CN100355763C - 钛螯合物分散液 - Google Patents
钛螯合物分散液 Download PDFInfo
- Publication number
- CN100355763C CN100355763C CNB2004800105328A CN200480010532A CN100355763C CN 100355763 C CN100355763 C CN 100355763C CN B2004800105328 A CNB2004800105328 A CN B2004800105328A CN 200480010532 A CN200480010532 A CN 200480010532A CN 100355763 C CN100355763 C CN 100355763C
- Authority
- CN
- China
- Prior art keywords
- dispersion liquid
- titanium chelate
- stablizer
- acid
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 79
- 239000010936 titanium Substances 0.000 title claims abstract description 77
- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 68
- 239000006185 dispersion Substances 0.000 title claims abstract description 47
- 239000013522 chelant Substances 0.000 title claims abstract description 46
- 239000000203 mixture Substances 0.000 claims abstract description 35
- 229920000642 polymer Polymers 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims description 40
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 33
- -1 polyoxyethylene Polymers 0.000 claims description 24
- 239000000126 substance Substances 0.000 claims description 21
- 239000002253 acid Substances 0.000 claims description 13
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 239000003352 sequestering agent Substances 0.000 claims description 11
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Natural products CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 8
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 6
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 5
- 239000004815 dispersion polymer Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims description 5
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical group OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 4
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 claims description 4
- 239000004310 lactic acid Substances 0.000 claims description 4
- 235000014655 lactic acid Nutrition 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 4
- 239000004575 stone Substances 0.000 claims description 4
- 229960004418 trolamine Drugs 0.000 claims description 4
- AOWPVIWVMWUSBD-RNFRBKRXSA-N [(3r)-3-hydroxybutyl] (3r)-3-hydroxybutanoate Chemical compound C[C@@H](O)CCOC(=O)C[C@@H](C)O AOWPVIWVMWUSBD-RNFRBKRXSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 150000005690 diesters Chemical class 0.000 claims description 3
- 125000005594 diketone group Chemical group 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 150000003009 phosphonic acids Chemical class 0.000 claims description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 239000011449 brick Substances 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- HOCOIDRZLNGZMV-UHFFFAOYSA-N ethoxy(oxido)phosphanium Chemical compound CCO[PH2]=O HOCOIDRZLNGZMV-UHFFFAOYSA-N 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 229910052816 inorganic phosphate Inorganic materials 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims description 2
- 239000010985 leather Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 2
- 239000001488 sodium phosphate Substances 0.000 claims description 2
- 235000019830 sodium polyphosphate Nutrition 0.000 claims description 2
- VZWGHDYJGOMEKT-UHFFFAOYSA-J sodium pyrophosphate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O VZWGHDYJGOMEKT-UHFFFAOYSA-J 0.000 claims description 2
- 229940095064 tartrate Drugs 0.000 claims description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 2
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 2
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 2
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims 1
- 239000003945 anionic surfactant Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 abstract 2
- 239000002738 chelating agent Substances 0.000 abstract 1
- 230000000087 stabilizing effect Effects 0.000 abstract 1
- 239000002002 slurry Substances 0.000 description 15
- 239000007787 solid Substances 0.000 description 12
- 238000000151 deposition Methods 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 230000008021 deposition Effects 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 description 6
- JWDSCUIQYJUHHM-UHFFFAOYSA-N 2-ethylacetoacetic acid Chemical compound CCC(C(C)=O)C(O)=O JWDSCUIQYJUHHM-UHFFFAOYSA-N 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 229960000448 lactic acid Drugs 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- WRQNANDWMGAFTP-UHFFFAOYSA-N Methylacetoacetic acid Chemical compound COC(=O)CC(C)=O WRQNANDWMGAFTP-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 3
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
- LTMRRSWNXVJMBA-UHFFFAOYSA-N 2,2-diethylpropanedioic acid Chemical compound CCC(CC)(C(O)=O)C(O)=O LTMRRSWNXVJMBA-UHFFFAOYSA-N 0.000 description 1
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 1
- KKOFYQBBUSZDKJ-UHFFFAOYSA-N 4-oxohexanal Chemical compound CCC(=O)CCC=O KKOFYQBBUSZDKJ-UHFFFAOYSA-N 0.000 description 1
- REIYHFWZISXFKU-UHFFFAOYSA-N Butyl acetoacetate Chemical compound CCCCOC(=O)CC(C)=O REIYHFWZISXFKU-UHFFFAOYSA-N 0.000 description 1
- JVTAAEKCZFNVCJ-UWTATZPHSA-N D-lactic acid Chemical compound C[C@@H](O)C(O)=O JVTAAEKCZFNVCJ-UWTATZPHSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- XSISQURPIRTMAY-UHFFFAOYSA-N Hydroxyethyl glycine Chemical compound NCC(=O)OCCO XSISQURPIRTMAY-UHFFFAOYSA-N 0.000 description 1
- FSVCELGFZIQNCK-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)glycine Chemical compound OCCN(CCO)CC(O)=O FSVCELGFZIQNCK-UHFFFAOYSA-N 0.000 description 1
- FOUZISDNESEYLX-UHFFFAOYSA-N N-hydroxyethyl glycine Natural products OCCNCC(O)=O FOUZISDNESEYLX-UHFFFAOYSA-N 0.000 description 1
- MUCRYNWJQNHDJH-OADIDDRXSA-N Ursonic acid Chemical compound C1CC(=O)C(C)(C)[C@@H]2CC[C@@]3(C)[C@]4(C)CC[C@@]5(C(O)=O)CC[C@@H](C)[C@H](C)[C@H]5C4=CC[C@@H]3[C@]21C MUCRYNWJQNHDJH-OADIDDRXSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- 125000005595 acetylacetonate group Chemical group 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007998 bicine buffer Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- BEPAFCGSDWSTEL-UHFFFAOYSA-N dimethyl malonate Chemical compound COC(=O)CC(=O)OC BEPAFCGSDWSTEL-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- NDOGLIPWGGRQCO-UHFFFAOYSA-N hexane-2,4-dione Chemical compound CCC(=O)CC(C)=O NDOGLIPWGGRQCO-UHFFFAOYSA-N 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- TZMFJUDUGYTVRY-UHFFFAOYSA-N pentane-2,3-dione Chemical compound CCC(=O)C(C)=O TZMFJUDUGYTVRY-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- GVIIRWAJDFKJMJ-UHFFFAOYSA-N propan-2-yl 3-oxobutanoate Chemical compound CC(C)OC(=O)CC(C)=O GVIIRWAJDFKJMJ-UHFFFAOYSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
Description
添加剂 | 浆液重量g | 添加剂重量g | 沉积时间h | 沉积度 | 评价1 |
乳酸2 | 15 | 0.04 | 96 | 0.53 | N |
乳酸2 | 15 | 0.07 | 96 | 0.53 | N |
乳酸2 | 15 | 0.20 | 120 | 0.14 | Y |
乙醇酸 | 15 | 0.03 | 96 | 0.53 | N |
乙醇酸 | 15 | 0.06 | 96 | 0.23 | Y |
乙醇酸 | 15 | 0.08 | 120 | 0.06 | Y |
柠檬酸 | 30 | 0.03 | 72 | 0.51 | N |
柠檬酸 | 30 | 0.06 | 72 | 0.14 | Y |
柠檬酸 | 30 | 0.11 | 72 | 0.06 | Y |
柠檬酸 | 30 | 0.18 | 72 | 0.03 | Y |
柠檬酸 | 30 | 0.24 | 72 | 0.00 | Y |
CA-DEA3 | 15 | 0.04 | 120 | 0.57 | N |
CA-NaOH4 | 15 | 0.03 | 120 | 0.56 | N |
乙醇胺 | 15 | 0.10 | 72 | 0.00 | Y |
乙醇胺 | 15 | 0.32 | 72 | 0.11 | Y |
85%二乙醇胺 | 15 | 0.12 | 72 | 0.46 | M |
85%二乙醇胺 | 15 | 0.35 | 72 | 0.54 | M |
三乙醇胺 | 15 | 0.06 | 72 | 0.14 | Y |
三乙醇胺 | 15 | 0.33 | 72 | 0.36 | Y |
E-sperse-1005 | 15 | 0.03 | 96 | 0.44 | N |
E-sperse-1005 | 15 | 0.07 | 96 | 0.00 | Y |
E-sperse-1005 | 15 | 0.14 | 120 | 0.00 | Y |
TPP6 | 30 | 0.02 | 72 | 0.08 | Y |
TPP6 | 30 | 0.07 | 72 | 0.54 | N |
TPP6 | 30 | 0.12 | 72 | 0.52 | Y |
Dysperbyk-1837 | 15 | 0.16 | 72 | 0.22 | N |
Dysperbyk-1837 | 15 | 0.47 | 72 | 0.68 | N |
Claims (9)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/420,149 | 2003-04-22 | ||
US10/420,149 US6737485B1 (en) | 2003-04-22 | 2003-04-22 | Titanium chelate dispersions |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1777615A CN1777615A (zh) | 2006-05-24 |
CN100355763C true CN100355763C (zh) | 2007-12-19 |
Family
ID=32298286
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2004800105328A Expired - Fee Related CN100355763C (zh) | 2003-04-22 | 2004-04-22 | 钛螯合物分散液 |
Country Status (7)
Country | Link |
---|---|
US (1) | US6737485B1 (zh) |
EP (1) | EP1615934B1 (zh) |
JP (1) | JP4829109B2 (zh) |
CN (1) | CN100355763C (zh) |
DE (1) | DE602004007256T2 (zh) |
HK (1) | HK1090378A1 (zh) |
WO (1) | WO2004094434A2 (zh) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070187642A1 (en) * | 2006-02-14 | 2007-08-16 | Putzig Donald E | Zirconium cross-linking composition and methods of use |
CA2662514C (en) * | 2006-09-19 | 2014-06-17 | Valspar Sourcing, Inc. | Food and beverage containers and methods of coating |
US7763565B2 (en) * | 2007-08-31 | 2010-07-27 | Millennium Inorganic Chemicals, Inc. | Transparent, stable titanium dioxide sols |
JP5149602B2 (ja) * | 2007-11-05 | 2013-02-20 | マツモトファインケミカル株式会社 | 水溶性チタンオリゴマー組成物 |
US8663380B2 (en) * | 2007-11-16 | 2014-03-04 | Cristal Usa Inc. | Gas phase production of coated titania |
US20090148605A1 (en) * | 2007-12-05 | 2009-06-11 | Akhtar M Kamal | Process for the production of coated titanium dioxide pigments |
US7820724B2 (en) | 2008-02-14 | 2010-10-26 | Millennium Inorganic Chemicals, Inc. | Colloidal titanium dioxide sols |
JP5172499B2 (ja) * | 2008-06-28 | 2013-03-27 | マツモトファインケミカル株式会社 | 無機粒子バインダー組成物 |
CN104910025B (zh) | 2008-11-07 | 2019-07-16 | 麻省理工学院 | 氨基醇类脂质和其用途 |
CN101665385B (zh) * | 2009-09-16 | 2012-10-31 | 钛谷(天津)科技有限公司 | 连续法生产抗水解稳定离子钛的工艺及装置 |
JP5885463B2 (ja) | 2010-11-02 | 2016-03-15 | 三菱マテリアル株式会社 | カーボンナノファイバー分散液、ならびに塗料組成物およびペースト組成物 |
WO2012135025A2 (en) | 2011-03-28 | 2012-10-04 | Massachusetts Institute Of Technology | Conjugated lipomers and uses thereof |
EP2818525B1 (en) * | 2012-02-21 | 2016-12-28 | Nitto Kasei Co., Ltd. | Electrodeposition coating composition, and catalyst for electrodeposition coating composition |
US9663707B2 (en) | 2013-10-23 | 2017-05-30 | Baker Hughes Incorporated | Stimulation method using biodegradable zirconium crosslinker |
AU2016278970B2 (en) | 2015-06-19 | 2020-10-29 | Massachusetts Institute Of Technology | Alkenyl substituted 2,5-piperazinediones and their use in compositions for delivering an agent to a subject or cell |
WO2019073924A1 (ja) | 2017-10-11 | 2019-04-18 | ユケン工業株式会社 | 金属粉末分散組成物および水系コーティング組成物 |
CN112159574B (zh) * | 2020-09-23 | 2022-04-15 | 漯河市罗弗文具制造有限公司 | 钛酸酯螯合剂、环保无硼高分子聚乙烯醇基超轻粘土及其制备方法 |
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US4313851A (en) * | 1980-03-04 | 1982-02-02 | Dynamit Nobel Ag | Liquid, cold-stable titanium catalyst preparation |
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GB1244233A (en) * | 1969-03-18 | 1971-08-25 | British Titan Ltd | Improvements in and relating to titanium chelates |
JPS5133890B2 (zh) | 1971-09-10 | 1976-09-22 | ||
JPS5936955B2 (ja) * | 1977-09-12 | 1984-09-06 | 住友化学工業株式会社 | 酸化チタン被膜形成方法 |
JPS5662830A (en) * | 1979-10-26 | 1981-05-29 | Dainichi Seika Kogyo Kk | Cross-linking agent |
JPS5841724A (ja) * | 1981-09-02 | 1983-03-11 | Nippon Soda Co Ltd | 金属酸化被膜形成組成物 |
US4470915A (en) | 1982-09-27 | 1984-09-11 | Halliburton Company | Method and compositions for fracturing subterranean formations |
DE3337098A1 (de) | 1983-10-12 | 1985-05-02 | Dynamit Nobel Ag, 5210 Troisdorf | Neue titanchelate und zubereitungen, die diese chelate enthalten |
US4861500A (en) | 1986-02-19 | 1989-08-29 | Dowell Schlumberger Incorporated | Delayed crosslinker composition containing organic titanium complexes and hydroxycarboxylic acids |
US4749040A (en) * | 1986-02-19 | 1988-06-07 | Dowell Schlumberger Incorporated | Method of fracturing a subterranean formation using delayed crosslinker compositions containing organic titanium complexes |
JPH02147667A (ja) * | 1988-11-30 | 1990-06-06 | Nippon Soda Co Ltd | 表面処理剤およびそれにより表面処理された充填剤粉末 |
JP2993928B2 (ja) | 1998-04-07 | 1999-12-27 | 日本写真印刷株式会社 | 光触媒膜形成用インキとその製造方法、成膜方法 |
JP2000086769A (ja) * | 1998-09-14 | 2000-03-28 | Matsumoto Seiyaku Kogyo Kk | 可溶性固体ポリチタノキサンおよびその誘導体の製造方法 |
JP2000259509A (ja) | 1999-03-12 | 2000-09-22 | Onkyo Corp | データ通信システムおよび方法 |
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2003
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2004
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Patent Citations (1)
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US4313851A (en) * | 1980-03-04 | 1982-02-02 | Dynamit Nobel Ag | Liquid, cold-stable titanium catalyst preparation |
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CN1777615A (zh) | 2006-05-24 |
US6737485B1 (en) | 2004-05-18 |
WO2004094434A3 (en) | 2005-01-20 |
JP4829109B2 (ja) | 2011-12-07 |
JP2006524745A (ja) | 2006-11-02 |
DE602004007256D1 (de) | 2007-08-09 |
EP1615934B1 (en) | 2007-06-27 |
WO2004094434A2 (en) | 2004-11-04 |
DE602004007256T2 (de) | 2008-02-28 |
EP1615934A2 (en) | 2006-01-18 |
HK1090378A1 (en) | 2006-12-22 |
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