CN100444820C - 清洁剂组合物 - Google Patents
清洁剂组合物 Download PDFInfo
- Publication number
- CN100444820C CN100444820C CNB2004100310254A CN200410031025A CN100444820C CN 100444820 C CN100444820 C CN 100444820C CN B2004100310254 A CNB2004100310254 A CN B2004100310254A CN 200410031025 A CN200410031025 A CN 200410031025A CN 100444820 C CN100444820 C CN 100444820C
- Authority
- CN
- China
- Prior art keywords
- surfactant
- acid
- alkyl
- polyoxyalkylene
- acrylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Abstract
本发明涉及一种清洁剂组合物，它含有(A)表面活性剂、(B)氨基酸或两性聚合物以及(C)水，用净水稀释到5重量%时或在使用时用水稀释后的pH值在成份(B)的等电点以下。该清洁剂组合物在清洁皮肤时无紧绷感，并有湿润感；而毛发在洗后用手指梳通时，可感到柔软顺滑。
Description
技术领域
本发明涉及清洁剂组合物以及用其洗净身体的方法。
背景技术
一直以来，在用于皮肤或毛发的清洁剂组合物中，广泛使用烷基硫酸酯盐、烷基醚硫酸盐、α-烯烃磺酸盐等阴离子表面活性剂作为起泡性表面活性剂。这些表面活性剂清洁力强、洗后有清爽感，但也存在着皮肤有紧绷感等问题。另一方面，作为所谓的低刺激性表面活性剂，有人提出过磺基琥珀酸类表面活性剂、醚羧酸类表面活性剂、酰胺基醚羧酸类表面活性剂、N-烷基酰胺基链烷醇硫酸酯盐等，但这些表面活性剂在单独使用时，不能充分满足起泡性或泡质等方面的要求。
因此，有人提出一种清洁剂组合物，它是将阴离子表面活性剂和甘氨酸三甲内盐(甜菜碱)以特定比率组合而得到泡沫丰富、使用舒适的皮肤清洁剂组合物(日本特开平11-180855号公报)。尽管该清洁剂组合物改善了起泡性和泡质，但洗后的皮肤残留有紧绷感，而毛发则有干硬感等，为此仍不能充分满足要求。
发明内容
本发明提供一种含有(A)表面活性剂、(B)氨基酸或两性聚合物以及(C)水的清洁剂组合物，且用净水将其稀释到5重量％时的pH值在成份(B)的等电点以下。
本发明还提供一种含有(A)表面活性剂、(B)氨基酸或两性聚合物以及水的清洁剂组合物，且使用时用水将其稀释后的pH值在成份(B)的等电点以下。
另外，本发明提供一种将水加入含有(A)表面活性剂、(B)氨基酸或两性聚合物以及(C)水的、且用净水将其稀释到5重量％时的pH值在成份(B)的等电点以下的清洁剂组合物中，以清洁身体的身体清洁方法。
本发明涉及稳定性好、洗后皮肤湿润、无紧绷感和干糙感，而洗发时手指梳通顺滑、没有干枯感的清洁剂组合物，以及使用该清洁剂组合物洗净身体的方法。
本发明人等发现：使用含有表面活性剂和氨基酸或两性聚合物的水性清洁剂组合物，并选择用水稀释后的pH值为在该氨基酸或两性聚合物的等电点以下的pH值的使用条件，就可解决上述问题。
本发明所用的成份(A)表面活性剂可为具有与用作身体清洁剂相应的起泡性的阴离子表面活性剂、非离子表面活性剂、两性表面活性剂、阳离子表面活性剂中的任一种。
就阴离子表面活性剂来说，可以举出，例如聚氧化烯烷基(或烯基)醚硫酸盐、烷基(或烯基)硫酸盐、高级脂肪酸盐、醚羧酸盐、酰胺基醚羧酸盐、烷基磷酸酯盐、N-酰基氨基酸盐、聚氧化烯脂肪酰胺醚硫酸盐、酰化羟乙磺酸盐、酰化牛磺酸盐等。其中，由于添加有烷基磷酸酯盐、聚氧化烯烷基醚硫酸盐、N-酰基谷氨酸盐的组合物易于调整为弱酸性清洁剂，故这类组合物为优选组合物。
作为非离子表面活性剂，可以举出，例如氧化胺、甘油脂肪酸酯、山梨糖醇酐脂肪酸酯、烷基糖类、聚氧化烯烷基醚、脂肪酸链烷醇酰胺、聚氧化烯固化蓖麻油等。具体优选为月桂胺氧化物、肉豆蔻胺氧化物、异硬脂酸单甘油酯、油酸单甘油酯、山梨糖醇酐单月桂酸酯、山梨糖醇酐单油酸酯、山梨糖醇酐倍半油酸酯、山梨糖醇酐单异硬脂酸酯、山梨糖醇酐三油酸酯、烷基多糖苷、椰油酸单乙醇酰胺、椰油酸二乙醇酰胺等。
作为两性表面活性剂，可以举出，例如羰基甜菜碱、磺基甜菜碱、咪唑啉甜菜碱、酰胺基甜菜碱等，优选为脂肪酰胺基丙基甜菜碱、羟基丙基磺基甜菜碱、经过脱盐处理的二级咪唑啉甜菜碱等。
作为阳离子表面活性剂，可以举出，例如具有可与环氧化物加成的直链或支链烷基的单烷基或双烷基季铵盐等，优选为碳原子数为12～16的直链单烷基季胺盐、具有碳原子数为20～28的支链烷基的季铵盐等。
成份(A)优选为上述阴离子表面活性剂。
成份(A)的表面活性剂可使用一种以上，且在总组成中的含量优选为1～50重量％，更优选为3～30重量％，因为此时起泡性好、清洁感强。
在本发明中，选择条件为，组合使用上述表面活性剂和身为两性物质的氨基酸或两性聚合物时，用水稀释后的pH值为该氨基酸或两性聚合物的等电点以下的pH值。在本发明中，所谓等电点是指在该两性物质的水溶液中，分子内的正、负电荷为0时的氢离子浓度，该值为25℃时的值。
本发明所用成份(B)的氨基酸，可以举出，例如甘氨酸(等电点5.97)、丙氨酸(等电点6.00)、丝氨酸(等电点5.68)、精氨酸(等电点10.8)、组氨酸(等电点7.47)、苏氨酸(等电点5.64)、天冬酰胺(等电点5.41)、谷氨酰胺(等电点5.65)、白氨酸(等电点5.98)、缬氨酸(等电点5.96)、赖氨酸(等电点9.59)、苯基丙氨酸(等电点5.48)、酪氨酸(等电点5.66)、尿刊酸(等电点4.60)、脯氨酸(等电点6.30)、羟基脯氨酸(等电点5.74)、异白氨酸(等电点5.94)、半胱氨酸(等电点5.02)、蛋氨酸(等电点5.74)、色氨酸(等电点5.89)、谷氨酸(等电点3.22)、天冬氨酸(等电点2.77)等。
而作为两性聚合物来说，可以举出，例如丙烯酸-二甲基二烯丙基氯化铵共聚物(MERQUAT 280：等电点14以上；MERQUAT 295：等电点14以上；ONDEO Nalco制)、丙烯酰胺-丙烯酸-二甲基二烯丙基氯化铵共聚物(MERQUAT PLUS 3330：等电点5.0；MERQUAT PLUS3331：等电点7.0以上；MERQUAT 3333：等电点4.3；ONDEO Nalco制)、丙烯酸甲酯-丙烯酸-甲基丙烯酰胺丙基三甲基氯化铵共聚物(MERQUAT 2001：等电点7.0，ONDEO Nalco制)、丙烯酰胺-丙烯酸-甲基丙烯酰胺丙基三甲基氯化铵共聚物(MERQUAT 2003：等电点7.0以上，ONDEO Nalco制)等。其中优选为丙烯酸-二甲基二烯丙基氯化铵共聚物(MERQUAT280、MERQUAT295)、丙烯酰胺-丙烯酸-二甲基二烯丙基氯化铵共聚物(MERQUAT PLUS 3330，MERQUAT PLUS3331)、丙烯酸甲酯-丙烯酸-甲基丙烯酰胺丙基三甲基氯化铵共聚物(MERQUAT 2001)。
就成份(B)来说，考虑到用作清洁剂时的优异特性，优选为等电点为3～12的、更优选为4～10的物质。
成份(B)可由氨基酸和两性聚合物中选用一种以上，考虑到使用时无发粘感，其在总组成中的含量优选为0.1～30重量％，更优选为1～20重量％。
另外，在本发明的清洁剂组合物中，成分(C)水在总组成中优选含量为20～99重量％，更优选为50～96重量％，进一步优选为70～90重量％。
本发明的清洁剂组合物为25℃时用净水稀释到5重量％时的pH值或使用时用水稀释后的pH值在成份(B)的等电点以下的组合物。使用两种以上的成份(B)时，将pH值调整到小于其中任一种成份的等电点。当pH值超过成份(B)的等电点时，不能抑制清洁后皮肤的紧绷感，也得不到充分的湿润感。pH值的调整可采用常用方法，使用酸或碱溶液进行。
其中的酸可以举出，例如盐酸、硫酸、磷酸等无机酸和抗坏血酸、己二酸、琥珀酸、乙酸、乙二酸、乳酸、苹果酸、天冬氨酸、谷氨酸等有机酸。
而碱可以举出，例如氢氧化钠、氢氧化钾和精氨酸、赖氨酸等碱性氨基酸。
另外，本发明的清洁剂组合物优选为，25℃时用净水稀释到5重量％时的pH值或使用时用水稀释后的pH值为2以上、小于11，特别优选为pH4～10。
另外，本发明的pH值为25℃时用pH计测定组合物稀释到5重量％时的水溶液的值，或稀释到使用时的浓度的水溶液的值。
当水溶液的pH值在等电点以下时，两性物质带正电荷。由于皮肤、毛发表面通常呈带负电荷的状态，因此，发明人推测，使用时的pH值在等电点以下时，就会促进带正电荷的两性物质吸附在皮肤、毛发上，由此可使两性物质达到其最大效果。
本发明的清洁剂组合物中还含有普通清洁剂中的常用成份，例如羊毛脂及其衍生物、肉豆蔻酸异丙酯等酯类、椰油等的甘油三酯等油性成份；多元醇、聚甘油脂肪酸酯等保湿剂；2，4，4′-三氯-2′-羟基二苯醚、三氯二苯脲等杀菌剂；甘草酸钾、生育酚乙酸酯等抗炎症剂；对羟基苯甲酸甲酯、对羟基苯甲酸乙酯、对羟基苯甲酸丙酯、对羟基苯甲酸丁酯、苯甲酸钠、异丙基甲基苯酚等防腐剂；乙二胺四乙酸或其盐、羟基乙二磺酸或其盐等螯合剂；聚羧乙烯、角叉菜胶、羟乙基纤维素、阳离子化纤维素等增稠剂；氯化钠等盐类；另外还可添加珠光剂、净洗(Scrub)剂、香料、1-薄荷醇等清凉剂、色素、紫外线吸收剂、抗氧化剂、植物提取物等。
本发明的清洁剂组合物可采用常用方法将上述成份混合后制成，例如，可制成洗面奶、卸妆用品、沐浴液、洗手液等皮肤清洁剂组合物，以及洗发香波等毛发清洁剂组合物。
在本发明中，当在这种清洁剂组合物中加水，并用其清洁身体、脸、手、脚或毛发时，其使用时的pH值被调至成份(B)的等电点以下。因此，清洁皮肤时无紧绷感，并有湿润感；而毛发在洗后用手指梳通时可感到柔软顺滑。
具体实施方式
在各实施例中，组合物的pH值是对25℃时用净水稀释各组合物到5重量％时的水溶液用堀场pH计F-22(日本堀场制作所制)测得的值。
(评价方法)
(1)清洁皮肤后皮肤有无紧绷感
由10名20～30岁日本女性志愿者，各用清洁剂组合物1g，使其起泡后，用之按摩脸部60秒，然后用水冲洗，用毛巾擦干，用下述标准对皮肤有无紧绷感进行官能评价。求得平均点数，平均点数为2.5～3.0时，用○表示，1.5～2.4时用△表示，1.0～1.4时用×表示。
3：无紧绷感
2：有轻微的紧绷感
1：有强烈的紧绷感
(2)清洁后皮肤的含水量
同(1)一样进行洗脸，用毛巾擦干，然后用皮肤水分计CM-825(Courage+Khazaka electronic GmbH公司)测定5分钟后的皮肤含水量。与洗脸前的皮肤含水量作比较，求得洗脸后/洗脸前之比，用下述标准评价。
○：与洗脸前同等程度(含水量之比为0.9以上)
△：比洗脸前稍少(含水量之比为0.6以上、小于0.9)
×：明显少于洗脸之前(含水量之比小于0.6)
(3)稳定性
将80g各清洁剂组合物装入100mL的玻璃制样品瓶中，在25℃下保存1天，然后测定粘度，用下述标准评价。
○：几乎未增稠
△：有明显增稠
×：有显著增稠
实施例5(洗面奶)
由常用方法制造如下所示组成的洗面奶。
(成份) (重量％)
烷基(C11，13，15)磷酸钾 15
甘油单-2-乙基己基醚 5
聚氧乙烯(9)三十烷基醚 5
椰油酰胺丙基甜菜碱 5
椰油酸二乙醇酰胺 0.5
聚甘油月桂酯 1
丝氨酸(等电点5.68) 20
羧乙烯聚合物 1
聚氧乙烯(ALCOX E-100明成化学工业制) 0.1
甘油 10
丙二醇 10
磷酸 适量
氧化钛 0.01
对羟基苯甲酸甲酯 0.2
香料 适量
二丁基羟基甲苯 0.1
净水 余量
(pH值(5重量％水溶液)：5.0)
实施例6(洗面奶)
由常用方法制造如下所示组成的洗面奶。
(成份) (重量％)
聚氧乙烯(2)月桂基醚磷酸钠 15
椰油基谷氨酸钠
(AMISOFT CS-11，Ajinomoto Takara Corporation制) 5
月桂基羟基磺基甜菜碱 5
二硬脂酸乙二醇酯 3
丙氨酸(等电点6.00) 5
羟乙基纤维素 0.5
阳离子性聚合物(MERQUAT 550 ONDEO Nalco制) 0.5
山梨糖醇 10
异戊二醇 10
乳酸钠 1
云母钛(Timiron Starluster MP-115MERCK JAPAN制) 0.01
苯甲酸钠 0.2
聚乙烯珠 0.8
香料 适量
滑石 3
乙二胺四乙酸二钠 0.1
净水 余量
(pH值(5重量％水溶液)：5.5)
实施例7(沐浴液)
由常用方法制造如下所示组成的沐浴液。
(成份) (重量％)
聚氧乙烯(2)月桂基醚磷酸钠 20
烷基多糖苷(AG-10LK花王制) 5
月桂基羟基磺基甜菜碱 5
月桂酸二乙醇胺 3
二硬脂酸乙二醇酯 3
精氨酸(等电点10.8) 0.5
两性聚合物(等电点5.5
MERQUAT PLUS3330，ONDEO Nalco制) 3
羟丙基甲基纤维素 0.5
山梨糖醇 10
二丙二醇 10
苹果酸 适量
1-薄荷醇 0.1
苯甲酸钠 0.2
香料 适量
1-羟基乙烷-1，1-二膦酸
(DEQUEST 2010CS SOLUTIA JAPAN制) 0.1
色素(青色1号) 0.0002
净水 余量
(pH值(5重量％水溶液)：5.0)
实施例8(香波)
由常用方法制造如下所示组成的香波。
(成份) (重量％)
聚氧乙烯(2)月桂基醚硫酸钠 15
椰油酸单乙醇胺 5
月桂酰胺丙基甜菜碱 5
椰油酰胺丙基甜菜碱 5
聚醚改性硅酮
(硅酮SH-3771E Toray Dow Corning Silicon制) 0.5
两性聚合物(等电点7.0
MERQUAT 2001，ONDEO Nalco制) 5
丝氨酸(等电点5.68) 0.5
二甲基聚硅氧烷
(硅酮SH-200C(5000cs)
Toray Dow Corning Silicon制) 0.5
丙二醇 10
乙醇 1
硅酐 0.2
对羟基苯甲酸甲酯 0.2
罗汉柏提取物 0.1
氧苯酮 0.1
香料 适量
柠檬酸 适量
净水 余量
(pH值(5重量％水溶液)：5.0)
实施例9(洗手液)
由常用方法制造如下所示组成的洗手液。
(成份) (重量％)
月桂基磷酸钾 5
椰油酸二乙醇胺 3
聚氧乙烯(3)聚氧丙烯(7)丁基醚 3
月桂胺氧化物 5
椰油酰胺丙基甜菜碱 5
精氨酸(等电点10.8) 15
麦芽糖醇 0.5
甘油 10
丙二醇 10
乙醇 5
晚香玉多糖 0.5
异丙基甲基苯酚 0.01
对羟基苯甲酸甲酯 0.2
1-薄荷醇 0.1
香料 适量
净水 余量
(pH值(5重量％水溶液)：8.5)
实施例10(药用洗手液)
由常用方法制造如下所示组成的药用洗手液。
(成份) (重量％)
烷基糖苷(AG-10LK花王制) 10
聚氧乙烯(4)月桂基醚 3
山梨糖醇酐聚氧乙烯(20)椰油酸酯
(RHEODOL TW-L120花王制) 1
聚氧乙烯(60)固化蓖麻油 0.5
阳离子性杀菌剂(SANISOL P花王制) 1
月桂基三甲基氯化铵 10
丝氨酸(等电点5.68) 0.5
甘油 10
两性聚合物
(等电点14以上，
MERQUAT 280ONDEO Nalco制) 1
乙醇 3
香料 适量
色素(黄色1号) 0.0001
乙二胺四乙酸二钠 0.1
对羟基苯甲酸甲酯 0.1
琥珀酸 适量
净水 余量
(pH值(5重量％水溶液)：5.5)
在实施例5～7、9和10的皮肤清洁剂组合物中加水以清洁皮肤时，清洁后没有紧绷感，并有湿润感；而在实施例8的毛发清洁剂组合物中加水以清洁毛发时，洗过的毛发用手指梳通时可感到柔软顺滑。另外，实施例5～10的清洁剂组合物任一种都是稳定性优异的组合物。
产业上的可利用性
本发明的清洁剂组合物稳定性优异，且清洁皮肤时无紧绷感且有湿润感；而毛发在洗后用手指梳通时可感到柔软顺滑。
Claims (6)
1.一种清洁剂组合物，其特征在于，含有(A)表面活性剂、(B)氨基酸或两性聚合物以及(C)水，
所述(A)表面活性剂选自阴离子表面活性剂、非离子表面活性剂、两性表面活性剂、阳离子表面活性剂，
所述阴离子表面活性剂选自，聚氧化烯烷基醚硫酸盐、聚氧化烯烯基醚硫酸盐、烷基硫酸盐、烯基硫酸盐、高级脂肪酸盐、醚羧酸盐、酰胺基醚羧酸盐、烷基磷酸酯盐、N-酰基氨基酸盐、聚氧化烯脂肪酰胺醚硫酸盐、酰化羟乙磺酸盐、酰化牛磺酸盐；
所述非离子表面活性剂选自，氧化胺、甘油脂肪酸酯、山梨糖醇酐脂肪酸酯、烷基糖类、聚氧化烯烷基醚、脂肪酸链烷醇酰胺、聚氧化烯固化蓖麻油；
所述两性表面活性剂选自，羰基甜菜碱、磺基甜菜碱、咪唑啉甜菜碱、酰胺基甜菜碱；
所述阳离子表面活性剂选自，具有与环氧化物加成的直链或支链烷基的单烷基或双烷基季铵盐、具有不与环氧化物加成的直链或支链烷基的单烷基或双烷基季铵盐；
所述氨基酸选自甘氨酸、丙氨酸、丝氨酸、精氨酸、组氨酸、苏氨酸、天冬酰胺、谷氨酰胺、白氨酸、缬氨酸、赖氨酸、苯基丙氨酸、酪氨酸、尿刊酸、脯氨酸、羟基脯氨酸、异白氨酸、半胱氨酸、蛋氨酸、色氨酸、谷氨酸、天冬氨酸；
所述两性聚合物选自丙烯酸-二甲基二烯丙基氯化铵共聚物、丙烯酰胺-丙烯酸-二甲基二烯丙基氯化铵共聚物、丙烯酸甲酯-丙烯酸-甲基丙烯酰胺丙基三甲基氯化铵共聚物、丙烯酰胺-丙烯酸-甲基丙烯酰胺丙基三甲基氯化铵共聚物；
且用净水稀释到5重量％时的pH值在成份(B)的等电点以下。
2.成份(B)为等电点3～12的物质的如权利要求1所述的清洁剂组合物。
3.成份(A)为阴离子表面活性剂的如权利要求1或2所述的清洁剂组合物。
4.如权利要求1或2所述的清洁剂组合物，其特征在于，成份(A)含量为1～50重量％，成份(B)含量为0.1～30重量％。
5.如权利要求1或2所述的清洁剂组合物在用作皮肤或毛发用清洁剂中的用途。
6.一种身体清洁方法，其特征在于，在含有(A)表面活性剂、(B)氨基酸或两性聚合物以及(C)水、且用净水稀释到5重量％时的pH值在成份(B)的等电点以下的清洁剂组合物中，加入水并洗净身体，
所述(A)表面活性剂选自阴离子表面活性剂、非离子表面活性剂、两性表面活性剂、阳离子表面活性剂，
所述阴离子表面活性剂选自，聚氧化烯烷基醚硫酸盐、聚氧化烯烯基醚硫酸盐、烷基硫酸盐、烯基硫酸盐、高级脂肪酸盐、醚羧酸盐、酰胺基醚羧酸盐、烷基磷酸酯盐、N-酰基氨基酸盐、聚氧化烯脂肪酰胺醚硫酸盐、酰化羟乙磺酸盐、酰化牛磺酸盐；
所述非离子表面活性剂选自，氧化胺、甘油脂肪酸酯、山梨糖醇酐脂肪酸酯、烷基糖类、聚氧化烯烷基醚、脂肪酸链烷醇酰胺、聚氧化烯固化蓖麻油；
所述两性表面活性剂选自，羰基甜菜碱、磺基甜菜碱、咪唑啉甜菜碱、酰胺基甜菜碱；
所述阳离子表面活性剂选自，具有与环氧化物加成的直链或支链烷基的单烷基或双烷基季铵盐、具有不与环氧化物加成的直链或支链烷基的单烷基或双烷基季铵盐；
所述氨基酸选自甘氨酸、丙氨酸、丝氨酸、精氨酸、组氨酸、苏氨酸、天冬酰胺、谷氨酰胺、白氨酸、缬氨酸、赖氨酸、苯基丙氨酸、酪氨酸、尿刊酸、脯氨酸、羟基脯氨酸、异白氨酸、半胱氨酸、蛋氨酸、色氨酸、谷氨酸、天冬氨酸；
所述两性聚合物选自丙烯酸-二甲基二烯丙基氯化铵共聚物、丙烯酰胺-丙烯酸-二甲基二烯丙基氯化铵共聚物、丙烯酸甲酯-丙烯酸-甲基丙烯酰胺丙基三甲基氯化铵共聚物、丙烯酰胺-丙烯酸-甲基丙烯酰胺丙基三甲基氯化铵共聚物。
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| JP2003102544 | 2003-04-07 | ||
| JP2003102544 | 2003-04-07 |
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| US (1) | US20040266656A1 (zh) |
| EP (1) | EP1466592A1 (zh) |
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| CN102178612A (zh) * | 2011-04-29 | 2011-09-14 | 杨北平 | 个人洗涤护理组合物的制备方法 |
| US10596214B2 (en) | 2016-10-04 | 2020-03-24 | Mary Kay Inc. | Methods and compositions for treating striae distensae |
| US11344595B2 (en) | 2016-10-04 | 2022-05-31 | Mary Kay Inc. | Methods and compositions for treating striae distensae |
| US11911429B2 (en) | 2016-10-04 | 2024-02-27 | Mary Kay Inc. | Methods and compositions for treating striae distensae |
Also Published As
| Publication number | Publication date |
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| TWI350180B (en) | 2011-10-11 |
| EP1466592A1 (en) | 2004-10-13 |
| CN1535677A (zh) | 2004-10-13 |
| US20040266656A1 (en) | 2004-12-30 |
| TW200423966A (en) | 2004-11-16 |
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