CN100358432C - Production method of fish scale collagen - Google Patents
Production method of fish scale collagen Download PDFInfo
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- CN100358432C CN100358432C CNB200310114500XA CN200310114500A CN100358432C CN 100358432 C CN100358432 C CN 100358432C CN B200310114500X A CNB200310114500X A CN B200310114500XA CN 200310114500 A CN200310114500 A CN 200310114500A CN 100358432 C CN100358432 C CN 100358432C
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- fish scale
- collagen
- fish
- scale collagen
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- 241000251468 Actinopterygii Species 0.000 title claims abstract description 102
- 102000008186 Collagen Human genes 0.000 title claims abstract description 44
- 108010035532 Collagen Proteins 0.000 title claims abstract description 44
- 229920001436 collagen Polymers 0.000 title claims abstract description 44
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 12
- 239000012535 impurity Substances 0.000 claims abstract description 11
- 238000005238 degreasing Methods 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- 238000009835 boiling Methods 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 150000002632 lipids Chemical class 0.000 claims description 7
- 229910052588 hydroxylapatite Inorganic materials 0.000 claims description 6
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 238000006555 catalytic reaction Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000011010 flushing procedure Methods 0.000 claims description 4
- 239000006260 foam Substances 0.000 claims description 4
- 238000006386 neutralization reaction Methods 0.000 claims description 4
- 239000012266 salt solution Substances 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 239000000284 extract Substances 0.000 claims description 3
- 238000013341 scale-up Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 6
- 235000013402 health food Nutrition 0.000 abstract description 4
- 108090000765 processed proteins & peptides Proteins 0.000 abstract description 4
- 102000004169 proteins and genes Human genes 0.000 abstract description 4
- 108090000623 proteins and genes Proteins 0.000 abstract description 4
- 239000003054 catalyst Substances 0.000 abstract description 3
- 235000015097 nutrients Nutrition 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000011345 viscous material Substances 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 4
- 235000016709 nutrition Nutrition 0.000 description 4
- 102000004196 processed proteins & peptides Human genes 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000006837 decompression Effects 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 1
- 208000035473 Communicable disease Diseases 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 208000002197 Ehlers-Danlos syndrome Diseases 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 208000001132 Osteoporosis Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000014103 egg white Nutrition 0.000 description 1
- 210000000969 egg white Anatomy 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000004833 fish glue Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 201000003068 rheumatic fever Diseases 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
Abstract
The present invention relates to a method for producing fish scale collagen. The present invention adopts high-quality fish scales as raw materials, the fish scales are pretreated so as to remove the viscous substances and the other impurities on the surfaces of the fish scales, and then the fish scales are dried so as to remove the fishy odour, an acid-base method is carried out for deliming and degreasing, and the fish scales are decomposed by being steamed at high pressure with the existence of catalysts after deliming and degreasing so as to extract liquid fish scale collagen with low-molecular protein peptide. The present invention fully utilizes fishery resources, waste fish scales are changed into valuables, environmental pollution is reduced, and the quality of collagen is fundamentally guaranteed; the present invention has simple production method, high operability and low cost; fish scale collagen can be prepared into various nutrient solutions and health foods, which are favorable for being absorbed by human bodies.
Description
Technical field
The present invention relates to a kind of production method of food, specifically is a kind of production method of fish scale collagen.
Background technology
We know, though the collagen product is widely used in cosmetic industry, medical industry, in the application of food service industry seldom.Up to now, nearly all collagen all is skin and the bone from the lively thing in land.But recently because in the extremely strong infectious diseases such as rabid ox disease of the popular infectiousness in Europe, people have proposed query to the security of the collagen that extracts from the lively thing in these land.Adding the needs of animal protection, the source of collagen product is limited.And contain abundant collagen in the fish scale, contain several amino acids in such collagen, can improve human body cell nutrition, promote the metabolism of skin and skeletal tissue, strengthen skin elastic force, make the skin lubrication exquisiteness, in addition to prevention of osteoporosis disease and rheumatic arthritis, raising human body exempt from service power, strengthen vitality and have good effect.But the nutritional labeling in the fish scale is forgotten, and is domestic, and a large amount of available fish scales are taken as garbage disposal, not only do not make full use of the value of fish scale, but also contaminated environment.
Summary of the invention
Technical problem to be solved by this invention is to overcome above-mentioned the deficiencies in the prior art, provide a kind of technology simple, strong operability, cost is low, can make full use of the fish scale leftover bits and pieces of fish processing industry, the production method of the fish scale collagen of turning waste into wealth, and then be processed into human edible nutrition and health food.
The technical scheme that the present invention solves the problems of the technologies described above employing is: a kind of production method of fish scale collagen is characterized in that:
A. adopt the fish scale of high-quality to make raw material, in 2%～8% salt solution, soaked 10-20 minute, stir, wash, remove thick substances and other impurity on fish scale surface;
B. dry, fish scale is dried naturally, less than 15%, remove impurity and uncleanly fish scale up to water content after drying, store standby;
C. degreasing is put into plastic containers with above-mentioned fish scale, is soaked in water, and adds the sodium acid carbonate of 1～3% fish scale weight, stirs, and removes the lipid material in the fish scale, filtration and washing;
D. deliming adds above-mentioned fish scale in the container, soaks, and then adds the watery hydrochloric acid of 50～75% fish scale weight, stirs, and till non-foam produces, sloughs the ash content in the fish scale, the water flushing, and add the sodium acid carbonate neutralization, PH is controlled at 5～5.5;
E. catalysis boiling will add the water boil of an amount of hydroxyapatite, more above-mentioned fish scale be put into pot and be continued a boiling, extract fish scale collagen, reach at 8～20% o'clock up to the concentration of fish scale collagen and stop to heat, and remove by filter insoluble matter;
F. HTHP steams and to separate, and the fish scale collagen solution after the filtration is packed in the pressure cooker, and HTHP steams down to be separated 2～5 hours, left standstill 3～8 hours, filter, liquid fish scale collagen product.
The present invention is owing to adopt the degreasing of acid-base method deliming, and HTHP catalysis is steamed and separated, and obtains being convenient to packing, stores, and is easy to the liquid fish scale collagen product of diet, absorption, has intrinsic color nutritional labeling.This product is made raw material can be used for various nutrient solutions of processing and fabricating and health food.
The specific embodiment
The present invention will be further described below in conjunction with embodiment.
Embodiment 1: a kind of production method of fish scale collagen, and its concrete steps are:
A. at first, select materials and carry out pre-treatment, adopt the fish scale of high-quality to make raw material, fish scale can be the fish scale of fresh-water fishes or seawater fish, soaks 12 minutes in 3% salt solution, constantly stirs, and removes thick substances and other impurity on fish scale surface, washing, draining.
B. dry, above-mentioned fish scale is dried naturally, less than 15%, main purpose is removed fish scale fishy smell, is more convenient for storing, and removes impurity and uncleanly fish scale after drying, and stores standby up to water content.
C. degreasing is selected above-mentioned fish scale double centner (being example with the double centner fish scale, as follows) and is added in the plastic containers, soaks, and adds 1.5 kilograms sodium acid carbonate, stirs, and removes the lipid material in the fish scale, filtration and washing.This process has been removed the lipid material in the fish scale.
D. deliming adds above-mentioned fish scale in the container, soaks, and then adds 50 kilograms watery hydrochloric acid, stirs immediately, till non-foam produces, sloughs the ash content in the fish scale, the water flushing, and add the sodium acid carbonate neutralization, PH is controlled at 5～5.5.
E. high-temperature catalytic boiling, with adding the water boil of an amount of hydroxyapatite, the fish scale of above-mentioned deliming, degreasing to be put into digester continue boiling, hydroxyapatite is made catalyst, temper out fish scale collagen, measure the concentration of fish scale collagen with densimeter, can be every survey in ten minutes, reach at 10% o'clock up to the concentration of fish scale collagen and stop to heat, filter, get liquid big molecule fish scale collagen, filter, remove insoluble matter.
F. HTHP steams and separates, in liquid was packed pressure cooker into after filtering, HTHP steams down to be separated 3.5 hours, made gluey big molecule fish scale collagen chain rupture, resolve into low molecular protein peptides, steam at last and separate into liquid fish scale collagen product, steaming decompression force is 1.1 atmospheric pressure, and temperature is 112 ℃, after leaving standstill 6 hours, filter, remove impurity, get liquid fish scale collagen product.
Embodiment 2: a kind of production method of fish scale collagen, and its concrete steps are:
A. at first, select materials and carry out pre-treatment, adopt the fish scale of high-quality to make raw material, fish scale can be the fish scale of fresh-water fishes or seawater fish, soaks 15 minutes in 5% salt solution, constantly stirs, and removes thick substances and other impurity on fish scale surface, washing, draining.
B. dry, above-mentioned fish scale is dried naturally, less than 15%, main purpose is removed fish scale fishy smell, is more convenient for storing, and removes impurity and uncleanly fish scale after drying, and stores standby up to water content.
C. degreasing is selected above-mentioned fish scale double centner (being example with the double centner fish scale, as follows) and is added in the plastic containers, soaks, and adds 3 kilograms sodium acid carbonate, stirs, and removes the lipid material in the fish scale, filtration and washing.This process has been removed the lipid material in the fish scale.
D. deliming adds above-mentioned fish scale in the container, soaks, and then adds 65 kilograms watery hydrochloric acid, stirs immediately, till non-foam produces, sloughs the ash content in the fish scale, the water flushing, and add the sodium acid carbonate neutralization, PH is controlled at 5～5.5.
E. high-temperature catalytic boiling, with adding the water boil of an amount of hydroxyapatite, the fish scale of above-mentioned deliming, degreasing to be put into digester continue boiling, hydroxyapatite is made catalyst, temper out fish scale collagen, measure the concentration of fish scale collagen with densimeter, can be every survey in ten minutes, reach at 14% o'clock up to the concentration of fish scale collagen and stop to heat, filter, get liquid big molecule fish scale collagen, filter, remove insoluble matter.
F. HTHP steams and separates, in liquid was packed pressure cooker into after filtering, HTHP steams down to be separated 3.5 hours, made gluey big molecule fish scale collagen chain rupture, resolve into low molecular protein peptides, steam at last and separate into liquid fish scale collagen product, steaming decompression force is 1.2 atmospheric pressure, and temperature is 115 ℃, after leaving standstill 4 hours, filter, remove impurity, get liquid fish scale collagen product.
Fish glue from scale original product after the present invention steams and to separate is packed in the Brown Glass Brown glass bottles and jars only with automatic filling machine, and carries out high temperature sterilization 120 ℃ of conditions.Do raw material with it, can various nutrient solutions of processing and fabricating and health food.
The advantage of fish scale collagen product processes of the present invention is: take full advantage of aquatic resources, The fish scale discarded object is turned waste into wealth, both reduced the pollution to environment, fundamentally guaranteed again the collagen egg White quality; In the production process, adopt the degreasing of acid-base method deliming, effectively removed carbohydrate and lipid component; HTHP catalysis is steamed and is separated, and collagen finally is broken down into low molecular protein peptides, is beneficial to very much human body Absorb; Technology is simple, strong operability, and cost is low.
Claims (1)
1. the production method of a fish scale collagen is characterized in that:
A. adopt the fish scale of high-quality to make raw material, in 2%～8% salt solution, soaked 10-20 minute, stir, wash, remove thick substances and other impurity on fish scale surface;
B. dry, fish scale is dried naturally, less than 15%, remove impurity and uncleanly fish scale up to water content after drying, store standby;
C. degreasing is put into plastic containers with above-mentioned fish scale, is soaked in water, and adds the sodium acid carbonate of 1～3% fish scale weight, stirs, and removes the lipid material in the fish scale, filtration and washing;
D. deliming adds above-mentioned fish scale in the container, soaks, and then adds the watery hydrochloric acid of 50～75% fish scale weight, stirs, and till non-foam produces, sloughs the ash content in the fish scale, the water flushing, and add the sodium acid carbonate neutralization, PH is controlled at 5～5.5;
E. catalysis boiling will add the water boil of hydroxyapatite, more above-mentioned fish scale be put into pot and be continued a boiling, extract fish scale collagen, reach at 8～20% o'clock up to the concentration of fish scale collagen and stop to heat, and remove by filter insoluble matter;
F. HTHP steams and to separate, and the fish scale collagen solution after the filtration is packed in the pressure cooker, and HTHP steams down to be separated 2～5 hours, left standstill 3～8 hours, filter, liquid fish scale collagen product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200310114500XA CN100358432C (en) | 2003-12-16 | 2003-12-16 | Production method of fish scale collagen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200310114500XA CN100358432C (en) | 2003-12-16 | 2003-12-16 | Production method of fish scale collagen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1628540A CN1628540A (en) | 2005-06-22 |
| CN100358432C true CN100358432C (en) | 2008-01-02 |
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| CNB200310114500XA Expired - Fee Related CN100358432C (en) | 2003-12-16 | 2003-12-16 | Production method of fish scale collagen |
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| CN (1) | CN100358432C (en) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100370033C (en) * | 2005-10-19 | 2008-02-20 | 由守谊 | Fishscale collagen production process |
| CN100411529C (en) * | 2006-06-09 | 2008-08-20 | 张鹏 | Processed freshwater fish scale and method for processing and cooking same |
| CN100381528C (en) * | 2006-11-06 | 2008-04-16 | 四川大学 | Preparation method of undenatured fish scale collagen |
| JP4369969B2 (en) * | 2007-10-26 | 2009-11-25 | 株式会社アールビーエス | Biocompatible material and method for producing the same |
| CN101402986B (en) * | 2008-11-20 | 2011-06-15 | 武汉工业学院 | Method for producing collagen, glutin or collagen by degreasing and deliming of fish scale |
| CN102246976A (en) * | 2010-05-17 | 2011-11-23 | 浙江海洋学院 | Pretreatment method and preparation method of nibe croaker frozen surimi |
| CN102633877A (en) * | 2011-12-07 | 2012-08-15 | 李世泰 | Preparation method of collagen powder by using fish skin and fish scale |
| CN103039999B (en) * | 2012-11-23 | 2014-04-23 | 广东海洋大学 | Manufacturing method of fish scale collagen congelation leisure food |
| CN103059746A (en) * | 2012-12-20 | 2013-04-24 | 青岛盛瀚色谱技术有限公司 | Modified method of extracting fish-scale gelatin |
| CN103131746B (en) * | 2013-03-12 | 2015-03-25 | 程云开 | Extraction method of collagen peptide contained in scaly fish skin |
| CN104293868A (en) * | 2013-07-18 | 2015-01-21 | 张明焕 | Preparation method of fish scale collagen peptide |
| CN103819685A (en) * | 2014-03-11 | 2014-05-28 | 武汉理工大学 | Fish scale collagen grafted chitosan as well as preparation method and application thereof |
| CN103947818B (en) * | 2014-04-22 | 2016-01-20 | 钦州市山海生物科技有限公司 | A kind of preparation method of squid active peptide |
| CN104892750A (en) * | 2015-05-27 | 2015-09-09 | 深圳先进技术研究院 | Preparation method of acid-soluble fish scale collagen |
| CN108030101A (en) * | 2017-11-08 | 2018-05-15 | 金华市飞凌生物科技有限公司 | The method of abstraction function small peptide from low value ocean fish |
| CN107987121A (en) * | 2017-11-08 | 2018-05-04 | 金华市飞凌生物科技有限公司 | Suppress the preparation method of the polypeptide extract of cancer cell |
| CN107840869A (en) * | 2017-11-08 | 2018-03-27 | 金华市飞凌生物科技有限公司 | Alleviate the preparation method of the active peptides of knee osteoarthritis |
| CN109007233A (en) * | 2018-09-06 | 2018-12-18 | 大连工业大学 | A kind of extracting method of stichopus japonicus intestines protein isolate |
| CN111778724B (en) * | 2019-04-03 | 2022-12-13 | 上海水星家用纺织品股份有限公司 | Preparation method of collagen modified polyacrylonitrile fiber |
| CN111165780A (en) * | 2020-02-22 | 2020-05-19 | 江西师范大学 | Method for quickly preparing fish sauce by taking silver carp processing by-product as raw material |
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Patent Citations (2)
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|---|---|---|---|---|
| JPH08104508A (en) * | 1994-09-29 | 1996-04-23 | Kyodo Kumiai Marine Riifu | Production of various apatite compound obtained by heat treatment, alkali treatment and acid-alkali treatment using scale of fish as starting material |
| CN1456363A (en) * | 2003-05-27 | 2003-11-19 | 重庆大学 | Preparing method for heteroossein base materials |
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Address after: 264200, Yu Wang Road, Huancui District, Weihai City, Shandong Province, Weihai Yu King Group Co., Ltd. Patentee after: WEIHAI YUWANG GROUP Co.,Ltd. Address before: 264200 Yu Wang aquatic products Co., Ltd., 40 Fishing Port Road, Huancui District, Weihai, Shandong Patentee before: WEIHAI YUWANG AQUATIC Co.,Ltd. |
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Denomination of invention: Production method of fish scale collagen Effective date of registration: 20220310 Granted publication date: 20080102 Pledgee: Weihai commercial bank Limited by Share Ltd. bridge sub branch Pledgor: WEIHAI YUWANG GROUP Co.,Ltd. Registration number: Y2022980002327 |
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