CH665648A5 - Thermoplastisch verarbeitbare massen aus polyamid, thermoplastischem polyurethan sowie aktiviertem polyolefin. - Google Patents
Thermoplastisch verarbeitbare massen aus polyamid, thermoplastischem polyurethan sowie aktiviertem polyolefin. Download PDFInfo
- Publication number
- CH665648A5 CH665648A5 CH6112/84A CH611284A CH665648A5 CH 665648 A5 CH665648 A5 CH 665648A5 CH 6112/84 A CH6112/84 A CH 6112/84A CH 611284 A CH611284 A CH 611284A CH 665648 A5 CH665648 A5 CH 665648A5
- Authority
- CH
- Switzerland
- Prior art keywords
- polyamide
- thermoplastic
- thermoplastic processable
- mass according
- activated
- Prior art date
Links
- 229920002647 polyamide Polymers 0.000 title claims description 37
- 239000004952 Polyamide Substances 0.000 title claims description 36
- 229920000098 polyolefin Polymers 0.000 title claims description 15
- 239000004433 Thermoplastic polyurethane Substances 0.000 title claims description 9
- 229920002803 thermoplastic polyurethane Polymers 0.000 title claims description 9
- 239000000203 mixture Substances 0.000 claims description 45
- 229920001169 thermoplastic Polymers 0.000 claims description 20
- 239000004416 thermosoftening plastic Substances 0.000 claims description 20
- 229920000299 Nylon 12 Polymers 0.000 claims description 11
- 229920002292 Nylon 6 Polymers 0.000 claims description 7
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 229920001971 elastomer Polymers 0.000 claims description 5
- 239000000806 elastomer Substances 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920000571 Nylon 11 Polymers 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 3
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims 1
- 150000008064 anhydrides Chemical class 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 238000002425 crystallisation Methods 0.000 claims 1
- 230000008025 crystallization Effects 0.000 claims 1
- 230000009477 glass transition Effects 0.000 claims 1
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims 1
- 229920006017 homo-polyamide Polymers 0.000 claims 1
- 229920006345 thermoplastic polyamide Polymers 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 description 17
- 229920002635 polyurethane Polymers 0.000 description 12
- 239000004814 polyurethane Substances 0.000 description 12
- 238000001746 injection moulding Methods 0.000 description 9
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000007792 addition Methods 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 239000004014 plasticizer Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000002349 favourable effect Effects 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 229920006347 Elastollan Polymers 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- RYECOJGRJDOGPP-UHFFFAOYSA-N Ethylurea Chemical compound CCNC(N)=O RYECOJGRJDOGPP-UHFFFAOYSA-N 0.000 description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- 239000004953 Aliphatic polyamide Substances 0.000 description 2
- 229920003698 Grilamid® L 20 G Polymers 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229920003231 aliphatic polyamide Polymers 0.000 description 2
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 238000002789 length control Methods 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- 239000004605 External Lubricant Substances 0.000 description 1
- 229920003620 Grilon® Polymers 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 239000004610 Internal Lubricant Substances 0.000 description 1
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- 238000009661 fatigue test Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000007719 peel strength test Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- -1 polytetramethylene Polymers 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polyurethanes Or Polyureas (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH6112/84A CH665648A5 (de) | 1984-12-21 | 1984-12-21 | Thermoplastisch verarbeitbare massen aus polyamid, thermoplastischem polyurethan sowie aktiviertem polyolefin. |
| GB08530606A GB2170502B (en) | 1984-12-21 | 1985-12-12 | Thermoplastic polymer blends |
| IT48942/85A IT1182093B (it) | 1984-12-21 | 1985-12-17 | Materiale termoplastico lavorabile a base di miscugli di poliammide, poliuretano termoplastico e poliolefina attivata |
| DE19853545033 DE3545033A1 (de) | 1984-12-21 | 1985-12-19 | Thermoplastisch verarbeitbare masse |
| FR858519007A FR2575167B1 (fr) | 1984-12-21 | 1985-12-20 | Melanges de polyamide, de polyurethane thermoplastique ainsi que de polyolefines activees |
| JP60287667A JPS61215655A (ja) | 1984-12-21 | 1985-12-21 | 熱可塑加工性組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH6112/84A CH665648A5 (de) | 1984-12-21 | 1984-12-21 | Thermoplastisch verarbeitbare massen aus polyamid, thermoplastischem polyurethan sowie aktiviertem polyolefin. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH665648A5 true CH665648A5 (de) | 1988-05-31 |
Family
ID=4304450
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH6112/84A CH665648A5 (de) | 1984-12-21 | 1984-12-21 | Thermoplastisch verarbeitbare massen aus polyamid, thermoplastischem polyurethan sowie aktiviertem polyolefin. |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS61215655A (xx) |
| CH (1) | CH665648A5 (xx) |
| DE (1) | DE3545033A1 (xx) |
| FR (1) | FR2575167B1 (xx) |
| GB (1) | GB2170502B (xx) |
| IT (1) | IT1182093B (xx) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR0147066B1 (ko) * | 1988-09-07 | 1998-08-17 | 아사구라 다쓰오 | 열가소성 수지 조성물 |
| DE69112661T2 (de) * | 1990-02-13 | 1996-04-18 | Atochem Elf Sa | Verfahren zur Modifizierung von thermoplastischen Polyurethanen mittels Extrusion sowie in diesem Verfahren verwendete Modifizierungsmittel. |
| EP0641828A1 (en) * | 1993-09-08 | 1995-03-08 | Bayer Corporation | A thermoplastic composition containing polyurethane and polypropylene |
| WO1995019403A2 (en) * | 1994-01-13 | 1995-07-20 | Bemis Associates | High-performance adhesive film |
| DE19502206A1 (de) * | 1995-01-25 | 1996-08-01 | Buna Sow Leuna Olefinverb Gmbh | Funktionalisierte Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung in thermoplastischen Formmassen |
| FR2752579B1 (fr) * | 1996-08-23 | 1998-10-30 | Atochem Elf Sa | Film et objet obtenus a partir d'un materiau comprenant un polyurethanne et un polymere a blocs polyamide et polyether, l'utilisation de ce dernier pour la fabrication desdits film et objet |
| US5973013A (en) * | 1997-08-26 | 1999-10-26 | E. I. Du Pont De Nemours And Company | Polyamide/polyurethane micro-blend and process |
| DE19820661C2 (de) * | 1998-05-08 | 2002-10-24 | Inventa Ag | Weichmacherfreies Polyamid und Formmasse und dessen Verwendung |
| JP5465459B2 (ja) * | 2008-05-15 | 2014-04-09 | 大日精化工業株式会社 | 熱可塑性ポリウレタン樹脂組成物 |
| CN109096593B (zh) * | 2018-09-01 | 2021-04-02 | 广东恒骏工贸发展有限公司 | 一种用作鞋底的eva橡塑复合发泡材料及制备方法 |
| CN117603492B (zh) * | 2023-10-24 | 2024-06-11 | 安徽开捷汽车部件有限公司 | 一种汽车减震缓冲用聚氨酯垫片及其制备方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2207955A1 (en) * | 1972-11-24 | 1974-06-21 | Aquitaine Total Organico | Polyurethane polyamide compsn. - for injection moulding ski boots or brake pipes |
| JPS5651107B2 (xx) * | 1973-07-06 | 1981-12-03 | ||
| JPS55165952A (en) * | 1979-06-14 | 1980-12-24 | Unitika Ltd | Polyamide composition |
| DE2931689A1 (de) * | 1979-08-04 | 1981-02-26 | Bayer Ag | Polyamid-formmassen mit verbesserter zaehigkeit |
| DE3101771A1 (de) * | 1981-01-21 | 1982-09-02 | Rudi H. Ing.(grad.) 8000 München Keuerleber | Verfahren zum herstellen von trocken- und kaelteschlagzaehen polyamiden aus chemisch reaktionsfaehigen gemischen |
| US4384083A (en) * | 1981-07-22 | 1983-05-17 | Applied Polymer Technology, Incorporated | Thermoplastic adhesive |
| WO1983000492A1 (en) * | 1981-08-13 | 1983-02-17 | Shiraki, Toshinori | Modified block copolymer composition |
| FR2532653B1 (fr) * | 1982-09-06 | 1986-06-13 | Rhone Poulenc Spec Chim | Compositions pour moulage a base de copolyamides semi-rigides derives de dimeres d'acides gras, d'elastomeres et eventuellement de polyamides conventionnels |
-
1984
- 1984-12-21 CH CH6112/84A patent/CH665648A5/de not_active IP Right Cessation
-
1985
- 1985-12-12 GB GB08530606A patent/GB2170502B/en not_active Expired
- 1985-12-17 IT IT48942/85A patent/IT1182093B/it active
- 1985-12-19 DE DE19853545033 patent/DE3545033A1/de active Granted
- 1985-12-20 FR FR858519007A patent/FR2575167B1/fr not_active Expired
- 1985-12-21 JP JP60287667A patent/JPS61215655A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FR2575167A1 (fr) | 1986-06-27 |
| GB8530606D0 (en) | 1986-01-22 |
| IT1182093B (it) | 1987-09-30 |
| IT8548942A0 (it) | 1985-12-17 |
| JPS61215655A (ja) | 1986-09-25 |
| DE3545033A1 (de) | 1986-07-03 |
| GB2170502B (en) | 1988-05-25 |
| DE3545033C2 (xx) | 1989-04-06 |
| FR2575167B1 (fr) | 1989-12-01 |
| GB2170502A (en) | 1986-08-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased |