CN100406520C - 环保阻燃pc/pbt塑料合金 - Google Patents
环保阻燃pc/pbt塑料合金 Download PDFInfo
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- CN100406520C CN100406520C CNB2005100225735A CN200510022573A CN100406520C CN 100406520 C CN100406520 C CN 100406520C CN B2005100225735 A CNB2005100225735 A CN B2005100225735A CN 200510022573 A CN200510022573 A CN 200510022573A CN 100406520 C CN100406520 C CN 100406520C
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- retardant
- pbt
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 37
- 229920006778 PC/PBT Polymers 0.000 title claims abstract description 32
- 239000000956 alloy Substances 0.000 title abstract description 25
- 229910045601 alloy Inorganic materials 0.000 title abstract description 11
- 239000004033 plastic Substances 0.000 title abstract description 5
- 229920003023 plastic Polymers 0.000 title abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 32
- 229920001707 polybutylene terephthalate Polymers 0.000 claims abstract description 23
- 239000004417 polycarbonate Substances 0.000 claims abstract description 22
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 19
- 239000002131 composite material Substances 0.000 claims abstract description 17
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 14
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 12
- 125000003118 aryl group Chemical group 0.000 claims abstract description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 150000002148 esters Chemical class 0.000 claims description 11
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 239000003112 inhibitor Substances 0.000 claims description 10
- 239000012757 flame retardant agent Substances 0.000 claims description 7
- 239000004615 ingredient Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 229920003002 synthetic resin Polymers 0.000 claims description 6
- 239000000057 synthetic resin Substances 0.000 claims description 6
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- 239000002075 main ingredient Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 3
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000007822 coupling agent Substances 0.000 claims description 3
- 238000009775 high-speed stirring Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 11
- 238000005516 engineering process Methods 0.000 abstract description 11
- 238000000465 moulding Methods 0.000 abstract description 6
- -1 polybutylene terephthalate Polymers 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 239000003963 antioxidant agent Substances 0.000 abstract 2
- 235000006708 antioxidants Nutrition 0.000 abstract 2
- 230000007547 defect Effects 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 239000012745 toughening agent Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000011161 development Methods 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 230000035939 shock Effects 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 239000011246 composite particle Substances 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 2
- 230000003044 adaptive effect Effects 0.000 description 1
- 150000008064 anhydrides Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000005501 phase interface Effects 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
特性项目 | 试验标准 | 单位 | 国外同类产品 | 本发明产品 |
比重 | D972 | g/cm<sup>3</sup> | 1.22 | 1.22 |
熔融指数 | D1238 | g/10min | 16 | 18 |
拉伸强度 | D638 | MPa | 50 | 50 |
拉伸率 | D638 | % | 100 | 105 |
弯曲强度 | D790 | MPa | 86 | 91 |
缺口冲击强度 | D256 | J/m | 427 | 452 |
弯曲模量 | D790 | MPa | 2380 | 2550 |
热变形温度1.8mPa | D648 | ℃ | 105 | 110 |
阴燃性 | UL94 | mm | V-0,15 | V-0,0.8 |
体积电阻 | D257 | Ohm-cm | 1.0E+17 | 1.0E+17 |
表面电阻 | D257 | Ohm-cm | 1.0E+14 | 1.0E+14 |
配方 | 增容剂重量份数 | 拉伸强度MPa | 拉伸率% | 弯曲强度MPa | 弯曲模量MPa | 缺口冲击强度J/m | 阴燃性UL94 | 热变形温度℃ |
1例 | 7 | 58 | 110 | 100 | 2730 | 483 | V-0 | 105 |
2例 | 9 | 50 | 105 | 91 | 2550 | 452 | V-0 | 110 |
3例 | 11 | 48 | 98 | 87 | 2930 | 425 | V-0 | 115 |
国外产品 | 50 | 100 | 86 | 2380 | 427 | V-0 | 105 |
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2005100225735A CN100406520C (zh) | 2005-12-20 | 2005-12-20 | 环保阻燃pc/pbt塑料合金 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2005100225735A CN100406520C (zh) | 2005-12-20 | 2005-12-20 | 环保阻燃pc/pbt塑料合金 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1789333A CN1789333A (zh) | 2006-06-21 |
CN100406520C true CN100406520C (zh) | 2008-07-30 |
Family
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CNB2005100225735A Expired - Fee Related CN100406520C (zh) | 2005-12-20 | 2005-12-20 | 环保阻燃pc/pbt塑料合金 |
Country Status (1)
Country | Link |
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CN (1) | CN100406520C (zh) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101759985B (zh) * | 2008-12-23 | 2012-07-11 | 安徽科聚新材料有限公司 | 一种透明聚碳酸酯和聚对苯二甲酸丁二醇酯合金及其制备方法 |
CN101508834B (zh) * | 2008-12-23 | 2012-09-26 | 深圳市科聚新材料有限公司 | 一种pc/pbt合金及其制备方法 |
CN102532849B (zh) * | 2011-12-26 | 2014-03-26 | 上海普利特复合材料股份有限公司 | 一种pc/asa/pbt合金材料及其制备方法 |
CN103289345B (zh) * | 2013-06-24 | 2015-03-04 | 苏州新区佳合塑胶有限公司 | 一种高韧性阻燃pbt/pc复合材料 |
CN103351593B (zh) * | 2013-07-14 | 2015-11-18 | 上海秋橙新材料科技有限公司 | 抗老化pc-pbt塑料合金 |
CN105670261B (zh) * | 2016-03-30 | 2018-06-22 | 南京利华工程塑料有限公司 | 用于气辅成型的pc/pbt合金专用料及其制备方法 |
CN106009585A (zh) * | 2016-05-28 | 2016-10-12 | 慈溪市法莱新塑料厂 | 一种无卤阻燃的聚碳酸酯材料及其制备方法 |
CN109575552A (zh) * | 2017-09-29 | 2019-04-05 | 中国石油化工股份有限公司 | 功能性阻燃高分子组合物及其制备方法和应用 |
CN109135241A (zh) * | 2018-08-09 | 2019-01-04 | 厦门巧亿科技有限公司 | 一种抗冲击流动性强的pc/pbt塑料合金及其制备方法 |
CN112029252B (zh) * | 2020-08-07 | 2022-11-11 | 青岛国恩科技股份有限公司 | 一种充电桩面板用耐候无卤阻燃光扩散pc/pbt材料及其制备方法 |
CN113278263A (zh) * | 2021-06-11 | 2021-08-20 | 南京酷科电子科技有限公司 | Pc/pbt合金材料作为电源适配器内部绝缘材料的用途 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4530965A (en) * | 1984-02-10 | 1985-07-23 | Atlantic Richfield Company | Polymeric molding composition containing styrenic copolymer, polycarbonate and MBS polymer |
JPH0812864A (ja) * | 1994-04-28 | 1996-01-16 | Toray Ind Inc | 熱可塑性樹脂組成物 |
CN1130198A (zh) * | 1994-12-05 | 1996-09-04 | 拜尔公司 | 阻燃性热塑性聚碳酸酯模塑组合物 |
-
2005
- 2005-12-20 CN CNB2005100225735A patent/CN100406520C/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4530965A (en) * | 1984-02-10 | 1985-07-23 | Atlantic Richfield Company | Polymeric molding composition containing styrenic copolymer, polycarbonate and MBS polymer |
JPH0812864A (ja) * | 1994-04-28 | 1996-01-16 | Toray Ind Inc | 熱可塑性樹脂組成物 |
CN1130198A (zh) * | 1994-12-05 | 1996-09-04 | 拜尔公司 | 阻燃性热塑性聚碳酸酯模塑组合物 |
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Publication number | Publication date |
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CN1789333A (zh) | 2006-06-21 |
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