017-10-24 2017-12-06 Econic Tech Ltd A polymerisation process
CN110684187B (zh) * 2018-07-06 2022-10-11 中国石油化工股份有限公司 多金属氰化络合物催化剂及其制备方法和应用
GB201814526D0 (en) 2018-09-06 2018-10-24 Econic Tech Ltd Methods for forming polycarbonate ether polyols and high molecular weight polyether carbonates
GB201906210D0 (en) 2019-05-02 2019-06-19 Econic Tech Limited A polyol block copolymer, compositions and processes therefor
GB201906214D0 (en) 2019-05-02 2019-06-19 Econic Tech Ltd A polyol block copolymer, compositions and processes therefor
GB202003003D0 (en) 2020-03-02 2020-04-15 Econic Tech Ltd A polyol block copolymer
GB202003002D0 (en) 2020-03-02 2020-04-15 Crane Ltd Method of preparation of a polyol block copolymer
CN112156797B (zh) * 2020-09-10 2022-02-15 中国科学院山西煤炭化学研究所 环状碳酸酯和甲醇酯交换合成碳酸二甲酯的催化剂及其制备方法和应用
GB202017531D0 (en) 2020-11-05 2020-12-23 Econic Tech Limited (poly)ol block copolymer
CN118103137A (zh) 2021-08-11 2024-05-28 伊科尼克技术有限公司 使用大环双金属催化剂与双金属氰化物催化剂的混合物通过环氧化物和co2共聚制备表面活性剂的方法
GB202115335D0 (en) 2021-10-25 2021-12-08 Econic Tech Ltd Surface-active agent
CN114230783B (zh) * 2022-01-12 2023-05-26 万华化学集团股份有限公司 一种用于环氧开环的复合催化剂及其制备方法和应用
KR102862622B1 (ko) * 2022-12-19 2025-09-19 아주대학교산학협력단 하이드로젠 헥사시아노코발테이트를 사용하여 제조된 더블메탈시아나이드 촉매
GB2626546A (en) 2023-01-25 2024-07-31 Econic Tech Ltd Surface-active agent
GB2626989A (en) 2023-02-10 2024-08-14 Econic Tech Ltd Surface-active agent
WO2024223596A1 (en) 2023-04-25 2024-10-31 Unilever Ip Holdings B.V. Compositions
GB2629367A (en) 2023-04-25 2024-10-30 Econic Tech Ltd Surface-active agent

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US5712216A (en) * 1995-05-15 1998-01-27 Arco Chemical Technology, L.P. Highly active double metal cyanide complex catalysts
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DE19709031A1 (de) 1997-03-06 1998-09-10 Basf Ag Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren
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Also Published As

Publication number Publication date
HK1078818A1 (zh) 2006-03-24
CN1623661A (zh) 2005-06-08
EP1510534B1 (en) 2016-05-11
US7034103B2 (en) 2006-04-25
SG127868A1 (en) 2006-12-29
JP2005068436A (ja) 2005-03-17
US20050159629A1 (en) 2005-07-21
EP1510534A1 (en) 2005-03-02
US20050049142A1 (en) 2005-03-03
SG141232A1 (en) 2008-04-28
BRPI0403520B1 (pt) 2014-10-21
CN101230133B (zh) 2013-07-24
KR101168425B1 (ko) 2012-07-25
KR20050021256A (ko) 2005-03-07
RU2004125640A (ru) 2006-02-10
CN101230133A (zh) 2008-07-30
US6855658B1 (en) 2005-02-15
BRPI0403520A (pt) 2005-05-31
CA2478778C (en) 2013-07-16
CA2478778A1 (en) 2005-02-26
MXPA04008285A (es) 2005-06-08

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